AbstractThis investigation attempts to address heat and mass transfer behavior exhibited by a steady fully developed natural convective flow of a viscous, incompressible, and electrically conducting fluid in a vertical porous annulus in the presence of radially applied magnetic field and velocity slip. The motion of the fluid in the annular gap is triggered by the buoyancy forces due to temperature gradient of the inner and outer cylinders. The governing momentum and energy equations responsible for the flow are transformed into dimensionless forms using the appropriate dimensionless parameters. Accordingly, analytical solutions of the energy and momentum fields are derived with the appropriate boundary conditions. The effects of the controlling parameters involved in the flow on the temperature field, velocity field, and drag on the walls of the cylinders are illustrated graphically and with the aid of tables. Findings affirm that fluid temperature can be decreased/increased by increasing suction/injection on the porous wall. Furthermore, the fluid flow in the annular gap can be enhanced by increasing Grashof number, fluid injection, and velocity slip.