Reaction Of Isonitriles Research Articles

Silaaziridines from the reaction of isonitriles with stable silenes

Stable silenes of the family (Me 3 Si) 2 Si=C-(OSiMe 3 )R react with isonitriles R'N=C: to yield unstable silacyclopropanimines which rapidly rearrange below room temperature to form the isomeric silaaziridines, as shown by the crystal structure of one of the compounds (R=Ad, R'=t-Bu). These are the first reported examples of three-membered rings containing both silicon and nitrogen

イソニトリルの化学 α‐イソシアノ酢酸誘導体を用いた合成反応

This review deals with the synthetic utilization of the isonitrile compounds ; in particular, the article focuses on the reaction of isonitrile- stabilized carban ions with an array of electrophiles. Emphasis has made on the syntheses of biologically interesting α-amino acids and heterocycles using α-isocyanoacetic acid derivatives as an “anionic amino acid synthon”.

Reaction of Isonitriles with Acids

Journal für Praktische ChemieVolume 324, Issue 4 p. 667-668 Arbeitsvorschriften und Meßergebnisse Zur Reaktion von Isonitrilen mit Säuren†Reaction of Isonitriles with Acids Dr. sc. J. Gloede, Dr. sc. J. Gloede Zentralinstitut für Organische Chemie der Akademie der Wissenschaften der DDR, DDR-1199 Berlin-Adlershof, Rudower Chaussee 5Search for more papers by this author Dr. sc. J. Gloede, Dr. sc. J. Gloede Zentralinstitut für Organische Chemie der Akademie der Wissenschaften der DDR, DDR-1199 Berlin-Adlershof, Rudower Chaussee 5Search for more papers by this author First published: 1982 https://doi.org/10.1002/prac.19823240424Citations: 8 † Herrn Prof. Dr. Dr. h. c. mult. Alfred Rieche zum 80. Geburtstag gewidmet AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat No abstract is available for this article.Citing Literature Volume324, Issue41982Pages 667-668 RelatedInformation

Reaction of isonitriles with perfluoromethacrylic acid derivatives

The amide and ester of perfluoromethacrylic acid easily add isonitriles to give the 1,4-cycloaddition adducts.

Reaction of isonitriles with?,?-unsaturated ketones

1. Trifluoromethyl β, β-dimethylvinyl ketone enters with isonitriles into the uncatalyzed l,4-dipolar cycloadditional reaction. 2. It was established for dimethyltrifluorolevulinic acid and its derivatives that the cyclic forms are more stable than the unfluorinated analogs.

Reaction of isonitrile with nitroalkene

The novel reaction of isonitrile ( 2) with nitroalkene ( 1) to produce isocyanate and α-cyano-α-substituted acetamide ( 3) is described. This involves the oxidation of 2 with 1. In the reaction of 1b and 2b, the primary product 3bb further reacted with 1b to give the Michael adduct 4bb.

Reaction of isonitriles with thallium(III) nitrate: an effective synthesis of carbamates.

Reaction of isonitriles with thallium(III) nitrate: an effective synthesis of carbamates.

A new method of synthesizing aminosugar derivatives

A new method of synthesizing aminosugar derivatives based on the condensation reaction of isonitriles with the ammonium salts of carbohydrates is proposed.