Raw Rice Husk Research Articles

Enhancing Rice Seedling Growth in Acidic Soil Using Fermented Raw Rice Husk as Soil Amendment

Enhancing Rice Seedling Growth in Acidic Soil Using Fermented Raw Rice Husk as Soil Amendment

Optimized Furfural Production Using the Acid Catalytic Conversion of Xylan Liquor from Organosolv-Fractionated Rice Husk

This study determined the optimal production of furfural (FuR) from liquid hydrolysate xylan liquor obtained through a two-stage pretreatment process using NaOH for de-ashing and EtOH for the delignification of raw rice husk (RH). The de-ashing pretreatment was conducted at 150 °C, with 6.0% (w/v) NaOH and a reaction time of 40 min. The optimal conditions for delignification pretreatment, performed using an organosolv fractionation method with EtOH, were a reaction temperature of 150 °C, 60% (v/v) EtOH, 0.25% (w/v) H2SO4, and a reaction time of 90 min. Through a two-stage pretreatment process, a liquid hydrolysate in the form of xylan liquor was obtained, which was subjected to an acid catalytic conversion process to produce FuR. The process conditions were varied, with reaction temperatures of 130–170 °C, H2SO4 catalyst concentrations of 1.0–3.0 wt.%, and reaction times of 0–90 min. The Response Surface Methodology tool was used to identify the optimal FuR yield from xylan liquor. Ultimately, the optimal process conditions for the acid catalytic conversion were found to be a substrate-to-catalyst ratio of 2:8, a reaction temperature of 168.9 °C, a catalyst concentration of 1.9 wt.%, and a reaction time of 41.24 min, achieving an FuR yield of 67.31%.

OPTIMIZATION OF THE EXTRACTION AND PREPARATION OF CELLULOSE MICROFIBERS FROM RICE HUSK USING A FULL FACTORIAL EXPERIMENT

Cellulose is one of the most abundant biopolymers on Earth and is of most significant interest due to its properties and uses. Cellulose can be obtained from agro-industrial residues, such as rice husk, whose cellulose content is approximately 30%. In this study, cellulose microfibers were extracted from rice husks. Fibers were obtained by submitting the biomass to alkali (NaOH) and bleaching treatments. These treatments have already been reported in the literature; however, variables such as the concentration of reagents, the time, and the temperature of the chemical treatment have yet to be optimized. A factorial design of experiments with 3 factors and 2 levels for each factor was proposed to optimize the chemical processes. It was determined through the analysis of variance (ANOVA) that the factors evaluated significantly influenced the elimination of non-cellulosic compounds, and that the chemical treatment was more efficient when the factors took high level values. Ultraviolet-visible spectroscopy (UV-Vis) analysis showed the successful removal of undesired components during the alkaline treatment. The effect of the treatments on the morphology upon removing hemicelluloses, lignin, and inorganic material was evaluated through Scanning Electron Microscopy (SEM). The increase in the thermal stability in the alkali-treated rice husk and in cellulose microfibers, compared to the raw rice husk, was established by thermogravimetric analysis (TGA). X-ray diffraction (XRD) indicated that the treatments increased the percentage of crystallinity.

Valorisation of Rice Husk and Bubble Wrap Plastic Waste through Co-Torrefaction to Optimise Biochar Production

Rice husk is one of the highest generated agricultural waste estimated to be 11.1-13.8 million tons in Indonesia in 2021. This quantity makes rice husk a potential biomass for conversion into energy to minimize the negative impacts of current processing methods, such as open-burning and mulching. Torrefaction was conducted at 300°C for 30 minutes in this study to enhance the characteristics of biomass fuel by producing biochar with improved combustion properties. The biochar produced from torrefaction of rice husk has a calorific value of 15.04 MJ/kg with a volatile matter content of 42.94% and fixed carbon content of 17.94%. Despite this improvement compared to raw rice husk, this biochar tends to have a relatively high mass loss, with a mass yield of only 54%. Therefore, the addition of LDPE plastic feedstock in the form of bubble wrap was carried out up to 50% of the feedstock mass, resulting in further optimization at the RH50 variation, which increased the calorific value to 19.98 MJ/kg and mass yield to 72%. These changes were statistically tested and found to be significant, indicating that torrefaction is a promising technology for rice husk processing, and bubble wrap in this study can significantly contribute to enhancing the characteristics of rice husk as a renewable fuel source.

Petroleum-contaminated soil bioremediation and microbial community succession induced by application of co-pyrolysis biochar amendment: An investigation of performances and mechanisms

This study aimed to remediate petroleum-contaminated soil using co-pyrolysis biochar derived from rice husk and cellulose. Rice husk and cellulose were mixed in various weight ratios (0:1, 1:0, 1:1, 1:3 and 3:1) and pyrolyzed under 500 °C. These biochar variants were labeled as R0C1, R1C0, R1C1, R1C3 and R3C1, respectively. Notably, the specific surface area and carbon content of the co- pyrolysis biochar increased, potentially promoting the growth and colonization of soil microorganisms. On the 60th day, the microbial control group achieved a 46.69% removal of pollutants, while the addition of R0C1, R1C0, R1C3, R1C1 and R3C1 resulted in removals of 70.56%, 67.01%, 67.62%, 68.74% and 67.30%, respectively. In contrast, the highest efficiency observed in the abiotic treatment group was only 24.12%. This suggested that the removal of petroleum pollutants was an outcome of the collaborative influence of co-pyrolysis biochar and soil microorganisms. Furthermore, the abundance of Proteobacteria, renowned for its petroleum degradation capability, obviously increased in the treatment group with the addition of co-pyrolysis biochar. This demonstrated that co-pyrolysis biochar could notably stimulate the growth of functionally associated microorganisms. This research confirmed the promising application of co-pyrolysis biochar in the remediation of petroleum-contaminated soil.

Artificial Neural Network [ANN] modeling for tetracycline adsorption on rice husk using continuous system

In this work, Tetracycline (TC) was dynamically adsorbed from aqueous solution using Raw Rice Husk (RRH). The removal of TC from various aqueous solutions was done continuously using a fixed bed column that was filled with RRH. It was investigated how various flowrates, bed heights, and TC concentrations impact the performance of the adsorption breakthrough. The dynamic TC adsorption process was modeled using an artificial neural network (ANN). Various error analysis techniques, such as the correlation coefficient, mean square error (MSE), and error histogram (R2) for the training, testing, and validation data, were employed to compare the model's predicted data with experimental data. The Artificial Neural Network (ANN) model that was utilized to predict TC adsorption using raw rice husk demonstrated a robust correlation coefficient of 0.999, This shows how well the trained model performed in predicting the TC adsorption process.

Cellulose nanocrystals extracted from rice husk using the formic/peroxyformic acid process: isolation and structural characterization.

Cellulose derived from biomass is a renewable resource with numerous applications. Using formic/peroxyformic acid at atmospheric pressure, cellulose nanocrystals (CNC) were isolated from rice husk (RH) in this study. This method was an excellent way to get rid of lignin and hemicelluloses from RH. The cellulose was subsequently acid hydrolyzed by H2SO4 (64%) for 30 minutes at 45 °C. The chemical and microstructure analysis showed that the lignin and hemicellulose contents of raw RH had been eliminated, and the crystallinity content of CNC was 67.16%. According to transmission electron microscopy (TEM) morphological analysis, CNC measured 19 ± 3.3 nm in diameter, 195 ± 24 nm in length, and 10.2 ± 6.8 in aspect ratio. The thermal stability of RH and CNC was also investigated using thermogravimetric analysis (TGA). These encouraging findings demonstrated the potential for reusing RH agricultural waste to create CNC and include nanocomposites as a reinforcing material.

Rice hull-based substrates and the influence of the type of transplant and the age of the plant on the strawberry culture

The soilless growing of strawberries using local materials as a substrate is an alternative to reduce costs and reuse waste. The objective of this work was to evaluate the growth and yield of strawberry plants cultivar Aromas, originated from bare root and plug plants, as well as second-year plants in comparison to first-year plants, in substrates formulated with raw rice husk (RRH) and two types of conditioners [carbonized rice husk (CRH) and commercial substrate (S10)]. The experimental factors consisted of four substrates [RRH (100%), RRH + CRH (80 %: 20 %), RRH + S10 (80 %: 20 %), and RRH + CRH + S10 (80 %:10 %:10 %)], two types of transplants (plug plants and bare-root), and the maintenance of second-year plants in comparison to first-year plants. For the first year of growing, regardless of the substrate, plug plants showed greater growth and yield, providing an increase of 62.1 % in the commercial yield of plug plants in relation to the growing of bare-root transplants. As for the growing of bare-root transplants, the addition of CRH and its simultaneous use with commercial substrate S10 as RRH conditioners increased plant growth. However, fruit yield gains were less expressive and clear positive responses for this variable were obtained only with the simultaneous use of CRH and the commercial substrate S10. The results obtained in the second experiment indicate that second-year plants, on mean, showed greater vegetative growth, number and yield of fruits, however, with lower mean weight of fruits than the plants of the first year. First year plants showed superior commercial yield in the RRH + S10 substrate.

Influence of Thermal and Chemical Treatment on Biosorbent from Rice Husk and Its Application in Removal of Resorcinol from Industrial Wastewater

The removal of phenolic compounds is of great importance because of their toxic nature and potentially harmful effects on the environment and human health. This study examines the use of rice husk as a biosorbent for eliminating phenolic compounds, particularly resorcinol, from industrial wastewater. Three types of rice husk, namely raw rice husk (RRH), chemically treated rice husk (CTRH), and thermally treated rice husk (TTRH), are utilized after grinding and methanol treatment. Characterization techniques including X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and optical microscopy are used to analyze the rice husk-based adsorbents. The microscopic analysis reveals the presence of nano-pores in TTRH and the existence of carbonyl and hydroxyl groups in all sorbent samples. XRD analysis confirms the presence of silica in biosorbents. This study also examines the influence of dosage and initial concentration on resorcinol sorption. Optimized dosages of 0.5 g (RRH), 0.5 g (CTRH), and 1.5 g (TTRH) result in sorption capacities of 14 mg/g (RRH), 11 mg/g (CTRH), and 5 mg/g (TTRH). Isotherm analysis indicates that the Langmuir isotherm best describes the sorption behavior of TTRH, while the Freundlich isotherm is observed for CTRH, and both RRH and CTRH follow the Temkin isotherm.

Pharmaceutical adsorption on NaOH-treated rice husk-based activated carbons: Kinetics, thermodynamics, and mechanisms

This study aims to explore the adsorption behavior of four pharmaceuticals: ciprofloxacin (CIP), sulfamethoxazole (SUL), diclofenac (DIC), and acetaminophen (ACE) on activated carbons produced from rice husk using different NaOH-based protocols at 800 °C. The main objective is to assess and compare the efficiency of activated carbons synthesized by solid-solid and wet treatment methods on pharmaceutical adsorption. All three activated carbons displayed strong affinity towards pharmaceutical adsorption, but the material produced with wet protocol after the carbonization process demonstrated the highest adsorption capacity and the lowest equilibrium time (15 min) due to its superior textural properties and higher surface area (1671 ± 31 m2 g−1). Further investigation of pharmaceutical adsorption in synthetic urine was carried out using the mentioned material. The results revealed that in both mono and multicomponent systems, CIP, SUL, and DIC did not exhibit any significant competition with each other or with the urine matrix. However, ACE showed competition for adsorption sites. For both CIP and ACE, the diffusion boundary layer and the adsorption process were identified as the velocity-limiting steps for adsorption in urine. To better understand the adsorption mechanism, both experimental and computational tools were employed. The results revealed that ACE exhibited typical Langmuir-like adsorption behavior with an exothermic nature on the mentioned material with an adsorption capacity of 209.6 ± 5.6 mg g−1. Regarding CIP, its adsorption displayed a non-typical endothermic nature, which was attributed to steric hindrance due to its zwitterionic structure and the porosity in the adsorbent. Analyzing the combination of Redlich-Peterson and Langmuir models with computational analysis supported this finding. However, the material exhibited an impressive adsorption capability of 584.4 ± 21.5 mg g−1. The parameter φ (cncreased cost associated with enhancing the adsorption process) revealed an augmentation in adsorption capacities of 45.1 and 125.6 mg USD−1 for ACE and CIP, respectively, compared to the raw rice husk. This research underscores the prospect of employing agricultural and industrial byproducts to create activated carbons capable of efficiently extracting pharmaceuticals from intricate mixtures, such as urine.

Raw Rice Husk Biochar as a Potential Valuable Industrial Byproduct for the Removal of Rhodamine B from Water

In this work, raw rice husk biochar (RRHB) was investigated for its potential as a valuable industrial byproduct for the decontamination of water using rhodamine B (RB) as a model pollutant. Specific functional chemical groups that were identified in the structure of the biochar using Fourier transform infrared (FTIR) spectra were determined to be responsible for the interaction between the biochar and the pollutant, explaining the sorption process. The interaction between the pollutant and biochar was also explained by the porosity of the sorbent, as demonstrated by scanning electron microscopy (SEM), and the specific surface area (Brunauer–Emmett–Teller analysis, BET). The ionic charge of the biochar structure was determined based on the point of zero charge (pHPCZ). The best kinetic fit for the sorption of the dye on/in the biochar was obtained with the nonlinear pseudo-second-order and Elovich models. The nonlinear Freundlich isotherm had the best fit to the experimental data, and it was determined that the maximum sorption capacity was ~40 mg g−1. The thermodynamic parameters indicated that the sorption of the RB on/in the RRHB was spontaneous. Overall, RRHB was demonstrated to be a potential biosorbent for cationic dyes such as RB. Finally, it is possible to recover the biosorbent, aggregating value to the byproduct and showing it to be an excellent option for use in water purification filters.

A SUSTAINABLE RAW RICE HUSK ADSORBENT FOR EFFECTIVE LEVOFLOXACIN REMOVAL FROM AQUEOUS SOLUTION: KINETIC, THERMODYNAMIC AND ISOTHERM STUDIES

Levofloxacin (LEV) is an important and widely used antibiotic. It is used to treat many bacterial infections. It may be found in water sources as a result of incomplete metabolism in humans and other sources. In this study, the adsorption of Levofloxacin by raw rice husk (RRH) was investigated. The effect of pH, time, temperature, RRH weight, and initial Levofloxacin concentration on the adsorption process were determined. Kinetic, isotherm and thermodynamic models were studied to explain the Levofloxacin adsorption mechanism on raw rice husk. The results of adsorption kinetics and isotherms revealed that the adsorption of LEV by RRH was better fitted with the Intraparticle model with coefficient of determination (R2=96%), while the Langmuir model represents the best isotherm model to describe the adsorption process with (R2 =95%). The removal efficiency reached 99% , the monolayer maximum uptake qmax is 2.47 mg/g and the adsorption intensity parameter (1/n) value is 0.763, which means that the adsorption is favorable. According to the thermodynamic coefficients, the adsorption process was spontaneous and feasible for the temperatures under investigation; the sorption efficiency was more favorable at higher temperatures, and the adsorption process is endothermic.

Soft computing techniques for predicting the properties of raw rice husk concrete bricks using regression-based machine learning approaches

In this study, the replacement of raw rice husk, fly ash, and hydrated lime for fine aggregate and cement was evaluated in making raw rice husk-concrete brick. This study optimizes compressive strength, water absorption, and dry density of concrete brick containing recycled aggregates via Response Surface Methodology. The optimized model's accuracy is validated through Artificial Neural Network and Multiple Linear Regression. The Artificial Neural Network model captured the 100 data's variability from RSM optimization as indicated by the high R threshold- (R > 0.9997), (R > 0.99993), (R > 0.99997). Multiple Linear Regression model captured the data's variability the decent R2 threshold confirming- (R2 > 0.9855), (R2 > 0.9768), (R2 > 0.9155). The raw rice husk-concrete brick 28-day compressive strength, water absorption, and density prediction were more accurate when using Response Surface Methodology and Artificial Neural Network compared to Multiple Linear Regression. Lower MAE and RMSE, coupled with higher R2 values, unequivocally indicate the model's superior performance. Additionally, employing sensitivity analysis, the influence of the six input parameters on outcomes was assessed. Machine learning aids efficient prediction of concrete's mechanical properties, conserving time, labor, and resources in civil engineering.

Analysis of The Susceptibility Value Dry Ink (Toner) From Raw Material Iron Sand Pasie Nan Tigo Beach and Rice Husk Biomass

The competition engaged in manufacture of the dry ink industry (toner) is increasing, with many types of dry ink (toner) emerging from various brands. This makes each brand compete to try to create quality dry ink. However, this is not easy, because raw material for making dry ink is expensive and stickiness of dry ink on the paper can change if the material is modified. The dry ink in this study was made by modifying the raw materials using natural mineral magnetic (Fe3O4) from the iron sand of Pasie Nan Tigo beach, activated carbon from rice husks biomass, and organic polymer Acacia Senegal. Taking into account the mixture of three raw materials in made of dry ink (toner) will affect the characteristics of dry ink (toner), one of the characteristics affected is the large content of magnetic minerals (Fe3O4) in it, it is necessary to test the value of susceptibility in dry ink (toner) to see the amount of magnetic minerals that are still present in the dry ink after mixing. The tool used for testing magnetic susceptibility values here is Bartington Magnetic Susceptibility MS2B. The purpose of this study is to produce quality dry ink with good dry ink paste power (toner) with based the characteristics of the susceptibility value of the dryink (toner). This research method uses extraction and coprecipitation methods and emulsion polymerization methods to increase the strength of the stickiness dry ink (toner) on paper. The results of characterization obtained by range 11924.60 x 10−8m3/kg until 27916.97 x 10−8m3/kg.

Investigating the effectiveness of rice husk-derived low-cost activated carbon in removing environmental pollutants: a study of its characterization

The chemically activated biochar was produced through the pyrolysis of rice husk. Thermal gravimetric and elemental analysis were conducted to characterize the raw rice husk. The activated biochar product underwent evaluation through SEM, BET and, FT-IR analysis. This cost-effective activated carbon was utilized as an adsorbent for the elimination of environmental pollutants. At a temperature of 25 °C, the activated biochar product exhibited an impressive maximum CO2 adsorption capacity of 152 mg/g. This exceptional performance can be attributed to its notable surface area and porosity, measuring at 2,298 m2/g and 0.812 cm3/g, respectively. This product was also utilized to remove methyl red (MR) dye from an aqueous solution. The optimal parameters for the removal of MR were determined as follows: a pH of 6.0, a temperature of 25 °C, an initial MR concentration of 50 mg/L, and an adsorbent dosage of 0.4 g/L. At a duration of 140 min, the system attained its maximum equilibrium adsorption capacity, reaching a value of 62.06 mg/g. Furthermore, the calculated maximum MR removal efficiency stood at an impressive 99.31%. The thermodynamic studies demonstrated that the MR removal process was spontaneous, exothermic, and increased randomness. Kinetic studies suggested that the pseudo-second-order model can fit well.

The use of rice husk in the substrate composition increases Pleurotus ostreatus mushroom production and quality

Rice husk is a waste generated in large quantities in various countries, although its reuse is limited due to low nutritional quality and high silica content. Therefore, this study sought to evaluate using raw or carbonized rice husks to partially substitute eucalyptus sawdust in substrates to produce the edible mushroom Pleurotus ostreatus. The substrates were formulated with proportions of 0 to 100% of eucalyptus sawdust and raw or carbonized rice husks. P. ostreatus was grown for 90 days on the substrates to evaluate mycelial growth, fresh mass production, biological efficiency, and protein and fat content. The organoleptic quality of the mushrooms produced was evaluated by sensory analysis. The substrates’ moisture, pH, and C and N contents were evaluated before and after cultivation. The substrates with 25 and 50% of raw or carbonized rice husk in a mixture with sawdust provided nitrogen and water more adequately to the fungus, improving the fresh mass production, the protein content of mushrooms, and biological efficiency (75–83%) compared to the reference substrate (100% eucalyptus sawdust), without altering the sensory quality. Given the environmental issues caused by carbonization, using raw rice husk in a mixture of up to 50% eucalyptus sawdust is recommended for P. ostreatus production.

Improvement of Higher Heating Value and Hygroscopicity Reduction of Torrefied Rice Husk by Torrefaction and Circulating Gas in the System

This study aimed to enhance the thermal characteristics of rice husk biomass through torrefaction conducted in a fixed-bed reactor. A novel approach was employed by circulating the gas produced within the system, instead of using traditional nitrogen. The torrefaction process took place at temperatures ranging from 200 to 320 °C, with different residence times of 10, 20, and 30 min for heat exchange. Quantitative analysis of the torrefied biomass revealed several notable improvements. The higher heating value of the biomass increased significantly, reaching 23.69 MJ/kg at a temperature of 320 °C and a residence time of 30 min. This enhancement indicates the effectiveness of torrefaction in increasing the energy content of the biomass. Furthermore, the torrefied biomass exhibited a remarkable reduction in hygroscopicity, with reduction by as much as 92 wt% compared to raw rice husk biomass. This reduction implies that the torrefied biomass is more resistant to moisture absorption, making it more stable and suitable for various applications. The torrefaction process in the fixed-bed reactor yielded a torrefied biomass with a production yield of 76 wt% (RH-320, RT30). This yield showcases the potential of the employed technique for producing a substantial amount of high-quality torrefied biomass. The resulting biomass holds great promise for diverse applications. It can be utilized for industrial steam production, contributing to the efficient use of biomass resources. Moreover, it could serve as an alternative fuel source for biomass power plants, offering a sustainable energy solution. Overall, this study demonstrates the effectiveness of the proposed torrefaction method in enhancing the thermal characteristics of rice husk biomass. The improved energy content and reduced hygroscopicity make torrefied biomass a valuable resource for various industries, promoting the utilization of biomass as a renewable energy source.

Applicability of Rice Husk Residue Generated by the Silica Extraction Process to Anaerobic Digestion for Methane Production

Rice husks are a feedstock of biogenic silica because of their high silica content. After silica extraction, a solid residue comprising mostly carbohydrates is present. Solid residue valorization is important for closed-loop systems using rice husk and has minimal negative environmental impacts. In this study, we used solid rice husk that was generated by silica extractionto anaerobic digestion for producing biomethane. The rice husk residue was characterized in terms of total solids, volatile solids, pH, composition, and particle size. Changing the characteristics increased biogas production by 2.48-fold compared to that of raw rice husk. The residue produced 166.4 mL-biogas g−1 vs. and 100.4 mL CH 4 g−1 VS, much more than previously reported. Microbial community analysis, which was conducted to investigate the biological reasons for increased biogas and methane, found increased Bacteroidetes levels in the rice husk samples. Among archaeal communities, Bathyarchaeota was more abundant in all rice husk samples than in the inoculum. The rice husk residue contained more operational taxonomic units than other samples. These changes in the microbial community significantly influenced the anaerobic digestion of the rice husk residue and improved methane production. Our findings provide a basis for the cleaner utilization of rice husk residue to produce renewable energy.

Enhancement in anaerobic biogas conversion by visible light photocatalytic Pre-treatment of rice husk with indium vanadate decorated titanium dioxide nanocomposite

Production of biogas from crop wastes via the biological route is one of the most demanding and promising technologies for energy generation for sustainable development. The incorporation of photocatalytic pretreatment as a robust catalytic technique has been reported to enhance the overall efficiency of the anaerobic process. Rice husk has been pretreated using Indium Vanadate decorated Titania nanocomposite to enhance its biodegradability for biogas production. Scanning electron microscopy confirmed the deformities and crevices that may support the role of the photocatalytic pretreatment in the subsequent anaerobic degradation process. FT-IR spectroscopy investigated the structural characteristics of pretreated and photolyzed rice husk samples. Gas chromatography was used to quantify the CH4 content of biogas yield after different treatments of rice husk. Photocatalytic pretreatment of rice husk showed 2.8 times higher cumulative biogas production than raw or untreated rice husk. Statistical analysis showed a significant difference between natural and pretreated rice husk biogas yield with a p-value of < 0.01. The results suggest that visible light active photocatalysis is an efficient pretreatment method that can facilitate the microbes to degrade the rigid rice husk for enhanced biogas production via the anaerobic digestion process.

Microporous melamine-formaldehyde networks loaded on rice husks for dynamic removal of organic micropollutants

The alteration of agricultural wastes into novel adsorbents can stimulate their scalability in realistic application, showing great economic and environmental advantages. Here, we proposed a strategy to engineer rice husk (RH) with microporous melamine-formaldehyde networks (MFNs) resins and the utilization for dynamic removal of organic micropollutants rapidly and efficiently. was pre-treated to acquire attractive surface and unique hierarchical porosity, endowing with surface functionalization and essential filtering properties. MFNs can be uniformly generated in-situ on the fully exposed cellulose backbones of the pre-treated RH. MFNs granules functionalized RH (RH@MFNs) exhibited high removal efficiencies over 90% within 30 min for the adsorption of hazardous organic compounds (e.g., phenolic and antibiotic micropollutants) in static tests. Experiment results and density functional theory (DFT) simulation revealed that the synergy of hydrogen bonding, π-πinteraction, and micropore preservation dominates the adsorption. Further dynamic adsorption experiments showed that the removal efficiency and equilibrium removal capacity towards bisphenol A by RH@MFNs packed bed up-flow column were 2.6 and 67 times higher than that of raw RH, respectively. The column adsorption fits well with the Thomas model and bed depth service time (BDST) kinetic model. The inherent macropores inside RH and the roughness caused by the spiky structures and mesopores outside RH, as well as the accumulated MFNs granules, can lead to local turbulence of water flow around RH@MFNs, enabling fast and efficient adsorption. This sustainable and cost-effective preparation of RH-based adsorbents sheds light on the rational design of biomass waste adsorbents for realistic wastewater.