Total cross sections for radiative double electron capture (RDEC) in collisions of fast highly charged ions with light target atoms were estimated. The applied method is based on the principle of detailed balance using the cross sections for the double photoionization process. Preliminary results of a dedicated RDEC experiment aiming at the observation of photons with twice the single REC photon energy, associated with double charge exchange, are discussed. Additionally, results of complementary measurements of double capture (without photon registration) by fully stripped U ions in collisions with C atoms at 295 MeV/u are presented. Here, a surprisingly enhanced cross section for double electron capture is found in accordance with observations reported in the literature.