Powder Ratio Research Articles

Enhancement of thermal and mechanical properties of PMMA nanocomposites by adding spark plug ceramic waste

In this research, poly methyl methacrylate (PMMA) resin was used as a base material and spark plug ceramic waste (CW) particles as a support material with different weight ratios (0%, 1%, 2%, 4%, 6%, 10%, 14%, and 20%) to study the thermal and mechanical properties through diffraction examination. FE-SEM surface structure images showed that the fracture surface of the (94% PMMA +6%CW) nanocomposite sample manifests a good distribution of particles at low and high levels. The result showed that the thermal conductivity (K) slightly increased until it reached the maximum value (0.6 watt/m.ºC) at the ratio (86%PMMA +14%CW). For the impact strength, it was noticed that the impact strength of PMMA increases with the increased weight ratios (1, 2, 4, 6, 10, 14, and 20%) of fine powder of ceramic waste compared with pure PMMA to reach the maximum value (6.02 kJ/mm2) at the sample (94% PMMA +6%CW) under L.C. Moreover, after 30 days of submersion in water, the PMMA reinforced with ceramic waste particles had enhanced impact strength. The shore D-number readings for all of the samples showed an increase as a result of the findings of nanocomposite compared with PMMA pure, where the sample (94% PMMA+6%CM) attained the greatest shore D numbers (87 H.NO). The compressive strength at the weight percentage (99% PMMA + 1% CW) was somewhat reduced. Then the compressive strength increased till it reached its maximum value (29.94 MPa) at the weight percentage (94% PMMA + 6% CW).

Aluminosilicate-based material fabricated from fly ash for energy harvesting application

A triboelectric nanogenerator (TENG) is an emerging energy harvesting technology that utilizes the combination of triboelectrification and electrostatic induction to collect wasted mechanical energy and convert it into electricity. In this work, an aluminosilicate (AS)-based composite, considered as a potential alternative to cement material, has been developed for the fabrication of TENGs. Herein, the AS material is synthesized through the alkali activation of fly ash using a mixture of sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) solutions as activating agents. The electrical output of AS TENGs can be optimized by tuning the liquid-to-solid powder (L/S) ratio during the fabrication of AS composites. The AS composites fabricated at different L/S ratios exhibit the variations in dielectric properties, surface morphology and microstructure. It is found that a high dielectric constant is not the only requirement for achieving optimal TENG output performance. The contribution of dielectric properties and microstructures of the AS composites on TENG performance is discussed. The AS composite with an optimal L/S ratio of 0.5 results in the highest TENG power output density of 2.78 W/m2. Additionally, the versatility of AS TENG to harvest mechanical energy and its application as a power source for portable electronic device are demonstrated. This research has proposed the promising aspect of AS composites as alternative construction materials capable of harvesting mechanical energy, which is essential for the development of green and sustainable power sources.

Fabrication of boron carbide ceramics reinforced with silicon carbide fibers

In the present study, the boron carbide ceramics reinforced with silicon carbide fibers (B4C-SiCf) were fabricated by incorporating various contents of SiCf ranging from 2.5 to 10 wt%. The B4C-SiCf powder mixtures were sintered using the Field Assisted Sintering Technique (FAST), also known as Spark Plasma Sintering (SPS), at temperatures of 1800 °C and 2000 °C for 5 min by applying a pressure of 70 MPa in argon atmosphere, while heating and cooling rates were maintained at 100 °C/min and 50 °C/min, respectively. The influence of the initial powder ratio on the sintering behavior, relative density, microstructural development, and mechanical properties of the obtained B4C-SiCf composites was investigated. The results indicated that the sintered ceramic materials contained only the initial compounds, i.e. B4C and SiC phases. Scanning Electron Microscopy (SEM) showed that the sintered composites consisted of densely compacted B4C grains. The highest relative density (>99 %) was achieved for the sample with 95 wt%B4C and 5 wt%SiCf, sintered at 2000 °C. Depending on the constituent content and the densification temperature the obtained composites demonstrated hardness values ranging from 29 to 43 GPa. The maximal hardness was attained in the composite with 95 wt%B4C sintered at 2000 °C. To assess the performance of the composites under extreme conditions, the ablation resistance was evaluated using a flowing oxyacetylene torch test. The material containing 5 wt%SiCf exhibited superior ablation resistance when compared to the other compositions. The attained results of this study showed that the SPS technique is a highly effective method for the densification of additive-free B4C-SiCf ceramic composites, showcasing promising properties for applications in extreme environments.

Effect of foaming and drying temperature on the physical, chemical, and functional properties of egg white powders produced using refractance window drying

This study investigated the effect of drying form (natural and foamed) and temperature (50–100 °C) on the physical, chemical, and functional properties of egg white powder produced using refractance window drying. The egg whites were dried in 4-55 min, depending on the drying conditions. On the one hand, the drying form was effective on the color properties, densities (bulk, tapped, or particle), Carr index, Hausner ratio, porosity, hygroscopicity, solubility, and foaming capacity of egg white powders. On the other hand, the drying temperature was effective for all analyzed properties except hygroscopicity, moisture content, and water activity of samples. The study demonstrated that foaming before refractance window drying enhances the color of the egg white powders and provides better solubility and foaming capacity. However, it has a detrimental effect on the flow properties of the powders evaluated according to the Carr index and Hausner ratio. Increasing the drying temperature until a certain extent (80 °C) generally provided better color, protein content, surface hydrophobicity, and functional properties. The study shows that egg powders suitable for different purposes (better foaming, low protein denaturation, better gelling, etc.) can be obtained if the drying form and temperature conditions are fine-tuned.

Research on additive manufacturing technology of high solid loading silica glass slurry

In this work, digital light processing (DLP) 3D printing technology was used to fabricate transparent silica glass with complex structures. The effects of different particle sizes and mixing ratios of silica powders on the viscosity of the prepared slurries were investigated. The results showed that when 100–200 nm and 800 nm silica powders were mixed in a 1:4 vol ratio, the slurry exhibited the lowest viscosity. The highest solid loading of the slurry prepared with this mixed silica powder reached 75 wt%, with a viscosity of only 1245 mPa·s. The high solid loading slurry was subjected to 3D printing, debinding, and sintering treatment, and the transparent silica glass samples with complex structures was obtained.

Combined preparation and application of geopolymer pavement materials from coal slurry-slag powder-fly ash mining solid waste: A case study

The solid waste treatment problem generated in the process of coal mining has always been an important factor restricting safe and environmentally friendly production, and the coal slurry from the coal mine road surface is a new type of mine solid waste, so it is of great significance to treat and efficiently utilize the coal slurry. Currently, a common method of solid waste utilization is to add modifying reagents to prepare functional materials. Select coal slurry, slag powder and fly ash as raw materials, and sodium sulfate and sodium hydroxide were used as alkali exciters to prepare coal slurry based geopolymer pavement material (CSGPM). Response surface methodology was used to establish regression equations between the design optimization objectives (coagulation time, compressive strength) and the variables (mass fraction, mass ratio of slag powder to fly ash, mass ratio of sodium sulfate to sodium hydroxide). The effects of two-by-two interactions of the factors on the optimization objective were explored, and the use of different raw materials was obtained. Under the optimal proportioning parameters, the coagulation time of CSGPM was 33 min and the compressive strength of 24 h of curing was 11.20 MPa. In addition, the generation mechanism of AFt and C-S-H gel substances inside the specimen was explained with the help of microscopic scanning. CSGPM showed good mechanical properties in both load-bearing numerical simulations and acoustic emission tests. Numerical simulation was used to establish the relationship between the design objective of the roadbed (maximum subsidence of the roadbed after bearing) and the design variable (thickness of CSGPM paving). Comparative analyses yielded an optimal subgrade surface layer design thickness of 5 cm, with a maximum subsidence of 0.0033 m after bearing vehicles. Synchronization of roadbed material and concrete damage in combined specimen acoustic emission tests with uniform load transfer. The final coal mine pavement was successfully paved and the total cost of CSGPMD is 63.2 per cent of C30 concrete. Those results are important for the preparation of new pavement functional materials.

Investigating pozzolanic glass waste's role in reinforcing ultra-high-performance concrete beams for enhanced sustainability

PurposeThis study aims to address sustainability challenges in construction by exploring the structural performance and environmental benefits of incorporating pozzolanic waste glass (WG) into ultra-high-performance reinforced concrete (UHPRC) beams.Design/methodology/approachA comprehensive evaluation of UHPRC beams was conducted, incorporating varying ratios (10%, 20% and 30%) of WG powder alongside a consistent 0.75% inclusion of basalt fiber. The investigation encompassed the entire UHPRC production process, including curing, casting and molding, while evaluating workability and physical properties. Furthermore, the environmental impact, particularly CO2 emissions associated with UHPRC mixture components, was also assessed. Type K thermocouples were employed to analyze temperature dynamics during fabrication, providing valuable insights.FindingsThe findings demonstrate positive implications for using pozzolanic WG as a cement substitute in UHPRC beams.Originality/valueThis research stands out for its unique focus on the combined effects of incorporating recycled pozzolanic glass waste on the structural performance and environmental footprint of UHPRC beams.

Investigation on the influence of waste-based fillers on the mechanical and thermal characteristics of rigid polyurethane foams

An investigation was conducted to analyze the impact of incorporating coal powder particles at different weight ratios (5, 10, 15, 25, and 35) on the mechanical properties and thermal conductivity coefficient of the polyurethane polymer. The thermal conductivity coefficient of the samples was calculated using Holmarc's Lee's Disc apparatus device. The mechanical properties like compressive, tensile, and bending strengths were measured using a universal machine. The results indicated that increasing the coal powder ratio leads to an improvement in the thermal insulation ability due to a decrease in the value of thermal conductivity. Also, the addition of these percentages led to a rise in the values of the mechanical qualities represented by the compressive strength, especially at the ratio of 25 wt. %, with a value equal to 2.79 MPa (MPa). The flexural resistance and tensile strength increase at a ratio of 35 wt. %, with values equal to 20.4 MPa and 2.86 MPa respectively. The results indicate that the addition of coal powder enhances the ability of thermal conductivity at the ratios (5 %, 10) wt. %, with values equal to 0.119 W/m ºC and 0.114 W/m ºC, respectively, by increasing the thermal conductivities of the samples. The aim of this study is, investigate the effect of filler used coal powder waste on the mechanical and thermal properties of PU. The filler materials show the advantages of recycling waste. Filler influences the morphology and strengthens the brittleness. Additionally, the technology of polyurethane materials conforms to the use of coal powder. The overall amount of energy used to produce PU composites is decreased when waste of filler is used to partially replace petrochemical components

Pumping-less 3D concrete printing using quick nozzle mixing

Nozzle technologies for 3D concrete printing have been evolving to balance the conflicting demands of buildability and pumpability. This study introduces a simplified approach that eliminates the need for pumping by developing a customized system, the parameters of which were evaluated. The effect of process parameters (i.e., the flow rates of liquid and solid materials) and mixture proportions (i.e., the ratios of powder to sand and liquid to solid) on the extrudability and print quality was explored. Furthermore, the mechanical properties and microstructure of concrete printed using the Quick Nozzle Mixing system were examined. Results show that Quick Nozzle Mixing Technology not only enables high-quality printing but also exhibits the potential for achieving better process efficiency and higher aggregate content. The water-to-solid ratio is a critical factor influencing extrudability and buildability. Due to anisotropy caused by this new method, printed concrete has a lower strength than cast concrete.

Effects of Adding Pectin to Milk in Varying Amounts on the Rheological Properties of Milk

Pectin, which is used as an additive in the food, cosmetics, pharmaceutical, and health sectors due to its safety, non-toxicity, low production cost, and high availability, is used as a thickener, gelling agent, brightener, stabilizer, emulsifier, and fat and sugar replacer in low-calorie foods. It is also used in milk and dairy products as a stabilizer to prevent proteins from clumping. In this study, the rheological properties of pectin and milk mixtures with pectin/milk powder (w/w) ratios of 0.1, 0.25, 0.5, 0.75, 1 and 1.5 were examined. First, a flow curve test was applied in the range of 0,01-1000 s-1 to obtain the viscosity curves and yield stress values of the samples. Then, an amplitude sweep test was performed at a fixed frequency of 10 rad/s and in the strain range of 0.01-100% to determine the linear viscoelastic range (LVR) of the samples and the solid and liquid structure of the samples. To determine the time-dependent behavior of the samples in non-destructive deformation, frequency sweep tests were performed at constant strain (0.01%) in the LVR range obtained from the amplitude sweep test and in the range of 0.1-100 rad/s. Finally, three interval thixotropy tests (3ITT) were performed to observe the structural recovery of the samples. As a result of rheological tests, it was determined that pectin-free milk showed Newtonian properties, other samples showed shear thinning properties, and viscosity values increased as the pectin rate increased. While all samples are solid at low strains, the liquid feature becomes dominant at high strains. It has been observed that as the pectin ratio in milk increases, the strain values at the yield point, where the liquid feature becomes dominant, also increase. Except for the sample with the highest pectin content, it was observed that the dominance of the storage modulus over the loss modulus was greater at low frequencies than at high frequencies. As a result of 3ITT, it was determined that the percentage of recovery at the 600th second increased as the pectin rate increased.

Effect of psyllium powder on the organoleptic properties of gluten‐free bread roll: application Simple Additive Weighting (SAW) method

SummaryDue to their gluten‐free dietary needs, celiac patients cannot find bread with the required texture characteristics. The aim of this study was to evaluate the performance of psyllium powder in the production of rice‐based, gluten‐free bread rolls. In this case, five different bread rolls were produced by adding different proportions (0%, 25%, 50%, 75% and 100%) of psyllium powder combinations to bread dough made with rice flour. Moisture and ash content, colour values, volume, symmetry and uniformity indices, textural properties and sensory properties were taken into consideration. It was observed that the addition of psyllium powder gave the bread rolls a spongy structure and decreased the hardness values. As the amount of psyllium powder in the dough formulation increased, darkening in colour and increase in moisture values were observed. In addition, the bread sample psyllium powder and rice flour ratios (1:1) had the largest volume index value (98.67 mm), while the same product received the highest score in SAW techniques.

Mechanical Properties of Adjacent Pile Bases in Collapsible Loess under Metro Depot

Metro transit construction has begun to develop rapidly in northwest China because of the acceleration of urbanization. Accordingly, metro depots are also regarded as an essential auxiliary facility for stopping, operation, and maintenance of trains. Meanwhile, many commercial buildings are constructed over metro depots to improve the utilization rate of land due to the increasingly scarce urban land resources, known as transit-oriented development (TOD). These buildings have a large covered area and transfer concentrated loads to the bases. Therefore, pile bases under metro depots have the bearing characteristics of undertaking large concentrated loads, while lesser loads are placed on the soil between the adjacent pile bases. Additionally, the main ground in northwest China is collapsible loess, so the collapsibility should also be considered. Based on the above background, this research performed static loading tests with and without immersion in a reduced scale of adjacent pile bases under a metro depot in Xi’an. The remolding process of natural loess could destroy its structure and the anisotropy of natural loess could also affect the test results. Therefore, four kinds of artificial collapsible loess with different mass ratios of barite powder, kaolin, river sand, cement, industrial salt, and calcium oxide were made by the free-drop method. This method could make the artificial loess simulate the structure of natural loess reasonably. Then, the artificial loess with the most similar properties to intact loess was selected by comparison. Finally, static loading tests with this artificial loess were implemented. The results showed that the ultimate bearing capacity was 4.5 kN. At the same time, the axial force decreased along depth, since the pile shaft friction was positive, and the load sharing ratio of pile tip force increased to 0.58 when the load exceeded 4.5 kN in the situation without immersion; the settlement of pile bases increased significantly after immersion, while the negative shaft friction occurred at the depth of −8 cm~−35 cm, and the load sharing ratio of pile tip force reached 0.92.

Defects, organization, and properties of TiB2–TiC Bi-ceramic phase by laser cladding in situ synthesis

An enhanced Ni50A composite coating was formed on the AISI 1045 steel surface using Ti, B4C, and Ni50A powders. The work meticulously examined the effects of various process parameters, including laser power (800, 1200, and 1600 W) and scanning speed (4, 6, and 8 mm/s), as well as different Ti/B4C powder ratios (2:1, 3:1, and 4:1, mol.%) on the defect, hardness, wear resistance, and corrosion resistance of the coating. The microstructure of the coating showed that TiB2 and TiC synthesized in situ were the key phases for coating enhancement, and there were a variety of solid solutions (FeNi3 and Cr2Ni3). TiB2 particles showed dark gray hexagons and long rectangular blocks. The TiC particles mainly appeared in light gray dendritic shapes, occasionally petal-shaped and equiaxial forms, and grew around TiB2. The research results showed that increased laser power and the Ti/B4C ratio decreased coating hardness and wear resistance. When the scanning speed increased, the hardness and wear resistance of the coating were significantly improved. The main wear mechanisms of the TiB2–TiC ceramic phase coating were oxidative wear and abrasive particle wear. Besides, the higher laser power and Ti/B4C ratio reduced the defect rate of the coating and enhanced the corrosion resistance. However, as the scanning speed increased, the defect rate increased, which decreased the corrosion resistance of the coating. The comprehensive performance evaluation showed that under the conditions of the laser power of 1200 W, a scanning speed of 8 mm/s, and a Ti/B4C ratio of 4:1, the coating exhibited optimal performance (dilution rate = 10.928±0.090%, defect rate = 8.657±0.128%, hardness = 63.300±1.159 HRC, wear volume = 0.0149±0.000100 mm3, Ecorr = −0.565±0.001 V, Icorr = 1.058E−06±1.528E−09A⋅cm2). The results provide an important basis for research on the high-quality and efficient strengthening technology and performance of refractory alloys.

Polyphenol Extraction from Musa corniculata Peel Using Microwave Assisted Extraction (MAE) Method with Ethanol Solvent

Banana peel (Musa corniculata) is one of the superior plants in Indonesia which is rich in polyphenolic compounds as a source of antioxidants. The potential of polyphenolic compounds as antioxidants can be used as an alternative to reduce banana peel waste. This study aims to determine the total content of polyphenols and antioxidant activity of horn banana peel extract. Extraction used the Microwave Assisted Extraction (MAE) method with ethanol solvent and the variables were extraction time (4, 7, and 10 minutes), solvent concentration (50, 73 and 96 %), ratio of simplicia mass to solvent volume (1:12, 1 :8, 1:6 g/mL) with a microwave power of 150 Watt. Determination of polyphenol content using the Folin-Ciocalteau method and the ability of polyphenols as antioxidants were analyzed by DPPH test. This study used the Design Expert 13 Response Surface Methodology software, the Box Behnken type, to determine the extraction parameters for the total polyphenol content. The highest total polyphenol content was obtained at 354.02 mg GAE/g from the combination of parameters 50% solvent concentration, 10 minutes extraction time, and the ratio of horn banana peel powder to 1:8 g/mL solvent.

Bimetallic MOFs-derived CoFe/Fe/C particles prepared by explosion and pyrolysis methods for electromagnetic wave absorption

In this study, {[CoFe3O(tza)6(H2O)3]·(NO3)3·5 H2O}n was applied as a precursor for fabricating CoFe/Fe/C composite materials via explosive and high-temperature calcination techniques. The explosive method was identified as a straightforward approach for achieving remarkable electromagnetic wave absorption properties. At a thickness of 2.03 mm, the CoFe/Fe/C (CoFe-700) composite material exhibited a minimum reflection loss of −77.84 dB. Similarly, it demonstrated the widest effective absorption (≦ −10 dB) bandwidth (4.06 GHz) with a thickness of 2.00 mm. Encompassing frequencies from 2.90 GHz to 18 GHz, the total effective absorption bandwidth extended throughout the thickness range of 1.00−5.50 mm. Under the same mixing ratio of powder and paraffin (1:1), the effective absorption bandwidth value of CoFe/Fe/C (CoFe-600) sample at a thickness of 1.40 mm is 4.95 GHz. The CoFe/Fe/C carbon composite materials emerged as optimal electromagnetic wave absorbers due to their exceptional conductivities, abundant dielectric losses, and magnetic loss mechanisms.

Synthesis of Si3N4 powder with a controllable alpha/beta ratio by sol-gel assisted carbothermal reduction and nitridation

The controllable α/β ratio of Si3N4 powder was synthesized using tetraethyl orthosilicate (TEOS), glucose, MgCl2 and YCl3·6H2O by sol-gel assisted carbothermal reduction and nitridation (CRN). This study aimed to investigate the impact of various parameters, including a H2O/TEOS mol ratio of the sol, a C/Si mol ratio, sintering aids, and the temperature of CRN on the phase transformation of α-Si3N4. The results demonstrated that the H2O/TEOS ratio significantly influenced the relative content of α and β phase in Si3N4 by changing the morphological characteristics of SiO2. When the H2O/TEOS ratio was 100, β-Si3N4 powder with an approximate β content over 88 wt% was synthesized at 1500 °C. This remarkable phase transformation was likely facilitated by the eutectic liquid phase consisting of MgSiO3/Mg2SiO4. The SEM image revealed rod-like whiskers with a length around 1.4 μm for the β-Si3N4 grains. Due to the presence of liquid phase, the synthesis of spherical-like α-Si3N4 nano-powder with an α-phase content of 91 wt% was achieved at a lower temperature of 1450 °C, with an H2O/TEOS ratio of 15 and a C/Si ratio of 4. The size of the particles was about 70 nm due to the reduced reaction temperature. Furthermore, without the addition of any sintering aids or Si3N4 seeds, high purity α-Si3N4 with an α phase content approaching 96 wt% could be synthesized at 1500 °C, using an H2O/TEOS ratio of 15 and a C/Si ratio of 4. The resulting α-Si3N4 powder exhibited an extremely regular hexagonal prism shape with a length of approximately 2 μm.

Statistical approach for the preparation of silicon-graphite anodes: The role of oxygen content and crystallite size on electrochemical performance

Increasing the overall performance of Si-based anodes is still challenging because of the influence of various parameters involved in the preparation processes. This study addresses this challenge by employing the design of experiment technique to assess the impact of ball milling parameters such as milling speed, time, ball to powder and medium to powder ratio on the properties of silicon/graphite (Si/Gr) powders, with a focus on their electrochemical performance. Si/Gr powders in 20:80 weight ratio and 4 factor - 2 level full factorial design were used to find the main effects and interactions. Crystallite sizes were calculated using the Scherrer equation, and span values were obtained from the particle size distribution (PSD) analysis. SEM analyses were carried out to check the microstructure of powders. Ultimately, regression equations were created with high adjusted R2 values for crystallite size (93%), contamination (92%), and span (91%), respectively. Optimization experiments were carried out using the created regression equations, and the models were verified. It was found that crystallite size obtained by XRD data is more reliable to assess powder properties on the performance instead of PSD because of the agglomeration at the particle level throughout the milling. Further milling experiments were performed to elaborate the role of oxygen content and crystallite size. Results showed that while initial capacity is strongly related to total oxygen content, decay in the first cycles is correlated to the crystallite size of the silicon powder.

Microstructure and Pore Characteristics of a Double-Layered Pore Structure Powder Filter Fabricated by the WPS Process

In order to supply high-purity process gas in the semiconductor manufacturing process, a gas filter is used to remove particles that may be contained in the gas. However, because the gas filters currently in use have simple pore structures, there is a need to increase filtration efficiency through the development of filters with complex pore structures. In this study, a metal powder filter with double-layered pores was manufactured using a Wet Powder Spraying process (WPS) to increase the filtering efficiency of gas filters used in semiconductor manufacturing. The effects of the mixing ratio of spherical-shape and flake-shape powders and the rolling process on the filter’s characteristics were investigated. The filter’s performance, microstructure, and surface roughness were evaluated by measuring porosity and gas permeability. The results showed that as the ratio of flake-shaped powder decreased, the thickness of the coating layer and the porosity of the filter decreased. Additionally, it was observed that as the rolling process progressed, the non-uniform pore structure was oriented parallel to the cross-section of the filter regardless of the mixing ratio. Measurements found that the gas permeability of the uncoated filter support was the highest, and that gas permeability decreased as the proportion of spherical powder increased regardless of the average particle size of the mixed powder. Lower gas permeability was observed in rolled samples. A filtration efficiency of LRV 3 or higher was confirmed.

Properties of polyamide epichlorohydrin resin‐modified wood fibers/soybean straw powder copolymerization enhanced soy protein biomass composites

AbstractThe biomass composites were prepared by hot molding with a pressure of 10 MPa, a temperature of 125 °C, a time of 15 minutes using soybean straw powder, poplar wood fibers, and soy protein as raw materials. The effects of different straw species, the ratio of soybean straw powder to poplar wood fibers, the particle size of soybean straw powder, and the theoretical density on the performance of biomass composites were investigated. The experimental results show that under the condition that the ratio of soybean straw powder and poplar wood fibers is 1 : 1, 20 mesh to 40 mesh soybean straw powder and 20 mesh to 60 mesh wood fibers are selected to copolymerize and strengthen the soy protein biomass composites when the theoretical density is 0.80 g/cm3, the actual density of the biomass composites is 0.90 g/cm3, the tensile strength was up to 22.04 MPa, and the bending strength was up to 44.92 MPa. Biomass composites have good water resistance while obtaining excellent mechanical properties. The above figures not only meet the relevant technical requirements of automotive interior parts but also enable the lightweight design of automobiles and the sustainable development concept of green, low carbon, and environmental protection.

Microstructure, hardness, electrical, and thermal conductivity of SZCN solder reinforced with TiO2 and ZrO2 nanoparticles fabricated by powder metallurgy method

The microstructure and characterization of Sn–Zn–Cu–Ni (SZCN) solder alloy reinforced with TiO2 and ZrO2 nanoparticles (NPs) synthesized by powder metallurgy were investigated. Sn, Zn, Cu and Ni metallic powders were mixed mechanical by 10:1 ball to powder ratio with 300 rpm speed for 2 h. Then 0.5 wt% from nano ZrO2 or TiO2 was mixed by the same parameters with the mixed metal powder. The morphologies and microstructures development during the fabrication process was investigated by X-ray diffractometer (XRD), optical microscope (OM), and scanning electron microscope (SEM) with energy dispersive X-ray spectrometry (EDX). The results reveal an improved distribution of TiO2 or ZrO2 NPs in the SZCN matrix solder, which resulted in an improvement in its density. The analyses of microstructural demonstrated that the addition of TiO2 or ZrO2 NPs to SZCN solder results in the grain refinement of the β-Sn phase, besides the formation of Ni3Sn IMC with small size and uniform distribution. The microhardness was enhanced as a result of the addition of TiO2 or ZrO2 NPs. The experimental results showed that the SZCN-ZrO2 composite solder had the greatest hardness and stress exponent values due to its effectiveness in suppressing the growth of β-Sn grains and the pile-up of dislocations. Both the electrical and thermal conductivities were improved by incorporating TiO2 NPs compared to other solders.