It is not only a theoretical problem, but also a practical problem to study the behavior of college students in social networks and the countermeasures of Ideological and political education. At present, the development of Internet and mobile communication technology for the birth of a new social media has become a contains a variety of social and cultural dissemination and communication, social psychology, group social groups living lifestyle and interpersonal relationships complex semantics of new media and social ecological network and information communication become more real-time, intuitive, convenient and widely, which also makes the subject consciousness and constantly enhance the contemporary college students, from the way of thinking to value orientation, from the aesthetic taste to the life etiquette is becoming more and more personalized and diversified, the choice of space is more broad. All these bring new opportunities and challenges to the ideological and political education in colleges and universities. With the development of the Internet social network and the popularity of smart phones, as young students more likely to try and accept new things, more and more college students to join the ranks of social networking users. In Microblogs, Webchat and other new media network platform to flourish, these new social media in the information at the same time, but also become an important platform for college students to express their own ideas and exchanges. In the "Several opinions of the Ministry of education to strengthen the ideological and political education work into the network" has made it clear that "according to changes in the environment and object of education, make full use of network means to expand the vision of Ideological and political education, correct, positive and healthy ideology and culture occupy the position of network". As a new carrier of College Students' network activity, social network has an important impact on college students. It is worth to pay attention to the ideological and political education work.