For the various forms of the spin-lattice coupling in paramagnetic salts of the iron group ions, derived in a previous paper, a semiclassical phonon radiation theory is developed. The phonon fields are analyzed in terms of phonon multipole fields, and the phonon multipole moments are expressed in terms of the effective spin variable. The phonon multipole fields are all monopole fields in the sense that the corresponding static fields fall off at large distances as R−2, but they are monopole, dipole, and quadrupole fields as far as the angular dependence is concerned. As a result, the rates of emission by the different phonon multipoles are all of the same order of magnitude. The equation of motion of a dressed spin is derived, and the phonon radiation damping is shown to depend on the third time derivative of the phonon multipole moments. As an application, the classical theory of the resulting spin-lattice relaxation is discussed briefly.
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