Reaction Of Diazonium Salts Research Articles

Reaction of onium salts with nucleophilic reagents

1. The reaction of iodonium and diazonium salts with tertiary amines includes the step of a one-electron transfer from the amine molecule to the onium compound. 2. The reaction of iodonium and diazonium salts with alcoholates also proceeds as a reaction of a one-electron transfer.

Reaction of diazonium salts with nucleophiles. XVII. Reaction of p-phenylenebisdiazonium ion with alcohols

Reaction of diazonium salts with nucleophiles. XVII. Reaction of p-phenylenebisdiazonium ion with alcohols

Crystal structure of an iridium-tetrazene complex formed in the reaction of diazonium salts with trans-chlorocarbonylbis(triphenylphosphine)iridium(I)

Crystal structure of an iridium-tetrazene complex formed in the reaction of diazonium salts with trans-chlorocarbonylbis(triphenylphosphine)iridium(I)

Reactions of diazonium salts with nucleophiles. XIV. Rearrangement of isotopically labeled diazonium salts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReactions of diazonium salts with nucleophiles. XIV. Rearrangement of isotopically labeled diazonium saltsEdward S. Lewis and Robert E. HollidayCite this: J. Am. Chem. Soc. 1969, 91, 2, 426–430Publication Date (Print):January 1, 1969Publication History Published online1 May 2002Published inissue 1 January 1969https://doi.org/10.1021/ja01030a037RIGHTS & PERMISSIONSArticle Views263Altmetric-Citations27LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (686 KB) Get e-Alerts Get e-Alerts

Reaction of diazonium salts with nucleophiles. XIII. Identity of the rate- and product-determining steps

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReaction of diazonium salts with nucleophiles. XIII. Identity of the rate- and product-determining stepsEdward S. Lewis, Levoy D. Hartung, and Bruce M. McKayCite this: J. Am. Chem. Soc. 1969, 91, 2, 419–425Publication Date (Print):January 1, 1969Publication History Published online1 May 2002Published inissue 1 January 1969https://doi.org/10.1021/ja01030a036RIGHTS & PERMISSIONSArticle Views286Altmetric-Citations25LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (813 KB) Get e-Alerts Get e-Alerts

Reaction of diazonium salts with nucleophiles. XII. Equilibria, rates, and mechanisms in the acidification of anti-diazotates

Reaction of diazonium salts with nucleophiles. XII. Equilibria, rates, and mechanisms in the acidification of anti-diazotates

The Reactions of Diazonium Salts with Nucleophiles. X. A Tracer Demonstration of the Reversible Step in Diazonium Ion Hydrolysis

The Reactions of Diazonium Salts with Nucleophiles. X. A Tracer Demonstration of the Reversible Step in Diazonium Ion Hydrolysis

The Kinetic Study of the Coupling Reaction of Aromatic Diazonium Salts with Malonaldehyde

芳香族ジアゾニウム塩のマロンアルデヒドへのカップリング反応を,いろいろなPHの緩衝溶液中で速度論的に研究した。反応速度は両成分の濃度積に比例し,2分子反応速度式を満足する。PH約4以下では次式が成立し,pH1単位の増加により速度定数K'は10倍になる。logK'=logK-pKEH+PHpHがこれより大きくなると々は一定値に近づき,上式は成立しなくなる。K'が反応溶液のpHによって変化するのは,β-オキシアクロレイン(マロンアルデヒドの互変異牲形)の解離によって生じるエノラートイオン濃度がpHによって変わるためであり,解離度の対数log aとpHとの関係を示す理論曲線の形状は,実測したlog k'/pH曲線とよく一致する。したがって反応はβ-オキシアクロレインのエノラートイオンにジアゾニウムイオンがカップリングすると結論される。

The Reaction of Diazonium Salts with Nucleophiles. VIII. The Formation of Diazosulfones and the Application of Linear Free Energy Equations to Diazonium Salt Reactions1

The Reaction of Diazonium Salts with Nucleophiles. VIII. The Formation of Diazosulfones and the Application of Linear Free Energy Equations to Diazonium Salt Reactions¹

The Reactions of Diazonium Salts with Nucleophiles. VII. p-Phenylene-bisdiazonium Ion1,2

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Reactions of Diazonium Salts with Nucleophiles. VII. p-Phenylene-bisdiazonium Ion1,2Edward S. Lewis and Michael D. JohnsonCite this: J. Am. Chem. Soc. 1960, 82, 20, 5408–5410Publication Date (Print):October 1, 1960Publication History Published online1 May 2002Published inissue 1 October 1960https://doi.org/10.1021/ja01505a028RIGHTS & PERMISSIONSArticle Views319Altmetric-Citations5LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (411 KB) Get e-Alerts Get e-Alerts

The Reactions of Diazonium Salts with Nucleophiles. V. the Substitution of Halogen by Thiocyanate1

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Reactions of Diazonium Salts with Nucleophiles. V. the Substitution of Halogen by Thiocyanate1Edward S. Lewis and Harald SuhrCite this: J. Am. Chem. Soc. 1960, 82, 4, 862–866Publication Date (Print):February 1, 1960Publication History Published online1 May 2002Published inissue 1 February 1960https://doi.org/10.1021/ja01489a025RIGHTS & PERMISSIONSArticle Views258Altmetric-Citations5LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (608 KB) Get e-Alerts Get e-Alerts

Mechanisms of Diazonium Salt Reactions. VI. The Reactions of Diazonium Salts with Alcohols under Acidic Conditions; Evidence for Hydride Transfer1

Mechanisms of Diazonium Salt Reactions. VI. The Reactions of Diazonium Salts with Alcohols under Acidic Conditions; Evidence for Hydride Transfer¹

A study of the mechanism of the Sandmeyer reaction

The one-electron-transfer mechanism for the Sandmeyer reaction, proposed by W. A. Waters in 1942 has now been confirmed by diagnostic experiments. Its initial stage, Ar ·N + 2 + Cu + → Ar · + N 2 + Cu 2+ , has been shown to produce free aryl radicals capable of initiating vinyl polymerization; this observation is also true for related reactions of diazonium salts for which analogous one-electron-transfer mechanisms have been suggested. The cupric ions thus produced are oxidizers that, like ferric ions, can effect chain-ending of vinyl polymerization. They bring about the final step in the Sandmeyer reaction by a similar process that apparently involves chlorine atom transfer; Ar · + Cl—Cu—Cl → Ar —Cl + Cu—Cl. Product studies show that cupric ions are needed to enable the Sandmeyer reaction to give aryl chlorides in high yield; in their absence other reactions of aryl radicals can occur extensively. Molecular weight measurements with acrylonitrile polymers indicate that in dilute solution up to 35% of the initial aryldiazonium cations can produce free aryl radicals by interaction with cuprous ions in chloride solutions, but that in more concentrated solutions the secondary reaction with the cupric chloride generated occurs so extensively that the full cycle of the Sandmeyer reaction becomes predominantly an intramolecular process.

The Mechanisms of Diazonium Salt Reactions. IV. A Kinetic Study of the Reactions of Benzenediazonium Fluoborate with Methanol in the Absence of Oxygen

The Mechanisms of Diazonium Salt Reactions. IV. A Kinetic Study of the Reactions of Benzenediazonium Fluoborate with Methanol in the Absence of Oxygen

The Mechanisms of Diazonium Salt Reactions. II. A Redetermination of the Rates of the Thermal Decomposition of Six Diazonium Salts in Aqueous Solution1

The Mechanisms of Diazonium Salt Reactions. II. A Redetermination of the Rates of the Thermal Decomposition of Six Diazonium Salts in Aqueous Solution¹

The Mechanisms of Diazonium Salt Reactions. V. A Kinetic Study of the Reactions of Benzenediazonium Fluoborate with Methanol in the Presence of Oxygen

The Mechanisms of Diazonium Salt Reactions. V. A Kinetic Study of the Reactions of Benzenediazonium Fluoborate with Methanol in the Presence of Oxygen

The Mechanisms of Diazonium Salt Reactions. I. The Products of the Reactions of Benzenediazonium Salts with Methanol

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Mechanisms of Diazonium Salt Reactions. I. The Products of the Reactions of Benzenediazonium Salts with MethanolDeLos F. DeTar and Melvin N. TuretzkyCite this: J. Am. Chem. Soc. 1955, 77, 7, 1745–1750Publication Date (Print):April 1, 1955Publication History Published online1 May 2002Published inissue 1 April 1955https://doi.org/10.1021/ja01612a008RIGHTS & PERMISSIONSArticle Views1324Altmetric-Citations47LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (798 KB) Get e-Alerts Get e-Alerts

The reaction of diazonium salts with α-aceto-γ-lactones

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The reaction of diazonium salts with 1-aryl-Δ2-pyrazolines

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The Reaction of Diazonium Salts with Alcohols

The Reaction of Diazonium Salts with Alcohols