Radial Pore Research Articles

Enhanced Hydrodeoxygenation performance through novel Al-Doped radial channel Silica-Supported Carbon-Encapsulated nickel catalysts

Hydrodeoxygenation (HDO) plays a crucial role in upgrading pyrolysis-oil derived from biomass. Here we describe a method for fabricating a carbon-encapsulated nickel metal–acid bifunctional catalyst (Ni@C/RCS-Al) supported on aluminum-doped radial channel silica (RCS-Al). This catalyst exhibits a large surface area and highly dispersed accessible active sites, achieved through a combination of salicylate- and MOF-assisted strategies. The RCS-Al was prepared by a one-pot salicylate-assisted hydrothermal method in an aqueous phase containing an Al source, which is simple, has a high yield, and saves time. The results show that Ni@C/RCS-Al displays a well-defined radial channel pore structure with a mesopore diameter of 31.1 nm, which can significantly increase the number of accessible active sites and accelerate mass transfer. The MOF-assisted strategy leads to the formation of highly dispersed smaller carbon-encapsulated nickel nanoparticle active sites, and Al doping contributes to the adjustable acid sites, demonstrating that Ni@C/RCS-Al is a metal–acid bifunctional catalyst. Importantly, the kinetics study revealed a high reaction constant for the constructed Ni@C/RCS-Al catalyst. Ni@C/RCS-Al demonstrates remarkable performance in HDO, achieving complete m-cresol conversion and 100 % selectivity to the target product methylcyclohexane within a brief period of 75 min (T = 250 °C p = 2 MPa, m-cresol/catalyst (g) = 7.5). This exceptional performance stems from its radial channel pore structure and optimization of metal–acid sites. The thin carbon layer on the Ni surface contributes to its superior stability and water resistance, as verified by an experimental study and DFT calculations. This work opens up a new idea for the application of radial channel silica-supported catalysts in various reactions.

The combustion characteristics and stable limit of a novel combustor with gradient porous media for hydrogen-enriched natural gas

Injecting hydrogen into natural gas pipelines for delivery to end users is currently considered as one of the potential solutions to the challenges of hydrogen transportation and utilization. However, the blending of hydrogen accelerates the flame propagation speed of the mixture, leading to flame instability and other issues. In this paper, a gradient porous structural burner was proposed, then the effects of pore size gradient and porosity gradient on the combustion characteristics and stability limits of hydrogen-enriched natural gas flames were investigated numerically. This paper proposed a spatial gradient-based porous structure, and the results showed that the axial gradient porous structure with increasing pore size enhances the maximum temperature by approximately 26 %. The radial gradient structures with decreasing porosity and increasing pore size increased the maximum temperature by approximately 25.8 % and 24.8 %, respectively, and improved flame uniformity. Compared to the conventional two-stage uniform structure, the axial pore size increment structure improved the stability limit by approximately 117 %, while the radial pore size increment structure increased the stability limit by 47 %. The results provide reference for the design and optimization of new porous media burner structures that are applicable under wide power ranges and hydrogen blending conditions.

Development of a five-axis printer for the fabrication of hybrid 3D scaffolds: From soft to hard phases and planar to curved surfaces

Three-dimensional (3D) printing of hybrid scaffolds with material gradients, combining soft and hard phases, is an appealing frontier in additive manufacturing. However, most 3D printers are limited to either three-axis or mono-material capabilities, rendering them unsuitable for fabricating hybrid scaffolds. Additionally, printing on curved surfaces requires advanced printing capabilities. Our work aims to advance additive manufacturing by developing a hybrid piezoelectric inkjet-extrusion printer equipped with five-axis functionalities. The printer could be used to fabricate customized hybrid scaffolds, surpassing conventional mono-material or linear three-axis printing strategies. The soft phase comprises a low-viscosity photocurable resin and a high-viscosity peptide hydrogel, while the hard phase comprises 3D-printed polylactic acid and hydroxyapatite parts. To validate the system, we fabricated three hybrid scaffolding use cases, characterized by multi-material porous structures fabricated on planar, single-curved, and free-form surfaces. The scaffolds were subsequently analyzed using digital microscopy to assess their accuracy, particularly the feature sizes of pores and struts (i.e., 0.8–3.6 mm). In the first part of the study, we demonstrated the versatility of inkjet and extrusion printing by hybrid printing an interconnected network in the soft phase on top of a planar ceramic hard phase. A pore width and height deviation of 6% was achieved compared to the intended design. In the second part of the study, we evaluated the 3D inkjet printing of a multi-material porous scaffold on a single-curved surface for osteochondral defects. The circumferential pore width and radial pore height deviated by 0.8% and 2%, respectively. Finally, we inkjet-printed a mesh structure on a free-form surface, which acted as a membrane for palatal implants. In this case, the pore width deviations were -16% in the printing direction and 2% perpendicular to the printing direction.

Cell-free chitosan/silk fibroin/bioactive glass scaffolds with radial pore for in situ inductive regeneration of critical-size bone defects

Tissue-engineered is an effective method for repairing critical-size bone defects. The application of bioactive scaffold provides artificial matrix and suitable microenvironment for cell recruitment and extracellular matrix deposition, which can effectively accelerate the process of tissue regeneration. Among various scaffold properties, appropriate pore structure and distribution have been proven to play a crucial role in inducing cell infiltration differentiation and in-situ tissue regeneration. In this study, a chitosan (CS) /silk fibroin (SF) /bioactive glass (BG) composite scaffold with distinctive radially oriented pore structure was constructed. The composite scaffolds had stable physical and chemical properties, a unique pore structure of radial arrangement from the center to the periphery and excellent mechanical properties. In vitro biological studies indicated that the CS/SF/BG scaffold could promote osteogenic differentiation of bone marrow mesenchymal stem cells (BMSCs) and the expression of related genes due to the wide range of connected pore structures and released active elements. Furthermore, in vivo study showed CS/SF/BG scaffold with radial pores was more conducive to the repair of skull defects in rats with accelerated healing speed during the bone tissue remodeling process. These results demonstrated the developed CS/SF/BG scaffold would be a promising therapeutic strategy for the repair of bone defects regeneration.

Dual signal amplification platform based on recombinant polymerase amplification and fluorescence-enhanced nanoparticles for sensitive detection of Salmonella

Salmonella is a common foodborne pathogen, and its detection is essential for managing public food safety. Lateral flow assay (LFA) strips are well suited for the purpose as they are inexpensive and easy to use. However, the sensitive detection of low-concentration targets requires the use of signal amplification strategies. This paper presents a LFA for the ultrasensitive detection of Salmonella based on recombinase polymerase amplification (RPA) and fluorescence-enhanced composite nanospheres dSiO2@CD@SiO2 (dCDS). RPA is capable of rapid (∼20 min) exponential amplification of bacterial DNA and does not require complex instrumentation. Mesoporous silica (dSiO2) has a large specific surface area and radial pore size, making it an excellent structural material for internal assembly. Nanoparticles obtained by loading carbon dots (CDs) had a strong fluorescence signal and stability. We used dCDSs as reporter molecules, which captured a large number of DNA-dCDS complexes on the test line of the LFA. With double signal amplification, the RPA and dCDS-based LFA showed greatly improved sensitivity: The limits of detection for Salmonella in buffer and milk were 3.8 CFU/mL and 36 CFU/mL, respectively. This study provides an inexpensive strategy for the sensitive detection of pathogenic bacteria.

Microfabrication of Li4SiO4 pebbles with complex pore structure via digital light processing: Accuracy control and properties optimizing

Li4SiO4 ceramic pebble is deemed as the most attractive tritium breeder for fusion reactor blanket. In this work, we fabricated a novel Li4SiO4 pebble with micrometer-scale pore structure by digital light processing to verify the feasibility of complex pore structure manufacturing for future breeders. The effects of processing parameters on printing accuracy, microstructure and mechanical properties of Li4SiO4 pebbles were investigated. For synthesizing the pure Li4SiO4 phase, the optimal stoichiometric ratio of Li2SiO3 to Li2CO3 was 1:1.09 in the premixed powder. The photosensitivity of dual-phase ceramic suspension was investigated according to an attenuation model, and the overgrowth was reduced to ∼50 μm by using the dimension formula. After optimizing the post-processing, the radial pore structure Li4SiO4 pebbles with excellent crush load (50.3 N, standard deviation = 4.4 N) and suitable open porosity (18.3 %) can be yielded. This work provides a fresh solution to control the pore structure of tritium breeding pebbles in an unprecedented micrometer scale.

Influence of structural parameters of 3D-printed triply periodic minimal surface gyroid porous scaffolds on compression performance, cell response, and bone regeneration.

In this study, multi-scale triply periodic minimal surface (TPMS) porous scaffolds with uniform and radial gradient distribution on pore size were printed based on the selective laser melting technology, and the influences of porosity, pore size and radial pore size distribution on compression mechanical properties, cell behavior, and bone regeneration behavior were analyzed. The results showed that the compression performance of the uniform porous scaffolds with high porosity was similar to that of cancellous bone of pig tibia, and the gradient porous scaffolds have higher elastic modulus and compressive toughness. After 4 days of cell culture, cells were distributed on the surface of scaffolds mostly, and the number of adherent cells was higher on the small pore size porous scaffolds; After 7 days, the area and density of cell proliferation on the scaffolds were improved; After 14 days, the cells on the small pore size scaffolds tended to migrate to adjacent pores. Animal implantation experiments showed that collagen fiber osteoid was intermittent on scaffolds with high porosity and large pore size, which was not conducive to bone formation. The appropriate pore size and porosity of bone regeneration were 792 um and 83%, respectively, and the regenerative ability of gradient pore size was better than that of uniform pore size. Our study explains the rules of TPMS gyroid structure parameters on compression performance, cell response and bone regeneration, and provides a reference value for the design of bone repair scaffolds for clinical orthopedics.

Effect of Borehole Radial Pore Pressure Gradient on the Initiation and Propagation of Sandstone Hydraulic Fractures

Effect of Borehole Radial Pore Pressure Gradient on the Initiation and Propagation of Sandstone Hydraulic Fractures

Multi-scale microstructure quantitative characterization and anti-erosion performance of PHC pipe pile

Pre-stressed high-strength concrete (PHC) pipe pile is widely used in many large-scale projects, thus their durability has attracted more and more attention. However, in most studies, PHC pipe pile is regarded as the same as ordinary reinforced concrete, ignoring the effect of special construction processes and hollow shape on its microstructure and anti-erosion performance. In this paper, the real PHC pipe pile was cored and cut to investigate the multi-scale microstructure and the anti-erosion performance of PHC pipe pile concrete layer. The results shown that pore content first increases and then decreases with PHC pipe pile from the outer layer to the inner layer (5F → 1F) by CT, BSE and LF-NMR results, and the pore content changes most significantly around the rebar in PHC pipe pile. In rebar interfacial transition zone (ITZ), the thickness of the voids in PHC pipe pile is greater than that of normal reinforced concrete under the same water-binder ratio condition. Additionally, the content of un-hydration products in aggregate ITZ is obviously greater than that in rebar ITZ. Furthermore, the chloride ion diffusion coefficient of the concrete on the outside of the PHC pipe pile is slightly larger than that on the inside, which is closely related to the higher pore connectivity of the concrete on the outside of the PHC pipe pile. Moreover, it was found that centrifugation can not only reduce the water-binder ratio of PHC pipe pile but also affect the radial pore structure of PHC pipe pile concrete, including porosity and pore connectivity. This work finally indicated that the microstructure of PHC pipe pile concrete is quite different from that of normal reinforced concrete, providing a theoretical basis for establishing the diffusion model of PHC pipe pile concrete.

Design and assessments on graded metal foam in heat storage tank: An experimental and numerical study

The effectiveness of solidification in latent heat storage (LHS) systems has been restricted by the low thermal conductivity of pure phase change materials (PCMs). To address this challenge, an innovative composite PCM impregnated with metal foam has been introduced. This study investigates a vertical thermal energy storage (TES unit) filling with foamed copper with radial gradient pore density, with a focus on enhancing energy storage and heat conduction mixing through natural convection. Experiments and numerical models are employed to research the variation of liquid fraction, solid-liquid interfaces, temperature field, and velocity field, as well as to assess heat release properties, including thermal transfer distribution and heat release quantity. Results indicate a 14.3% reduction in solidification duration for both positive and negative radially graded pore density arrangements, compared to a homogeneous structure. In addition, temperature uniformity is improved by 4.0% in these two optimization structures, due to the influence of varied pore density. Findings from this work offer guidance for building more efficient latent energy storage tanks.

Radially graded metal foams arrangement in heat storage device of photothermal utilization systems

Metal foam was adopted for improving inherent low thermal conductivity of traditional thermal energy storage (TES), which conducted higher solar energy conversion efficiency. With consideration of more energy response and the mixing enhancement effect on heat conduction and natural convection, this work investigated a vertical TES tube in solar energy photothermal utilization systems, embedded in metallic foam with radial gradient porosity and pore density. Experiments and simulations have both been carried out. It is thoroughly examined how the liquid fraction, solid-liquid interface, temperature field, and velocity field evolve, and the properties of energy storage, such as heat transfer density and energy storage quantity, are further assessed. Results demonstrated that the melting duration was shortened by 11.2% for the positive radially graded porosity arrangement and prolonged by 16.8% for the negative, in comparison to the homogeneous structure. Meanwhile, influenced by the varied porosity, the temperature uniformity was enhanced by 4.9% for the positive and was deteriorated by 15.1% for the negative. In addition, positive and negative gradient pore density respectively increased the temperature uniformity of by 15.1% and 16.7%. Based above, metal foam tube with negative gradient porosity and pore density was suggested to build the more efficient photothermal solar energy conversion systems due to faster melting process and more homogeneous temperature uniformity.

Storing CO2 in geothermal reservoir rocks from the Kizildere field, Turkey: Combined stress, temperature, and pore fluid dependence of seismic properties

As part of a seismic monitoring project in a geothermal field, where the feasibility of re-injection and storage of produced CO2 is being investigated, a P- and S-wave seismic velocity characterisation study was carried out. The effect of axial and radial (up to 42 MPa) stress, pore pressure (up to 17 MPa), pore fluid (100% brine or supercritical CO2) and temperature (21–100 °C) on seismic properties were studied in the laboratory for the two main reservoir formations at the Kızıldere geothermal reservoir. Each (un)confined compressive strength test performed revealed a similar trend: rapidly increasing velocity at low stresses followed by a more moderate increase at higher stresses. The data implied that the stress-dependency of the velocity increased with temperature. Increasing temperatures resulted in decreasing P-wave velocities due to mineral thermal expansion. This temperature-dependency increased with reducing stress levels. The S-wave velocity seems to be more sensitive to changes in pore pressure than the P-wave velocity. On the other hand, the S-wave velocity is less affected by an increasing axial stress compared to the P-wave velocity. By performing multiple nonlinear regression on the velocity dataset, related to a brine-saturated fractured marble, second-degree polynomial trends were found for the P- and S-wave velocity, as a function of temperature, axial stress, and pore pressure, that can potentially be used for predicting velocities at Kızıldere, or other similar, geothermal site(s). For distinguishing between a 100% brine-saturated versus a fully supercritical CO2-saturated fracture, the arrival times of the first arrivals were too close to each other to allow their utilization. The fracture aperture was too small compared to the wavelength of the source signal. However, differences in P- and S-wave amplitudes of the first arrivals were seen, where the supercritical CO2-saturated crack revealed consistently lower peak and trough amplitudes compared to the brine-saturated scenario.

Stress‐Regulation Design of Mesoporous Carbon Spheres Anodes with Radial Pore Channels Toward Ultrastable Potassium‐Ion Batteries

Electrochemical energy storage (EES) devices are expected to play a critical role in achieving the global target of “carbon neutrality” within the next two decades. Potassium‐ion batteries (KIBs), with the advantages of low cost and high operating voltage, and they could become a major component of the required energy‐material ecosystems. Carbon‐based materials have shown promising properties as anode materials for KIBs. However, the key limitation of carbon anodes lies in the dramatic mechanical stress originating from large volume fluctuation during the (de)potassiation processes, which further results in electrode pulverization and rapid fading of cycling performance. Here, a controllable self‐assembly strategy to synthesize uniform dual‐heteroatom doped mesoporous carbon sphere (DMCS) anodes with unique radial pore channels is reported. This approach features a modified Stöber method combined with the single‐micelle template from the molecule‐level precursor design. The DMCS anodes demonstrate exceptional rate capability and ultrahigh cycling stability with no obvious degradation over 12 000 cycles at 2 A g−1, which is one of the most stable anodes. Furthermore, finite element simulations quantitatively verify the stress‐buffering effect of the DMCS anodes. This work provides a strategy from the perspective of stress evolution regulation for buffering mechanical stress originating from large volume fluctuations in advanced KIBs electrodes.

Co-immobilization of Cellulase and β-Glucosidase into Mesoporous Silica Nanoparticles for the Hydrolysis of Cellulose Extracted from Eriobotrya japonica Leaves.

Fungal cellulases generally contain a reduced amount of β-glucosidase (BG), which does not allow for efficient cellulose hydrolysis. To address this issue, we implemented an easy co-immobilization procedure of β-glucosidase and cellulase by adsorption on wrinkled mesoporous silica nanoparticles with radial and hierarchical open pore structures, exhibiting smaller (WSN) and larger (WSN-p) inter-wrinkle distances. The immobilization was carried out separately on different vectors (WSN for BG and WSN-p for cellulase), simultaneously on the same vector (WSN-p), and sequentially on the same vector (WSN-p) in order to optimize the synergy between cellulase and BG. The obtained results pointed out that the best biocatalyst is that prepared through simultaneous immobilization of BG and cellulase on the same vector (WSN-p). In this case, the adsorption resulted in 20% yield of immobilization, corresponding to an enzyme loading of 100 mg/g of support. 82% yield of reaction and 72 μmol/min·g activity were obtained, evaluated for the hydrolysis of cellulose extracted from Eriobotrya japonica leaves. All reactions were carried out at a standard temperature of 50 °C. The biocatalyst retained 83% of the initial yield of reaction after 9 cycles of reuse. Moreover, it had better stability than the free enzyme mixture in a wide range of temperatures, preserving 72% of the initial yield of reaction up to 90 °C.

Axisymmetric transient response of a cylindrical cavity in an unsaturated poroelastic medium

In this study, the transient response of an infinite unsaturated poroelastic medium with an infinitely long uniform cylindrical cavity subjected to axially symmetric transient radial tractions is investigated. Using the Laplace transform, analytical solutions are obtained for three different types of prescribed transient radial pressures (step, gradually applied step, and triangular pulse loads) acting on the surface of a permeable cavity and that of an impermeable cavity. The time histories of the radial displacement, stresses, pore pressure, and discharge are derived by inverting the Laplace domain solutions using a reliable numerical scheme. The solution can be simplified to one in which the infinite medium is assumed to be a saturated poroelastic medium. The validity of the solution was confirmed by comparison with COMSOL numerical solutions. A detailed parametric study is presented to illustrate the influence of the saturation of the unsaturated poroelastic medium on the response of the radial displacement, hoop stress, and pore fluid pressure at the cavity surface under different boundary conditions.

Optimization on the gradually varied pore structure distribution for the irradiated absorber

An optimization method for the gradually varied porous absorber is proposed. The Monte Carlo Ray Tracing method based on the acceptance-rejection sampling is established to obtain the absorption distribution of irradiation in the gradually varied porous absorber. The fluid flow, convection, and thermal radiation in the porous absorber are evaluated. Combined with the genetic algorithms, the distribution of porosity and pore size of the porous absorber could automatically adjust to match the non-uniform radiation flux in both radial and axial directions. Moreover, the internal flow layout could be regulated by an optimized radial pore distribution that directs more fluid enters the high heat flux zone. The optimization results demonstrate that the gradually varied porous absorber with porosity ranging from 0.95 to 0.90 and pore size ranging from 2.5 mm to 1.5 mm could achieve high thermal efficiency and low flow resistance. Compared with the standard model of the uniform porous absorber, the thermal efficiency of the optimal gradually varied porous absorbers could be further increased by 1.23%–9.76%, while the pressure drop could be reduced by 7.88%–55.73%.

3DICE coding matrix multidirectional macro-architecture modulates cell organization, shape, and co-cultures endothelization network

Natural extracellular matrix governs cells providing biomechanical and biofunctional outstanding properties, despite being porous and mostly made of soft materials. Among organs, specific tissues present specialized macro-architectures. For instance, hepatic lobules present radial organization, while vascular sinusoids are branched from vertical veins, providing specific biofunctional features. Therefore, it is imperative to mimic such structures while modeling tissues. So far, there is limited capability of coupling oriented macro-structures with interconnected micro-channels in programmable long-range vertical and radial sequential orientations. Herein, a three-directional ice crystal elongation (3DICE) system is presented to code geometries in cryogels. Using 3DICE, guided ice crystals growth templates vertical and radial pores through bulky cryogels. Translucent isotropic and anisotropic architectures of radial or vertical pores are fabricated with tunable mechanical response. Furthermore, 3D combinations of vertical and radial pore orientations are coded at the centimeter scale. Cell morphological response to macro-architectures is demonstrated. The formation of endothelial segments, CYP450 activity, and osteopontin expression, as liver fibrosis biomarkers, present direct response and specific cellular organization within radial, linear, and random architectures. These results unlock the potential of ice-templating demonstrating the relevance of macro-architectures to model tissues, and broad possibilities for drug testing, tissue engineering, and regenerative medicine.

An integral feature of porous silicon and its classification

Porous silicon is currently one of the most studied materials which is used both in the areas traditional for silicon, such as electronics and optoelectronics, and in completely unconventional ones, such as catalysis, energetics, biology, and medicine. The multiple possibilities of the material are revealed due to the fact that its structure can be radically different depending on the properties of the initial silicon and the methods of obtaining porous phases. The use of any material inevitably leads to the need to classify its various forms. The purpose of the article was to find the most significant parameter that can be used as the basis for the classification of porous silicon.Historically, the terminology defined by the IUPAC pore size classification has been used to classify porous silicon. Due to the authority of IUPAC, many researchers have considered this terminology to be the most successful and important, and the radial pore size has often been regarded as a main parameter containing the most important properties of porous silicon. Meanwhile, the unique properties and practical application of porous silicon are based on its developed inner surface. The method of nitrogen porosimetry, which is simple in its practical implementation, is often used in scientific literature to determine this value.The most suitable integral parameter for the classification of porous silicon, regardless of its structure and morphology, is the total specific internal surface (cm-1) that can be relatively easily established experimentally and is of fundamental importance for almost all applications of porous silicon. The use of this value does not exclude the use of other parameters for a more detailed classification

Radial porous SiO2 nanoflowers potentiate the effect of antigen/adjuvant in antitumor immunotherapy

Here, we reported a cancer nanovaccine based on SiO2 nanoflowers with a special radial pore structure, which greatly enhanced cross-presentation and induced the production of cytotoxic T lymphocyte cells secreting granzymes B and interferon-γ. The antigen ovalbumin was covalently conjugated onto the as-synthesized hierarchical SiO2 nanoflowers, and the adjuvant cytosine-phosphate-guanine was electrostatically adsorbed into their radial pore by simple mixing before use. The nanovaccine exhibited excellent storage stability without antigen release after 27 days of incubation, negligible cytotoxicity to dendritic cells, and a high antigen loading capacity of 430 ± 66 mg·g−1 support. Besides, the nanovaccine could be internalized by dendritic cells via multiple pathways. And the enhancement of antigen/adjuvant uptake and lysosome escape of antigen were observed. Noteworthy, in vitro culture of bone marrow-derived dendritic cells in the presence of nanovaccine proved the activation of dendritic cells and antigen cross-presentation as well as secretion of proinflammatory cytokines. Besides, in vivo study verified the targeting of nanovaccine to draining lymph nodes, the complete suppression of tumor in six out of ten mice, and the triggering of notable tumor growth delay. Overall, the present results indicated that the nanovaccine can be served as a potential therapeutic vaccine to treat cancer.

Orienting the Pore Morphology of Core-Shell Magnetic Mesoporous Silica with the Sol-Gel Temperature. Influence on MRI and Magnetic Hyperthermia Properties.

The controlled design of robust, well reproducible, and functional nanomaterials made according to simple processes is of key importance to envision future applications. In the field of porous materials, tuning nanoparticle features such as specific area, pore size and morphology by adjusting simple parameters such as pH, temperature or solvent is highly needed. In this work, we address the tunable control of the pore morphology of mesoporous silica (MS) nanoparticles (NPs) with the sol-gel reaction temperature (Tsg). We show that the pore morphology of MS NPs alone or of MS shell covering iron oxide nanoparticles (IO NPs) can be easily tailored with Tsg orienting either towards stellar (ST) morphology (large radial pore of around 10 nm) below 80 °C or towards a worm-like (WL) morphology (small randomly oriented pores channel network, of 3–4 nm pore size) above 80 °C. The relaxometric and magnetothermal features of IO@STMS or IO@WLMS core shell NPs having respectively stellar or worm-like morphologies are compared and discussed to understand the role of the pore structure for MRI and magnetic hyperthermia applications.