Single Grains Of Quartz Research Articles

Identifying well-bleached quartz using the different bleaching rates of quartz and feldspar luminescence signals

When dating older sedimentary deposits using quartz, there are no unambiguous methods for identifying the presence of incomplete bleaching. Current statistical analysis of dose distributions depends entirely on the assumption that incomplete bleaching and mixing are the main causes of any excess dispersion in the distribution; the only existing way to test this assumption is using independent age control. Here we suggest a new approach to this question, based on the differential bleaching rates of quartz and feldspar luminescence signals. We first present data that confirm the differences in relative bleaching rates of quartz optically stimulated luminescence (OSL) and feldspar luminescence stimulated at 50 °C by infrared light (IR 50 ) and feldspar luminescence stimulated at 290 °C by infrared light after a stimulation at 50 °C (pIRIR 290 ), and use recently deposited samples to determine the likely significance of the difficult-to-bleach residual feldspar signals in non-aeolian samples. For a set of mainly Late Pleistocene non-aeolian sediments, large aliquot quartz doses are then used to predict feldspar doses (based on a knowledge of the sample dose rates). The differences between observed and predicted feldspar doses as a function of the quartz dose, combined with a conservative assumption concerning the relative feldspar and quartz residual signals after natural bleaching prior to deposition, are used to identify those samples for which the quartz is very likely to be well bleached (20 out of 24). Two of these apparently well-bleached samples are then examined using single-grain quartz dose distributions; one of these is consistent with the well-bleached hypothesis, and one indicates poor bleaching or a multi-component mixture. However, independent age control makes it clear that the large aliquot data are more likely to be correct. We conclude that a comparison of quartz and feldspar doses provides a useful independent method for identifying well-bleached quartz samples, and that it is unwise to apply statistical models to dose distributions without clear evidence for the physical origins of the distributions.

Single-grain dating of young sediments using the pIRIR signal from feldspar

In this article we test for the first time the potential of single-grains of K-rich feldspar to date well-bleached and poorly bleached sediments using a post-IR IRSL (pIRIR) protocol. We measure natural dose distributions using K-rich feldspars from four coastal samples applying the pIRIR protocol with a preheat of 200°C and a pIRIR stimulation temperature of 180°C; each sample had an independent age control obtained from quartz OSL and radiocarbon dating. We also analyse single-grain dose distributions of “zero-dose” and γ-irradiated samples to determine thermal transfer/residual doses and the intrinsic sources of variability of pIRIR single-grain measurements, respectively. Based on these experiments, we conclude that thermal transfer/residual dose give rise to an offset of ∼0.6Gy in these samples and that the uncertainty assigned to individual pIRIR single-grain dose estimates cannot be smaller than 16.5%.The analysis of the well-bleached samples shows that only the brightest 30% of the grains give pIRIR single-grain ages in agreement with the age control; this effect may arise from the suggested correlation between blue emission and potassium content of individual grains. Comparison of single-grain quartz and feldspar dose distributions from the poorly bleached samples shows that quartz is relatively better bleached; nevertheless, selection of a reliable ‘minimum’ feldspar dose was achieved using two different statistical models.

Sheared-bedding parallel quartz vein as an indicator of deformation processes

Monomineralic veins are well known as good recording of filling and precipitation processes. However, they are also able to register the action of deformation in rocks. We used monomineralic, quartz veins from Quadriláterro Ferrífero, Brazil, to represent how the deformation actuated during the transformation of different structures. They were analyzed using a combination of a u-stage and EBSD. Two main types of quartz aggregates are distinguished: single crystals with subgrain development and strain-free grains of quartz. We interpret the microstructures and textures as the result of a combination of concurrent crystal plasticity, microfracturing, solution transfer and recrystallization. The single quartz grains were deformed by dislocation glide. However, as the c-axis orientation of the grain was not favorable for further glide on basal planes, the deformation was accommodated by microfracturing. New grains were formed along the deformed zones with crystallographic orientations suitable for gliding on basal planes. As the deformation proceeded, the new grains continue to develop until the vein was completely recrystallized into an aggregate of granular grains.

New ages for Middle and Later Stone Age deposits at Mumba rockshelter, Tanzania: Optically stimulated luminescence dating of quartz and feldspar grains

The archaeological deposits at Mumba rockshelter, northern Tanzania, have been excavated for more than 70 years, starting with Margit and Ludwig Köhl-Larsen in the 1930s. The assemblages of Middle Stone Age (MSA) and Later Stone Age (LSA) artefacts collected from this site constitute the type sequences for these cultural phases in East Africa. Despite its archaeological importance, however, the chronology of the site is poorly constrained, despite the application since the 1980s of several dating methods (radiocarbon, uranium-series and amino acid racemisation) to a variety of materials recovered from the deposits. Here, we review these previous chronologies for Mumba and report new ages obtained from optically stimulated luminescence (OSL) and infrared stimulated luminescence (IRSL) measurements on single grains of quartz and multi-grain aliquots of potassium (K) feldspar from the MSA and LSA deposits. Measurements of single grains of quartz allowed the rejection of unrepresentative grains and the application of appropriate statistical models to obtain the most reliable age estimates, while measurements of K-feldspars allowed the chronology to be extended to older deposits. The seven quartz ages and four K-feldspar ages provide improved temporal constraints on the archaeological sequence at Mumba. The deposits associated with the latest Kisele Industry (Bed VI-A) and the earliest Mumba Industry (Bed V) are dated to 63.4 ± 5.7 and 56.9 ± 4.8 ka (thousands of years ago), respectively, thus constraining the time of transition between these two archaeological phases to ∼60 ka. An age of 49.1 ± 4.3 ka has been obtained for the latest deposits associated with the Mumba Industry, which show no evidence for post-depositional mixing and contain ostrich eggshell (OES) beads and abundant microlithics. The Nasera Industry deposits (Bed III) contain large quantities of OES beads and date to 36.8 ± 3.4 ka. We compare the luminescence ages with the previous chronologies for Mumba, and briefly discuss how the revised chronology fits in the context of existing archaeological records and palaeoclimatic reconstructions for East Africa.

Application of single-grain OSL to date quartz xenocrysts within a basalt flow, San Francisco volcanic field, northern Arizona, USA

Previous age estimates for SP Crater in the San Francisco volcanic field in northern Arizona, USA, suggested it erupted 70 ka; however its non-weathered geomorphic character places it as one of the youngest volcanic vents in the region. Samples of quartz xenocrysts were extracted from the SP Crater basalt flows and dated using single-grain dating. Analysis of the luminescence signals indicate they were dominated by medium- to slow-decaying OSL components, which can produce age underestimates if not removed. In order to reduce their contribution, the fast component was deconvolved from the initial OSL signal, a high-temperature bleach (blue-green LED exposure at 280 °C) was added at the end of each measurement cycle and elevated cutheat temperatures were used. Fading tests and crushing experiments indicate no dependence on recovered equivalent dose values. Resultant single-grain quartz xenocryst OSL ages are consistent with the geomorphic character of SP Crater and suggest it erupted 5.5–6 ka. Revision of the age of SP Crater has implications for the eruption recurrence interval in the region and assessment of volcanic hazards in nearby communities.

Luminescence dating of mammoth remains from northern Switzerland

Remains of at least two individuals of woolly mammoths (Mammuthus primigenius) were discovered after blastings in a limestone quarry located on the southern slope of the Jura Mountains, northern Switzerland. During the subsequent excavation two blocks were taken for luminescence dating from the sediment surrounding the remains; the deposits are interpreted to represent the filling of a karst hole. Luminescence dates on the polymineral and purified quartz fine grain fraction are compared to those obtained for single grains of quartz and small aliquots of quartz as well as feldspar coarse grains. All approaches give ages consistent within the dating uncertainties and are interpreted to prove the robustness of the dating results. The age of the sediment of ca. 63 ka indicates deposition during Marine Isotope Stage (MIS) 4, thus, during a time when Switzerland experienced rather cold climatic conditions. These are some of the oldest numerically dated woolly mammoth remains of Europe.

Comparative optical and radiocarbon dating of laminated Holocene sediments in two maar lakes: Lake Keilambete and Lake Gnotuk, south-western Victoria, Australia

Sediment core chronologies of optical dates on single-grains/very small aliquots of sand-sized quartz are compared with Accelerator Mass Spectrometry (AMS) radiocarbon (14C) chronologies from ostracod carbonate, mixed carbonates, sedimentary organic matter and charcoal in order to establish the age of laminated Holocene sediments in maar crater lakes Keilambete and Gnotuk, Victoria, Australia. Samples for optical and AMS 14C dating were taken from the same Mackereth cores, allowing a direct comparison of the two techniques from two laminated sedimentary sequences. Additional AMS 14C samples were taken from water in Lake Keilambete and from groundwater discharging into Lake Keilambete from the crater wall, with equivalent reservoir ages of 150 ± 30 and 1940 ± 30 years respectively.AMS 14C dating of modern ostracod carbonate in Lake Keilambete demonstrates a reservoir age of 670 ± 175 years. Optical dating of ‘single-grain/very small aliquots’ of sand-sized-quartz indicate the presence of a radiocarbon reservoir in Lake Keilambete that is consistent with that measured on modern ostracods, and also demonstrate that there is no 14C reservoir in Lake Gnotuk during the Holocene. The chronology presented here supports the premise that previously published bulk conventional 14C dates from Lake Keilambete were affected by old carbon, meaning that past chronologies require revision.Limitations on the use of optical dating of single-grain/very small aliquots include the relative paucity of sand-sized quartz, which decreases the precision of the sample equivalent dose (De), and is further confounded by low environmental dose rates and resultant large uncertainties on the final age assessment. Nevertheless, evidence for partial bleaching confirms that single-grain quartz dating is the most appropriate luminescence technique, and may prove a useful alternative in situations where 14C dating is unsuitable or an alternative chronometer is required.

Improving the accuracy and precision of equivalent doses determined using the optically stimulated luminescence signal from single grains of quartz

Optically stimulated luminescence (OSL) measurements of quartz are widely used to measure equivalent dose ( D e ). At radiation doses above ∼100 Gy, saturation of traps results in a decrease in the rate of growth of the OSL signal, and this makes calculation of D e increasingly difficult. A series of dose recovery experiments was undertaken using single grains of quartz from Kalambo Falls, Zambia to explore saturation of single grains. When the OSL signal from many grains is averaged, the characteristic dose ( D 0 ) is 47 Gy, typical of published values for quartz. However, D 0 for individual grains varies from ∼10 to 100 Gy. Doses up to two times the average D 0 could be accurately recovered, but above this dose the D e became increasingly underestimated. Overdispersion for this type of experiment should be zero, but was observed in all data sets; furthermore the value of overdispersion increased with D e . An additional acceptance criterion, the Fast Ratio, is suggested for single grain OSL analysis. This criterion assesses the relative contribution of the fast component of the OSL signal. Including this as an additional acceptance criterion leads to an improved precision, with overdispersion reduced to zero, and improved accuracy in dose recovery at high doses. ► Dose recovery measurements using OSL from single grains of quartz are expected to have zero overdispersion. ► This paper shows that overdispersion in dose recovery data increases systematically with the size of the dose being recovered. ► The Fast Ratio is shown to reduce overdispersion to near zero, and this is recommended as an additional acceptance criteria. ► Single grain OSL measurements may be a more accurate method for dating old sediments than multiple grain measurements.

Luminescence characteristics and dose distributions for quartz and feldspar grains from Mumba rockshelter, Tanzania

Mumba rockshelter is a key archaeological site for the Middle and Later Stone Age occupation of East Africa, but its chronology has remained unresolved. We report the results of a dating study, focussing on the characterisation of the optically stimulated luminescence (OSL) and infrared stimulated luminescence (IRSL) properties of quartz- and potassium-rich feldspar grains. Quartz has previously proven troublesome for dating in East Africa. We identified five general types of quartz grain behaviour, based on the shapes of their OSL decay and dose–response curves. Dose recovery experiments and measurement of the natural samples revealed particular problems with quartz grains that had hyperbolic dose–response curves, low characteristic saturation doses and anomalously large changes in sensitivity between regenerative-dose cycles. The use of pulsed irradiation during measurement and standard and additional quality-assurance criteria during data analysis reduced the number of grains that suffered from these problems. We applied these procedures to individual grains of quartz from eight samples and, using appropriate statistical models, identified post-depositional mixing in three samples. The remaining samples had scattered equivalent-dose distributions typical of quartz grains that had received variable beta dose rates during burial. Stratigraphically consistent OSL ages were obtained for all but the deepest sample. Feldspar ages were estimated for the latter sample and three other samples, using the elevated temperature IRSL signal that exhibited low rates of anomalous fading. Fading-corrected feldspar ages for the latter three samples are consistent with their single-grain quartz ages, but single-grain dating is needed to address problems of post-depositional mixing.

RTL dating of single quartz grains from tephra

RTL dating of single quartz grains from tephra

An assessment of the luminescence sensitivity of Australian quartz with respect to sediment history

This study provides a preliminary systematic characterisation of OSL sensitivity, with respect to sediment history, of single grains of Australian quartz from a variety of source rocks and depositional contexts. Samples from two distinct lithologies and with relatively short modern sedimentary histories were compared in an examination of the influence of rock type on OSL sensitivity. Sediments derived from weathered sandstone were found to be brighter than those from metamorphosed schists, suggesting that sensitivity may be inherited from the source rock and its earlier sedimentary history. Secondly, quartz from the same source, but different modes of deposition, was compared to assess the effect on sensitivity of nature of exposure to light during the most recent bleaching event. Quartz grain sensitivity appears not to vary depending on the mode of sediment deposition, suggesting that the nature of exposure to light during deposition is less important in the sensitisation process. This study highlights the complexity and variety of natural sedimentary quartz, demonstrating the limitations of an investigation based solely on OSL sensitivity. Further systematic investigation into the physical, geological and geomorphological characteristics of sediments is proposed to better understand the mechanisms of luminescence sensitisation in quartz.

Palaeoenvironmental change recorded in the palaeodunefields of the western Murray Basin, South Australia – New data from single grain OSL-dating

This study is concerned with the reconstruction of the palaeoenvironmental history of southeastern Australia for the last ∼300 ka by establishing a luminescence chronology of dune sand deposition in the western Murray Basin (South Australia). In the study area, vast fields of palaeodunes, stabilised by vegetation, provide evidence of past environmental change. In total 98 samples were collected from dune sand layers at 13 different dune sections. The time of their deposition was determined using optically stimulated luminescence dating of single quartz grains, accounting for the impact of post-depositional mixing by the use of a finite mixture model. The oldest depositional phase demonstrates that dune sand layers of great antiquity are preserved in the western Murray Basin, ranging up to at least 380 ka. Phases of substantial dune sand deposition were identified for the periods 18–38 ka and 63–72 ka. Older depositional phases also exist, but are poorly resolved due to relatively large errors of the luminescence ages. Aeolian deposition during the last termination and the Holocene is relatively limited, with a slight clustering of ages at the time of the Antarctic Cold Reversal and from 5–8 ka. Two modern ages give evidence of very recent dune sand deposition. Comparison with other palaeoclimate records from the region suggests that phases with high aeolian sedimentation coincide with more arid conditions and breaks in the dune record with more humid phases. Thus, although dune records are often discontinuous and their interpretation in palaeoclimatic terms is not always straightforward, the palaeodunes of the western Murray Basin show a good preservation of phases of aeolian activity and provide useful information for palaeoenvironmental reconstruction.

Thermal history versus sedimentary history: OSL sensitivity of quartz grains extracted from rocks and sediments

The optically stimulated luminescence (OSL) sensitivity of quartz has a significant influence on luminescence dating procedures. Furthermore, identifying the natural controls of quartz OSL sensitivity is an important step towards new applications of OSL in geology such as provenance tracing. We evaluate the OSL sensitivity (total and the proportion of the informally assigned fast, medium and slow components) of single grains of quartz extracted from 10 different igneous and metamorphic rocks with known formation conditions; and from fluvial and coastal sediments with different sedimentary histories and known source rocks. This sample suite allows assessment of the variability of the OSL sensitivity of single quartz grains with respect to their primary origin and sedimentary history. We observed significant variability in the OSL sensitivity of grains within all studied rock and sediment samples, with the brightest grains of each sample being those dominated by the fast component. Quartz from rocks formed under high temperature (>500 °C) conditions, such as rhyolites and metamorphic rocks from the amphibolite facies, display higher OSL sensitivity. The OSL sensitivity of fluvial sediments which have experienced only a short transport distance is relatively low. These sediments show a small increase in OSL sensitivity downstream, mainly due to a decreasing fraction of “dim” grains. The quartz grains from coastal sands present very high sensitivity and variability, which is consistent with their long sedimentary history. The high variability of the OSL sensitivity of quartz from coastal sands is attributed more to the mixture of grains with distinct sedimentary histories than to the provenance from many types of source rocks. The temperature of crystallization and the number of cycles of burial and solar exposure are suggested as the main natural factors controlling the OSL sensitivity of quartz grains. The increase in OSL sensitivity due to cycles of erosion and deposition surpasses the sensitivity inherited from the source rock, with this increase being mainly related to the sensitization of fast OSL components. The discrimination of grains with different sedimentary histories through their OSL sensitivities can allow the development of quantitative provenance methods based on quartz.

An OSL chronology for the sedimentary deposits from Pinnacle Point Cave 13B—A punctuated presence

Optically stimulated luminescence (OSL) measurements are reported for single aliquots and single grains of quartz from sedimentary deposits within Cave 13B at Pinnacle Point, South Africa (PP13B). Ages have been obtained for 30 samples from the Middle Stone Age and from sterile geological deposits at the base and top of the sediment sequence. The ages for all the archaeological units have been obtained from single-grain measurements that enable unrepresentative grains to be rejected after they have been scrutinized for their OSL behavior. The shape of the equivalent dose distribution and the degree of spread in equivalent dose for each sample have also been scrutinized for evidence of depositional and post-depositional effects that can influence the accuracy of the age estimates. This study also used the same systematic approach as that used for the dating of the Howieson’s Poort and Still Bay in South Africa. This single-grain approach results in more accurate and precise age estimates that place all ages measured and analyzed in this way on a common timescale. Four periods of human occupation have been dated to ∼162 ka, ∼125 ka, ∼110 ka, and ∼99–91 ka during Marine Isotope Stage (MIS) 6, 5e, 5d, and 5c, respectively. Occupation of the site appears to have occurred at periods of higher sea level and increased aeolian activity, and the cave was ultimately sealed by the accumulation of a large dune ∼90 ka ago that infilled the cave, but also blanketed the cliff face above the cave, thus preventing further habitation of the site until ∼39 ka.

SAR–RTL dating of single grains of volcanic quartz from the late Pleistocene Toya Caldera

We performed the single aliquot regeneration–red thermal luminescence (SAR–RTL) dating on single quartz grains from Toya Caldera, northern Japan, which erupted during the late Pleistocene. The use of an H7421-40 photomultiplier tube and a combination of R60 and IRC65L filters, which were developed for isothermal red thermoluminescence (IRTL), resulted in improved RTL signal detection, enabling weak RTL signals to be detected from a single quartz grain. In addition, the use of a silver holder with a biotite shield helped to reduce the black body emissions from the heating device. Analysis of RTL glow curves obtained for individual grains suggests that quartz grains that yield a sharp peak (sharp type) are essential grains derived from a magmatic source, showing similar erupted ages, whereas quartz grains with broad peaks (broad type) are detritus in origin and show a range of ages. The average ages of the four tested samples, which range from 104 ± 15 to 118 ± 15 ka, are concordant with the age of eruption (112–115 ka) estimated based on geological evidence. In conclusion, SAR–RTL dating of single quartz grains is reliable for dating the early stage of late Pleistocene volcanic events.

Dating ice shelf edge marine sediments: A new approach using single‐grain quartz luminescence

To develop an alternative dating tool for the Antarctic Peninsula (where the 14C method requires large, spatially variable reservoir corrections), we tested the clock‐zeroing assumption of photon‐stimulated luminescence (PSL) dating using a variety of PSL procedures. At ice shelf edges around the Antarctic Peninsula, sediment‐water‐interface (“zero‐age” analogs), silt‐rich short cores were collected in 2001–2003, originally only for fine silt dating tests. Later access to suitable instrumentation also permitted testing the potential of single‐grain quartz (SGQ) dating of sand grains from these cores. For the fine silt grains we employed multiple‐aliquot and single‐aliquot methods to obtain last daylight exposure age estimates from near‐core‐top material. With the sand fraction we employed automated SGQ PSL methods to isolate the youngest grains. Five of six fine silt samples gave unreasonably large age estimates (>20 ka), with the sixth sample yielding a multiple‐aliquot short‐bleach age estimate of 1.1 ± 0.6 ka. In contrast, five of seven sand samples yielded geologically reasonable last daylight exposure ages of 0.2–0.6 ka. These SGQ results are also remarkable when compared to published 14C ages of 1 ka to 9.7 ka from core top living calcite and acid‐insoluble organic matter. These SGQ results establish the likely utility of this single‐grain dating approach in such settings to provide chronologies for calving line histories of ice shelves. To take advantage of this utility, core collection should employ large‐diameter coring devices (e.g., Kasten and multicorers). A caveat is that large numbers (e.g., ∼10,000) of quartz grains may need analysis to provide acceptable statistics for useful age calculations.

Single- and Multigrain Luminescence Dating of Sediments Related to the Greenville Fault, Eastern San Francisco Bay Area, California

Near urban areas and extending ∼60 km along the eastern margin of the Livermore Valley, the Greenville fault is the easternmost right-lateral strike-slip fault of the San Andreas system in the greater San Francisco Bay area. Notwithstanding the 1980 Livermore earthquake sequence (mainshock M L 5.9) on the Greenville fault, there is no record of recency or of Holocene rates of activity on the Greenville fault, yet this fault exhibits clear geomorphic evidence of late Quaternary faulting. In trenches parallel and normal to the fault through alluvial fan deposits at the Laughlin Road site only pedogenic carbonate was available for ![Graphic][1] dating. Therefore, we applied several photon-stimulated luminescence (PSL) sediment-dating procedures to the silt and sand fractions of six samples. The polymineral-fine-silt multi-aliquot age estimates are generally inaccurate, but the single-grain quartz (SGQ) and multigrain quartz single-aliquot regenerative-dose (SAR) ages from sand grains are in stratigraphic sequence. In trench 3A these SAR ages range from 125±11 yrs (before 2007) within the topmost unit L to 13.45±0.79 ka in the base of the lowermost channel-fill unit G. The SAR PSL results demonstrate the importance of the use of SGQ dating for such sediments and provide the first numerical ages used to constrain the slip rate on the Greenville fault. Trench exposures reveal that unit G is an alluvial sequence infilling a paleochannel offset in a right-lateral sense along the northern Greenville fault. Age estimates from upper and middle unit G bracket deposition of subunit Gb are between 11.12±0.55 ka and 10.64±0.85 ka and those from middle and lower unit G bracket deposition of subunit Go are between 11.12±0.55 ka and 13.45±0.79 ka. These SAR PSL age estimates and measurements of the lateral offset constrain a preliminary slip-rate estimate to about 2 mm/yr or higher for the northern Greenville fault zone. [1]: /embed/inline-graphic-1.gif

Single-grain and multigrain luminescence dating of on-ice and lake-bottom deposits at Lake Hoare, Taylor Valley, Antarctica

The large radiocarbon ( 14C) reservoir effect in Antarctica varies regionally and with settings. Luminescence sediment dating has potential as an alternate geochronometer. Extending our earlier tests of the effectiveness of resetting of photon-stimulated-luminescence (PSL) that employed only multi-aliquot analyses of fine-silt grains, we applied single-aliquot multigrain, and single-grain-quartz (SGQ) PSL procedures to a variety of samples from on and under the meters-thick perennial ice cover at Lake Hoare. These procedures yielded quartz sand age estimates for ice-surface sand (the source of the lake-bottom sand) of 10–80 a. Sand within a small dune on the perennial lake ice in front of Canada Glacier gave an SGQ age estimate of 48 ± 23 a. These methods produced realistic age estimates in lake-bottom short cores that are at least 5–20 times younger than comparable (uncorrected-for-reservoir) 14C results. Near-core-top PSL age estimates ranged from zero to ∼500 a, depending on the core site. Four of the 7 short cores revealed clear linear age-depth trends for the upper few cm of core. These results demonstrate that for such lake-core deposits, single-aliquot and single-grain PSL dating can replace 14C dating, at least in Lake Hoare, because PSL dating lacks a significant ‘zero-point’ offset such as the 14C reservoir effect, and because PSL dating of quartz is applicable to samples as old as ∼150 ka under normal sedimentary conditions. Moreover, these results imply that isolated paleo-lake-bottom deposits (e.g., microbial-mat sand mounds above present lake levels) throughout the McMurdo Dry Valleys can now be dated directly.

A late Pleistocene record of aeolian sedimentation in Blanche Cave, Naracoorte, South Australia

We provide geochemical analyses and grain size data for a clearly layered, 80 cm thick sedimentary deposit close to a roof collapse in Blanche Cave near Naracoorte in SE South Australia. This deposit contains aeolian material deposited between ∼40 ka and 14 ka cal BP and which yields airborne sediments spanning the Last Glacial Maximum, a period of time with little information for the Australian continent. The deposit also contains abundant vertebrate fossil material derived from owl pellets, accumulation and pitfall entrapment. Below the studied profile, large vertebrate remains are found but are not discussed here. No Holocene sedimentation occurred at the site examined in the cave, and the top of the sequence is capped with a layer that has been anthropologically disturbed and contains exotic Pinus pollen. Chronologies of the deposit were obtained using two dating techniques: single stage accelerator mass spectrometer (SSAMS) 14C analysis of 23 charcoal samples and optically stimulated luminescence (OSL) dating of quartz from 6 sediment samples. The 14C chronology is preferred to describe the history of the deposits since the OSL chronology, which consistently overestimates the associated radiocarbon dates, may be inaccurate due to complexities in calculating dose rates, and may in addition represent the timing of sediment deposition through the cave opening rather than sediment transport to the deposit site. Morphological analysis of single quartz grains and grain size analysis indicate different provenance that is confirmed through the geochemical analyses of bulk sediment. Major elements were measured by X-ray Fluorescence (XRF), trace and rare earth elements by Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA ICP-MS), and Neodymium isotopic ratios were obtained using a Thermal Ionisation Mass Spectrometer (TIMS). Our results indicate that the aeolian material deposited in Blanche Cave over the 40–14 ka cal BP period originated from different sources across South Australia, although Nd isotopes clearly indicate a close association with sediments of the Kanmantoo Group outcropping along the eastern portion of the Mount Lofty Ranges and the Padthaway Ridge further south, both being located to the NW and NNW of the cave. During the latter part of Marine Isotope Stage 3, conditions were wetter and windblown sediment came from the coastal region just north and south of the Coorong Lagoon, with winds originating from the north-northwest. At that time, woody taxa appear to have vegetated the landscape. During the drier phases, especially the Last Glacial Maximum, sediment came from further inland, thus suggesting a different predominant wind direction, more from the northwest. The deglaciation saw material originating from a more northerly direction.

Single and multigrain quartz‐luminescence dating of irrigation‐channel features in Santa Fe, New Mexico

AbstractAcequias (irrigation channels and ditches) were used by Spanish settlers, their descendants, and Native Americans in New Mexico. Several such features were recently excavated in Santa Fe, but material for numeric dating was difficult to find. Therefore, for this high‐energy‐deposition irrigation‐feature setting we applied optically stimulated luminescence (OSL) sediment dating methods to determine the timing of last filling of some of these acequias. We report multigrain single‐aliquot quartz (MGSAQ) OSL dating results and the first single‐grain quartz (SGQ) OSL dating results for irrigation features. One sample yielded an average age of 96 ± 13 yr, consistent with the maximum expected age of 127 yr (before 2007). An OSL age of 175 ± 15 yr for another sample delimits a sedimentation event since the first construction of that feature ca. 300 yr ago. A sample known to be younger than 400–450 yr but predating the mid‐19th century gave an SGQ age of 376 ±31 yr. These results indicate that: (1) Regional quartz in New Mexico is highly favorable to OSL dating; (2) in this setting, SGQ OSL dating is preferred to MGSAQ dating; and (3) for the last 500–600 yr, SGQ OSL dating in such settings is preferred to 14C dating because OSL dating lacks those ambiguities inherent in converting 14C ages to calendar years. © 2009 Wiley Periodicals, Inc.