Redistributive Effects Research Articles

Control of protein activity by photoinduced spin polarized charge reorganization

Considerable electric fields are present within living cells, and the role of bioelectricity has been well established at the organismal level. Yet much remains to be learnedabout electric-field effects on protein function. Here, we use phototriggered charge injection from a site-specifically attached ruthenium photosensitizer to directly demonstrate the effect of dynamic charge redistribution within a protein. We find that binding of an antibody to phosphoglycerate kinase (PGK) is increased twofold under illumination. Remarkably, illumination is found to suppress the enzymatic activity of PGK by a factor as large as three. These responses are sensitive to the photosensitizer position on the protein. Surprisingly, left (but not right) circularly polarized light elicits these responses, indicating that the electrons involved in the observed dynamics are spin polarized, due to spin filtration by protein chiral structures. Our results directly establish the contribution of electrical polarization as an allosteric signal within proteins. Future experiments with phototriggered charge injection will allow delineation of charge rearrangement pathways within proteins and will further depict their effects on protein function.

Pension Wealth and the Gender Wealth Gap

We examine the gender wealth gap with a focus on pension wealth and statutory pension rights. By taking into account employment characteristics of women and men, we are able to identify the extent to which the redistributive effect of pension rights reduces the gender wealth gap. The data for our analysis come from the German Socio-Economic Panel (SOEP), one of the few surveys that collects information on wealth and pension entitlements at the individual level. Pension wealth data are available in the SOEP for 2012 only. While the relative raw gender wealth gap is about 35% (or 31,000 euros) when analysing the standard measure of net worth, it shrinks to 28% when pension wealth is added. This reduction is due to redistributive elements such as caregiver credits provided through the statutory pension scheme. Results of a recentred influence functions (RIF) decomposition show that pension wealth reduces the gap substantially in the lower half of the distribution. At the 90th percentile, the gender wealth gap in net worth and in augmented wealth remains more stable at roughly 27–30%.

Constructing methyl methacrylate/MXene artificial solid-electrolyte interphase layer for lithium metal batteries with high electrochemical performance

Lithium metal is a promising anode material due to its high theoretical capacity and low redox potential. However, lithium metal anode suffers from lithium dendrite, which reduces the cycle stability and reversibility of lithium metal batteries (LMBs). In order to solve this issue, we designed an in-situ polymerization method of organic–inorganic composite materials (methyl methacrylate (MMA)/MXene) to prepare artificial solid-electrolyte interphase (SEI). The as-prepared LMBs exhibit good interfacial contact and high electrochemical performance owing to the charge redistribution effect of MXene layer for decreasing the nucleation energy barrier and on the lithium metal anode. The specific capacity can sustain 106.6 mAh/g even after 1000 h cycles at 1C, and the capacity retention is 80.1 % with LiFePO4 (LFP) as a cathode material. Therefore, we believe this simple and inexpensive method can effectively restrain the growth of lithium dendrites and improve the cyclic stability and reversibility of the LMBs.

Selective law enforcement at the intersection of ethnicity and entrepreneurship

ABSTRACT This paper discusses the inconsistent law enforcement which only targets Chinese manufacturing firms active in the Italian fashion industry. Theory building is deeply embedded in rich empirical data and in a dialogue with concepts and theories developed in a wide range of fields and subfields such as urban studies, development studies, studies on local governance, and migration studies. While focusing on dynamics unfolding at the local scale, the paper positions selective law enforcement measures into a wider, multi-layered context which encompasses shifts in the global division of labour, processes of capital investment and disinvestment putting pressure on territories, local policies of migrant inclusion/exclusion, and the trajectory of local production systems. I analyse non-enforcement of the law as an ethnicised battle over economic accumulation, with significant redistributive consequences. At the same time, I point at the role of ethnically selective forced compliance as a tool used by the stakeholders in the territory to counter the potential loss of political authority engendered by the impact of crucial global shifts on the locality. In short, the paper proposes a political economy perspective: it teases out the underlying logic of selective law enforcement disentangling its economic, social, axiological, ethnical, and ultimately political dimensions.

Income taxation and equity: new dominance criteria with a microsimulation application

This paper addresses the problem of the normative evaluation of income tax systems and income tax reforms. While most of the existing criteria, framed in the utilitarian tradition, are uniquely based on information about individual incomes, this paper, building upon the opportunity egalitarian theory, proposes new equity criteria which take into account also the socio-economic characteristics of individuals. Suitable dominance conditions that can be used to rank alternative tax systems are derived by means of an axiomatic approach. Moreover, the theoretical results are used to assess the redistributive effects of an hypothetical tax reform in Romania through a microsimulation analysis.

Assessing the regional redistributive effect of renewable power production through a spot market algorithm simulator: The case of Italy

In order to study the sensitivity of market equilibria to changes in production from renewable units at different locations, we developed an algorithm that simulates the hourly equilibrium (price–quantity) of the Italian day-ahead market. Our analysis shows that, when power markets are organised on zonal basis with locational price signals and final buyers pay a unique wholesale price, a larger renewable production decreases the average zonal prices, but the distribution of benefits largely depends on power plants’ localisation. We study the impact of such expansion on network congestion occurrence, supply–demand zonal balance and zonal generation mix; we calculate the zonal substitution effects between renewable and non-renewable technologies, and within renewable technologies. We finally discuss the possible implications on national and local market power. Our paper analyses the multifaceted consequences of energy transition policies based on boosting renewable production and it highlights the importance of location in such expansion; in zonal markets, this aspect in crucial to get price decrease.

Research of redistribution of impurities in silicon wafers under influence of white light pulses

Research of redistribution of impurities in silicon wafers under influence of white light pulses. / A. B. Gerasimov, G. D. Chiradze. / Nano Studies. – 2020. – # 20. – pp. 95-98. – rus. The aim of this work is to study the redistribution of impurities in silicon wafers caused by exposure to white light pulses. There are investigated silicon wafers of n-type conductivity doped with phosphorus with resistivity of 0.5 Ohm·cm and thickness of 500 μm (KEF–0.5). The samples surface was treated according to the 14th class of cleanliness. In order to remove natural oxide, before exposure to light and before each measurement the samples were processed in aqueous solution of HF in ratio of 1:50 for 50 s. Microhardness was measured by the indentation method. It was found that in the region, where the microhardness decreases in comparison with the initial sample, the impurity concentration increases, while in the region of increasing microhardness the concentration decreases. With an increase in the duration of light pulses and their number, the effect of redistribution of impurity atoms increases. Moreover, the effect of redistribution is greater near the surface, from which the illumination took place. Fig. 2, Ref. 7.

Zonations and oscillations via heterotrophic processes in tidal unvegetated aquifers

AbstractGlobal‐change drivers that alter tidal amplitude or sea level could directly impact coastal aquifers' seawater–microbe interactions. The semidiurnal or diurnal tide can have consequences for chemical redistribution, because it deepens oxygen and nutrients penetration depth, thereby increasing O2 depletion via microbial respiration in sediments during groundwater circulation. However, chemical and microbial distributions in tidal aquifers remain unclear, in deference to their link with depth and lateral location. By combining the microbes‐accumulated equation with the traditional groundwater flow model in coastal aquifers, we explicitly unravelled the heterotrophic zonation, the salinity zonation, and the oxic zonation of tidal aquifers. According to the model estimates, salt penetrates deeper than reactive chemicals, and the heterotrophic high biomass zone is presumably 2–3 m deep. Such depth of heterotrophic distribution is 2–3 orders of magnitude higher than phototrophic distribution. Additionally, heterotrophic biomass can exhibit faint oscillations, even under the tide forces, whereas dissolved chemicals fluctuate significantly with tidal pumps. Due to the transport of nutrients by tidal penetration, intertidal sediments have a higher respiration rate than subtidal sediments, converting more organic carbon from seawater to atmospheric CO2 via microbes. We demonstrate that heterotrophic biomass may play the dominant role in the chemical reactions of nearshore sediments. Our results confirm the efficacy of unvegetated tidal sediments that rely on ubiquitous heterotrophs as a driver of oxygen consumption and DOC transformation. These steps above will allow for better field investigations of coastal aquifers within a framework of zonations and oscillations.

Numerical solutions to linear transfer problems of polarized radiation

Context. The polarization signals produced by the scattering of anistropic radiation in strong resonance lines encode important information about the elusive magnetic fields in the outer layers of the solar atmosphere. An accurate modeling of these signals is a very challenging problem from the computational point of view, in particular when partial frequency redistribution (PRD) effects in scattering processes are accounted for with a general angle-dependent treatment. Aims. We aim at solving the radiative transfer problem for polarized radiation in nonlocal thermodynamic equilibrium conditions, taking angle-dependent PRD effects into account. The problem is formulated for a two-level atomic model in the presence of arbitrary magnetic and bulk velocity fields. The polarization produced by scattering processes and the Zeeman effect is considered. Methods. The proposed solution strategy is based on an algebraic formulation of the problem and relies on a convenient physical assumption, which allows its linearization. We applied a nested matrix-free GMRES iterative method. Effective preconditioning is obtained in a multifidelity framework by considering the light-weight description of scattering processes in the limit of complete frequency redistribution (CRD). Results. Numerical experiments for a one-dimensional (1D) atmospheric model show near optimal strong and weak scaling of the proposed CRD-preconditioned GMRES method, which converges in few iterations, independently of the discretization parameters. A suitable parallelization strategy and high-performance computing tools lead to competitive run times, providing accurate solutions in a few minutes. Conclusions. The proposed solution strategy allows the fast systematic modeling of the scattering polarization signals of strong resonance lines, taking angle-dependent PRD effects into account together with the impact of arbitrary magnetic and bulk velocity fields. Almost optimal strong and weak scaling results suggest that this strategy is applicable to realistic 3D models. Moreover, the proposed strategy is general, and applications to more complex atomic models are possible.

Does foreign aid reduce the country's risk of OFDI? The Chinese experience

AbstractUsing a sample of 124 countries assisted by China from 2000 to 2019, this paper examines the impact of foreign aid on outward foreign direct investment (OFDI) and the mitigation mechanism of risk. The research finds that, first, foreign aid can significantly reduce the country risk of recipient countries, especially political risk and financial risk, and thus play a role in promoting the inflow of OFDI of donor countries, and there is a lagged effect of this role; Second, foreign aid from other countries has a negative impact on China's OFDI to recipient countries, indicating that foreign aid is nonaltruistic and exclusive; Third, the mitigation effect of foreign aid on country risk is achieved through five channels: compensation effect, synergistic effect, pioneer effect, assimilation effect, and redistribution effects.

Numerical Simulation of the Bearing Capacity of Variotropic Short Concrete Beams Reinforced with Polymer Composite Reinforcing Bars.

One of the disadvantages of reinforced concrete is the large weight of structures due to the steel reinforcement. A way to overcome this issue and develop new types of reinforcing elements is by using polymer composite reinforcement, which can successfully compensate for the shortcomings of steel reinforcement. Additionally, a promising direction is the creation of variotropic (transversely isotropic) building elements. The purpose of this work was to numerically analyze improved short bending concrete elements with a variotropic structure reinforced with polymer composite rods and to determine the prospects for the further extension of the results obtained for long-span structures. Numerical models of beams of a transversally isotropic structure with various types of reinforcement have been developed in a spatially and physically nonlinear formulation in ANSYS software considering cracking and crashing. It is shown that, in combination with a stronger layer of the compressed zone of the beam, carbon composite reinforcement has advantages and provides a greater bearing capacity than glass or basalt composite. It has been proven that the use of the integral characteristics of concrete and the deflections of the elements are greater than those when using the differential characteristics of concrete along the height of the section (up to 5%). The zones of the initiation and propagation of cracks for different polymer composite reinforcements are determined. An assessment of the bearing capacity of the beam is given. A significant (up to 146%) increase in the forces in the reinforcing bars and a decrease in tensile stresses (up to 210–230%) were established during the physically non-linear operation of the concrete material. The effect of a clear redistribution of stresses is in favor of elements with a variotropic cross section in height.

Force Transfer Mechanism and Component-Based Model of Cast-Steel-Stiffened Circular-Tube-Column Frames for Progressive Collapse Analysis

In this paper, the system response, stress redistribution, failure mode, and catenary effect of steel frames with circular tube columns and cast steel stiffener (CSS) joints under a sudden column removal scenario were revealed. Based on this force transfer mechanism analysis, a practical and computationally efficient component-based model considering catenary effects and CSS joint details with a series of springs was established and validated by a detailed solid-element method. By using this component-based model, the proper dynamic response increase factor of the CSS joint frames was investigated. The results show that the great overall stiffness and strength of the CSS limit the deformation of the column front shell. Therefore, the CSS joint frames have superior performance for progressive collapse prevention than the frames using welded joints without stiffeners. In addition, the component-based model is validated to be effective and the dynamic response increase factor of the frames with circular tube columns and CSS joints is smaller than 2.0.

Seepage Law of Nearly Flat Coal Seam Based on Three-Dimensional Structure of Borehole and the Deep Soft Rock Roadway Intersection

Exploring the evolution characteristics of gas seepage between boreholes during the drainage process is critical for the borehole’s layout and high-efficiency gas drainage. Based on the dual-porous medium assumption and considering the effect of stress redistribution on coal seam gas seepage characteristics, a coal seam gas seepage model with a three-dimensional roadway and borehole crossing structure has been established and numerically calculated, concluding that the coal seam is between the drainage boreholes. The temporal and spatial evolution characteristics of gas pressure and permeability help elucidate the gas seepage law of the nearly flat coal seam associated with the deep soft rock roadway and borehole intersection model. The results indicate that: (1) The roadway excavation results in localized stress in some areas of the surrounding rock, reducing the strength of the coal body, increasing the expansion stress, and increasing the adsorption of gas by the coal body. (2) Along the direction of the coal seam, the permeability decreases initially and then increases. The gas pressure in the coal seam area in the middle of the borehole is higher than the pressure in the coal seam around the borehole, and the expansion stress and deformation increase, reducing the permeability of the coal body; when near the next borehole, the greater the negative pressure, the faster the desorption of the gas attracts the matrix shrinkage effect and causes the coal seam permeability rate to keep increasing. (3) The improvement of gas drainage with the overlapping arrangement of two boreholes firstly increases and then decreases as time goes on. (4) When the field test results and numerical simulation of the effective area of gas extraction are compared, the effectiveness of the model is verified. Taking the change of the porosity and the permeability into the model, it is able to calculate the radius of gas drainage more accurately.

The inverted leading indicator property and redistribution effect of the interest rate

The interest rate at which US firms borrow funds has two features: (i) it moves in a countercyclical fashion and (ii) it is an inverted leading indicator of real economic activity: low interest rates today forecast future booms in GDP, consumption, investment, and employment. We show that a Kiyotaki–Moore model accounts for both properties when interest-rate movements are driven, in a significant way, by self-fulfilling belief shocks that redistribute income away from lenders and to borrowers during booms. The credit-based nature of such self-fulfilling equilibria is shown to be essential: the dynamic correlation between current loanable funds rate and future aggregate economic activity depends critically on the property that the interest rate is state-contingent. Bayesian estimation of our benchmark DSGE model on US data shows that the model driven by redistribution shocks results in a better fit to the data than both standard RBC models and Kiyotaki–Moore type models with unique equilibrium.

Accelerated carbonate dissolution caused by anthropogenic acidification - contrast of watershed soils to lake sediments in Taihu Region, China.

Although Taihu watershed is an "acid-insensitive" region, anthropogenic acidification has greatly changed the water chemistry in Taihu Lake. However, how soil carbonates responded to the long-term human-induced acidification received less attention. In this work, we investigated soil carbonate concentrations from different land uses in the upstream of the lake and sediment carbonate profiles in the lake, to explore the linkage of carbonates dissolution in the land and sedimentation in the lake. The result showed that the wheat-rice surface soil, the most acidification-impacted by fertilization and acid deposition, had significantly lower pH than vegetable and wetland soils (p < 0.05). Meanwhile, the carbonate concentration in wetland soils, only impacted by acid deposition, was significantly higher than that in wheat-rice and vegetable soils (p < 0.05). The pH profile of fertilized soils, with an increasing trend from the surface to bottom, further indicated the acidifying effect of fertilization. Although the average soil pH across all land uses was 6.6 in the upstream of the lake, remaining carbonate buffering system, the significant carbonate decrease especially in surface soils evidenced the definite carbonate dissolution by acidification, which is cumulative and irreversible. Contrary to the topsoils, the sediment carbonate concentration presented an increasing trend from the depth of 15cm (denoting around the early 1980s) to the surface, indicating that lake sediment is a major sink of carbonate Ca and Mg from the watershed, particular under an alkaline lake environment caused by frequent algae blooms in the past decades. In addition, Ca/Mg ratio in the sediment, having higher values in a higher pH environment, was quite different from the watershed soil pattern, suggesting different biogeochemical processes Ca and Mg underwent during their transportation and sedimentation. The effects of acidification-altered re-distribution of carbonate Ca and Mg and Ca/Mg ratio in the terrestrial and aquatic environments deserve wider considerations of ecosystem consequence.

Interference between avian corona and influenza viruses: The role of the epithelial architecture of the chicken trachea

Respiratory viral infections are among the major causes of disease in poultry. While viral dual infections are known to occur, viral interference in chicken airways is mechanistically hardly understood. The effects of infectious bronchitis virus (IBV) infection on tissue morphology, sialic acid (sia) expression and susceptibility of the chicken trachea for superinfection with IBV or avian influenza virus (AIV) were studied. In vivo, tracheal epithelium of chickens infected with IBV QX showed marked inflammatory cell infiltration and loss of cilia and goblet cells five days post inoculation. Plant lectin staining indicated that sialic acids redistributed from the apical membrane of the ciliated epithelium and the goblet cell cytoplasm to the basement membrane region of the epithelium. After administration of recombinant viral attachment proteins to slides of infected tissue, retained binding of AIV hemagglutinin, absence of binding of the receptor binding domain (RBD) of IBV M41 and partial reduction of IBV QX RBD were observed. Adult chicken trachea rings were used as ex vivo model to study the effects of IBV QX-induced pathological changes and receptor redistribution on secondary viral infection. AIV H9N2 infection after primary IBV infection was delayed; however, final viral loads reached similar levels as in previously uninfected trachea rings. In contrast, IBV M41 superinfection resulted in 1000-fold lower viral titers over the course of 48 h. In conclusion, epithelial changes in the chicken trachea after viral infection coincide with redistribution and likely specific downregulation of viral receptors, with the extend of subsequent viral interference dependent on viral species.

Current Crowding in Nanoscale Superconductors within the Ginzburg-Landau Model

The current density in a superconductor with turnarounds or constrictions is nonuniform due to a geometrical current-crowding effect. This effect reduces the critical current in the superconducting structure compared to a straight segment and is of importance when designing superconducting devices. We investigate the current-crowding effect in numerical simulations within the generalized time-dependent Ginzburg-Landau (GTDGL) model. The results are validated experimentally by measuring the magnetic field dependence of the critical current in superconducting-nanowire structures, similar to those employed in single-photon detector devices. Comparing the results with London theory, we conclude that the reduction in critical current is significantly smaller in the GTDGL model. This difference is attributed to the current redistribution effect, which reduces the current density at weak points of the superconductor and counteracts the current-crowding effect. We numerically investigate the effect of the fill factor on the critical current in a meander and conclude that the reduction of the critical current is low enough to justify fill factors higher than 33% for applications where the detection efficiency is critical. Finally, we propose a meander design that can combine a high fill factor and low current crowding.

Effects of Competition Policy on Macroeconomic Outcomes

This paper examines existing empirical research regarding the importance of competition and competition policy for variables relevant to macroeconomic outcomes. This research provides evidence on the correlations between competition, competition policy, and macroeconomic outcomes, such as productivity, growth, innovation, employment, and inequality. Competition policy is demonstrated to bring multiple benefits for macroeconomic outcomes in several economic studies. Gains from enhanced competition can essentially be divided into efficiency and redistribution effects. Efficiency gains result from the positive impact of competition on productivity growth, which allows firms and industries to produce more and better products and services at lower cost, whereas redistribution effects are associated with the impact of competition on inequality and employment in the market.

Labor market effects of technology shocks biased toward the traded sector

Our VAR evidence for OECD countries reveals that the non-traded sector alone drives the increase in hours worked following a technology shock that increases permanently traded relative to non-traded TFP. The shock generates a reallocation of labor toward the non-traded sector which contributes to 35% of the rise in non-traded hours worked. Both labor reallocation and variations in labor income shares are found empirically connected with factor-biased technological change. Our quantitative analysis shows that a two-sector open economy model with flexible prices can reproduce the labor market effects we document empirically once we allow for imperfect mobility of labor, a demand for home-produced traded goods which is elastic enough w.r.t. the terms of trade, and factor-biased technological change. When calibrating the model to country-specific data, its ability to account for the cross-country reallocation and redistributive effects we estimate increases once we let factor-biased technological change vary between sectors and countries.

Harmonic price targeting

This paper studies third-degree price discrimination in a classical model of price competition with differentiated products. Firms charge different prices to different consumers, based on their estimate of their price sensitivity. If the market is fully covered and information is symmetric, more accurate information has a pure redistributive effect, leading to higher profits but lower consumer welfare. If the market is not covered, information always benefit firms but the welfare effects are ambiguous. If information is asymmetric, firms benefit from more information, but less so than in the symmetric case, and total welfare depends on the extent of this asymmetry. I conclude that firms have strong incentives to share information about consumer tastes.