The heteroatom-doped carbon nanomaterials can be the active catalysts in hydrogen transfer reactions, however, carbon-catalyzed hydrogen transfer processes in the absence of additives and cocatalysts have been rarely described. Herein, functional biochar catalysts (FBCs) were successfully fabricated from wheat straw by a simple scalable two-step strategy via reconstructing the catalytic active sites in carbon precursors and subsequently controlled carbonization. The characterization of FBCs was discussed with regard to morphologic structures, chemical constitutions and performance, revealing that the high hydrophobicity is beneficial for obtaining high activity. Wherein the optimized FBC-850 catalyst exhibited high activity and durability toward the reaction of N-heterocycles and nitrobenzene in the aqueous systems due to the synergistic effects that were attributed to the external superhydrophobicity, internal capillary repulsion and hydrogen transfer property, eliminating the need for additional co-catalysts or additives. In the model reaction, the yields of quinoline and aniline were respectively achieved at 92% and 90%. Furthermore, the encapsulated quinone units as the active sites in FBC-850 formed the bipyramidal structure, enabling the hydrogen transfer process through a cyclical hydrogen exchange, which was proved from kinetic studies combined with spectral characterization and theoretical calculation. In addition, a possible reaction mechanism was proposed based on the observation of key intermediates and DFT calculations, also providing a rationale for the existing active site structures.