The Cave Peak deposit is a rift-related, breccia-hosted, fluorine-rich porphyry molybdenum deposit that is enriched in Nb, REE, and other critical minerals. Cave Peak is the easternmost member of a northwest-trending group of Paleogene intrusions in the Diablo Plateau along with the Marble Canyon stock, an unmineralized, petrogenetically related, compositionally zoned mafic alkaline pluton. The Cave Peak intrusions show within-plate geochemical affinity and is the product of a highly differentiated magma series. Curvilinear trends in Harker variation and trace element diagrams record magma differentiation from mafic to intermediate (44–69 wt% SiO2) to felsic (70–76 wt% SiO2) compositions at Marble Canyon and Cave Peak, respectively. Quartz syenite and monzonite from the Marble Canyon stock yielded zircon UPb ages of 36.2 ± 0.15 Ma and 36.1 ± 0.09 Ma, respectively. The youngest major intrusion at Cave Peak, an alkali feldspar granite porphyry, has a zircon UPb age of 34.8 ± 0.4 Ma, supporting that these intrusions represent a magma differentiation trend. The δ98Mo of Cave Peak molybdenites range between −0.39 ± 0.06 ‰ and + 0.52 ± 0.06 ‰ with a total Mo isotope range of 0.91 ‰. Cave Peak samples predominantly fractionated towards heavier δ98Mo. The Cave Peak data are distinctly heavier than data obtained from the nearby subduction-related Red Hills porphyry Cu deposit which has δ98Mo values of −0.25‰ to −0.51‰.