Discrete modulation can make up for the shortage of transmission distance in measurement-device-independent continuous-variable quantum key distribution (MDI-CVQKD), providing a unique advantage against all side-channel attacks but also creating a challenge for further performance improvement. Here we suggest a quantum catalysis (QC) approach for enhancing the performance of the discrete-modulated (DM) MDI-CVQKD in terms of the achievable secret key rate and lengthening the maximal transmission distance. The numerical simulation results show that the QC-based MDI-CVQKD with discrete modulation, involving a zero-photon catalysis (ZPC) operation, can not only obtain a higher secret key rate than the original DM protocol, but also contribute to a reasonable increase of the corresponding optimal variance. As for the extreme asymmetric and symmetric cases, the secret key rate and maximal transmission distance of the ZPC-involved DM MDI-CVQKD system can be further improved under the same parameters. This approach enables the system to tolerate lower reconciliation efficiency, which may provide excellent potential for practical implementations with state-of-art technology.
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