Record Values Research Articles

Performance enhancement of solution-processed organic thin-film transistors incorporating an improved Corbino structure

The solution-processed organic thin-film transistors (OTFTs) with a minimal device footprint and improved performance are desirable for flexible electronics and other circuit applications. It is demonstrated that the enhanced performance can be achieved for solution-processed OTFTs by adopting an improved Corbino structure. The bottom-gate bottom-contact OTFTs of W/L ratio of 500 are fabricated using the standard poly-3-hexylthiophene (P3HT) as a semiconductor with an improved interdigitated pseudo-Corbino (IPC) structure. The exhibited IPC structure is a combination of interdigitated structure in the enclosed-Corbino design to achieve infinite output resistance, suppressed parasitic leakage current, and high ON current by accommodating a high W/L ratio in a minimal device footprint. For the fabricated solution-processed OTFTs, infinite output resistance with an OFF-current of the order of 10−12 A and an ON/OFF ratio of drain current of the order of 107 is achieved. Incorporating an enhanced hexamethyldisilazane treatment of the SiO2 gate dielectric improves the ON/OFF ratio to a record value of 108 and the mobility of the order of 10−2 cm2/Vs for P3HT. Implementation of IPC-TFT structure for intentionally chosen moderate-mobility, solution-processed P3HT semiconductor results in a consistent low OFF-current, high ON/OFF ratio, and infinite output resistance with excellent device-to-device uniformity.

Sublimation and Recrystallization of CsPbBr3 Constructing a Perovskite-Carbon Interface to Facilitate Hole Transfer in Printable All-Inorganic Perovskite Solar Cells.

All-inorganic perovskite solar cells (APSCs) are a promising photovoltaic technology due to their unique physical and optical properties. For printable all-inorganic perovskite solar cells, the key factors limiting their photoelectric conversion performance are the crystallization of perovskite and the hole collection capability at the perovskite-carbon interface. In this study, leveraging the high-temperature tolerance of CsPbBr3 perovskite, the sublimation and recrystallization processes were controlled, significantly improving the crystalline quality of the perovskite and suppressing the generation of the nonphotovoltaic CsPb2Br5 phase. Furthermore, a continuous distribution of high-quality CsPbBr3 crystals was achieved at the interface between the carbon electrode and the zirconium oxide layer, ensuring efficient collection of photogenerated holes. The photoelectric conversion efficiency of the printable mesoscopic all-inorganic perovskite solar cell was increased from 5.04 to 8.34% (with a record value of 10.04%) and achieved an ultrahigh open-circuit voltage of 1.54 V due to the significant improvement in the crystal quality of CsPbBr3. This study proposes a novel strategy to enhance the photovoltaic conversion performance of carbon-based all-inorganic perovskite solar cells by suppressing the presence of nonphotovoltaic phases.

Boosting Coercivity of 3D Printed Hard Magnets through Nano-Modification of the Powder Feedstock.

The demand for strong, compact permanent magnets essential for the energy transition drives innovation in magnet manufacturing. Additive manufacturing, particularly Powder Bed Fusion of metals using a laser beam (PBF-LB/M), offers potential for near-net-shaped Nd-Fe-B permanent magnets but often falls short compared to conventional methods. A less explored strategy to enhance these magnets is feedstock modification with nanoparticles. It is demonstrated that modifying a Nd-Fe-B-based feedstock with 1wt.%Ag nanoparticles boost the coercivity of the magnets to a record value of 935±6kAm-1 without further post-processing or heat treatments. Suitable volumetric energy densities for the PBF-LB/M process are determined using finite element simulations predicting melt pool behavior and part density. Microstructural analyses reveal finer grain sizes and more equiaxed nanocrystalline structures due to the modification. Atom probe tomography identifies three phases in the Ag-modified samples, with Ag forming nanophase regions with rare-earth elements near the amorphous Zr-Ti-B-rich intergranular phase, potentially decoupling the Nd2Fe14B primary phase. The study shows that superior magnetic properties primarily result from microstructure modification rather than part density. These findings highlight inventive material design approaches via feedstock surface modification to achieve superior magnetic performance in additively manufactured Nd-Fe-B magnets.

Extropy and statistical features of dual generalized order statistics’ concomitants arising from the Sarmanov family

Abstract In this study, we disclose several statistical properties of concomitants of dual generalized order statistics (DGOSs) under a generic setting from the Sarmanov family of bivariate distributions. For this family, cross-moments and joint distributions of concomitants of DGOSs are explored. These results' implications for order statistics and record values are examined. Extropy and cumulative residual extropy (CRE), two well-known information measures, are also investigated. This study offers a few beautiful symmetrical relationships that these inaccuracy measurements satisfy. In addition, based on the concomitants of DGOSs, the issue of estimating the negative cumulative residual extropy (NCRE), empirical NCRE and NCE are investigated using the empirical technique. Lastly, a set of bivariate data from the real world is examined.

A Fluorinated Imide-Functionalized Arene Enabling a Wide Bandgap Polymer Donor for Record-Efficiency All-Polymer Solar Cells.

All-polymer solar cells (all-PSCs) present compelling advantages for commercial applications, including mechanical durability and optical and thermal stability. However, progress in developing high-performance polymer donors has trailed behind the emergence of excellent polymer acceptors. In this study, we report a new electron-deficient arene, fluorinated bithiophene imide (F-BTI) and its polymer donor SA1, in which two fluorine atoms are introduced at the outer β-positions in the thiophene rings of BTI to fine-tune the energy levels and aggregation of the resulting polymers. SA1 exhibits a deep HOMO level of -5.51 eV, a wide bandgap of 1.81 eV and suitable miscibility with the polymer acceptor. Polymer chains incorporating F-BTI result in a highly ordered π-π stacking and favorable phase-separated morphology within the all-polymer active layer. Thus, SA1 : PY-IT-based all-PSCs exhibit an efficiency of 16.31 % with excellent stability, which is further enhanced to a record value of 19.33 % (certified: 19.17 %) by constructing ternary device. This work demonstrates that F-BTI offers an effective route for developing new polymer materials with improved optoelectronic properties, and the emergence of F-BTI will change the scenario in terms of developing polymer donor for high-performance and stable all-PSCs.

A Fluorinated Imide‐Functionalized Arene Enabling a Wide Bandgap Polymer Donor for Record‐Efficiency All‐Polymer Solar Cells

AbstractAll‐polymer solar cells (all‐PSCs) present compelling advantages for commercial applications, including mechanical durability and optical and thermal stability. However, progress in developing high‐performance polymer donors has trailed behind the emergence of excellent polymer acceptors. In this study, we report a new electron‐deficient arene, fluorinated bithiophene imide (F‐BTI) and its polymer donor SA1, in which two fluorine atoms are introduced at the outer β‐positions in the thiophene rings of BTI to fine‐tune the energy levels and aggregation of the resulting polymers. SA1 exhibits a deep HOMO level of −5.51 eV, a wide bandgap of 1.81 eV and suitable miscibility with the polymer acceptor. Polymer chains incorporating F‐BTI result in a highly ordered π–π stacking and favorable phase‐separated morphology within the all‐polymer active layer. Thus, SA1 : PY‐IT‐based all‐PSCs exhibit an efficiency of 16.31 % with excellent stability, which is further enhanced to a record value of 19.33 % (certified: 19.17 %) by constructing ternary device. This work demonstrates that F‐BTI offers an effective route for developing new polymer materials with improved optoelectronic properties, and the emergence of F‐BTI will change the scenario in terms of developing polymer donor for high‐performance and stable all‐PSCs.

Comparative evaulation of condylar guidance obtained by digital panoramic radiographic images with that of obtained during jaw relation and try-in using two different interocclusal record material in completely edentulous patients: an in vivo study

Background In completely edentulous patients, maintaining the patient’s temporomandibular joint (TMJ) health and intraoral components is very essential, which can be achieved by an accurate interocclusal record, which can be taken by various materials and also at various stages. Simulation of the temporomandibular joint anatomy and mandibular movements is possible on a semi-adjustable articulator, which is widely used in prosthodontics. Transferring the record on articulator is a critical step in the fabrication of complete dentures, so it should be done precisely to reduce chair side time and also to avoid complications for patients. This study examines which material is more accurate and records which stage gives more precision by comparing the Condylar guidance on radiographs. This is because it is a relatively consistent bony landmark and can be used to correlate with clinical methods in terms of verification. The objective is to determine the inter occlusal records created during the Jaw Relation stage and Try-in using reinforced wax and Polyvinyl siloxane and compare these values to the condylar guidance obtained by orthopantomogram (OPG). Methods Recording the Condylar Guidance value on OPG by tracing the Glenoid fossa, Articular eminence, and the Frankfurt Horizontal Plane. Followed by conventional steps in making complete dentures at jaw relation and try-in stage. We will record values of condylar guidance with the two different Interocclusal record materials. Expected result It will help the clinicians to gain knowledge about obtaining precise condylar inclination angle by using suitable interocclusal record materials. Conclusions This study will help us to obtain condylar inclination, which in turn helps the patient’s satisfaction as it preserves the intraoral components and health of TMJ.

Prediction intervals for future Pareto record claims

AbstractStochastic models and methods for quantifying extreme events are of interest in numerous disciplines. Within this paper, statistical prediction of extreme claims or losses in insurance industry is considered based on upper record values, which describe successively largest observations in a sequence of data over time. The problem of predicting a future record value (here in particular, a future record claim) based on a sequence of previously observed record values (here, past record claims) is addressed by means of prediction intervals. For an underlying Pareto distribution, respective exact and approximate intervals from the literature are summarized and modified and new ones are developed. In a simulation study, these prediction intervals are evaluated and compared regarding coverage frequency and length. The impact of the number of observed record values as well as the choice of the Pareto distribution is discussed. In the case of a small number of record values, the use of k-th record values is considered as an option for statistical analyses to predict, e.g., second largest record claims. Selected prediction methods are applied to several real data sets, which turn out to perform well and to be able to capture the magnitude of future record claims, even for fairly small numbers of record observations. For comparison, generalized Pareto distributions are fitted to real data sets and a corresponding point predictor as well as a respective upper prediction interval for the next record to appear are derived and evaluated.

Структурный подход к оценке работоспособности системы мониторинга инженерных конструкций вантового моста через Петровский канал в створе автомобильной дороги «Западный скоростной диаметр» в городе Санкт-Петербурге. Часть 2

Purpose: assessing the performance of the monitoring system for engineering structures and assessing the current state of the structures of the cable-stayed bridge across the Petrovsky Canal in the alignment of the Western High-Speed Diameter highway in the city of St. Petersburg due to the occurrence of emergency situations in which accelerometers on the pylons record values exceeding the limit. Methods: statistical data from the databases of the existing system of monitoring engineering structures is used to obtain the results. The tasks, set within the framework of the study, are accomplished by applying the theoretical methods of scientific knowledge: the analytical method, the mathematical statistics theory, induction. Results: the resulting structural approach to assessing the performance of the monitoring system for engineering structures on cable-stayed bridges makes it possible to reduce the number of false alarms of the system and assess the current state of the bridge structure. Within the framework of the III stage of the structural approach, it is proposed to develop a methodology for assessing the performance of the monitoring system for engineering structures with subsequent assessment of the current state of cablestayed bridge structures. Practical significance: the results of the work are important for construction as they expand the understanding of the features of the mechanism of soil freezing.

Technical aspect of the operation of accelerometers as composition of a system for monitoring engineering structures of a cable-stayed bridge over the Petrovsky canal in the construction of the Western Speed Diameter highway in Saint Petersburg

Aim. This study analyzes the current monitoring system for the engineering structures of a cable-stayed bridge across the Petrovsky Canal, part of the Western High-Speed Diameter highway in St. Petersburg, focusing on emergency situations where accelerometers on pylons record values that exceed limits. Methods and Materials. The study utilizes statistical data from existing monitoring system databases. The tasks, set within the framework of the study, are accomplished by applying theoretical scientific methods including analytical techniques, mathematical statistics, and induction. Results. The analysis presents an overview of the current system used for monitoring engineering structures and highlights issues related to emergency situations in which accelerometer readings exceed threshold values. This study proposes a method for assessing the reliability of the monitoring system by classifying the data obtained from the accelerometer into two groups. The research identifies the need for further investigations to understand the root causes of these issues. Conclusion. Тhe results can assist in the design and installation of monitoring systems of the engineering structures for cable-stayed bridges, as well as for modernization and optimization of existing monitoring systems to improve the quality of structural technical condition assessments.

Record High March 2024 Arctic Total Column Ozone

AbstractObservations of March 2024 Arctic (63°N–90°N) total column ozone set a record high of 477 Dobson Units (DU) against the 1979–2023 satellite era time series. It was about 60 DU higher than average and 6 DU higher than the previous March 1979 471 DU record. Daily Arctic ozone was above average for every day in March 2024, and set record highs from 11–26 March 2024. Microwave Limb Sounder data show this record ozone anomaly was concentrated in the lower stratosphere (10–30 km). These record values developed over the 2023–2024 winter and can be associated with vertically propagating planetary‐scale wave events that caused significant stratospheric warmings. These wave events forced poleward and downward ozone advection into the lower stratosphere, leading to record column ozone levels. The above average levels persisted through August 2024 and across the northern hemisphere.

Giant Piezoelectric Effect Induced by Porosity in Inclined ZnO Thin Films

AbstractPiezoceramics have been the common choice for sensing applications, however their integration with other electronics is limited due to their large size. Also, environmental concerns have been limiting the use of ceramics due to their lead content, toxic for humans. Piezoelectric crystalline thin films have arisen as alternative materials offering compatibility with miniaturization and integrated processes, though their piezoelectric properties are low (d33 < 15 pC N−1) compared to ceramics (d33 > 300 pC N−1), hindering their applicability. Several methods have been studied aiming to improve the piezoelectric output of thin films, including doping or the less investigated inclusion of porosity. However, they all require complex techniques that increase the cost. In this work, a giant electromechanical d33 coefficient of 115.6 pC N−1 has been obtained inducing porosity in inclined ZnO thin films via oblique angle deposition, which is beyond record values reported for doped ZnO thin films and an order of magnitude higher than standard ZnO thin films (11.6 pC N−1). Morphology, composition, crystal structure, porosity, and piezoelectricity are reported for standard and inclined films. Finite element simulations have been carried out to investigate the performance of the piezoelectric‐enhanced thin films in an ultrasonic pulse‐echo setup.

Massive Onset Potential Shifting with an Epitaxial GaAs/Si Photocathode for Solar H2 Production

Solar photoelectrochemical (PEC) H2 production has the potential to solve one of the biggest issues confronting humanity nowadays: producing inexpensive, clean and renewable energy. Among various semiconductor materials, GaAs is an excellent candidate for the development of photoelectrodes within PEC cells for unassisted solar water splitting thanks to its appropriate band gap, good transport and optical properties and high quantum yield. However, the main limitations of GaAs photoelectrodes are related to the high substrate cost, their huge overpotentials and the short lifetime under operation. To address these issues, in this work, we report on the photocathode performance of 1 µm-thick GaAs layers grown on a low-cost Si p-doped substrate by MBE (Molecular Beam Epitaxy) and compare them to those of GaAs:p doped wafers . The photocathodes were investigated in 0.2 M H2SO4 (aq) electrolyte under 1 sun (100 mW/cm2) illumination. The onset potential (Vonset) of bare GaAs/Si and bare GaAs:p wafer is quite comparable, at around -0.2 V vs reversible hydrogen electrode (RHE). The significant reduction of surface states density with a sulfur passivation (S-passivation) by immersing samples in (NH4)2S solution is demonstrated but with very limited changes on the Vonset value, for both GaAs:p wafer and GaAs/Si photocathodes. In contrast, the deposition of thin Pt catalyst layers on both photocathodes by electroless deposition technique leads to a large positive shift Vonset. The Vonset of GaAs/Si and GaAs:p wafer photocathodes are increased up to 0.34 and 0.15 V vs RHE respectively. We show that the Vonset of GaAs/Si can be even improved by combining the Pt catalyst and the S-passivation process, reaching 0.4 V vs RHE (Fig. 1), a record value for GaAs-based Schottky-like photocathodes.STEM-EDX analysis was performed to investigate further the difference between Pt/GaAs/Si and Pt/GaAs:p wafer photocathodes. The EDX-line scans show that after the Pt electroless deposition, the Pt layer on GaAs:p wafer is homogeneous and shows an As0-rich Pt surface that can explain the weaker catalytic activity in comparison with GaAs/Si. Indeed, for the latter, Pt is deposited inhomogenously in the form of clusters leaving some bare surface. Here, As0 is expected to be more easily removed from the surface during the electroless deposition, resulting in more efficient catalyst properties of Pt. The morphology differences between the two Pt-coated electrodes are confirmed by XPS measurements. Since the process of electroless deposition strongly depends on the doping concentration of the materials deposited, the difference between GaAs:p wafer and GaAs/Si photocathodes is attributed to variations in their doping concentrations. Furthermore, the inhomogeneity of the Pt coating on GaAs/Si can also benefit to the passivation process by allowing the (NH4)2S solution to reduce more efficiently the surface defects at the oxide/semiconductor interface. Finally, the stability of Pt/GaAs/Si photocathodes was evaluated, and a lifetime larger than 112 h was established. These findings provide guidance for further studies towards the fabrication of scalable, cost-efficient and stable unassisted PEC cells for green hydrogen production. This research is supported by the “France 2030” French National Research Agency NAUTILUS Project (Grant no. ANR-22-PEHY-0013). Figure 1

RETRACTED ARTICLE: Significantly enhanced critical current density and pinning force in nanostructured, (RE)BCO-based, coated conductor

High-temperature superconducting wires have many large-scale, niche applications such as commercial nuclear fusion as well as numerous other large-scale applications in the electric power industry and in the defense, medical and transportation industries. However, the price/performance metric of these coated conductor wires is not yet favorable to enable and realize most large-scale applications. Here we report on probing the limits of Jc (H, T) possible via defect engineering in heteroepitaxially deposited high-temperature superconducting thin-films on coated conductor substrates used for long-length wire fabrication. We report record values of Jc (H, T) and pinning force, Fp (H, T) in (RE)BCO films with self-assembled BaZrO3 nanocolumns deposited on a coated conductor substrate. A Jc of ~190 MA/cm2 at 4.2 K, self-field and ~90 MA/cm2, at 4.2 K, 7 T was measured. At 20 K, Jc of over 150 MA/cm2 at self-field and over 60 MA/cm2 at 7 T was observed. A very high pinning force, Fp, of ~6.4 TN/m3 and ~4.2 TN/m3 were observed at 7 T, 4.2 K and 7 T, 20 K respectively. We report on the highest values of Jc and Fp obtained to date for all fields and operating temperatures from 4.2 K to 77 K. These results demonstrate that significant performance enhancements and hence far more favorable price/performance metrics are possible in commercial high-temperature superconducting wires.

Giant nonlinear optical wave mixing in a van der Waals correlated insulator.

Optical nonlinearities are one of the most fascinating properties of two-dimensional (2D) materials. While tremendous efforts have been made to find and optimize the second-order optical nonlinearity in enormous 2D materials, opportunities to explore higher-order ones are elusive because of the much lower efficiency. Here, we report the giant high odd-order optical nonlinearities in centrosymmetric correlated van der Waals insulator manganese phosphorus triselenide. When illuminated by two near-infrared femtosecond lasers, the sample generates a series of profound four- and six-wave mixing outputs. The near-infrared third-order nonlinear susceptibility reaches near the highest record values of 2D materials. Comparative measurements to other prototypical nonlinear optical materials [lithium niobate, gallium(II) selenide, and tungsten disulfide] reveal its extraordinary wave mixing efficiency. The wave mixing processes are further used for nonlinear optical waveguide with multicolor emission. Our work highlights the promising prospect for future research of the nonlinear light-matter interactions in the correlated 2D system and for potential nonlinear photonic applications.

On the recent-$k$-record of discrete random variables

Let $X_1,~X_2,\cdots$ be a sequence of independent and identically distributed random variables which are supposed to be observed in sequence. The $n$th value in the sequence is a $k-record~value$ if exactly $k$ of the first $n$ values (including $X_n$) are at least as large as it. Let ${\bf R}_k$ denote the ordered set of $k$-record values. The famous Ignatov's Theorem states that the random sets ${\bf R}_k(k=1,2,\cdots)$ are independent with common distribution. We introduce one new record named $recent-k-record$ in this paper: $X_n$ is a $j$-recent-k-record if there are exactly $j$ values at least as large as $X_n$ in $X_{n-k},~X_{n-k+1},\cdots,~X_{n-1}$. It turns out that recent-k-record brings many interesting problems and some novel properties such as prediction rule and Poisson approximation which are proved in this paper. One application named "No Good Record" via the Lov{\'a}sz Local Lemma is also provided. We conclude this paper with some possible connection with scan statistics.

Female-Biased Odorant Receptor MmedOR48 in the Parasitoid Microplitis mediator Broadly Tunes to Plant Volatiles.

Odorant receptors (ORs) play a crucial role in insect chemoreception. Here, a female-biased odorant receptor MmedOR48 in parasitoid Microplitis mediator was fully functionally characterized. The qPCR analysis suggested that the expression level of MmedOR48 increased significantly after adult emergence and was expressed much more in the antennae. Moreover, an in situ hybridization assay showed MmedOR48 was extensively located in the olfactory sensory neurons. In two-electrode voltage clamp recordings, recombinant MmedOR48 was broadly tuned to 23 kinds of volatiles, among which five plant aldehyde volatiles excited the strongest current recording values. Subsequent molecular docking analysis coupled with site-directed mutagenesis demonstrated that key amino acid residues Thr142, Gln80, Gln282, and Thr312 together formed the binding site in the active pocket for the typical aldehyde ligands. Furthermore, ligands of MmedOR48 could stimulate electrophysiological activities in female adults of the M. mediator. The main aldehyde ligand, nonanal, aroused significant behavioral preference of M. mediator in females than in males. These findings suggest that MmedOR48 may be involved in the recognition of plant volatiles in M. mediator, which provides valuable insight into understanding the olfactory mechanisms of parasitoids.

Predicting future failures in generalized order statistics and related models

Quantile regression predictions are considered for generalized order statistics which extend results previously established for record values and order statistics. In order to derive the results, some (univariate and bivariate) distortion representations of generalized order statistics are established. In particular, prediction of the sth generalized order statistic X ( s ) ∗ based on F given a single (generalized) order statistic X ( r ) ∗ with r<s will be addressed. The presentation includes results for both known and unknown baseline distributions. In the latter case, we consider exponential distributions with unknown mean as well as the proportional hazards model. Using unimodality properties of the marginal density functions (pdf) of generalized order statistics, we find a simple representation of the maximum likelihood prediction of X ( s ) ∗ given X ( r ) ∗ .

Stochastic comparisons of record values based on their relative aging

Stochastic comparisons of record values based on their relative aging

Over 50 years of a field experiment on cropping systems in Bałcyny, Poland: Assessing pesticide residues in soil and crops from the perspective of their field application history

Many agricultural problems can be illustrated and solved through long-term field experiments. Since 1967, an experiment has been conducted in Bałcyny, Poland, to compare continuous cropping with growing crops in crop rotation. The experiment also provides information on the history of chemical crop protection, which may have influenced soil and crop contamination with pesticide residues. In this study, fields of winter rye in continuous cropping (CCrye) and a 5–6-field crop rotation (CRrye) were used as an example to investigate the occurrence of pesticides in soil and grain in the context of previous use of chemical crop protection products. Two levels of crop protection were also examined: herbicide (since the 1972/73 growing season) and fungicide (since 1982/83) application (HF) and control treatment (CT; no herbicides since 1972/73, no fungicides since 1982/83). Insecticides were used only when absolutely necessary. Between 1967 and 2019, 58 different active substances were applied to the fields selected for this study. Soil and grain samples collected in 2019 after rye harvest were analyzed for the presence of 441 and 496 different substances, respectively. Only DDT and its metabolites were detected in soil, even though DDT was not applied to the fields after 1967. The concentration of ΣDDT (sum of all metabolites and isomers) ranged from 038 to 130 µg kg–1 soil and exceeded the limit set in Poland (120 µg kg–1) under CRrye-HF treatment. In winter rye grain, no pesticide residues were found. The results show that long-term rational use of less persistent pesticides does not lead to contamination of the soil or the test cereal grain, but DDT continues to threaten the environment five decades after its probable last use. The study points to the value of comprehensive long-term recording for providing a retrospective assessment of pesticide exposure. Long-term field experiments facilitate this approach.