For a class of models of random two-phase media we derive and numerically evaluate expressions for the porosity (matrix volume fraction) φ and the specific surface (interface area per unit volume) s, as well as certain generalizations of these quantities. In these models the medium is considered as a suspension of mutually interpenetrable D-dimensional spheres of radius R, embedded in a uniform matrix. The models and quantities considered have applications to a variety of problems concerning transport, mechanical, electromagnetic, and chemical properties of composite media. Spatial dimensionality D=3 is appropriate for a wide range of composite media, whereas D = 2 describes certain fiber composites (parallel cylindrical inclusions), and D = 1 is appropriate for layered structures. The models considered here contain a hardness parameter ϵ, such that for ϵ = 1 they reduce to mutually impenetrable (hard) spheres, and for ϵ = 0 they reduce to randomly placed spheres. We consider three specific models in this class. The first of these, the permeable—sphere model, is considered in the Percus-Yevick approximation to obtain the two-point distribution function g 2(r 1, r 2). We obtain the n-point distribution functions g n (r 1, …, r n ) for n ⩾ 3 in the generalized superposition approximation. We also evaluate the lowest-order corrections to this approximation, finding that for all φ and ϵ it reliably gives φ as a function of inclusion number density. For the second model, the concentric-shell model, φ and s are evaluated in the scaled-particle approximation. The generalizations φ( R̂) and s( R̂), which are the volume fraction and specific surface available to a probe particle of finite radius R ̂ , are also derived and evaluated. For randomly placed spheres (ϵ = 0) these quantities are also considered for polydisperse media. An application to gel size-exclusion chromatography is considered. We find that varying the hardness parameter ϵ or the polydispersivity provides better agreement between theory and experiment than is obtained by using a monodisperse randomly placed sphere model of the gel. A comparison of the density expansions of φ and s for the permeable-sphere and concentric-shell models confirms that the considerable quantitative differences we find between these two conceptually distinct models are not simply the result of the approximation procedures that we use in evaluating their properties. Finally we introduce a new class of models, based on mixtures of spheres of different mutual interpenetrability. For one particular such model we obtain exact expressions for φ and s for general ϵ, as well as the two-point matrix function S 2(r) in the Percus—Yevick and Verlet—Weis approximations.
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