Recent Results Research Articles

Riesz and Kolmogorov inequality for harmonic quasiregular mappings

Let K⩾1 and p∈(1,2]. We obtain an asymptotically sharp constant c(K,p) as K→1 in the inequality‖ℑf‖p≤c(K,p)‖ℜf‖p, where f∈hp is a K-quasiregular harmonic mapping in the unit disk belonging to the Hardy space hp. This result holds under the conditions arg⁡(f(0))∈(−π2p,π2p) and f(D)∩(−∞,0)=∅. Our findings improve a recent result by Liu and Zhu [12]. Additionally, we extend this result to K-quasiregular harmonic mappings in the unit ball in Rn. Finally, we consider the Kolmogorov theorem for quasiregular harmonic mappings in the plane.

Differences in Protein Capture by SP3 and SP4 Demonstrate Mechanistic Insights of Proteomics Cleanup Techniques.

The goal of proteomics experiments is to identify proteins to observe changes in cellular processes and diseases. One challenge in proteomics is the removal of contaminants following protein extraction, which can limit protein identifications. Single-pot, solid-phase-enhanced sample preparation (SP3) is a cleanup technique in which proteins are captured on carboxylate-modified particles through a proposed hydrophilic-interaction-liquid-chromatography (HILIC)-like mechanism. Recent results have suggested that proteins are captured in SP3 due to a protein-aggregation mechanism. Solvent precipitation, single-pot, solid-phase-enhanced sample preparation (SP4) is a newer cleanup technique that employs protein aggregation to capture proteins without modified particles. We hypothesize that differences in capture mechanisms of SP3 and SP4 affect which proteins are identified by each cleanup technique. Herein, we assess the proteins identified and enriched using SP3 versus SP4 for MCF7 subcellular fractions and correlate protein capture in each method to protein hydrophobicity. Our results indicate that SP3 captures more hydrophilic proteins through a combination of HILIC-like and protein-aggregation mechanisms, while SP4 captures more hydrophobic proteins through a protein-aggregation mechanism. Ultimately, we demonstrate that protein-capture mechanisms are distinct, and the selection of a cleanup technique that yields high proteome coverage is dependent on protein-sample hydrophobicity. Data has been deposited into MassIVE (MSV000094130) and ProteomeXchange (PXD049965).

General Relations between Stress Fluctuations and Viscoelasticity in Amorphous Polymer and Glass-Forming Systems.

Mechanical stress governs the dynamics of viscoelastic polymer systems and supercooled glass-forming fluids. It was recently established that liquids with long terminal relaxation times are characterized by transiently frozen stress fields, which, moreover, exhibit long-range correlations contributing to the dynamically heterogeneous nature of such systems. Recent studies show that stress correlations and relaxation elastic moduli are intimately related in isotropic viscoelastic systems. However, the origin of these relations (involving spatially resolved material relaxation functions) is non-trivial: some relations are based on the fluctuation-dissipation theorem (FDT), while others involve approximations. Generalizing our recent results on 2D systems, we here rigorously derive three exact FDT relations (already established in our recent investigations and, partially, in classical studies) between spatio-temporal stress correlations and generalized relaxation moduli, and a couple of new exact relations. We also derive several new approximate relations valid in the hydrodynamic regime, taking into account the effects of thermal conductivity and composition fluctuations for arbitrary space dimension. One approximate relation was heuristically obtained in our previous studies and verified using our extended simulation data on two-dimensional (2D) glass-forming systems. As a result, we provide the means to obtain, in any spatial dimension, all stress-correlation functions in terms of relaxation moduli and vice versa. The new approximate relations are tested using simulation data on 2D systems of polydisperse Lennard-Jones particles.

"Exploring the role of lithium in Al2O3 tritium permeation barrier development: A crucial challenge for fusion reactor progress"

The development and application of robust tritium permeation barriers (TPBs) are crucial for a safe and economical fusion reactor operation because tritium permeation could cause serious safety problems, such as the brittleness of the structural material, fuel loss, and radioactive contamination. Coatings may effectively inhibit the permeation through the structural materials of tritium fuel generated inside the breeding blanket (BB) reducing the loss of lithium inventory contamination of the ancillary systems and the exposure of workers and the population. Al2O3 has been preliminary selected as the EU candidate for tritium permeation reduction of structural steels in the Water-cooled lithium–lead breeding blank (WCLL) concept, because of its very high permeation reduced factor (PRF). However, because of the chemical reactivity of lithium, several authors report the formation of Lithium aluminates after exposure to PbLi baths, based on different experimental techniques. In this contribution, we will show recent results about the quantification of the extent of the reaction and the thickness of the reacted layer and discuss the possible effects, that may happen under neutron irradiation based on the species produced (T and He) in the nuclear reactions (n, T) and (n, α) with 6Li and 7Li, with the Li atoms in the reacted layer To do that, the atomic density of produced T and He per second out of the transmutation reaction and the He/T ratio are calculated for diverse Li contents. Subsequently, we implant He into the coatings and characterize the desorption rate and the morphology. Finally, discussion and recommendations for further coating development will be presented.

Machine learning discovery of cost-efficient dry cooler designs for concentrated solar power plants

Concentrated solar power (CSP) is one of the few sustainable energy technologies that offers day-to-night energy storage. Recent development of the supercritical carbon dioxide (sCO2) Brayton cycle has made CSP a potentially cost-competitive energy source. However, as CSP plants are most efficient in desert regions, where there is high solar irradiance and low land cost, careful design of a dry cooling system is crucial to make CSP practical. In this work, we present a machine learning system to optimize the factory design and configuration of a dry cooling system for an sCO2 Brayton cycle CSP plant. For this, we develop a physics-based simulation of the cooling properties of an air-cooled heat exchanger. The simulator is able to construct a dry cooling system satisfying a wide variety of power cycle requirements (e.g., 10–100 MW) for any surface air temperature. Using this simulator, we leverage recent results in high-dimensional Bayesian optimization to optimize dry cooler designs that minimize lifetime cost for a given location, reducing this cost by 67% compared to recently proposed designs. Our simulation and optimization framework can increase the development pace of economically-viable sustainable energy generation systems.

Information geometry and alpha-parallel prior of the beta-logistic distribution

The hyperbolic secant distribution has several generalizations with applications in, for example, finance. In this study, we explore the dual geometric structure of one such generalization: the beta-logistic distribution. Within this family, two special cases of random variables, as examples, are of particular interests: their moments, by some recent results, give the Bernoulli and Euler polynomials, which are important objects in many areas of mathematics. This current study also uncovers that the beta-logistic distribution admits a α-parallel prior for any real number α, that has the potential for application in geometric statistical inference.

Evaluating Phthalates and Bisphenol in Foods: Risks for Precocious Puberty and Early-Onset Obesity.

Recent scientific results indicate that diet is the primary source of exposure to endocrine-disrupting chemicals (EDCs) due to their use in food processing, pesticides, fertilizers, and migration from packaging to food, particularly in plastic or canned foods. Although EDCs are not listed on nutrition labels, their migration from packaging to food could inadvertently lead to food contamination, affecting individuals by inhalation, ingestion, and direct contact. The aim of our narrative review is to investigate the role of phthalates and bisphenol A (BPA) in foods, assessing their risks for precocious puberty (PP) and early-onset obesity, which are two clinical entities that are often associated and that share common pathogenetic mechanisms. The diverse outcomes observed across different studies highlight the complexity of phthalates and BPA effects on the human body, both in terms of early puberty, particularly in girls, and obesity with its metabolic disruptions. Moreover, obesity, which is independently linked to early puberty, might confound the relationship between exposure to these EDCs and pubertal timing. Given the potential public health implications, it is crucial to adopt a precautionary approach, minimizing exposure to these EDCs, especially in vulnerable populations such as children.

Modeling of plasma facing component erosion, impurity migration, dust transport and melting processes at JET-ILW

An overview of the modeling approaches, validation methods and recent main results of analysis and modeling activities related to the plasma-surface interaction (PSI) in JET-ILW experiments, including the recent H/D/T campaigns, is presented in this paper. Code applications to JET experiments improve general erosion/migration/retention prediction capabilities as well as various physics extensions, for instance a treatment of dust particles transport and a detailed description of melting and splashing of PFC induced by transient events at JET. 2D plasma edge transport codes like the SOLPS-ITER code as well as PSI codes are key to realistic description of relevant physical processes in power and particle exhaust. Validation of the PSI and edge transport models across JET experiments considering various effects (isotope effects, first wall geometry, including detailed 3D shaping of plasma-facing components, self-sputtering, thermo-forces, physical and chemically assisted physical sputtering formation of W and Be hydrides) is very important for predictive simulations of W and Be erosion and migration in ITER as well as for increasing quantitative credibility of the models. JET also presents a perfect test-bed for the investigation and modeling of melt material dynamics and its splashing and droplet ejection mechanisms. We attribute the second group of processes rather to transient events as for the steady state and, thus, treat those as independent additions outside the interplay with the first group.

Palynological investigation of some genera of Cichorieae (Asteraceae) in Iran.

The pollen morphology of 33 species belonging to the genera Lactuca, Launaea, Cicerbita, Sonchus, Condrilla (tribe Cichorieae: Asteraceae) from Iran were studied with light and electron microscopies. The pollen grains of the investigated taxa are almost oblate-spherical to prolate-spherical, the shapes are circular in equatorial view, hexagonal in polar view, only Sonchus species are triangular or quadrangular in polar view, isopolar, symmetrical and trizonocolporate, except Sonchus and Chondrilla species, which have tri- to tetrazonocolporate pollen grains, and echinolophate. The size and number of spines in the polar area and the number of spines in the paraporal ridges and equatorial ridges proved to be the most taxonomically authentic characteristics in this study. Three pollen types were distinguished, as in alignment with previous studies. Cluster analysis by Ward method based on 10 quantitative morphological characteristics of pollen grains revealed that the species could be grouped based on the pollen characteristics. Moreover, three species of Cicerbita including Cicerbita scoparia (Rech. f. & Köie) Kitam, C. rechingeriana (Tuisl) Coșkunç., M. Güzel & N. Kilian and C. microcephala (DC.) M. Güzel, Coșkunç. & N. Kilian were recorded for the first time in Iran. Although the characteristics of the pollen grains were useful for distinguishing the species in sub-tribes, in some cases, this did not confirm recent phylogenetic results. The pollen characteristics described in this study provide data that may be useful for future systematic studies aiming to complete the knowledge on Cichorieae species. RESEARCH HIGHLIGHTS: In the present study, the pollen morphology of 33 species belonging to five genera of the Cichorieae are investigated with scanning electron microscopy and 12 species are analyzed for the first time. The cluster analysis based on the quantitative morphological characteristics of pollen grains revealed that the species could be grouped based on the pollen characteristics. In addition, three species of Cicerbita are reported for the first time in Iran.

Logarithmic correlation functions in 2D critical percolation

It is believed that the large-scale geometric properties of two-dimensional critical percolation are described by a logarithmic conformal field theory, but it has been challenging to exhibit concrete examples of logarithmic singularities and to find an explanation and a physical interpretation, in terms of lattice observables, for their appearance. We show that certain percolation correlation functions receive independent contributions from a large number of similar connectivity events happening at different scales. Combined with scale invariance, this leads to logarithmic divergences. We study several logarithmic correlation functions for critical percolation in the bulk and in the presence of a boundary, including the four-point function of the density (spin) field. Our analysis confirms previous findings, provides new explicit calculations and explains, in terms of lattice observables, the physical mechanism that leads to the logarithmic singularities we discover. Although we adopt conformal field theory (CFT) terminology to present our results, the core of our analysis relies on probabilistic arguments and recent rigorous results on the scaling limit of critical percolation and does not assume a priori the existence of a percolation CFT. As a consequence, our results provide strong support for the validity of a CFT description of critical percolation and a step in the direction of a mathematically rigorous formulation of a logarithmic CFT of two-dimensional critical percolation.

Mathematical results on the chiral models of twisted bilayer graphene (with an appendix by Mengxuan Yang and Zhongkai Tao)

The study of twisted bilayer graphene (TBG) is a hot topic in condensed matter physics with special focus on magic angles of twisting at which TBG acquires unusual properties. Mathematically, topologically non-trivial flat bands appear at those special angles. The chiral model of TBG pioneered by Tarnopolsky, Kruchkov, and Vishwanath (2019) has particularly nice mathematical properties and we survey, and in some cases, clarify, recent rigorous results which exploit them.

Exponential quintessence: curved, steep and stringy?

We explore the possibility that our universe’s current accelerated expansion is explained by a quintessence model with an exponential scalar potential, V = V0e−λ ϕ, keeping an eye towards λ ≥ 2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \\sqrt{2} $$\\end{document} and an open universe, favorable to a string theory realisation and with no cosmological horizon. We work out the full cosmology of the model, including matter, radiation, and optionally negative spatial curvature, for all λ > 0, performing an extensive analysis of the dynamical system and its phase space. The minimal physical requirements of a past epoch of radiation domination and an accelerated expansion today lead to an upper bound λ ≲ 3\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \\sqrt{3} $$\\end{document}, which is driven slightly up in the presence of observationally allowed spatial curvature. Cosmological solutions start universally in a kination epoch, go through radiation and matter dominated phases and enter an epoch of acceleration, which is only transient for λ > 2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \\sqrt{2} $$\\end{document}. Field distances traversed between BBN and today are sub-Planckian. We discuss possible string theory origins and phenomenological challenges, such as time variation of fundamental constants. We provide theoretical predictions for the model parameters to be fitted to data, most notably the varying dark energy equation of state parameter, in light of recent results from DES-Y5 and DESI.

Weighted approximations by sampling type operators: recent and new results

In this paper, we collect some recent results on the approximation properties of generalized sampling operators and Kantorovich operators, focusing on pointwise and uniform convergence, rate of convergence, and Voronovskaya-type theorems in weighted spaces of functions. In the second part of the paper, we introduce a new generalization of sampling Durrmeyer operators including a special function $\rho$ which satisfies certain assumptions. For the family of newly constructed operators, we obtain pointwise convergence, uniform convergence and rate of convergence for functions belonging to weighted spaces of functions.

Recent Development of Transition Metal‐based Amorphous Electrocatalysts for Water Splitting

AbstractElectrochemical water splitting, including the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), is a promising hydrogen production technology. However, in practice, the high overpotentials and sluggish reaction kinetics associated with the anode OER process are the major obstacles to the smooth progress of electrocatalytic water splitting. Amorphous electrocatalysts, a crucial family of functional materials, exhibit unexpected performance due to their special short‐range ordered and long‐range disordered atom arrangement, abundant defect sites and adjustable composition. To date, while numerous recent publications showcase promising results for transition metal‐based amorphous electrocatalysts, including amorphous metal phosphide and metal hydroxide electrocatalysts with remarkable HER and OER properties respectively, the utilization of single‐function HER or OER catalysts tends to augment system complexity for water electrolysis, thereby escalating the cost of hydrogen production. In this regard, amorphous HER/OER bifunctional electrocatalysts are desired. In this review, we summarize the recent development on transition metal‐based amorphous catalysts for electrochemical water splitting. The design strategies for constructing HER/OER bifunctional transition‐metal‐based amorphous electrocatalysts are highlighted here, also including the exploration of relationship between catalyst structures and their remarkably improved performance. Finally, the possibilities of amorphous bifunctional catalysts for practical industrial applications are evaluated and future research direction are suggested.

Multiomics-Based Biocargo Components Analysis in Enterococcus faecium Membrane Vesicles.

Enterococcus spp. have been shown to have gastrointestinal tract protective functions; our recent results suggest that membrane vesicles (MVs) play an important role in the gastric protection of Enterococcus faecium (E. faecium). The specific function is determined by molecular compositions of MVs. To resolve biocargo components in E. faecium MVs (EfmMVs), MVs were isolated from E. faecium culture. Transcriptomics, label-free quantitative proteomics, and untargeted metabolomics were performed to obtain information about the complexity of ribonucleic acids (RNAs), proteins, and metabolites biocargo they carry, respectively. RNA-sequencing identified a total of 2122 transcripts. The top 20 transcripts accounted for 27.63% of total counts, which, including enzymes, participate in glycolysis, ribosomal proteins, DNA-directed RNA polymerases, protein-synthesizing relative enzymes, molecules associated with protein post-translational processing and transport, and peptidoglycan lyases. Label-free quantitative proteomics analysis identified a total of 711 proteins. The top 20 proteins accounted for 48.02% of all identified proteins, which including ribosomal proteins, enzymes participate in glycolysis, DNA-directed RNA polymerases, protein-synthesizing relative enzymes, peptidoglycan lyases, and autolysin. Untargeted metabolomics analysis identified a total of 519 metabolites. The top 20 metabolites accounted for 79.55% of all identified metabolites, which included amino acids, substrates, or products in the metabolism of amino acids, natural organic acids, products in the metabolism of organic acids, ketone compounds, and two other compounds. Gene Ontology and Kyoto Encyclopedia of Genes and Genomes pathway analyses indicated that the identified biocargo components enriched in metabolism, genetic, and environmental information processing. Overall, we hope that the current exploration of multiple "-omics" analyses of this EfmMVs will provide useful information and further groundwork for future studies on E. faecium application.

Finite groups with some σ-primary subgroups weakly m-ℋ-permutable

Let σ = { σ i | i ∈ I } be some partition of the set of all primes P , G a finite group and σ ( G ) = { σ i | σ i ∩ π ( G ) ≠ ∅ } . A set H of subgroups of G is said to be a complete Hall σ-set of G if every nonidentity member of H is a Hall σi -subgroup of G for some i and H contains exactly one Hall σi -subgroup of G for every σ i ∈ σ ( G ) . Let H be a complete Hall σ-set of G. A subgroup H of G is said to be H -permutable if HA = AH for every member A ∈ H ; m- H -permutable if H = 〈 A , B 〉 for some modular subgroup A and H -permutable subgroup B of G; weakly m- H -permutable in G if there exists a σ-subnormal subgroup T of G such that G = HT and H ∩ T ≤ S ≤ H for some m- H -permutable subgroup S of G. In this paper, we study the structure of finite groups G by assuming that some σ-primary subgroups are weakly m- H -permutable in G. Some recent results are generalized and unified.

Improved delay-dependent stability analysis of digital filters with generalized overflow arithmetic

This paper introduces a new set of conditions that establish Input-to-State Stability (ISS) for digital filters with external disturbance input and time-varying delays, all within the context of generalized overflow arithmetic. A unique augmented Lyapunov function and a novel summation inequality are applied to formulate a new criterion for ISS. This criterion assesses the ISS of digital filters in the presence of external disturbance, enabling the identification of asymptotic stability even in the absence of such disturbance. The criteria are developed using linear matrix inequalities (LMIs). The efficacy of the results is demonstrated through three numerical examples, highlighting that the proposed criteria are less conservative than some recent results.

(Invited) Core-Multi-Shell Design: Unlocking Multimodal Capabilities in Lanthanide-Based Nanoparticles

The remarkable optomagnetic properties of the lanthanides (Ln) make Ln-based materials ideal for biomedical applications, including diagnostic (e.g., imaging, nanothermometry) and therapeutic (e.g., drug delivery, photodynamic therapy) approaches. This is due the unique electronic properties of the f-elements allowing for upconversion and near-infrared emission under near-infrared excitation as well as high magnetic moments. Yet, challenges remain, including low emission intensity and efficiency of small nanoparticles (NPs), and reliable, fast synthesis routes. As material chemists, we tackle these challenges with new designs of Ln-NPs by chemically controlled synthesis, application-oriented surface chemistry, and understanding of structure-property-relationships. We developed a straightforward and rapid microwave-assisted synthesis approach towards core-multi-shell Ln-NPs. Careful architecture design and choice of RE3+ dopant ions allow to tune the optical properties of the resultant nanoparticles, i.e., upconversion and near-infrared emission. This presentation will shed light on recent results with respect to microwave-assisted synthesis of Ln-NPs as well as structural and optomagnetic properties, seeking biomedical application.For instance, multimodal bioimaging probes merging optical imaging, magnetic resonance imaging (MRI), and X-ray computed tomography (CT) capabilities have attracted considerable attention due to their potential biomedical applications. This includes nanoparticles that combine upconverting Er3+/Yb3+ and magnetic NaDyF4 for optical/T2-weighted MRI/CT multimodal capabilities. A known drawback of multimodal probes that merge the upconverting Er3+/Yb3+ ion pair with magnetic Dy3+ ions for T2-weighted MRI is the loss of upconversion emission due to Dy3+ poisoning. The synthesis of controlled nanoparticle architectures with tuned inner NaGdF4 shell thicknesses separating Dy3+ and Er3+/Yb3+ allow to shed light on this distance-dependent loss of upconversion due to Yb3+ → Dy3+ energy transfer. As a result, the Ln-NP architecture was tuned to not only restore but enhanced the upconversion emission. In addition to multimodal imaging, Ln-NPs are promising candidates for application in nanothermometry due to the distinct, temperature-induced changes in their spectral features. We seek the development of novel Ln-NP nanothermometers for new opportunities in the near-infrared biological transparency windows (1000 to 2000 nm), by doping RE3+ ions, such as Er3+ and Tm3+ as well as unconventional Pr3+, into core-multi-shell lanthanide-based nanoparticles.

(Invited) Distance Dependent Electron Transfer Kinetics in Water Soluble Axially Connected Silicon Phthalocyanine-Fullerene Conjugates

The effect of donor-acceptor distance in controlling the rate of electron transfer in axially linked silicon phthalocyanine – C60 dyads has been investigated. Herein we will presented the synthesis and photophysical properties of two water soluble C60-SiPc-C60 dyads, 1 and 2, varying in their donor-acceptor distance.In previous investigation for C60-SiPc-C60 dyads where the SiPc and C60 are separated by a phenyl spacer, faster electron transfer was observed with k cs equal to 2.7 x 109 s-1 in benzonitrile. However, in the case of C60-SiPc-C60, where SiPc and C60 are separated by a biphenyl spacer, a slower electron transfer rate constant, k cs equal to 9.1 x108 s-1 was recorded. The addition of an extra phenyl spacer in 2 increased the donor-acceptor distance by ~ 4.3 Å, and consequently, slowed down the electron transfer rate constant by a factor of ~3.7. The charge separated state lasted over 3 ns, monitoring time window of our femtosecond transient spectrometer. Complimentary nanosecond transient absorption studies revealed formation of 3SiPc* as the end product and suggested that the final lifetime of charge separated state to be in the 3-20 ns range. Energy level diagram established to comprehend these mechanistic details indicated that the comparatively high-energy SiPc .+ -C60 .- charge separated states (1.57 eV) to populate the low-lying 3SiPc* (1.26 eV) prior returning to the ground state.[1]Here we will present our recent results using water soluble SiPc-C60 1-2 systems where the SiPc is substituted with pyridine units.[3]AcknowledgmentsThis work was supported by the Ministerio de Ciencia e Innovación of Spain and FEDER funds (Grants PID2020-117855RB-I00 to ASS) and National Science Foundation (Grant No. 1401188 and 2000988 to FD).References L. Martín-Gomis, S. Seetharaman, D. Herrero, P. A. Karr, F. Fernández-Lázaro, F. D’Souza, and Á. Sastre-Santos, Chem Phys. Chem., 2020, 21, 2254-2262.V. Sobrino, L. Martín-Gomis, S. Seetharaman, P. A. Karr, D’Souza, and Á. Sastre-Santos, under preparation. Figure 1

(Invited) CA Hydrogen Hub and Advanced Electrolysis R&D at LBNL

Widespread use of hydrogen energy is contingent on the development of reliable and economical sources of hydrogen. This is seen in DOE’s Hydrogen Energy Earthshot goal of production of hydrogen of $1 per 1 kg in 1 decade, as well as the Regional Hydrogen Hub Program. Endemic to reaching these cost metrics using renewable, clean electricity as a feedstock is the use of electrolysis. Prime among the electrolysis technologies are those utilizing ion-conducting polymers (ionomers) including polymer-electrolyte water electrolyzer (PEWE), high-temperature solid-oxide electrolyzer (SOEC), and those using liquid alkaline systems (LAWE). However, these technologies need to exhibit increased efficiency, (dynamic) performance, and durability to reduce costs and be commercially viable. In this talk, we will overview some of these technologies through the lens of recent advances at Lawrence Berkeley National Laboratory.In addition, key to enabling a hydrogen ecosystem is the deployment of various hydrogen technologies at scale in resilient and sustainable system. Recently, the Alliance of Renewable Clean Hydrogen Energy Systems (ARCHES), a collective representing the CA region, was selected for negotiation with DOE as a hydrogen hub. In this talk, an overview of ARCHES and its approach will be given.Finally, like most electrochemical devices, PEWEs involve multiple components (e.g., catalyst, ionomer, transport layers, membrane, plates) and multiple phases, with phenomena occurring across different time and length scales. Key in PEWE technologies is the interface between the ionomer and the catalyst. In this talk, time-permitting, recent results from the Center for Ionomer-based Water Electrolysis (CIWE) will be introduced including the description of interfacial properties and double layers at this interface.