Recovery Technology Research Articles

The importance of quantifying fitness-determining traits throughout life to assess the application of reproductive technologies for amphibian species recovery

The application of reproductive technologies to amphibian conservation breeding programs is gaining momentum and the field is poised to contribute significantly toward amphibian species recovery. We briefly discuss the opportunities for reproductive technologies to enhance conservation breeding outcomes, including their potential to enhance the genetic management, and in turn, the fitness of threatened species. Despite this potential, an important consideration that is not yet well understood is the degree to which specific reproductive technologies might influence (either enhance, or in some instances potentially decrease) individual fitness and lead to shifts in population viability. The development of a standardised approach to monitoring offspring throughout life-stages to detect changes to morphology, behaviour, physiology, survivorship, and developmental trajectories is essential. The primary focus of this review is to provide a ‘best-practise’ framework for quantifying key fitness determining traits expected to contribute to the fitness of individuals and long-term viability of populations, which will ultimately allow us to progress the field of amphibian reproductive technologies and assess the impact of protocol refinement.

Green iron recovery through hydrogen-based mineral phase transformation using ultrafast air-cooling for heat recycling: A pilot-scale investigation

The utilization of ultrafast air-cooling has been proposed to reduce energy consumption in hydrogen-based mineral phase transformation (HMPT) technology for more sustainable iron recovery. Optimal conditions, including a grinding fineness of −74 μm accounting for 90 wt%, a reducing gas concentration of 20 vol%, a roasting temperature of 540 °C, and an air-cooling temperature of 300 °C, yielded an iron concentrate with a TFe grade of 59.29 wt% and a recovery of 89.40 wt%. The beneficiation indexes obtained by ultrafast air-cooling were comparable to those of the N2-cooling method. The reaction mechanisms were comprehensively studied to optimize the process, which revealed controlled oxidation of artificial magnetite to maghemite and hematite under ultrafast air-cooling conditions. The heat released during oxidation was recycled, leading to reduced energy consumption. Furthermore, ultrafast air-cooling increased particle porosity and cracks, thereby reducing subsequent grinding energy requirements. This research advances carbon reduction efforts in the steel industry, facilitating the transition to carbon neutrality.

Coordinated control strategy of electro-mechanical composite braking for four-wheel drive electric vehicles

Regenerative braking energy recovery technology is critical for electric vehicles, which can significantly improve vehicle mileage. In addition, the regenerative braking system is often used with the friction braking system to provide vehicle braking force. This paper presents an electro-mechanical compound brake control strategy for four-wheel drive electric vehicles equipped with an electro-mechanical braking system. Firstly, the configuration of a four-wheel drive electric vehicle with an electro-mechanical braking system is introduced. The mathematical models of the driving motor, battery, and electro-mechanical braking are established. Secondly, a new control method is introduced by optimizing torque allocation based on maximum energy recovery with considering battery limits and a cooperative control method of the electro-mechanical composite braking system. It can be ensured that the braking energy recovery capability and braking comfort. Finally, simulation results indicate that the introduced control strategy can increase the braking recovered energy by 3% and 4%, respectively, under NEDC and WLTC conditions, compared to the ideal braking force distribution strategy. The introduced control method can effectively decrease the braking impact and ensure braking comfort in the coordination control section.

Life cycle and techno-economic assessment of bioresource production from wastewater

Thermochemical conversion technologies present an opportunity to flip the paradigm of wastewater biosolids management operations from energy-intense and expensive waste management processes into energy-positive and economical resource extraction centers. Herein, we present a uniform “grading framework” to consistently evaluate the environmental and commercial benefits of established and emerging wastewater biosolids management processes from a life cycle and techno-economic perspective. Application of this approach reveals that established wastewater biosolids management practices such as landfilling, land application, incineration, and anaerobic digestion, while commercially viable, offer little environmental benefit. On the other hand, emerging thermochemical bioresource recovery technologies such as hydrothermal liquefaction, gasification, pyrolysis, and torrefaction show potential to provide substantial economic and environmental benefit through the recovery of carbon and nutrients from wastewater biosolids in the form of biofuels, fertilizers, and other high-value products. Some emerging thermochemical technologies have developed beyond pilot scale although their commercial viability remains to be seen.

Design and performance analysis on a breathing-type instant heat recovery module for fresh air ventilation

The process of air exchange in buildings is essential for maintaining optimal indoor air quality. However, this process results in the loss of thermal energy in the form of sensible heat carried by the air, thereby increasing the energy demand of the buildings. In order to recover this thermal energy, the present study introduces a breathing-type instant heat recovery module for fresh air ventilation, inspired by the biological nasal breathing process. The performance of this module was thoroughly investigated through Fluent simulation and experimental tests. Based on the simulation results, the module exhibits the capability to decrease the outdoor air temperature by an average of 7.5 ℃ prior to its entry into the room. Consequently, this leads to a daily energy conservation of approximately 2.354 kW·h, accompanied by an energy recovery rate of 62.9 % under typical summer conditions. Notably, the heat recovery performance is more favorable during winter, resulting in daily energy savings of about 5.446 kW·h and an energy recovery rate of 62.2 %. The conducted experiments substantiate that the module is able to recuperate approximately 70 % of heat when the indoor temperature is set at 22 °C, while the outdoor temperature reaches its lowest point at 6 °C. The study describes an effective heat recovery technology for building air exchange using a breath-type instant heat recovery module. This could offer a new energy-saving solution for the renovation of fresh air systems.

Research on Boiler Energy Saving Technology Based on Internet of Things Data

This paper proposes a heat demand prediction model that analyzes the heat behavior of heat users, and analyzes the heat behavior data of heat users through a clustering algorithm to predict their heat demand. This paper is based on the supply-demand balance strategy to reduce the heat loss during the transmission of heat medium, and then improve the energy-saving efficiency of the boiler. The traditional boiler energy-saving and consumption reduction method is to optimize the boiler combustion parameters, improve the fuel combustion efficiency and waste heat recovery technology through the Internet of Things and big data technology. The method of balancing the heat-using end with the load of the boiler at low usage frequency is seldom considered. Therefore, this paper predicts the heat demand of the heat-using end by analyzing its thermal behavior, and balances the heat demand and boiler heat supply under the condition of meeting the heat demand. Finally, through simulation experiments, the validity of the model is verified, and the trend and data can be well predicted in the short-term heat demand prediction.

Burgeoning innovation and scalability activities for phosphorus recovery from wastewater treatment facilities

Phosphorus has been described as life's bottleneck due to its finite source and indispensable role in sustaining living cell functionalities. The paradigm shift from recycling to linear phosphorus consumption that transpired after the Green Revolution brought about one of the most concerning recent environmental challenges-eutrophication. Many recovery technologies have been developed to reinstate phosphorous recycling in sophisticated and safe ways. This study critically reviewed the current state of global phosphorous natural reserves and pollution. It also discussed forecasted consumption trends and how the recovery could assist in meeting the increasing phosphorous demands. The current phosphorous recovery processes were reviewed. A multi-criteria comparison of the technologies within their technology redness levels (TRLs) groups was carried out using the PROMETHEE ranking approach. The comparison criteria focused on efficiency, product quality, and energy and chemicals consumption. The processes with the highest preference scores in their respective TRL groups employed chemical leaching and struvite precipitation. This study also presents patent analyses of P recovery technologies over the past 8 years. These analyses showed that China is at the forefront of patent production, while Europe leads in commercialization. Biochar modification and electrode materials development dominate recent innovations in P recovery.

INTERFACIAL TENSION AND CONTACT ANGLE TESTS OF RHAMNOLIPIDS AND SOPHOROLIPIDS IN SANDSTONE FOR ENHANCED OIL RECOVERY

In the context of the development of enhanced oil recovery technology, biotechnology can be used to develop new methods that are more environmentally friendly and sustainable, one of which is the use of biosurfactants. Rhamnolipids and sophorolipids are non-toxic biosurfactants, biodegradable, and environmentally favorable substances. This study compares the results of laboratory studies on fluid-to-fluid interactions, including the interfacial tension and rock wetness tests at various concentrations and salinities, which represent high salinity, medium salinity, and low salinity. The mechanism of these two biosurfactants is based on reducing the interfacial tension (IFT) between the fluids and changing the wettability of the rock to a more water-wet state. In the interfacial tension test, the reduction in the interfacial tension of rhamnolipids reached 10-2 mN/m, while that of sophorolipids only reached 10-1 mN/m. Then, the sandstone wettability test showed that the two biosurfactants were classified as water-wet (<75°). This happens because of its chemical structure, which has two parts: the hydrophobic part and the hydrophilic part. Within the salinity range of 8,000-32,000 ppm, the rhamnolipids work better in the higher salinity to reduce interfacial tension, and the salinity has a subtle effect on the contact angle. On the other hand, sophorolipids were not affected by salinity for both interfacial tension and contact angle. These two biosurfactants have the potential to increase oil recovery in sandstone so that they can contribute to environmentally friendly biotechnology.

Life cycle assessment of ammonium sulfate recovery from urban wastewater

ABSTRACT Anthropogenic nitrogen fluxes are profoundly altering the global biogeochemical nitrogen cycle. Better management of these nitrogen fluxes is essential. Recovering nitrogen from urban wastewater reduces both the energy and resources required to produce nitrogen-based fertilizer and to remove nitrogen from wastewater collected. Nitrogen can be recovered from wastewater in the form of ammonium sulfate, a common nitrogen-based fertilizer. In the urban setting, the technology can be applied to target source-separated urine or municipal wastewater. To assess the environmental sustainability of this approach, this study compared the life cycle environmental impacts of ammonium sulfate recovered from urban wastewater (through eight different recovery technology trains) and ammonium sulfate produced by six different industrial processes. The results show that wastewater-derived ammonium sulfate generally has lower potential environmental impacts than industrially produced ammonium sulfate in most of the impact categories assessed. The impact for the source-separated urine centralized recovery train is the smallest. The contribution analysis shows that energy, sulfuric acid and sodium hydroxide use are the major contributors, while the background inventory analysis shows that the results can be sensitive to the choice of region-specific background inventory. In the future, nitrogen recovery from urban wastewater is promising for the circular economy in cities.

Numerical analysis of water, energy, and environment nexus in the hybrid thermal and solar multigeneration power plants

AbstractThe challenge of providing water, energy, and managing the environment is widely recognized as a significant barrier to global advancement in light of the increasing population. Based on projections, it is anticipated that the global community will encounter crises pertaining to water, energy and the environment in the foreseeable future. In this research, the application of the hybrid renewable system in a thermal power plant has been assessed based on the approach of analyzing the link between energy, water, and environment. The design of the solar system and the assessment of carbon balance during the power plant lifetime have been conducted in PVsyst application in 2022. Moreover, ReCipe environmental model has been used for assessing the effect of decrease in carbon emission on the ecosystem. The findings of the research indicate that the replacement of at least 2% of the nominal capacity of the fossil fuel power plant with the renewable one, prevents the emission of 1340.37 tons of carbon dioxide yearly. This amount equals to 371.25 m3 of reserve in fossil fuel consumption and 382.64 tons of crude oil. The results also showed that in addition to preserving natural resources, the hybrid cycle design leads to significant water demand reduction which equals to 3751 m3 with the capacity to supply underground water sources. Due to the interests of preserving water and energy resources and decreasing carbon emission in power plant industry, within the framework of nexus approach, management of energy supply by replacing resources and using water and heat recovery technologies and application of energy demand management policies based on energy efficiency and environmental implications is recommended.

An integrated constructed wetland-Microbial fuel cell system with sewage sludge-biochar to enhance treatment and energy recovery efficiencies

Constructed wetlands and microbial fuel cells (CW-MFCs) are a promising green and sustainable wastewater treatment technology. However, the power production performance of CW-MFCs has long been limited by low-performance cathodes. In this study, we designed two CW-MFC systems using cheap and readily available sewage sludge biochar (SSB) as the substrate for the experimental units. The integration of SSB significantly facilitated the removal of chemical oxygen demand, ammonium nitrogen, total nitrogen, and total phosphorus. Moreover, SSB enhanced the electrochemical performance of the air cathode, resulting in higher power density (44.64 mW/m2) and lower internal resistance (900.00 Ω) compared to gravel-integrated CW-MFC (0.88 mW/m2, 2057.14 Ω). In addition, a typical electroactive bacterium---Geobacter was enriched in the SSB-integrated CW-MFC system. The iron oxides and graphic nitrogen of the SSB favor the growth of Geobacter, and the redox-active groups on the surface of SSB accelerate the extracellular electron transfer process, contributing to the enhancement of treatment performance. Meanwhile, the metal and nitrogen doping improves the oxygen reduction reaction activity and conductivity of SSB, enhancing the cathode area of CW-MFC and improving the energy recovery. Overall, these results demonstrated that SSB-integrated CW-MFC can be a competitive technology for effective wastewater treatment and energy recovery.

Global enhanced oil recovery assessment: A comprehensive data-driven analysis using self-organizing maps

This study presents a comprehensive analysis of Enhanced Oil Recovery (EOR) methods' application in the global oil industry, identifying trends and main factors influencing their adoption. A wealth of unstructured and scattered data from public documents covering traditional EOR methods and newer technologies was processed to create a reliable global database, encompassing 1237 EOR projects in reservoirs around the world. Data science techniques and self-organizing maps (SOM) were employed for data analysis, dimensionality reduction, and visualization of complex problems, proving suitable for high-dimensionality and incomplete data. The research integrates various data modalities and data science visualization techniques, enabling a high-level representation of EOR projects' self-contained knowledge, and providing a comprehensive view of EOR application worldwide. The study reveals implicit interrelationships between multiple variables and EOR methods, identifying trends, research and development directions, and better-informed decisions. In-depth analysis showed that factors impacting the choice, application, and success of EOR methods include technical properties of reservoirs, local, commercial, and temporal aspects. Despite the diffusion of secondary and tertiary recovery technologies, a concentration of EOR methods exists in specific regions. Factors influencing EOR projects' implementation, maintenance, and expansion range from technical reasons, deselected reserves, and infrastructure to incentive policies and regulatory aspects of each country, business structure, and global economic scenario. Both petrophysical and non-petrophysical variables influence the application of EOR methods. Availability and costs of purchasing and transporting injection fluids greatly impact decision-making processes. The analysis contributes to understanding the complex network of factors influencing EOR, and this work can aid in making more informed decisions in the industry and research for EOR applications.

Optimized flare gas recovery technology with consideration of life cycle assessment, reliability analyses, and uncertainity of parameters

One of the most important sources of carbon dioxide emissions is gas flaring from oil wells. In addition to having an adverse effect on the environment, burning gases with a high energy value causes significant economic losses. The present work evaluated the best allocation for flare gas recovery technologies between eleven technologies considering life cycle assessment, reliability, and uncertainty analysis of some economic parameters in Iran's oil field. By choosing three objective functions, i.e., the carbon dioxide emission reduction, return payback period, and global warming by life cycle assessment analysis, the best combination of system was selected from eleven technologies using the genetic (NSGAII) algorithm and decision-making technique (TOPSIS) simultaneously. It was shown that the technology's reliability affects the best solution. Correspondingly, the integration of an enhanced oil recovery plant and a natural gas liquid at the capital investment of 120 M$ and a benefit of 263 M$ annually, with a repayment period of nine months, CO2 reduction of 1314,579 tons per year, and global warming effect of 699,820 tone CO2 equivalent was introduced as the best technology.

Technologies for Heat Hazard Governance and Thermal Energy Recovery in Deep Mines

As the depth of mines continues to increase, the problems of high temperature and potential heat damage become more prominent. In this study, the characteristics of natural and industrial heat sources in mines were reviewed, and then mainstream heat hazard governance technologies and corresponding utilization methods were discussed and compared. The first category of technologies comprises the optimization of ventilation systems, the insulation of roc heat, and artificial refrigeration. These cooling approaches are limited because the heat resources cannot be recovered. The second category is the utilization of waste industrial heat in mines, including the use of waste heat from the air compressors, drainage water, and foul airflow, but the current applications of these approaches have limited effectiveness in cooling the underground space. The third category is the application of geo-structures to recover natural heat in mines. Based on the principles of the chiller/heat pump cycle and the characteristics of heat sources and sinks in mines, the potential and constraints of each technology were discussed and summarized. This study provides a scientific reference for the selection of suitable heat governance and utilization technologies.

Enhanced the simultaneous removal and recovery of phosphorus in induced crystallization coupled biological phosphorus removal process

Remove and recovery of phosphorus from wastewater is expected to be a promising strategy to solve the shortage of phosphorus resources and control the water environment pollution. In this study, induced crystallization coupled biological phosphorus removal (IC-BPR) process was established to achieve simultaneous removal and recovery of phosphorus in wastewater. The effects of side stream ratio (SSR) on the removal and recovery efficiency of phosphorus and the microbial community structure were explored. The results indicated that the SSR of 40% was optimal to phosphorus removal and recovery in the IC-BPR. The total phosphorus removal efficiency was 94.23% under the SSR of 40%, of which the phosphorus removal efficiency by IC accounted for 74.87%. And the total phosphorus recovery efficiency was 67.29%. The particle size and crystal structure analysis of the crystallized products indicated that the increase of SSR was conductive to heterogeneous crystallization. Furthermore, typical polyphosphate accumulation organisms (PAOs), including Rhodocyclaceae, Acinetobacter, and Dechloromonasin, were enriched under the side stream ratio of 40%. And functional genes related to amino acid transport and metabolism, energy production and conversion were activated. The above results indicated that the IC could significantly enhance the removal and recovery of phosphorus under a suitable SSR condition. It will provide important reference for wastewater treatment coupled phosphorus resource recovery technology.

A sustainable bioprocess to produce bacterial cellulose (BC) using waste streams from wine distilleries and the biodiesel industry: evaluation of BC for adsorption of phenolic compounds, dyes and metals

BackgroundThe main challenge for large-scale production of bacterial cellulose (BC) includes high production costs interlinked with raw materials, and low production rates. The valorization of renewable nutrient sources could improve the economic effectiveness of BC fermentation while their direct bioconversion into sustainable biopolymers addresses environmental pollution and/or resource depletion challenges. Herein a green bioprocess was developed to produce BC in high amounts with the rather unexplored bacterial strain Komagataeibacter rhaeticus, using waste streams such as wine distillery effluents (WDE) and biodiesel-derived glycerol. Also, BC was evaluated as a bio-adsorbent for phenolics, dyes and metals removal to enlarge its market diversification.ResultsBC production was significantly affected by the WDE mixing ratio (0–100%), glycerol concentration (20–45 g/L), type of glycerol and media-sterilization method. A maximum BC concentration of 9.0 g/L, with a productivity of 0.90 g/L/day and a water holding capacity of 60.1 g water/g dry BC, was achieved at 100% WDE and ≈30 g/L crude glycerol. BC samples showed typical cellulose vibration bands and average fiber diameters between 37.2 and 89.6 nm. The BC capacity to dephenolize WDE and adsorb phenolics during fermentation reached respectively, up to 50.7% and 26.96 mg gallic acid equivalents/g dry BC (in-situ process). The produced BC was also investigated for dye and metal removal. The highest removal of dye acid yellow 17 (54.3%) was recorded when 5% of BC was applied as the bio-adsorbent. Experiments performed in a multi-metal synthetic wastewater showed that BC could remove up to 96% of Zn and 97% of Cd.ConclusionsThis work demonstrated a low-carbon approach to produce low-cost, green and biodegradable BC-based bio-adsorbents, without any chemical modification. Their potential in wastewater-treatment-applications was highlighted, promoting closed-loop systems within the circular economy era. This study may serve as an orientation for future research towards competitive or targeted adsorption technologies for wastewater treatment or resources recovery.

Evaluation of the Potential for CO2 Storage and Saline Water Displacement in Huaiyin Sag, Subei Basin, East China

CO2 geological storage combined with deep saline water recovery technology (CO2-EWR) is one of the most effective ways to reduce carbon emissions. Due to the complex structural features, it is difficult to use CO2-EWR technology in Huaiyin Sag, Subei basin, East China. In this study, the multi-source information superposition evaluation technology of GIS was utilized for the selection of CO2 storage sites and water displacement potential target areas in this area, which mainly focused on the sandstone reservoirs of Cretaceous Pukou Formation. Based on the results, a three-dimensional injection–extraction model was established. Various scenarios with different production/injection well ratios (PIR) were simulated. Research has shown that the suitability of the surrounding site of Huaiyin Power Plant can be divided into two levels: relatively suitable and generally suitable; the area in the generally suitable level accounts for more than 80%. At a PIR of 1, CO2 is distributed asymmetrically, whereas at PIRs of 2 or 4, CO2 is distributed symmetrically. When the number of production wells is constant, a higher injection rate results in a faster expansion rate of the CO2 plume. This means that the time taken for the CO2 plume to reach the production wells is shorter. Reservoir pressure increases rapidly after more than 60 years of CO2 injection at lower PIR values, while at higher PIRs, reservoir pressure eventually stabilizes. Higher PIR values correspond to higher gas saturation, indicating a greater capacity for CO2 sequestration with more producing wells. When PIR = 4, the total CO2 injection increased by 55.73% compared to PIR = 1. However, the extraction of saline decreases with an increase in the number of producing wells, resulting in a decrease in replacement efficiency. This study provides a theoretical basis and technical support for the implementation of large-scale CO2-EWR engineering and technology demonstration in this region.

An efficient process for preparing regenerated magnets by dynamic recovery of Nd-Fe-B sintered magnet sludge

As a new technology for the short-process recovery of Nd–Fe–B sintered magnet sludge, the calcium thermal reduction diffusion method has attracted significant attention due to its low energy consumption, environmental friendliness, and high recovery rate. However, traditional calcium thermal reduction diffusion technology still has issues such as an insufficient reaction between the sludge and reducing agent after increasing the amount of reactants, the use of a large amount of reducing agent, and low recovery efficiency. Therefore, a novel dynamic calcium thermal reduction diffusion technology was proposed, with the calcium reduction diffusion of sludge and calcium undergoing a continuous mixing and diffusion state throughout the entire process, greatly improving the efficiency of the reaction. Compared with the traditional process, the amount of reactants was increased from a few grams to hundreds of grams, and the amount of reducing agent calcium was reduced by 25%. Subsequently, regenerated magnetic powder with a uniform particle size, good dispersion, and excellent magnetic properties was obtained. The saturation magnetization under a 3 T magnetic field was increased by 27.9% compared with the initial sludge. The maximum magnetic energy product of the magnet prepared by doping 50 wt% regenerated magnetic powder was 45 MGOe, which reached the highest level of the regenerated magnets prepared by recycling sludge. What is encouraging that this new technology had the advantage of achieving large-scale production and reducing production costs, providing a potential industrialization solution for the green and efficient recovery of Nd–Fe–B sintered magnet sludge.

Design and Development of Hydrogen Isotopes Extraction System at IPR

Tritium breeding, recovery and safe storage are very important for achieving self-sustainability in a nuclear fusion reactor. Indeed, it is one of the essential task in terms of safety and fuel cycle aspects. Usually, tritium breeding is performed in the blanket module. In Indian blanket module, there are mainly two types of tritium breeder materials, one is Lithium based ceramic pebbles Li2TiO3 (Lithium Titanate) as solid breeders and second is the lithium based alloy Pb-Li (Lead Lithium) as a liquid breeder. Tritium bred in solid breeders is extracted with purge helium gas, whereas tritium bred in liquid Pb-Li needs suitable gas-liquid contactor. It should be noted that, tritium recovery (i.e.,-extraction) from Pb-Li is very challenging due to low solubility of tritium in liquid Pb-Li and no such separation technology readily available commercially. Therefore, the necessity for developing a reliable and efficient tritium recovery technology (i.e.,- extractor) for liquid Pb-Li is of key interest.In present work, design and development of Hydrogen Isotopes Extraction System (HIES) for hydrogen recovery from liquid Pb-Li is discussed. As hydrogen and tritium are isotopes, hydrogen is used instead of tritium in present system due to several safety concerns with tritium. Recovery of hydrogen from liquid Pb-Li is carried out using structured packing as a Gas-Liquid Contactor (GLC). The design details of gas-liquid contactor (i.e.-extractor column) and various process tanks of HIES are discussed. In present design, configuration of vertically mounted extractor column makes overall HIES relatively tall (∼ 3 m height) and use of liquid Pb-Li as process fluid makes the system heavy weight (∼1500 kg) too. In addition to this, system needs to be operated above Pb-Li melting temperature (> 235 C) to keep Pb-Li in liquid form. Therefore, thermal analysis of piping as well as seismic analysis of whole system is carried out and discussed along with various operational stages of HIES.

Evaluation of CO2 storage and enhanced gas recovery potential in gas shale using kerogen nanopore systems with mesopores and micropores

With the continuous development of shale gas, CO2 storage in shale gas reservoirs has gained significant attention due to the massive available space in these reservoirs. These shale formations exhibit a complex pore structure with micropores (<2 nm) and mesopores (2–50 nm), which profoundly influence gas sorption behaviors. This work used grand canonical Monte Carlo to study the sorption behavior of CH4, CO2, and their binary mixtures (from 1:9 to 9:1) in kerogen nanopore systems with mesopores and micropores at 327 K and pressures ranging from 1 to 50 MPa. The kerogen nanopore system with mesopores and micropores faithfully describes sorption isotherms. The adsorption profile highlights the adsorption characteristics and relative contribution of mesopores and micropores. The molar ratio of CO2 to CH4 in the replacement process is greater than 1, indicating the possibility of achieving negative emissions by storing CO2 in shale gas reservoirs. The extraction ratio reveals that CH4 in micropores is more easily extracted. As for CO2 storage in shale gas formation, the sorption phase dominates at low pressure, while the free gas phase becomes more significant at higher pressure. At a reservoir pressure of 35 MPa, approximately 125 tons of CO2 can be stored in 1000 m3 of shale gas formation. Using CO2 huff-n-puff technology, the recovery factor more than doubles compared to pressure drawdown. While pressure drawdown primarily extracts CH4 from the free gas phase, CO2 injection extracts CH4 from the sorption phase, particularly micropores. This research provides valuable insights into the competitive sorption behavior of CH4 and CO2 in shale nanopore systems for further development of CO2 storage and enhanced gas recovery technologies.