Quantum Phase Research Articles

Intertwined quantum phase transitions in the zirconium and niobium isotopes

Nuclei in the A ≈ 100 region exhibit intricate shape-evolution and configuration crossing signatures. Exploring both even–even and their adjacent odd-mass nuclei gives further insight on the emergence of deformation and shape-phase transitions. We employ the algebraic frameworks of the interacting boson model with configuration mixing and the new interacting boson-fermion model with configuration mixing in order to investigate the even–even zirconium with neutron number 52–70 (40Zr) and odd-mass niobium (41Nb) isotopes with 52–62. We compare between the evolution in energy levels, configuration and symmetry content of the wave functions, two neutron separation energies and E2 transition rates, alongside comparison with the experimental data. The comparisons between the two chains of isotopes denote the occurrence of two types of QPTs, a crossing of normal and intruder configurations (named Type II QPT), and a shape-evolution of the intruder configuration (named Type I QPT). The latter QPT begins from spherical shape to axially deformed rotor in the Zr isotopes and from weak to strong coupling scenario in the Nb isotopes. This occurrence, named intertwined quantum phase transitions (IQPTs), in the even–even Zr chain is thus demonstrated to persists when coupling a proton to the boson core for the odd-mass Nb chain, even as deformation increases.

Quantum phase structural stability and switching in twist-graphenes

This study examines the electronic structure and potential energy surfaces of migration paths in various types of bilayer graphene. Using periodic boundary conditions, density functional theory (DFT), and the generalized gradient approximation (GGA) exchange–correlation functional, along with the nudged elastic band (NEB) method, to investigate the structural stability and dynamic equilibrium of twisted bilayer graphenes (TBGs) with twist angles of 13.2° and 21.8°. The results suggest that twist angles significantly impact atomic and electronic properties, including moiré patterns, superlattice periods, and interfragment distances, which in turn influence bilayer graphene strongly correlated electronic quantum states. This research elucidates the fundamental mechanisms of superlubricity and mutual migration pathways of graphene fragments in TBGs. The low migration barriers observed could facilitate transitions between different energy-related phases, which are determined by the lattice moiré patterns and the localization character of the electronic states, resulting in superlubricity. External mechanical factors may affect the quantum properties of TBGs, indicating potential applications in quantum computing and quantum sensing.

Emergent flat band and topological Kondo semimetal driven by orbital-selective correlations

Flat electronic bands are expected to show proportionally enhanced electron correlations, which may generate a plethora of novel quantum phases and unusual low-energy excitations. They are increasingly being pursued in d-electron-based systems with crystalline lattices that feature destructive electronic interference, where they are often topological. Such flat bands, though, are generically located far away from the Fermi energy, which limits their capacity to partake in the low-energy physics. Here we show that electron correlations produce emergent flat bands that are pinned to the Fermi energy. We demonstrate this effect within a Hubbard model, in the regime described by Wannier orbitals where an effective Kondo description arises through orbital-selective Mott correlations. Moreover, the correlation effect cooperates with symmetry constraints to produce a topological Kondo semimetal. Our results motivate a novel design principle for Weyl Kondo semimetals in a new setting, viz. d-electron-based materials on suitable crystal lattices, and uncover interconnections among seemingly disparate systems that may inspire fresh understandings and realizations of correlated topological effects in quantum materials and beyond.

Quantum counting on the complete bipartite graph

Quantum counting is a key quantum algorithm that aims to determine the number of marked elements in a database. This algorithm is based on the quantum phase estimation algorithm and uses the evolution operator of Grover’s algorithm because its nontrivial eigenvalues are dependent on the number of marked elements. Since Grover’s algorithm can be viewed as a quantum walk on a complete graph, a natural way to extend quantum counting is to use the evolution operator of quantum-walk-based search on noncomplete graphs instead of Grover’s operator. In this paper, we explore this extension by analyzing the coined quantum walk on the complete bipartite graph with an arbitrary number of marked vertices. We show that some eigenvalues of the evolution operator depend on the number of marked vertices and using this fact we show that the quantum phase estimation can be used to obtain the number of marked vertices. The time complexity for estimating the number of marked vertices in the bipartite graph with our algorithm equates closely with that of the original quantum counting algorithm.

Quantum Voting Machine Encoded with Microwave Photons

Abstract We propose a simple quantum voting machine using microwave photon qubit encoding, based on a setup comprising multiple microwave cavities and a coupled superconducting flux qutrit. This approach primarily relies on a multi-control single-target quantum phase gate. The scheme offers operational simplicity, requiring only a single step, while ensuring verifiability through the measurement of a single qubit phase information to obtain the voting results. And it provides voter anonymity, as the voting outcome is solely tied to the total number of affirmative votes. Our quantum voting machine also has scalability in terms of the number of voters. Additionally, the physical realization of the quantum voting machine is general and not limited to circuit QED. Quantum voting machine can be implemented as long as the multi-control single-phase quantum phase gate is realized in other physical systems. Numerical simulations indicate the feasibility of this quantum voting machine within the current quantum technology.

Degeneracy in excited-state quantum phase transitions of two-level bosonic models and its influence on system dynamics

Degeneracy in excited-state quantum phase transitions of two-level bosonic models and its influence on system dynamics

Lieb-Robinson correlation function for the quantum transverse-field Ising model

The Lieb-Robinson correlation function is the norm of a commutator between local operators acting on separate subsystems at different times. This provides a useful state-independent measure for characterizing the specifically quantum interaction between spatially separated qubits. The finite propagation velocity for this correlator defines a “light cone” of quantum influence. We calculate the Lieb-Robinson correlation function for one-dimensional qubit arrays described by the transverse-field Ising model. Direct calculations of this correlation function have been limited by the exponential increase in the size of the state space with the number of qubits. We introduce a technique that avoids this barrier by transforming the calculation to a sum over Pauli walks which results in linear scaling with system size. We can then explore propagation in arrays of hundreds of qubits and observe the effects of the quantum phase transition in the system. We observe the emergence of two distinct velocities of propagation: a correlation front velocity, which is affected by the phase transition, and the Lieb-Robinson velocity which is not. The correlation front velocity is equal to the maximum group velocity of single quasiparticle excitations. The Lieb-Robinson velocity describes the extreme leading edge of correlations when the value of the correlation function itself is still very small. For the semi-infinite chain of qubits at the quantum critical point, we derive an analytical result for the correlation function. Published by the American Physical Society 2024

Hidden Charge Order and Multiple Electronic Instabilities in EuTe4.

The rare-earth telluride compound EuTe4 exhibits a charge density wave (CDW) and an unconventional thermal hysteresis transition. Herein, we report a comprehensive study of the CDW states in EuTe4 by using low-temperature scanning tunneling microscopy. Two types of charge orders are observed at 4 K, including a newly discovered spindle-shaped pattern and a typical stripe-like pattern. As an exotic charge order, the spindle-shaped CDW is off-axis and barely visible at 77 K, indicating that it is a hidden order developed at low temperature. Based on our first-principles calculations, we reveal the origins of the observed electronic instabilities. The spindle-shaped charge order stems from a subsequent transition based on the stripe-like CDW phase. Our work demonstrates that the competition and cooperation between multiple charge orders can generate exotic quantum phases.

Singular Hall Response from a Correlated Ferromagnetic Flat Nodal-Line Semimetal.

Topological quantum phases are largely understood in weakly correlated systems, which have identified various quantum phenomena, such as the spin Hall effect, protected transport of helical fermions, and topological superconductivity. Robust ferromagnetic order in correlated topological materials particularly attracts attention, as it can provide a versatile platform for novel quantum devices. Here, a singular Hall response arising from a unique band structure of flat topological nodal lines in combination with electron correlation in a van der Waals ferromagnetic semimetal, Fe3GaTe2, with a high Curie temperature of Tc = 347 K is reported. High anomalous Hall conductivity violating the conventional scaling, resistivity upturn at low temperature, and a large Sommerfeld coefficient are observed in Fe3GaTe2, which implies heavy fermion features in this ferromagnetic topological material. The scanning tunneling microscopy, circular dichroism in angle-resolved photoemission spectroscopy, and theoretical calculations support the original electronic features of the material. Thus, low-dimensional Fe3GaTe2 with electronic correlation, topology, and room-temperature ferromagnetic order appears to be a promising candidate for robust quantum devices.

Boundary effect and quantum phases in spin chains

Boundary effect and quantum phases in spin chains

Quantum Phase Transitions in periodically quenched systems

Quantum phase transitions encompass a variety of phenomena that occur in quantum systems exhibiting several possible symmetries. Traditionally, these transitions are explored by continuously varying a control parameter that connects two different symmetry configurations. Here we propose an alternative approach where the control parameter undergoes abrupt and time-periodic jumps between only two values. This approach yields results surprisingly similar to those obtained by the traditional one and may prove experimentally useful in situations where accessing the control parameter is challenging.

Quantum kernels for classifying dynamical singularities in a multiqubit system

Dynamical quantum phase transition is a critical phenomenon involving out-of-equilibrium states and broken symmetries without classical analogy. However, when finite-sized systems are analyzed, dynamical singularities of the rate function can appear, leading to a challenging physical characterization when parameters are changed. Here, we report a quantum support vector machine algorithm that uses quantum Kernels to classify dynamical singularities of the rate function for a multiqubit system. We illustrate our approach using N long-range interacting qubits subjected to an arbitrary magnetic field, which induces a quench dynamics. Inspired by physical arguments, we introduce two different quantum Kernels, one inspired by the ground state manifold and the other based on a single state tomography. Our accuracy and adaptability results show that this quantum dynamical critical problem can be efficiently solved using physically inspiring quantum Kernels. Moreover, we extend our results for the case of time-dependent fields, quantum master equation, and when we increase the number of qubits.

Ground states of planar dipolar rotor chains with recurrent neural networks

In this contribution, we employ a recurrent neural network (RNN) architecture in a variational optimization to obtain the ground state of linear chains of planar, dipolar rotors. We test different local basis sets and discuss their impact on the sign structure of the many-body ground state wavefunction. It is demonstrated that the RNN ansatz we employ is able to treat systems with and without a sign problem in the ground state. For larger chains with up to 50 rotors, accurate properties, such as correlation functions and Binder parameters, are calculated. By employing quantum annealing, we show that precise entanglement properties can be obtained. All these properties allow one to identify a quantum phase transition between a paraelectric and a ferroelectric quantum phase.

Neural-network quantum-state study of the long-range antiferromagnetic Ising chain.

We investigate quantum phase transitions in the transverse field Ising chain with algebraically decaying long-range (LR) antiferromagnetic interactions using the variational Monte Carlo method with the restricted Boltzmann machine employed as a trial wave function ansatz. First, we measure the critical exponents and the central charge through the finite-size scaling analysis, verifying the contrasting observations in the previous tensor network studies. The correlation function exponent and the central charge deviate from the short-range (SR) Ising values at a small decay exponent α_{LR}, while the other critical exponents examined are very close to the SR Ising exponents regardless of α_{LR} examined. However, in the further test of the critical Binder ratio, we find that the universal ratio of the SR limit does not hold for α_{LR}<2, implying a deviation in the criticality. On the other hand, we find evidence of the conformal invariance breakdown in the conformal field theory (CFT) test of the correlation function. The deviation from the CFT description becomes more pronounced as α_{LR} decreases, although a precise breakdown threshold is yet to be determined.

Discovery of charge order above room-temperature in the prototypical kagome superconductor La(Ru1−xFex)3Si2

The kagome lattice is an intriguing and rich platform for discovering, tuning and understanding the diverse phases of quantum matter, crucial for advancing modern and future electronics. Despite considerable efforts, accessing correlated phases at room temperature has been challenging. Using single-crystal X-ray diffraction, we discovered charge order above room temperature in La(Ru1−xFex)3Si2 (x = 0, 0.01, 0.05), where charge order related to out-of-plane Ru atom displacements appears below TCO,I ≃ 400 K. The secondary charge ordered phase emerges below TCO,II ≃ 80–170 K. Furthermore, first principles calculations reveal both the kagome flat band and the van Hove point near the Fermi energy in LaRu3Si2, driven by Ru-dz2 orbitals. Our results identify LaRu3Si2 as the kagome superconductor with the highest known charge ordering temperature, offering a promising avenue for researching room temperature quantum phases and developing related technologies.

Quantum scaling of the spin lattice relaxation rate in the checkerboard J-Q model

Motivated by recent progress on the experimental realization of proximate deconfined quantum critical point in a frustrated quantum magnet, we study the low-energy spin dynamics of a related checkerboard J-Q model by using quantum Monte Carlo simulations. The ground state of this model undergoes a weakly first-order quantum phase transition with an emergent O(4) symmetry between an antiferromagnetic state and a plaquette valence bond solid. The calculated spin lattice relaxation rate of nuclear magnetic resonance, 1/T1 , exhibits distinct low-temperature behaviors depending on the ground states. With decreasing the temperature, 1/T1 rises up on the antiferromagnetic side, characterizing a crossover to the renormalized classical regime, whereas 1/T1 drops exponentially on the side of valence bond solid, reflecting the gap opening in the plaquette ordered phase. The extracted spin gap scales with the distance to the transition point as a power-law with an exponent φ ≈ 0.3, consistent with the scaling ansatz ϕ=νz with ν ≈ 0.3 and z = 1. Near the quantum phase transition, the temperature dependent 1/T1 shows a broad crossover regime where a universal scaling 1/T1∼Tη with η ≈ 0.6 is found. Our results suggest a quantum scaling regime associated with the emergent enhanced symmetry near this first-order quantum phase transition.

Tuning Displacement Fields in a Two-Dimensional Topological Insulator Using Nanopatterned Gates.

Epitaxial heterostructures with topological insulators enable novel quantum phases and practical device applications. Their topological electronic states are sensitive to the microscopic parameters, including structural inversion asymmetry (SIA), which is an inherent feature of many real heterostructures. Controlling SIA is challenging, because it requires the ability to tune the displacement field across the topological film. Here, using nanopatterned gates, we demonstrate a tunable displacement field in a heterostructure of the two-dimensional topological insulator cadmium arsenide. Transport studies in magnetic fields reveal an extreme sensitivity of the band inversion to SIA. We show that a relatively small displacement field (∼50 mV/nm) converts the crossing of the two zeroth Landau levels in magnetic field to an avoided crossing, signaling a change to trivial band order. This work demonstrates a universal methodology for tuning electronic states in topological thin films.

Analytical solution and spectral structure of the two-photon anisotropic Rabi-Stark model

Since the realization of the strong coupling between light and matter in experimental setups, the quantum Rabi model and its generalized models describing the interaction between the boson field and the two-level system have attracted extensive interest again. The study of anisotropic generalized Rabi models enables us to better understand the novel physical properties of the interaction between light and matter in the ultra-strong and deep-strong coupling regions. In this work, the two-photon anisotropic Rabi-Stark model (tpARSM) is analytically solved by using the Bogoliubov operator approach and the su(1, 1) Lie algebra. We derive the G-function, whose zeros give the regular spectrum of the system. By studying the pole structure of the G-function and the coefficients in the function, exceptional solutions, including the first-order quantum phase transition points, doubly degenerate exceptional solutions and nondegenerate exceptional solutions, are obtained. By discussing the spectral structure, we give the conditions for the first-order quantum phase transition of tpARSM. Furthermore, we find that the property that all of the lowest doubly degenerate crossing points in the two-photon Rabi-Stark model have the same energy only holds for the special case of the tpARSM in which the anisotropy parameter is equal to 1. Finally, from the perspective of first-order quantum phase transitions, concise conditions for the ground state energy level to collapse to or escape from the collapse point for the tpARSM are presented. A good understanding of the tpARSM will lay a good foundation for studying the extended two-photon systems involving multiple levels and multiple bosonic modes, and even the relevant open quantum systems.

Magnetic order induced by magnetic impurities in the Haldane chain compound SrNi2V2O8

Understanding the topological properties of Haldane spin systems offers promising avenues for exploring exotic quantum phases. We investigate the impact of S = 5/2 Mn2+ impurities on the magnetic properties of SrNi2V2O8, a well-known Haldane spin gapped system. Structural characterizations of SrNi2-xMnxV2O8 (x = 0.05, 0.15, 0.30 and 0.60) through Rietveld analyses of X-ray diffraction data confirm the preservation of the I41cd space group for all studied x , along with a preferential insertion of Mn2+ ions into Ni2+ sites. Magnetic susceptibility and magnetization data unveil a magnetic transition occurring in the temperature range of T = 93–99.3 K for x = 0.05–0.60. Dielectric data evince the absence of coupling between magnetic and ferroelectric phases. Notably, the magnetic ordering temperature varies little over a wide range of Mn concentrations, while notable anomalies are observed at x = 0.15. This peculiar behavior suggests that, across low-to-high concentrations, disorder-induced magnetic moments compete with the formation of spin singlets between the nearest Mn2+ impurities, which cancel out the magnetic moments.

Spin and valley-polarized Faraday rotation in irradiated buckled Xene materials

This study delves into the theoretical exploration of Faraday rotation and ellipticity in light beams transmitted through buckled Xene materials. These materials undergo topological phase transitions (TPTs), shifting from topologically non-trivial to trivial systems under the influence of an off-resonance irradiated laser field or a staggered electric potential. Specifically, we investigate the manifestation of these phenomena when the buckled Xene material is exposed to an off-resonant laser and staggered sublattice potential. Using the Kubo formula, we derive the optical conductivities of the buckled Xene material to analyze transmission spectra through Fresnel’s transmission coefficients. Additionally, we calculate the spin and valley-dependent Faraday rotation angles and ellipticities of the buckled Xene by selecting suitable parameters for the circularly polarized off-resonant laser field and staggered electric potential across distinct topological quantum phases. Our findings reveal a high sensitivity of Faraday rotation and ellipticity to the topological invariants. In particular, we find that due to the broken time-reversal symmetry (TRS), the amount of the maximum spin and valley polarized Faraday rotation angle and ellipticity in irradiated buckled Xene material without magnetic field are ≊±0.53∘ and ≊±0.2∘, respectively. Our results suggest possible techniques for probing topological numbers and topological phase transitions in buckled Xene materials by Faraday rotation.