The urge for energy storage and the advancement of state-of-the-art supercapacitor technology necessitates the exploration of robust electrodes with superb specific capacitance (Cs) and excellent cyclic life. In this perspective, an anomalous quaternary hybrid material (NiMn2O4/NiWO4/NGO/PANI) is synthesized through polymerization of aniline in the presence of a ternary hybrid (NiMn2O4/NiWO4/NGO), while the ternary (NiMn2O4/NiWO4/NGO), binary (NiMn2O4/NiWO4), and pristine (NiMn2O4 and NiWO4) materials are synthesized by hydrothermal route. The electrochemical performance as well as the physiochemical peculiarities of all the hybrids and pristine materials are analyzed. Electrochemical experimentation reveals that among all prepared electrodes, the quaternary electrode (NiMn2O4/NiWO4/NGO/PANI) possesses remarkable Cs = 636 F/g at 2 mV/s, with minimum ohmic (0.6125 Ω) and charge transfer (0.357 Ω) resistances. Moreover, the proposed quaternary electrode exhibits Cs = 682 F/g at 0.5 A/g with superior energy density (28.68 Wh/kg at 0.5 A/g), power density (5499.92 W/kg at 20 A/g), and 94.11 % capacitive retention over continuous 10,000 charge/discharge cycles at 30 A/g, through GCD experiment. Optimized composition, morphology, mesoporosity, and quasi-crystalline nature of NiMn2O4/NiWO4/NGO/PANI recommend the novel quaternary hybrid as a distinctive electrode for composite hybrid-type supercapacitor applications.