Results are presented from FIR, sub-mm, and mm spectroscopic observations of the radio arc and the +20/+50 km/s molecular clouds in the Galactic center. The results for the radio arc are analyzed, including the spatial distribution of C II forbidden line emission, the spatial distribution of CO emission, the luminosity and mass of C(+) regions, and the CO 7 - 6 emission and line profiles. Model calculations are used to study molecular gas in the radio arc. In addition, forbidden C II, CO 7 - 6, and C(O-18) mapping is presented for the +20/+50 km/x clouds. Consideration is given to the impact of the results on the interpretation of the physical conditions, excitation, and heating of the gas clouds in the arc and near the center.