Fly Ash Ratio Research Articles

Design of a novel ternary blended Self-Compacting Ultra-high-performance Geopolymer Concrete

In this research study, the Taguchi orthogonal array (TOA) optimisation method was used to design the optimum mixture proportions of ternary blended Self-Compacting Ultra-High-Performance Geopolymer Concrete (SCUHPGC). The SCUHPGC mixtures, cured at ambient conditions, included Ground Granulated Blast Furnace Slag (GGBFS), Fly Ash (FA), and Silica Fume (SF) as aluminosilicate sources and sodium hydroxide solution and sodium silicate solution as alkaline activators. The effects of six factors at three levels on the compressive strength of SCUHPGC were investigated. The considered factors were the binder content, the ratio of fly ash to ground granulated blast furnace slag (FA/GGBFS), the ratio of silica fume to binder content (SF/Binder content), the ratio of alkaline activator to binder content (AAL/Binder content), the ratio of sodium silicate to sodium hydroxide (SS/SH), and the concentration of sodium hydroxide solution. Twenty-seven SCUHPGC mixtures were evaluated. The slump flow diameter of the optimum SCHUPGC was 740 mm, which satisfies the requirements of self-compacting concrete. The maximum 28-day compressive strength of 132.7 MPa was achieved by the optimum SCUHPGC mixture, which contained a binder content of 1050 kg/m3, a FA/GGBFS ratio of 0.3, an SF/Binder content ratio of 0.05, an AAL/Binder content ratio of 0.4, a SS/SH ratio of 4.0, and an SH concentration of 12 M. The 28-day flexural strength and tensile strength of the optimum SCUHPGC mixture were 9.6 MPa and 4.9 MPa, respectively.

Effect of glass powder on alkali-silica reaction mitigation for tunnel waste rock slag in concrete

Alkali-silica reaction (ASR) poses a critical damage to concrete structures, which will lead to a serious reduction for the service life of concrete. This study investigated the mitigation of ASR using glass powder (GP) through accelerated mortar bar tests (AMBT), with fly ash (FA) and ground granulated blast-furnace slag (GGBS) setting as control groups, and the replacement ratio of GP, FA and GGBS is 0, 5 %, 10 %, 20 %, 30 % and 40 % respectively. The results reveal that both FA and GGBS can mitigate the possibility of ASR: GGBS can significantly mitigate ASR only when its content reaches up to 40 % and FA effectively suppressed ASR with a dosage of 20 %. For the GP, particles larger than 75 μm will increase the risk of ASR, and as evidenced by the clear presence of ASR-gel and cracks in the mortar bars observed. Conversely, GP with particle sizes smaller than 75 μm effectively mitigated ASR, achieving significant suppression at a content of 20 %. The possible mitigation mechanism of GP could be attributed to the pozzolanic reaction between the GP and the alkali in the concrete, which reduces the alkali in the cement. This work might offer some reference to ASR risk control in concrete.

Study on optimization of mixing ratio and shrinkage property of alkali-activated ultrafine fly ash-slag mortar

Alkali-activated cementitious materials have received widespread attention due to their favorable mechanical properties and environmental benefits. However, there are fewer studies on the optimal mixing ratio of alkali-activated ultrafine fly ash-slag (AAUS) mortar, and shrinkage cracking is a critical issue that hinders its further application. Based on this, the study used the response surface method (RSM) to optimize the mixing ratio of AAUS mortar, explored the effect of basalt fibers (BF) on the compressive strength and drying shrinkage of AAUS mortar, and finally analyzed the energy consumption and carbon emission of fiber-reinforced AAUS mortar. The experiment used X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques for microstructural characterization to research the microstructure and mineral phase changes of AAUS mortar. The results demonstrated that the 28d compressive strength of AAUS mortar reached its maximum when the substitution ratio of ultrafine fly ash (UFA) was 14.5%, the alkali equivalent was 10.34%, and the modulus of the activator was 1.6, based on the RSM; BF of appropriate length and volume fraction can productively improve the compressive strength of AAUS mortar and limit drying shrinkage; AAUS mortar with optimal mixing ratio can be sufficiently activated by alkali activator to construct a considerable number of C-(A)-S-H gels to establish a high-density microstructure; the carbon emission of the B124 test group was reduced by 61.1% compared with ordinary Portland cement (OPC) mortar.

Feasibility study of utilizing Autoclaved Aerated Concrete (AAC) waste for the production of cold bonded lightweight artificial aggregate using high volume fly ash (HVFA) binders

Autoclaved Aerated Concrete (AAC) is a popular construction material used for partitions and insulation in buildings. At the end of its service life, AAC (Autoclaved Aerated Concrete) will be demolished and subsequently disposed of in landfills, thereby creating depository problem. Therefore, the study of reutilization and recycling of AAC waste is imperative. Artificial aggregate production can be an alternative to the reutilization of AAC waste. This paper assesses the feasibility of using Autoclaved Aerated Concrete Powder (AACP) waste as a raw material for the production of artificial aggregate and investigate its physico-mechanical properties. The investigation incorporates the comparison of cement-based binder with high-volume fly ash (HVFA) binder with different replacement levels of cement. The study uses image analysis based on photographic, optical microscopic, and scanning electron microscopy (SEM) images, to describe the porosity of the aggregate. The results show that the AACP aggregates with both cement and HVFA binders meets the current industry requirement for density and cylinder crushing strength as lightweight artificial aggregate. The appropriate binder content lies between 30 % and 40 %. The best cement to fly ash ratio in HVFA binder is determined to be of 1:1 with 50 % replacement of cement with fly ash. Image analysis showed that the porosity largely affected the properties of the AACP aggregate such as density and water absorption. However, further investigation into the reducing high-water absorption of AACP aggregates is necessary to improve their overall quality.

Experimental study on the stabilization of marine soft clay as subgrade filler using binary blending of calcium carbide residue and fly ash

This study endeavors to realize the concurrent utilization of marine soft clay (MSC) and industrial waste, specifically calcium carbide residue (CCR) and fly ash (FA), through a series of experimental investigations. The optimal ratio between CCR and FA, as well as the efficacy of the composite agent (CF–1), were examined, and an empirical equation associating the unconfined compressive strength (qu) of stabilized MSC was developed through unconfined compressive strength (UCS) tests. Microscopic analyses, including X–ray diffraction (XRD), scanning electron microscopy (SEM), and energy–dispersive spectroscopy (EDS), were employed to unveil the intrinsic mechanisms underlying CF–1 stabilized MSC. Subsequently, the suitability of CF–1 solidified MSC as a roadbed filler was ascertained through laboratory tests. Results revealed the optimum CCR:FA ratio for CF–1 to be 4:1, demonstrating superior curing effects compared to individual components such as Portland cement (PC), CCR, and FA, with commendable environmental and economic benefits. The developed empirical equation exhibited effectiveness in predicting the qu of CF–1 solidified MSC under varying curing dates (T) and dosages (Wg) conditions. Characterization through XRD, SEM, and EDS identified the primary products formed within the stabilized MSC matrix with CF–1 as comprising calcium–silicate–hydrate (C–S–H) gel, calcium–aluminate–hydrate (C–A–H) gel, and a minor amount of calcite. As T and Wg increased, the reduction in pores between soil particles enhanced the structural integrity and macro–strength of the cured MSC. The failure pattern of CF–1–solidified MSC elementary samples depended on the CF–1 dosage and curing duration. The solidification mechanism of CF–1 on MSC involved pozzolanic, ion exchange, and carbonation reactions. CF–1 solidified MSC satisfied all the specified requirements for roadbed filler in the relevant code, demonstrating substantial potential for in–situ solidification projects involving MSC.

Pengaruh Air Laut terhadap Kuat Tekan, Permeabilitas, dan Mikrostruktur Beton Geopolimer dengan Flyash dan Tanah Putih sebagai Pengganti Semen

The increasing infrastructure development of an area is sometimes located in an aggressive environment, one of which is in coastal areas so that direct contact with sea air cannot be avoided. This research aims to determine the effect of sea water on geopolymer concrete using fly ash and white soil as cement substitutes with testing parameters for compressive strength, permeability and microstructure. The test objects used were cylindrical in shape measuring 150x300 mm and 100x200 mm. The ratio of fly ash and white soil used was 85%:15% and the activator used was NaOH 8M and Na2SiO3 with a ratio of 1:2,5. The mixture proportion using a ratio of 1 fly ash: 1,497 sand: 2 split: 0,451 alkali activator with a mutual plan is 35 MPa. Tests were carried out after the concrete had gone through a curing process for 56 days, then the concrete was conditioned without soaking and with soaking for 28 days. Tests were carried out at concrete ages of 56 and 87 days. The test results show that geopolymer concrete with the influence of sea water has a higher compressive strength value and a smaller permeability coefficient compared to concrete without the influence of sea water. Microstructural testing of geopolymer concrete under the influence of sea air produces a matrix-shaped structure morphology that is denser with fewer pores compared to concrete without the influence of sea air.

Investigating key factors for superior CRMC-based mortars cured under CO2 pressurized environment

An exploratory programme was undertaken to individually test the influence of reactive magnesia to waste-based material (biomass fly ash) ratio, water to solids in binder ratio, static compaction pressure, accelerated carbonation curing period, and curing temperature, on the compressive strength results of Carbonated Reactive Magnesia Cement (CRMC)-based mortars. Subsequently, the observed optimal conditions of each parameter were combined to assess their influence when applied together. A total of twenty-four mixture labels were designed, with specimens moulded under static compaction pressure and subjected to a pressurized accelerated carbonation curing under controlled conditions. The devised mortars were evaluated through compressive strength tests, and the microstructure was carried out through TG-DTG, ATR-FTIR, XRD, SEM-EDX, and MIP analyses. The results demonstrated that none of the tested influencing factors can be exclusively considered as the sole determinant for the compressive strength outcomes. Thus, this study highlights the importance of thoroughly considering any modifications in both mixture design and accelerated carbonation curing conditions to achieve the optimal properties of CRMC-based mortars. Additionally, the devised CRMC-based mortars exhibited favourable binding properties with biomass fly ashes, allowing for its secondary use and contributing to waste circularity by avoiding landfill disposal, supporting the development of the waste circularity and CO2 sequestration through mineralization in carbonated materials.

Optimization and Evaluation of Alkali Activated Fly Ash for Lightweight Aggregate Production

This study investigates the utilization of solid waste, specifically fly ash, and other materials to produce aggregates through geopolymerisation. The research aims to explore the properties of fly ash aggregates and assess their viability in concrete production. The objectives of the study encompass the preparation of aggregates using different proportions of fly ash and alkali activator such as sodium hydroxide and sodium silicate, alongside the casting of concrete cubes utilizing the artificial aggregate. The methodology employed involves the preparation of alkali activator, mix proportioning, and the subsequent processes of mixing, casting, crushing, and curing. Various ratios of fly ash to activator (2.5:1, 3:1, and 3.5:1) were investigated, with corresponding results obtained for properties such as abrasion value, impact value, bulk specific gravity, and water absorption. The findings reveal that the properties of the fly ash aggregates vary with different ratios, with notable differences observed in abrasion value, impact value, bulk specific gravity, and water absorption. For 2.5:1 abrasion value is 26.02%, impact value is 19.32%, bulk specific gravity 1.821 and water absorption 9.61%.For 3:1 abrasion value is 37.14%, impact value is 25.15%, bulk specific gravity 1.78 and water absorption 10.58%.For 3.5:1 abrasion value is 46.5%, imapct value is 32.87%, bulk specific gravity 1.648 and water absorption 12.83%. Casting cude using ratio 2.5:1, 28 day strength is 20.46 N/mm2.. This research project offers an eco-friendly solution for utilizing fly ash in the production of high-performance aggregates, contributing to sustainable construction practices. The implications of the findings include reduced environmental impact, enhanced resource efficiency, and the potential for resilient and environmentally conscious built environments. Further research and development in this area could lead to broader adoption of geopolymerized fly ash aggregates in the construction industry, paving the way for a more sustainable and Greener future.

Mineralized carbon sequestration evaluation of coal-based solid waste consolidated backfill: A novel data-driven approach

The coal mining industry and its byproduct utilization are confronted with challenges such as the accumulation of coal-based solid waste and the emission of CO2, which seriously jeopardize environmental protection. A lucrative way of mitigating these problems is CO2 mineralization storage technology of coal-based solid waste consolidated backfill. Its successful realization stringy depends on the CO2 mineralization sealing stock and requires accurate account of the carbon sequestration rate of cemented backfill. Therefore, this study proposes a novel hybrid intelligent model combining the adaptive enhanced whale optimization algorithm and the support vector regression (A-E-WOA-SVR) to forecast the carbon sequestration performance of cemented backfill. The respective data set of cemented backfill was obtained through laboratory tests under different values of seven factors influencing the carbon sequestration rate, including water–solid ratio, cement ratio, fly ash ratio, slag ratio, curing pressure, curing temperature, and curing time. The results exhibit that the adaptive enhanced whale optimization algorithm can effectively optimize the hyperparameters of the support vector regression. The A-E-WOA-SVR hybrid intelligent model proposed in this paper accurately predicted the carbon sequestration rate of cemented backfill. Coefficient of determination, mean absolute error, root mean square error, and other indices were used to evaluate the performance of the intelligent prediction model. The obtained values of these indices implied small errors. The mean impact value sensitivity analysis revealed that water–solid ratio, cement content, curing pressure, and curing time were the key sensitive factors controlling the carbon sequestration performance of cemented backfill, which should mainly considered in the control of cemented backfill mineralization carbon sequestration performance. The research results provide a theoretical reference which enhance the CO2 mineralization storage performance of coal-based solid waste consolidated backfill.

Determining the appropriate ratio of fly ash as cement replacement in concrete and evaluating the radiation dose of the fly ash concrete

Determining the appropriate ratio of fly ash as cement replacement in concrete and evaluating the radiation dose of the fly ash concrete

New geopolymer preparation methods and its application by recycle of double-waste: ground granulated blast furnace slag and fly ash

ABSTRACT This article mainly studies new geopolymer preparation methods by recycle of double waste:ground granulated blast furnace slag (GGBFS) and fly ash as geopolymer precursor, through different mass ratio of GGBFS and fly ash, to prepare geopolymers by alkali activation, the samples is cured at ambient temperature and the mechanical test is carried out together with the analysis of XRD, SEM and EDS to research the mechanism of strengthening and geopolymerisation. After analysis we find that the sample prepared by 30% mass ratio of GGBFS have good initial strength and short setting time, as well as best mechanical performance, which is attributed to moderate Ca2+ introduction accelerates the speed of geopolymerisation and the reactants of N-A-S-H gel, C-A-S-H gel and hydrated C-S-H help to bridge the gaps between the different hydrated phases, unreacted particles and matrix, result in a homogeneous and compacted geopolymeric sample. When GGBFS mass ratio above 50%, the mechanical of samples is deteriorated due to too much hydrated calcium containing compounds are formed and covered on the unreacted GGBFS particles surface to block further geopolymerisation. The acid attack test and water resistance test are carried out to analysis the durability between 30% GGBFS introduced geopolymer and ordinary Portland cement (OPC). In additional, a field application in case of 30% GGBFS introduced geopolymer grouting repair material indicated desirable construction based on visual observation and ground-penetration radar scanning.

Evaluation of Bonding Behavior between Engineered Geopolymer Composites with Hybrid PE/PVA Fibers and Concrete Substrate.

Engineered geopolymer composites (EGCs) exhibit excellent tensile ductility and crack control ability, making them promising for concrete structure repair. However, their widespread use is limited by high costs of reinforcement fiber and a lack of an EGC-concrete interface bonding mechanism. This study investigated a hybrid PE/PVA fiber-reinforced EGC using domestically produced unoiled PVA fibers to replace commonly used PE fibers. The bond performance of the EGC-concrete interface was evaluated through direct tensile and slant shear tests, focusing on the effects of PE fiber content (1%, 2%, and 3%), fiber hybrid ratios (2.0:0.0, 1.5:0.5, 1.0:1.0, 0.5:1.5, and 0.0:2.0), concrete substrate strength (C30, C50, and C70), and the ratio of fly ash (FA) to ground granulated blast furnace slag (GGBS) (6:4, 7:3, and 8:2) on interface bond strength. Results showed that the EGCs' compressive strength ranged from 77.1 to 108.9 MPa, with increased GGBS content significantly enhancing the compressive strength and elastic modulus. Most of the specimens exhibited strain-hardening behavior after initial cracking. Interface bonding tests revealed that a PE/PVA ratio of 1.0 increased tensile bond strength by 8.5% compared with using 2.0% PE fiber alone. Increasing the PE fiber content, PVA/PE ratio, GGBS content, and concrete substrate strength all improved the shear bond strength. This improvement was attributed to the flexible fibers' ability to restrict thermo-hydro damage and deflect and blunt microcracks, enhancing the interface's failure resistance. Cost analysis showed that replacing 50% of the PE fiber in EGC with unoiled PVA fiber reduced costs by 44.2% compared with PE fiber alone, offering the best cost-performance ratio. In summary, hybrid PE/PVA fiber EGC has promising prospects for improving economic efficiency while maintaining tensile ductility and crack-control ability. Future optimization of fiber ratios and interface design could further enhance its potential for concrete repair applications.

Study on the properties of anorthite-based porous sound-absorbing materials prepared by steel slag and fly ash

The efficient utilization of solid wastes, such as fly ash and steel slag, has attracted significant attention across the globe. In this paper, these two kinds of waste materials are used to prepare porous sound-absorbing materials, so as to achieve efficient resource utilization and environmental protection, and promote green manufacturing and circular economy. In this study, steel slag and high-alumina fly ash were used as the primary raw materials to prepare green bodies via organic foam impregnation. Subsequently, a high-temperature sintering process was implemented to get the porous sound absorption material product from the green bodies. The effects of several factors, including the ratio of steel slag and fly ash, sintering temperature, and pore structure, on the sound absorption and mechanical properties of the product were investigated. Based on the anorthite region in the CaO–Al2O3–SiO2 ternary phase diagram region, the composition ratio of the material was designed. The composition and microstructure of the material were characterized by X-ray diffraction and scanning electron microscopy. From the results, with the increase of the ratio of fly ash and steel slag, the composition of low melting point substances in the system decreases, and the amount of liquid phase decreases, which weakens the pore blocking phenomenon inside the material, resulting in the increase of pore size and noise reduction coefficient of the material. Besides, higher sintering temperature tends to correlate to greater density and higher compressive and flexural strengths but lower porosity, and the sound absorption coefficient demonstrated a peak with respect to sintering temperature. Furthermore, when the reduction of polyurethane sponge body pore size was taken into account, the product's sound absorption coefficient also showed a peak. The optimal parameters for our porous materials are as follows: fly ash:steel slag = 48 : 25, polyurethane sponge pore size = 40 ppi, sintering temperature = 1160 °C at 1-h duration (bulk density = 573.98 kg/m3), compressive strength = 1 MPa, porosity = 79.35 %, and noise reduction coefficient = 0.47.

Understanding the synergistic geopolymerization mechanism of multiple solid wastes in ternary geopolymers

The use of ground granulated blast furnace slag (GBFS), fly ash (FA) and steel slag (SS) to form ternary geopolymers consumes several industrial solid wastes and produces high-performance construction materials. However, the unexplored synergistic geopolymerization mechanism of multiple solid wastes limits the design of high-performance ternary geopolymers. This study investigated the synergistic mechanism through testing the macroscopic performances such as unconfined compressive strength (UCS), final setting time (FST) and fluidity, and characterizing the microscopic structure of ternary geopolymers with different mixture proportions. In addition, the influence of variables on strength development of ternary geopolymers is analyzed by developing machine learning models. Results reveal that the highest strength of ternary geopolymers was achieved at a ratio of FA to GBFS to SS of 3:5:2, and alkali activator to precursor materials of 0.08. Addition of 20 % SS refines the pore network, reducing cumulative and detrimental pore volumes, thus enhancing compressive strength. In addition, the SS addition extends the heat generation peak during geopolymerization due to its slower reaction kinetics. Material components (Na/Al, Si/Al, Ca/Si) have a significant influence on UCS, with Na/Al ratio being the most sensitive variable. The study provides a new approach for utilization of bulk industrial wastes.

Study on the high-temperature resistance of metakaolin-fly ash-based geopolymers

The effect of high temperature will trigger the evolution of a series of phase compositions and microstructures within metakaolin-fly ash-based geopolymers, resulting in changes in the deterioration of mechanical properties. To study the high-temperature resistance of metakaolin-fly ash-based geopolymers, the ratio of metakaolin and fly ash was adjusted. This article studied compressive strengths, visual appearance, mass loss ratio, permeability, products, and microstructure. The results showed that as the temperature increases, the compressive strength first increases and then decreases. The geopolymers have the highest compressive strength after exposure to temperatures of 200 °C. The change in compressive strength is determined by both the increase caused by the polymerization reaction and the decrease caused by microcracks. Moreover, metakaolin-fly ash-based geopolymers containing 75% metakaolin (GFMK-75) have the best high-temperature resistance. The residual compressive strengths of GFMK-75 after exposure to 200, 600, 800, and 1000 °C for 2 h are 183.1%, 95.2%, 75.8%, and 65.2%, respectively. Other analyses all confirmed the above conclusions. In summary, the residual compressive strength of metakaolin-fly ash-based geopolymers is highest after exposure to 200 °C, and GFMK-75 shows the best high-temperature resistance compared to others. The findings offer a theoretical foundation for the high-temperature resistance of metakaolin-fly ash-based geopolymers.

Experimental study on CO2 sequestration capacity and mechanical characteristics evolution of solid wastes based carbon-negative backfill materials

The employment of solid waste, notably coal gangue, in carbon-negative backfill mining technology for mineralization and filling in coal mine gobs, is recognized as a productive method for carbon sequestration and waste management, with research primarily dedicated to engineering advanced mineralized backfill materials. Under this background, four variables, including the ratio of gangue to solids (RG-S), water-cement ratio (RW-C), ratio of fly ash to solid wastes providing calcium (Ca) (RA-Ca), and ratio of flue gas desulfurization (FGD) gypsum to carbide slag (RF-CS) were defined to formulate gangue-based mineralized backfill materials, with orthogonal experiments assessing their effects on CO2 sequestration and mechanical characteristics. The results indicate that RW-C consistently emerges as the primary factor influencing both the amount of sequestered CO2 and the mechanical properties of gangue-based solid waste mineralized backfill materials. The amount of sequestered CO2 demonstrates a direct proportionality to RW-C and mechanical strength demonstrates an inverse relationship with RW-C. After 45 minutes of stirring and carbon sequestration, samples in various groups exhibited an maximum sequestered CO2 amount of 18.96 g·kg−1, with a maximum sequestration rate of 0.20 g·kg−1·min−1. The process of CO2 sequestration enhances the compressive properties of mineralized backfill materials derived from gangue based solid wastes.

Low-temperature subcritical water dechlorination composites of waste PVC/coal fly ash with powerful sensing activity for chemiluminescent detection of acetamiprid and imidacloprid

Pesticide residues in agricultural products are serious threat to people's health. Real-time monitoring of pesticides residues in the environment and agricultural products posed challenges to sustainable methods with high analytical performance for pesticide detection. Herein, waste PVC/coal fly ash (the mass ratio of PVC and coal fly ash was 4:1) was dechlorinated in subcritical water at low temperature to achieve nearly 100 % dechlorination of PVC and obtain carbon-based composite materials (CM-Fe/Al/Si-dPVC) with strong sening activity. For CM-Fe/Al/Si-dPVC, CFe bonding resulted in strong electron migration, and nano/μm SiO2 and Al2O3 doping in the layered polyene C matrix provided large specific surface area, and silicon hydroxyl created good heterogeneous catalytic interfaces. CM-Fe/Al/Si-dPVC could strongly trigger luminol chemiluminescence (CL) reaction and produce intense CL signals. Neonicotinoid pesticides (acetamiprid and imidacloprid) bonded with CM-Fe/Al/Si-dPVC through coordination chelation and hydrogen bonding, which shielded the catalytic active site and increased the Fermi level of system, thus quenching CL reaction. Inspired by these, a cheap CL assay was constructed for detecting neonicotinoids combinations of acetamiprid and imidacloprid (NICs). The detection limits of NICs were 0.7 ng/L. Satisfactory recoveries were obtained for real agricultural products and environmental samples. The results of life cycle evaluation (LCA) revealed that the strategy had significantly small global warming potential (GWP). This work presented a sustainable method with environmental benefits for the detection of neonicotinoids, and also opened up new way for the recycling of organic solid wastes.

Multi-objective optimization of ternary geopolymers with multiple solid wastes

The design of the mixtures of ternary geopolymers is challenging due to the need to balance multiple objectives, including cost, strength, and carbon emissions. In order to address this multi-objective optimization (MOO) problem, machine learning models and the NSGA-II algorithm are employed in this study. To train the machine learning models, namely Artificial Neural Network (ANN), Support Vector Regressor, Extremely Randomized Tree, and Gradient Boosting Regression, 120 mixtures with uniaxial compressive strength (UCS) values of ternary geopolymers with fly ash (FA), granulated blast furnace slag (GBFS) and steel slag (SS) as precursor materials were obtained from laboratory tests. Results show that the ternary geopolymer with the ratio of FA:GBFS:SS of 2:5:3 has the highest 28-d UCS of 46.8 MPa. The predictive accuracy of the ANN model is the highest with R = 0.949 and RMSE=3.988 MPa on the test set. Furthermore, the Shapley Additive Explanations analysis indicates that precursor materials exhibit the most significant influence on the UCS, with the content of GBFS being particularly influential. Based on the ANN model and NSGA-II algorithm, a multi-objective optimization (MOO) model is developed to optimize simultaneously the strength, cost and carbon emission of the ternary geopolymer. The derived MOO model can be used to design mixtures of other cementitious materials with multiple objectives.

Investigation and Utilization of Alkali-Activated Grouting Materials Incorporating Engineering Waste Soil and Fly Ash/Slag

The alkali-activated composites technique is a promising method for the in situ preparation of cavity filling/grouting materials from engineering waste soil. To investigate the feasibility of engineering waste soil utilization by the alkali activation process, the macroscopic and microscopic properties of the fly ash/slag-based alkali-activated composites, after solidification/stabilization (S/S) with sandy clay excavated at Baishitang Station of Shenzhen Metro, were studied. The unconfined compressive strength (UCS) test was conducted to evaluate the S/S effect of alkali-activated composites. The results show that the optimum quality ratio of slag and fly ash correspond to 7:3, the modulus of alkaline activator to 1.3, and the alkalinity of alkaline activator to 10%. The alkali-activated composite’s strength under these parameters can reach 45.25 MPa at 3 days, 49.85 MPa at 7 days, and 62.33 MPa at 28 days. A maximum 3-day UCS of 21.71 MPa, 75% of the 28-day UCS, was achieved by an engineering waste soil and alkali-activated composites mass ratio of 5:5, slaked lime content of 4.5%, and a water-to-solid ratio of 0.26, and it can also meet the required fluidity and setting time for construction well. Fluidity is primarily affected by the soil-to-binder ratio, which decreases as the ratio decreases, while the water-to-solid ratio increases fluidity. Slaked lime has minimal impact on fluidity. The setting time is mainly influenced by the soil-to-binder ratio, followed by slaked lime content and water-to-solid ratio, with setting time shortening as the soil-to-binder ratio and slaked lime content increase, and lengthening as the water-to-solid ratio increases. Through Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), and Energy Dispersive Spectroscopy (EDS) tests, microscopic analysis showed that loose granular units are firmly cemented by alkali-activated composites. Based on the results of on-site grouting tests in karst caves, the alkali-activated grout materials reached a strength of 5.2 MPa 28 days after filling, which is 162.5% of the strength of cement grouting material, satisfying most of the requirements for cavity filling in Shenzhen.

Age-dependent deflection analysis of high-volume fly ash RC beams: experimental and artificial neural network modelling

This research examines the influence of high-volume fly ash (HVFA) on reinforced concrete (RC) beam deflections over 180 days of continuous loading. The study comprises eight fly ash-based concrete mixes with varying fly ash ratios (0–60%). Experimental assessments were conducted on two load levels, corresponding to 25% and 50% of the initial cracking load. Thirty-two full-scale RC beams, each measuring 100 × 150 × 1800 mm, were fabricated for both load levels. Long-term deflections were monitored for all concrete mixes through sustained four-point bending tests at ages ranging from 1 to 180 days. A comparative analysis of the overall mid-span deflection between conventional and fly ash concrete RC beams was carried out against established design codes. It was determined that high-volume fly ash RC beams exhibited less creep and shrinkage deflection compared with conventional RC beams. Moreover, artificial neural network (ANN) modelling was also carried out to propose a significant model helpful in predicting the total deflection of RC beams containing any fly ash content and at any age of concrete. The present study offers valuable insights for engineers and designers, facilitating the evaluation of age-dependent deflection patterns in RC beams constructed with reinforced high-volume fly ash concrete.