Entry to the Chemistry of Simple Rhenium Sulfur Complexes and Clusters. Preparation and Crystal Structures of R′[ReS4], R′[ReS9], (NH4)4[Re4S22]·2H2O, R′2[Cl2Fe(MoS4)FeCl2]1‐x, R′2[(ReS4)Cu3I4] and RR′2[(ReS4)Cu5Br7] (R NEt4; R′ PPh4, x = 0.3, 0.5)The compounds R[ReS4] (1), R′[ReS9] (2), (NH4)4[Re4S22]·2 H2O (3), R′2[Cl2Fe(MoS4) FeCl2]x[Cl2Fe(ReS4)FeCl2] 1‐x (x = 0.3 (4), 0.5), R′2[(ReS4)Cu3I4] (5) and R′2[(ReS4)Cu5Br7] (6) (R NEt4; R′ PPh4) have been prepared by reaction of perrhenates or rhenium(VII)oxide with Sx2− solutions (under different conditions) or by reactions of metal‐halides with [ReS4]−‐ions. All compounds have been characterized by complete X‐ ray structure analysis. For further details see Inhaltsübersicht.
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