Quantum Sensors Research Articles

Controlling the morphology of polycrystalline diamond films via seed density: Influence on grain size and film texture

Controlling the morphology of polycrystalline diamond (PCD) films is crucial for various applications, including thermal management and quantum sensors. PCD films are typically produced by plasma-enhanced chemical vapor deposition on substrates seeded with nanodiamonds. Different film morphologies can be achieved by controlling growth rates of crystal-forming facets, which is commonly managed through deposition temperature and hydrocarbon concentration in the plasma. However, the impact of seed density on film morphology remains largely unexplored. In this study, we observed that reducing seed density on silicon substrates has a similar effect on PCD film morphology as increasing hydrocarbon concentration in the plasma. Specifically, as seed density decreases, deposition rate increases, and film texture transitions from (1 1 1) to (1 0 0), followed by the formation of large grains with (1 0 0) facets surrounded by clusters of small grains. These changes were observed using electron microscopy, Raman spectroscopy, and X-ray diffraction. To explain our results, we hypothesize that the silicon–plasma interface surrounding the growing diamond seeds acts as a diamond precursor source. Our proposed explanation requires relatively long precursor migration lengths compared to those assumed in standard diamond deposition theory. Finally, we also propose two new mechanisms for diamond precursor adsorption based on well-established physical phenomena and recent publications. Our findings may open new avenues in diamond research, applicable not only to polycrystalline but also to single-crystal diamond deposition.

XPS analysis of molecular contamination and sp2 amorphous carbon on oxidized (100) diamond

The efficacy of oxygen (O) surface terminations on diamond is an important factor for the performance and stability for diamond-based quantum sensors and electronics. Given the wide breadth of O-termination techniques, it can be difficult to discern which method would yield the highest and most consistent O coverage. Furthermore, the interpretation of surface characterization techniques is complicated by surface morphology and purity, which if not accounted for will yield inconsistent determination of the oxygen coverage. We present a comprehensive approach to consistently prepare and analyze oxygen termination of surfaces on (100) single-crystalline diamond. We report on x-ray photoelectron spectroscopy (XPS) characterization of diamond surfaces treated with six oxidation methods that include various wet chemical oxidation techniques, photochemical oxidation with UV illumination, and steam oxidation using atomic layer deposition (ALD). Our analysis entails a rigorous XPS peak-fitting procedure for measuring the functionalization of O-terminated diamond. The findings herein have provided molecular-level insights on oxidized surfaces in (100) diamond, including the demonstration of clear correlation between the measured oxygen atomic percentage and the presence of molecular contaminants containing nitrogen, silicon, and sulfur. We also provide a comparison of the sp2 carbon content with the O1s atomic percentage and discern a correlation with the diamond samples treated with dry oxidation which eventually tapers off at a max O1s atomic percentage value of 7.09 ± 0.40%. Given these results, we conclude that the dry oxidation methods yield some of the highest oxygen amounts, with the ALD water vapor technique proving to be the cleanest technique out of all the oxidation methods explored in this work.

Chiral photon blockade in the spinning Kerr resonator

We propose how to achieve chiral photon blockade by spinning a nonlinear optical resonator. We show that by driving such a device at a fixed direction, completely different quantum effects can emerge for the counter-propagating optical modes, due to the spinning-induced breaking of time-reversal symmetry, which otherwise is unattainable for the same device in the static regime. Also, we find that in comparison with the static case, robust non-classical correlations against random backscattering losses can be achieved for such a quantum chiral system. Our work, extending previous works on the spontaneous breaking of optical chiral symmetry from the classical to purely quantum regimes, can stimulate more efforts towards making and utilizing various chiral quantum effects, including applications for chiral quantum networks or noise-tolerant quantum sensors.

Strained diamond for quantum sensing applications

Apart from being an extraordinary optical and electronic material, diamond has also found applications in quantum mechanics especially in quantum sensing with the discovery and research development of various color centers. Elastic strain engineering (ESE), as a powerful modulation method, can tune the quantum properties and improve the performance of diamond quantum sensors. In recent years, deep ESE (DESE, when >5% elastic strain, or >σ ideal/2 is achieved) has been realized in micro/nano-fabricated diamond and shows a great potential for tuning the quantum mechanical properties of diamond substantially. In this perspective, we briefly review the quantum properties of diamond and some of the corresponding sensing applications carried out with ESE, and look at how DESE could be applied for further tuning the quantum sensing properties of diamond with desired applications and what the critical challenges are.

Quantum Sensing for the Cities of the Future

Quantum Sensing for the Cities of the Future

Floquet time crystals as quantum sensors of ac fields

Floquet time crystals as quantum sensors of ac fields

Optimizing luminescent properties of ZnO: Er3+ through temperature and dopant variation: XRD and emission spectroscopy studies

This study focuses on optimizing the synthesis conditions for the luminescent properties of ZnO:Er3[Formula: see text], a key step toward improving its applicability in optoelectronics. X-ray diffraction (XRD) patterns at [Formula: see text]C with Er3[Formula: see text] dopant concentrations (1, 3 and 5[Formula: see text]wt.%) show the preservation of the crystalline phase of ZnO, indicating that the dopants did not affect the structural integrity. Luminescence properties were observed in ZnO with 1[Formula: see text]wt.% erbium doping at 900–[Formula: see text]C, with the sample at [Formula: see text]C exhibiting the highest emission peak at 533[Formula: see text]nm. The optimal conditions for significant luminescence were identified at [Formula: see text]C, with 5[Formula: see text]wt.% Er3[Formula: see text] showing the most pronounced effect. The practical implications of the achievement of optimal luminescence in ZnO:Er3[Formula: see text] are profound for optoelectronics. These conditions are critical for efficient light-emitting devices, particularly in applications such as light-emitting diodes (LEDs) and lasers, where emission characteristics have a direct impact on performance. In addition, the enhanced luminescence holds great promise for sensors, especially in biomedical and environmental monitoring, as well as in quantum technologies. It contributes to the advancement of quantum sensors and quantum computing applications. This research provides a basis for tailoring the properties of ZnO:Er3[Formula: see text] for specific applications by identifying optimal luminescence conditions at different dopant concentrations. While the identification of optimal conditions has been successful, further research is essential to unravel the underlying mechanisms at the atomic and molecular levels. Overcoming these challenges and exploring additional applications will be critical to realizing the practical impact of these findings in various technological fields, as the study paves the way for advances in optoelectronics, sensing, and quantum information processing.

Measurement of Light Interception by Crops under Solar Panels using PARbars

To analyse agrivoltaics systems and understand crop responses to shading, measurements of available light for the crop and light interception by the crop are important. Especially in row crops, there is a lot of variation in the amount of light at different heights, different positions relative to the row and over time. This spatial and temporal variation in light is difficult to capture with standard point measurement technology. Commercially available line quantum sensors are not long enough to cover the desired width within an agrivoltaics system and come at high cost. Therefore, custom made PARbars were used: bars of 1.5 m long having light sensors every 5 cm facing the sky and giving a total (line) irradiance value per time step. PARbars were installed above and below a raspberry crop row in both the agrivoltaics system and the control with a plastic foil cover, and a point sensor was installed in the open field. The difference between open field radiation and the top PARbar gives the light interception by the panel construction or the foil cover, the difference between the top and bottom PARbar gives the light interception by the crop. This information can be used in conjunction with destructive crop measurements to analyse impacts on leaf area and light interception, dry matter production and derived efficiency of photosynthesis. The crop in the current agrivoltaics system received half of the amount of light compared to the control system, but total biomass production was less reduced because of compensation by increasing specific leaf area and photosynthesis efficiency. Further analysis is needed to evaluate the agrivoltaics system and the impact of increasing shade on the crop, and to assess the trade-off between electricity production and crop production.

Benchmarking Bayesian quantum estimation

The quest for precision in parameter estimation is a fundamental task in different scientific areas. The relevance of this problem thus provided the motivation to develop methods for the application of quantum resources to estimation protocols. Within this context, Bayesian estimation offers a complete framework for optimal quantum metrology techniques, such as adaptive protocols. However, the use of the Bayesian approach requires extensive computational resources, especially in the multiparameter estimations that represent the typical operational scenario for quantum sensors. Hence, the requirement to characterize protocols implementing Bayesian estimations can become a significant challenge. This work focuses on the crucial task of robustly benchmarking the performances of these protocols in both single and multiple-parameter scenarios. By comparing different figures of merits, evidence is provided in favor of using the median of the quadratic error in the estimations in order to mitigate spurious effects due to the numerical discretization of the parameter space, the presence of limited data, and numerical instabilities. These results, providing a robust and reliable characterization of Bayesian protocols, find natural applications to practical problems within the quantum estimation framework.

A quantum coherent spin in hexagonal boron nitride at ambient conditions.

Solid-state spin-photon interfaces that combine single-photon generation and long-lived spin coherence with scalable device integration-ideally under ambient conditions-hold great promise for the implementation of quantum networks and sensors. Despite rapid progress reported across several candidate systems, those possessing quantum coherent single spins at room temperature remain extremely rare. Here we report quantum coherent control under ambient conditions of a single-photon-emitting defect spin in a layered van der Waals material, namely, hexagonal boron nitride. We identify that the carbon-related defect has a spin-triplet electronic ground-state manifold. We demonstrate that the spin coherence is predominantly governed by coupling to only a few proximal nuclei and is prolonged by decoupling protocols. Our results serve to introduce a new platform to realize a room-temperature spin qubit coupled to a multiqubit quantum register or quantum sensor with nanoscale sample proximity.

Squeezed light from an oscillator measured at the rate of oscillation.

Sufficiently fast continuous measurements of the position of an oscillator approach measurements projective on position eigenstates. We evidence the transition into the projective regime for a spin oscillator within an ensemble of 2 × 1010 room-temperature atoms by observing correlations between the quadratures of the meter light field. These correlations squeeze the fluctuations of one light quadrature below the vacuum level. When the measurement is slower than the oscillation, we generate and detect of squeezing in a tunable band that is a fraction of the resonance frequency. When the measurement is as fast as the oscillation, we detect 4.7 dB of squeezing that spans more than one decade of frequencies below the resonance. Our results demonstrate a new regime of continuous quantum measurements on material oscillators, and set a new benchmark for the performance of a linear quantum sensor.

Microcontroller-Optimized Measurement Electronics for Coherent Control Applications of NV Centers.

Long coherence times at room temperature make the NV center a promising candidate for quantum sensors and quantum computers. The necessary coherent control of the electron spin triplet in the ground state requires microwave π pulses in the nanosecond range, obtained from the Rabi oscillation of the mS spin states of the magnetic resonances of the NV centers. Laboratory equipment has a high temporal resolution for these measurements but is expensive and, therefore, uninteresting for fields such as education. In this work, we present measurement electronics for NV centers that are optimized for microcontrollers. It is shown that the Rabi frequency is linear to the output of the digital-to-analog converter (DAC) and is used to adapt the time length π of the electron spin flip, to the limited pulse width resolution of the microcontroller. This was achieved by breaking down the most relevant functions of conventional laboratory devices and replacing them with commercially available integrated components. The result is a cost-effective handheld setup for coherent control applications of NV centers.

Quantum Sensing of Free Radical Generation in Mitochondria of Human Keratinocytes during UVB Exposure.

Ultraviolet (UV) radiation is known to cause skin issues, such as dryness, aging, and even cancer. Among UV rays, UVB stands out for its ability to trigger problems within cells, including mitochondrial dysfunction, oxidative stress, and DNA damage. Free radicals are implicated in these cellular responses, but they are challenging to measure due to their short lifetime and limited diffusion range. In our study, we used a quantum sensing technique (T1 relaxometry) involving fluorescent nanodiamonds (FNDs) that change their optical properties in response to magnetic noise. This allowed us to monitor the free radical presence in real time. To measure radicals near mitochondria, we coated FNDs with antibodies, targeting mitochondrial protein voltage-dependent anion channel 2 (anti-VDAC2). Our findings revealed a dynamic rise in radical levels on the mitochondrial membrane as cells were exposed to UVB (3 J/cm2), with a significant increase observed after 17 min.

The Optimization of Microwave Field Characteristics for ODMR Measurement of Nitrogen-Vacancy Centers in Diamond

A typical solid-state quantum sensor can be developed based on negatively charged nitrogen-vacancy (NV−) centers in diamond. The electron spin state of NV− can be controlled and read at room temperature. Through optical detection magnetic resonance (ODMR) technology, temperature measurement can be achieved at the nanoscale. The key to ODMR technology is to apply microwave resonance to manipulate the electron spin state of the NV−. Therefore, the microwave field characteristics formed near the NV− have a crucial impact on the sensitivity of ODMR measurement. This article mainly focuses on the temperature situation in cellular applications and simulates the influence of structural parameters of double open loop resonant (DOLR) microwave antennas and broadband large-area (BLA) microwave antennas on the microwave field’s resonance frequency, quality factor Q, magnetic field strength, uniformity, etc. The parameters are optimized to have sufficient bandwidth, high signal-to-noise ratio, low power loss, and high magnetic field strength in the temperature range of 36 °C to 42.5 °C. Finally, the ODMR spectra are used for effect comparison, and the signal-to-noise ratio and Q values of the ODMR spectra are compared when using different antennas. We have provided an optimization method for the design of microwave antennas and it is concluded that the DOLR microwave antenna is more suitable for living cell temperature measurement in the future.

Essay: Quantum Sensing with Atomic, Molecular, and Optical Platforms for Fundamental Physics.

Atomic, molecular, and optical (AMO) physics has been at the forefront of the development of quantum science while laying the foundation for modern technology. With the growing capabilities of quantum control of many atoms for engineered many-body states and quantum entanglement, a key question emerges: what critical impact will the second quantum revolution with ubiquitous applications of entanglement bring to bear on fundamental physics? In this Essay, we argue that a compelling long-term vision for fundamental physics and novel applications is to harness the rapid development of quantum information science to define and advance the frontiers of measurement physics, with strong potential for fundamental discoveries. As quantum technologies, such as fault-tolerant quantum computing and entangled quantum sensor networks, become much more advanced than today's realization, we wonder what doors of basic science can these tools unlock. We anticipate that some of the most intriguing and challenging problems, such as quantum aspects of gravity, fundamental symmetries, or new physics beyond the minimal standard model, will be tackled at the emerging quantum measurement frontier. Part of a series of Essays which concisely present author visions for the future of their field.

Exploring the impact of fluctuation-induced criticality on non-Hermitian skin effect and quantum sensors

In this paper we present a concrete example comparing the results predicted by non-Hermitian quantum mechanics with those of a more comprehensive description that considers environment-induced fluctuations. Our results highlight inaccuracies in the non-Hermitian model. Specifically, we investigate the non-Hermitian skin effect and sensor in the Hatano-Nelson model, contrasting it with a more precise Lindblad description. Our analysis reveals that these phenomena can undergo breakdown when environmental fluctuations come to the forefront, resulting in a nonequilibrium phase transition from a localized skin phase to a delocalized phase. Beyond this specific case study, we engage in a broader discussion regarding the interpretations and implications of non-Hermitian quantum mechanics. This examination serves to broaden our understanding of these phenomena and their potential consequences. Published by the American Physical Society 2024

Optical control and coherent coupling of spin diffusive modes in thermal gases

Quantum science and technology devices exploiting collective spins in thermal gases are extremely appealing due to their simplicity and robustness. This comes at the cost of dealing with the random thermal motion of the atoms which is usually an uncontrolled source of decoherence and noise. There are however conditions, for example, when diffusing in a buffer gas, where thermal atoms can occupy a discrete set of stable spatial modes. Diffusive modes can be extended or localized, have different magnetic properties depending on boundary conditions, and can react differently to external perturbations. Here, we selectively excite, manipulate, and interrogate the longest-lived of these modes by using laser light. In particular, we identify the conditions for the generation of modes that are exceptionally resilient to detrimental effects such as light induced frequency shifts and power-broadening, which are often the dominant sources of systematic errors in atomic magnetometers and comagnetometers. Moreover, we show that the presence of spatial inhomogeneities in the pump introduces a coupling that leads to a coherent exchange of excitation between the two longest-lived modes. Our results demonstrate that systematic engineering of the multi-mode nature of diffusive gases has great potential for improving the performance of quantum sensors based on alkali-metal thermal vapors, and opens new perspectives for quantum information applications. Published by the American Physical Society 2024

Quantum Sensing Can Already Make a Difference. But Where?

Quantum sensing technology is already providing value and potential use cases can shape multiple industries. There are four core technologies with promising applications - solid state spins, neutral atoms, superconducting circuits, and trapped ions - which have sensing capabilities across a broad range of physical properties, including magnetic fields, electric fields, rotation, temperature, gravity, time, and pressure. Which quantum sensing technology and implementation type to use depends on the use case, as they measure different properties and are best suited to specific environments. This paper discusses the potential and current applications of the abovementioned quantum sensing technologies through varied use-case studies. They are presented around four specific industries and along different time horizons, emphasizing the need for further development and enhancement that can be achieved over the conventional counterparts. The full power of quantum sensors is not yet known, but they have the potential to create an entire new ecosystem if researchers, start-ups, and industry leaders work together to explore their applications and get them out of the lab. Here, the paper outlines necessary actions and possible avenues for the stakeholders to realize this potential across academia and industry.

Multi-site integrated optical addressing of trapped ions

One of the most effective ways to advance the performance of quantum computers and quantum sensors is to increase the number of qubits or quantum resources in the system. A major technical challenge that must be solved to realize this goal for trapped-ion systems is scaling the delivery of optical signals to many individual ions. In this paper we demonstrate an approach employing waveguides and multi-mode interferometer splitters to optically address multiple 171Yb+ ions in a surface trap by delivering all wavelengths required for full qubit control. Measurements of hyperfine spectra and Rabi flopping were performed on the E2 clock transition, using integrated waveguides for delivering the light needed for Doppler cooling, state preparation, coherent operations, and detection. We describe the use of splitters to address multiple ions using a single optical input per wavelength and use them to demonstrate simultaneous Rabi flopping on two different transitions occurring at distinct trap sites. This work represents an important step towards the realization of scalable integrated photonics for atomic clocks and trapped-ion quantum information systems.

Do qubits dream of entangled sheep? Quantum measurement without classical output

Quantum mechanics is usually formulated with an implicit assumption that agents who can observe and interact with the world are external to it and have a classical memory. However, there is no accepted way to define the quantum–classical cut and no a priori reason to rule out fully quantum agents with coherent quantum memories. In this work, we introduce an entirely quantum notion of measurement, called a sensation, to account for quantum agents that experience the world through quantum sensors. Sensations eschew probabilities and instead describe a deterministic flow of quantum information. We quantify the information gain and disturbance of a sensation using concepts from quantum information theory and find that sensations always disturb at least as much as they inform. Viewing measurements as sensations could lead to a new understanding of quantum theory in general and to new results in the context of quantum networks.