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Published in last 50 years
New substrate to investigate radical cycloadditions. II. Addition reactions of some representative carbenes to 1,1-dicyclopropylethylene
Fluorenylidene reacts with 1,1-dicyclopropylethylene to give a cycloadduct (5) and the rearranged adduct (6) in a ratio of 10:1; dilution with decalin inverses the ratio to 1:3, which may be due to the increased amount of triplet fluorenylidene.