Solvent Ratio Research Articles

Total Flavonoid Content and Antioxidant Properties of Different Extraction Methods of Red Spinach Leaf (Amaranthus tricolor L.)

Red spinach leaf (Amaranthus tricolor L.) has been well-proven to contain flavonoids that exhibit antioxidant activities. In this study, a comparison between maceration and ultrasonic methods has been carried out to evaluate the effect of these two methods on the level of red spinach leaf flavonoid. In this study, for maceration 1, 2, and 3 days while for the ultrasonic method 10-, 20-, and 30-minutes time duration have been used. The ratios of material and solvent were 1:5 and 1:10. The flavonoid content was determined with the help of a spectrophotometer at a maximum wavelength of 436.80 nm. The antioxidant activity was evaluated by the DPPH method to obtain the IC50. The result of the study revealed that the highest flavonoid content of 4.27 mgQE/g and antioxidant activity (IC50) of 110.47 ppm were obtained by an ultrasonic under conditions of 1:10 ratio and 30-minute extraction time. Results of the study suggested a significant difference (p<0,05) in the isolation of total flavonoid contents and antioxidant activities in the maceration and ultrasonic. In these two methods, ultrasonic was found to be more efficient than maceration because of minimum time, the highest flavonoid content and antioxidant activity could be obtained.

Optimization of Ultrasonic-Assisted Extraction Condition for Total Phenolic Compounds from Citrus Hystrix Peel

This study aims to optimize the extraction conditions of Ultrasonic-Assisted Extraction (UAE) on the extraction of phenolic compound and antioxidant activity of Citrus Hystrix (C. Hystrix) peel. The experimental design was carried out using Face Centered Central Composite Design. A total of 20 sets of different combination experiment designs were generated from 3 parameters; temperature (30-50°C), time (20-40 min), and raw material to the solvent ratio (1:30-1:70). The highest yield of total phenolic compounds was 4.36 mg/g with the optimize extraction condition of , 30 min extraction time and 1:50 raw material to the solvent ratio. The result of this study indicates that the phenolic compounds extracted from C. Hystrix peel could have the potential to be used for pharmaceutical and food applications.

Investigation of electrospinning parameters and fiber collection methods on morphology of thermoplastic polyester elastomer fibers

Electrospinning is an easy and simple process for the preparation of ultrafine fibers with tunable morphology. Thermoplastic Elastomers (TPEs) are engineering polymers with an elastomeric nature that can be processed as thermoplastics. They can be classified based on their chemical structure and polyester-based TPEs are counted as high-performance materials due to their mechanical properties and can be used for various applications from automotive, construction, furniture, and consumer goods. In this study, electrospun polyester-based thermoplastic elastomer fibers were prepared and characterized. Thermoplastic polyester elastomer, Hytrel 4056 was used as the polymer, and chloroform was used as a solvent. The effects of polymer: solvent weight ratio, feed rate, applied voltage, and collector type were investigated in terms of fiber formation and morphology. For this aim, the polymer: solvent weight ratio was varied as 1:7, 1:11, and 1:15; the feed rate was set to 1 and 3 ml h-1. To collect the fibers metal plate and water bath collectors were used at a constant needle-to-collector distance under 10, 15, and 20 kV. The viscosity of the polymer solutions was measured as a function of the polymer: solvent ratio to observe the effects of viscosity on fiber morphology.

Ultrasound-assisted extraction and encapsulation of betalain from prickly pear: Process optimization, in-vitro digestive stability, and development of functional gummies

The study aimed to extract and encapsulate betalain pigment from prickly pear (Opuntia ficus-indica) using ultrasound-assisted extraction and eco-friendly glycerol. Subsequent analysis encompassed assessing its thermal stability, shelf-life, bio-accessibility, and biological properties. The process optimization employed Response Surface Methodology (RSM), focusing on glycerol concentration (20–50 %), sample to solvent ratio (1:10–1:20), temperature (30–60 °C), and time (10–30 min). Optimal conditions were determined as 23.15 % glycerol, 1:10 sample to solvent ratio, 10.43 min treatment time, and 31.15 °C temperature. Under these conditions, betalain content reached 858.28 mg/L with a 93.76 % encapsulation efficiency. Thermal stability tests (80–180 °C; 30 & 60 min) showed degradation of betalain with higher temperatures and longer durations, affecting the visual aspect (ΔE) of the pigment. Encapsulated betalain exhibited favorable shelf stability, with optimal storage life of 404.27 days at 4 °C in amber conditions, compared to 271.99 days at 4 °C without amber, 141.92 days at 25 °C without amber, and 134.22 days at 25 °C with amber. Bio-accessibility of encapsulated betalain was significantly higher (2.05 ± 0.03 %) than conventionally extracted pigment (1.03 ± 0.09 %). The encapsulated pigment displayed strong anti-inflammatory properties in dosages of 2–20 µL, with no cytotoxic effects. Additionally, incorporation into gummies was successful and visually approved by sensory panellists. Glycerol proved to be a green encapsulating agent for betalain, offering high shelf life and bio-accessibility, making it suitable for food industry applications. The encapsulated pigment demonstrated robust thermal stability and shelf life, making it suitable for food industry applications. This study highlights glycerol’s potential as a sustainable alternative for natural pigment extraction.

Synthesis and analysis of (2z)-4-(4-methylanilino)-4-oxobut-2-enoic acid

The paper identified the structure of synthesised maleic acid monoamide by physical methods of analysis. The authors have determined the solubility of maleic acid monoamide in organic solvents with different properties and dielectric constant values. The paper describes the solvent ratio allowing the analysis with the best metrological properties. The reaction between p-toluidine and maleic anhydride to form (2z)-4-(methylanilino)-4-oxobut-2-enoic acid proceeds with high yield; mass fraction of the main substance is 94.23±0.69 %.

A Novel Process for Improving the Drug Loading of Highly Water-Soluble High-Dose Drug in FDM 3D Printed Tablets

ABSTRACTBackground: 3D printing technologies, also known as additive manufacturing technologies, are gaining importance in pharmaceutical research and manufacturing. These technologies are widely used in automobile, plastic, and material fabrication industries. In the recent past, pharmaceutical industries are actively working to increase the applicability of these technologies in commercial manufacturing. On the other hand, clinics and hospitals are ready to adopt these technologies due to their versatility such as flexibility, individual customization, and low-cost investment. FDM 3D printing technology is one of the widely used technologies for the manufacturing of finished products. However, this technology has limitations such as drug loading, scale-up issues, and regulatory requirements. The present study focused on developing a suitable solvent system along with a drug-loading method to increase the industrial applicability of this technology. Methods: Metformin, a high-dose, highly soluble drug, was selected as a model. Solvents such as water, ethanol, and methanol and their combinations were explored. Saturation solubility and drug loading in both PVA filaments and printed tablets were tested for drug loading. The solvent ratio of ethanol/methanol/water (8:1:1) was selected. The different infills of 10, 25, 50, 75, and 100% were printed using PVA filaments and were subjected to drug loading using soaking and solvent curing methods. Results: The soaking method has resulted in poor drug loading as well as layer separation and swelling of the polymer. The solvent curing method has a maximum drug loading of 91.9% w/w without physical deformities of the tablets. Moreover, the solvent curing method is a scalable process with less process time, and hence this method could be useful for both large-scale commercial manufacturing as well as customized formulations for personalized therapies. Conclusion: This method could be used for manufacturing thermoliable drug products and moderate-dose drug substances. Based on the research outcomes, we propose a novel, scalable, and rapid solvent-curing method for drug loading in the FDM 3D printing technique.

Flexibility analysis on absorption-based carbon capture integrated with energy storage

Post-combustion carbon capture in power plants is essential in reducing greenhouse gas emission. As the available heat in the plant is instable in time, it becomes a challenge to maintain the efficient operation of capture system. The lean/rich solvent storage proves to be a potential way for the capture system to keep high CO2 capture rate. However, the performance of the integrated system under different operating conditions is not fully evaluated, especially for the match criterion of lean/rich solvent process. The impact factors of single and coupled operating conditions of solvent storage still remain unclear. In this work, system performance during peak/off-peak period is first evaluated. Results indicates that heat duty, split ratio, solution concentration and absorption solvent flow rate are key factors for CO2 capture rate. Then, system performance under continuous operation is explored at the global CO2 capture rate from 0.918 to 0.978. It demonstrates that maintaining a relatively equal CO2 capture rate during peak/off-peak period efficiently improves the global CO2 capture rate, which can be achieved by adjusting flow rate and split ratio of solvent. Finally, volume and cost of integrated CO2 capture with solvent storage are compared with that of CO2 capture with heat storage. The volume of solvent storage decreases by over 69% and the cost of solvent storage decreases by over 84%, which indicates a promising application in terms of technical and economic aspects.

Fenugreek seed proteins: Ultrasonic‐assisted extraction, characterization, and cupcake application

AbstractIn this study, fenugreek seed proteins were extracted using ultrasonic‐assisted extraction with varying solid:solvent ratios (20–60 g/L) and sonication amplitudes (30%–80%) to determine optimal conditions for the highest extraction yield. The functional, structural, and nutritional characteristics of the protein isolates of fenugreek seeds were investigated. The highest yield (98.74 ± 0.49%) was achieved at a solid:solvent ratio of 43.83 g/L and an amplitude of 67.51%. The coagulated protein values of fenugreek seed protein isolates ranged from ~15.8% to 31.2%, water‐holding capacities ranged from ~2.2 to 3.2 g/g, oil‐holding capacities ranged from ~2.6 to 4.1 g/g, foaming capacities ranged from ~16.3% to 21.3%, foam stabilities ranged from ~59.7% to 78.1%, emulsion stabilities ranged from ~30.2 to 34.5 min, emulsion activities ranged from ~73.8 to 76.8 m2/g, and emulsion capacities ranged from ~26.9% to 30.5% under different extraction conditions. SDS‐PAGE analysis revealed three distinct bands (46, 59, and 80 kDa) for the protein isolates. FT‐IR spectroscopy showed a high presence of β‐sheet structures. The amino acid composition analysis of fenugreek seed protein isolates was determined, revealing richness in essential amino acids (317.97 g amino acid/kg protein isolate). In addition, cupcakes enriched with protein isolates (5%, 10%, and 20% as flour substitutes) were produced, and quality properties such as color change, browning index, moisture content, water activity, baking yield, bulk density, hardness, volume, symmetry, and uniformity indexes were determined. The application of protein isolates in cupcake production demonstrated the potential of fenugreek seeds as valuable ingredients for enhancing the nutritional profile of bakery products.

Influence of solvent type and leaf moisture on extraction efficiency of major steviol glycosides in stevia (var. Levent 93) plant

AbstractSteviol glycosides (SGs) are natural sweeteners derived from stevia leaves, which have various applications in food and beverage products. The extraction efficiency of SGs depends on several factors, such as solvent type, solid to solvent ratio, centrifugal force, and temperature. This study aimed to compare the effects of different solvents (ethanol and water) and leaf moisture (dry and fresh) on the extraction efficiency of major steviol glycosides (SGs) of rebaudioside A (Reb A), stevioside (ST), and rebaudioside C (Reb C) in stevia (var. Levent 93) plant. A Box–Behnken design was used to optimise the extraction parameters for each extraction type. The results showed that ethanol was a more effective solvent than water, however, aqueous extraction was more environmentally friendly and low-cost, and could also yield high concentrations of SGs when fresh leaves were used. The major SGs had similar concentrations in ethanolic extraction, but Reb A was twice as high as ST in aqueous extraction. Reb C was influenced by the solid to solvent ratio in both extraction types, but more so in water extraction. Temperature had a positive effect on ST and Reb C in water extraction of fresh leaves, but not in water extraction of dry leaves or ethanolic extraction. The results of this study contribute to the optimisation of SGs extraction from stevia leaves and provide insights for future research on the effects of different solvents and extraction parameters on the quality and purity of SGs.

A short review: fish oil extraction methods obtaining oils with high amounts of unsaturated fatty acids

Abstract Nutrition improvement can be ensured by prioritizing the consumption of animal foods, one of which is fish. Fish consumption generally requires cooking at high temperatures which trigger the protein denaturation, therefore consumption of fish oil is more beneficial for human health. However, extraction of oil from fish is quite challenging, particularly the extraction which produce high amount of unsaturated fatty acid. This short review aims to summarizes and evaluate the best fish oil extraction method by observing temperature, time, solvent ratio, oil yield, and unsaturated fatty acid content. The best quality of fish oil can be obtained through a series of extraction processes, namely the extraction without solvent and using solvent. Each fish oil extraction method takes into account several parameters, such as producing different amounts of oil with unsaturated fatty acid content. Ultrasound-assisted extraction methods provide an excellent oil yield and unsaturated fatty acids with better quality than other extraction methods. It is also underlined that fish oil obtained from the ultrasound-assisted extraction method can be used as a nutritional alternative to improve human health.

Optimization of Fe/Ni, Fe/Cu bimetallic nanoparticle synthesis process utilizing concentrated Camellia sinensis extract solution and activity evaluation through methylene blue removal reaction

In this study, we introduce a synthesis process of bimetallic nanoparticles (BNPs) Fe/Ni and Fe/Cu utilizing concentrated Camellia sinenis extract that was optimized with a solvent ratio of ethanol/H2O 4/1 (v/v), a metal ratio of 5/1 (w/w), a total polyphenol content (TPC) in the solution of 12.5 g.l−1, pH = 3–4, 25 °C, and the reaction time ranging from 30 min to 50 min. The structural and morphological characteristics of the resulting materials were determined using several techniques, such as scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive x-ray spectroscopy (EDX), x-ray diffraction (XRD), and x-ray photoelectron spectroscopy (XPS). The maximum removal efficiency of methylene blue (MB) by BNPs Fe/Ni and Fe/Cu materials was found to be 88.60% and 91.06%, respectively, at a concentration of MB = 25 mg.l−1 and 25 °C. According to the results of the kinetic modeling study, the adsorption process of MB on the two BNPs materials followed second-order kinetics, with the maximum adsorption capacities of MB on Fe/Ni and Fe/Cu BNPs being 26.94 mg.g−1and 28.00 mg.g−1, respectively.

Effect of solvent ratio on omega-3 extraction of catfish (Clarias sp.) and pangasius catfish (Pangasius sp.) using low-temperature crystallization method

Effect of solvent ratio on omega-3 extraction of catfish (Clarias sp.) and pangasius catfish (Pangasius sp.) using low-temperature crystallization method

Ultrasound Microwave Assisted Extraction Pada Daun Serai Wangi Menggunakan Pelarut Ionik.

Leaves of citronella (Cymbopogon nardus L.) have pretty much essential oil. Essential oil from citronella leaves is generally extracted by conventional methods. Conventional method is still less effective. The problem can be overcome by using non-conventional methods in the form of UMAE (Ultrasound-Microwave Assisted Extraction). UMAE is an extraction process assisted by ultrasound and microwaves. NaCl solution can be used as a solvent in the UMAE method because NaCl has a large dielectric constant. The aim of this study was to examine the effect of extraction time and the addition of salt on the yield and color of essential oils produced using the UMAE. The extraction process begins with the raw material preparation stage, such as harvesting, size reduction, and drying. Then, pre-treatment was carried out using ultrasound for 5 minutes at 35oC with the addition of 2, 4, 6, 8, and 10% (w/v) salt. Pre-treatment results were followed by the extraction process using microwaves for 30, 45, 60, 75, and 90 minutes. The best results were obtained with the addition of 6% salt and 60 minutes of extraction time with a feed to solvent ratio of 0.1 with a yield of 1.975% and the color is yellow.

Prediction of mass spectrometry ionization efficiency based on COSMO-RS and machine learning algorithms.

Non-targeted analysis of high-resolution mass spectrometry (MS) can identify thousands of compounds, which also gives a huge challenge to their quantification. The aim of this study is to investigate the impact of mass spectrometry ionization efficiency on various compounds in food at different solvent ratios and to develop a predictive model for mass spectrometry ionization efficiency to enable non-targeted quantitative prediction of unknown compounds. This study covered 70 compounds in 14 different mobile phase ratio environments in positive ion mode to analyze the rules of the matrix effect. With the organic phase ratio from low to high, most compounds changed by 1.0 log units in log IE. The addition of formic acid enhanced the signal but also promoted the matrix effect, which often occurred in compounds with strong ionization capacity. It was speculated that the matrix effect was mainly in the form of competitive charge and charged droplet' gasification sites during MS detection. Subsequently, we present a log IE prediction method built using the COSMO-RS software and the artificial neural network (ANN) algorithm to address this difficulty and overcome the shortcomings of previous models, which always ignore the matrix effect. This model was developed following the principles of QSAR modeling recommended by the Organization for Economic Cooperation and Development (OECD). Furthermore, we validated this approach by predicting the log IE of 70 compounds, including those not involved in the log IE model development. The results presented demonstrate that the method we put forward has an excellent prediction accuracy for log IE (R2pred = 0.880), which means that it has the potential to predict the log IE of new compounds without authentic standards.

Processing parameters, techno-functional properties and potential food application of lentil protein concentrate as an ingredient for the plant-based market

Lentil (Lens culinaris) is a protein-rich legume consumed worldwide and it also has the potential to become an alternative source of protein ingredient for human nutrition. The aim of this study was to determine the best processing parameters for the whole grain protein wet extraction, as well as to analyze the techno-functional properties, and physical characteristics of the protein concentrate and its flour. It was also evaluated the application of the concentrate into a fish-like croquette. The processing route was carried out by alkaline extraction and acid precipitation of the proteins where the pH, stirring time and solute:solvent ratio were evaluated. The final dried protein concentrate presented 85% protein on dry basis and a mass yield of 14%. The results were reproducible when tested on a first scaling up test. For the techno-functional properties, solubility, water and oil retention capacities, emulsification and foaming capacities and stability, and gelling capacity were tested. As for the food application into fish-like croquettes, the lentil protein showed similar scores for sensory acceptance, flavor and texture when compared to a commercial clean-taste concentrate. The results observed in this study were compatible to other alternative pulse-protein ingredients on the market, positioning lentil protein as a promising alternative protein source to produce ingredients for the plant-based market.

Greening the supply chain: Sustainable approaches for rare earth element recovery from neodymium iron boron magnet waste

The increasing demand for modern technologies has led to a growing reliance on rare earth elements (REEs). To address this issue, recycling used products such as permanent magnet waste containing REEs. However, this approach necessitates the development of advanced extraction and separation techniques to ensure high yields and purity of the REEs extracted. This review provides an overview of the latest extraction and separation technologies, with a particular focus on the hydrometallurgical approach for extracting REEs from secondary sources, notably permanent magnets. Hydrometallurgy, which involves leaching followed by solvent extraction for purification, has gained widespread use for obtaining REEs from secondary sources, as evidenced by its reported high recovery efficiencies. We found that the recovery of REEs using chemical leaching varied between 80% and 99%, influenced by factors such as type of source material, leaching solvent, leaching conditions, impurities, reaction kinetics and solid-liquid ratio. However, effectively employing this process on a larger scale still faces certain challenges due to the excessive use of corrosive solvents for leaching magnet waste and the generation of toxic chemicals as end products in the form of leachate. Additionally, the current process exhibits deficiencies in the targeted recovery of REEs from magnet waste, specifically in achieving purity and selectivity by eliminating iron impurities. This article concludes that the future prospects for the selective recovery of REEs from neodymium iron boron magnet waste lie in green and environment-friendly solvents. One such approach revolves around the utilization of biodegradable organic acids and salt aqua regia for leaching. These solvents are less corrosive and have high dissolution efficiency, which results in less chemical consumption and an overall environment-friendly and cost-effective recovery process.

Submicron PAN and nanofiber CTA air filters: Fabrication, optimization, and performance

This study investigates the fabrication, optimization, and performance of submicron polyacrylonitrile (PAN) and nanofiber cellulose triacetate (CTA) air filters produced through electrospinning. PAN fibers with diameters ranging from 379 to 804 nm were generated from PAN/DMF solutions, while genuine CTA nanofibers (65–102 nm) were successfully produced using a recycled CTA polymer and a binary solvent system (DMSO/TCM). The effects of electrospinning parameters, including solution concentration (10–12 wt% for PAN, 8 wt% for CTA), applied voltage (10–16 kV), tip-to-collector distance (16–24 cm), solution supply rate (0.08–0.10 mL/hr), and binary solvent ratio (7:1 to 20:1 DMSO/TCM), on fiber morphology and diameter were systematically examined. Reducing PAN solution concentration and increasing applied voltage effectively decreased fiber diameter, enhancing filtration efficiency. Filtration performance tests revealed that CTA nanofibers outperformed PAN submicron fibers, exhibiting higher quality factors (0.043–0.046 Pa−1) due to their smaller fiber diameters and increased fiber packing density. Decreasing CTA solution supply rate and increasing DMSO/TCM ratio reduced fiber diameter and increased packing density. Longer spinning collection times improved filtration efficiency but increased thickness and pressure drop. The optimization of electrospinning parameters proved crucial for controlling fiber diameter and achieving enhanced filtration efficiency, particularly at the most penetrating particle size (MPPS), which usually covers the ultrafine particle size range. This study provides valuable insights into the development of high-performance air filtration media through the optimization of electrospinning parameters and the utilization of recycled materials.

Optimization of the Parameters Influencing the Antioxidant Activity and Concentration of Carotenoids Extracted from Pumpkin Peel Using a Central Composite Design.

It has been discovered that the peel of a pumpkin (Cucurbita maxima), regarded as a waste product of pumpkin processing, has significant amounts of carotenoids and other antioxidants. This study aims to identify the most effective extraction parameters for an ultrasonic-assisted extraction method to extract the total carotenoids (TCs) and assess the antioxidant activity (AA) of pumpkin peel. To determine the effects of the extraction time, temperature, and material-to-solvent ratio on the recovery of TCs and AA, a response surface methodology utilizing the central composite design (CCD) was used. The extraction temperature (6.25-98.75 °C), extraction duration (13.98-128.98 min), and solvent ratio (0.23-50.23 mL) were the variables studied in the coded form of the experimental plan. The carotenoid concentration varied from 0.53 to 1.06 mg/g DW, while the AA varied from 0.34 to 7.28 µM TE/g DW. The findings indicated that the optimal extraction parameters were an 80 °C temperature, a 10 mL solvent ratio, and a 100 min extraction time. The study confirmed that the optimum extraction conditions resulted in an experimental TC yield of 0.97 mg/g DW and an AA of 7.25 µM TE/g DW. Overall, it should be emphasized that the extraction process can be enhanced by setting the operating factors to maximize the model responses.

Kinetics and thermodynamic studies on biodiesel synthesis via Soxhlet extraction of Scenedesmus parvus algae oil

In recent times, there has been a notable surge in interest regarding the utilization of microalgae for biodiesel production through wastewater treatment. This can be attributed to the versatile nature of microalgae to thrive in various water systems, including wastewater systems, and their ability to show a high rate of photosynthesis. This research aims to assess the viability of utilizing Scenedesmus parvus microalgae, commonly used in the treatment of wastewater, as a potential source of oil feedstock for biofuel production. To extract oil from microalgae, a Soxhlet extraction technique was employed, using methanol for both extraction and separation processes. The extraction process was carried out under differing experimental conditions, including variable extraction temperatures (40–80 °C), extraction period (3–12 h), and algae to solvent ratios (S/L) (1:05–1:10). The microalgae exhibited a maximum oil yield of about 24% when subjected to the extraction conditions of an 8-hour extraction period, an extraction temperature of 70 °C, and a methanol to algae ratio of 1:10. The extraction process of algae oil using the Soxhlet method was analyzed for its thermodynamic and kinetic properties using a second-order equation and Eyring's theory, respectively. In this process, biodiesel was successfully produced with an efficiency of approximately 92.2 ± 0.8% through an alkaline transesterification reaction. This reaction was conducted at a temperature of 65 °C, using a catalyst concentration of 1 wt% (KOH), with the ratio of algae oil to methanol set at 1:9, for 3 h. The biodiesel obtained from microalgae in this research conformed to the global biodiesel standards, specifically ASTM D6751 and EN 14214. The findings emphasize the viability of Scenedesmus parvus microalgae as a valuable resource for biodiesel production.

Spherical Fe3O4 morphology modulation for enhancing infrared emissivity and radiant heat dissipation

Radiant heat dissipation has emerged as a critical technique for effective thermal management, offering energy efficiency, cost-effectiveness, and adaptability to various shapes while promoting environmental sustainability. However, the intricate relationship between material structures and emissivity remains inadequately understood. This study primarily utilizes a straightforward and economical solvothermal method to regulate the synthesis of Fe3O4 ferrite, exploring its structural relationship with infrared radiation performance. By adjusting the solvent ratio of ethylene glycol and diethylene glycol in the solvothermal system, we successfully synthesized uniformly dispersed Fe3O4 nanospheres ranging from 10 to 800 nm. Notably, our research revealed a positive correlation between infrared emissivity and the particle size. Submicron hollow spheres with a size of 800 nm exhibit an exceptionally high emissivity of 0.992 within the 8–13 μm wavelength range. Morphological and size variations induced alterations in lattice strain, oxygen vacancies, and phonon lifetimes, which consequently influencing the lattice vibration absorption and infrared emissivity. Moreover, the device surface with a composite coating formed by combining 15 wt% Fe3O4 particles with organic matter, achieves a temperature difference of 17.6 °C under a 4 W input power condition compared to blank device. This finding contributes to further revealing the process of material radiative heat dissipation, driving the application of high-emissivity materials for heat dissipation in high-power electronic devices.