Microwave Quantum Research Articles

Modulating the Amine-CO2 Interaction Strength: Toward Efficient Carbon Capture.

This study contributes to a comprehensive understanding of the interactions between CO2 and amines at the molecular level by exploring the rotational spectra of binary complexes between CO2 and eight different amines through pulsed-jet Fourier transform microwave spectroscopy and quantum chemical calculations. The findings reveal a consistent pattern in which CO2 is bonded to the amino group, primarily through a C···N tetrel bond, while being supported by C-H···O/C hydrogen bonds. Notably, the binding energies increase from primary through tertiary amines and with increasing chain length of the alkyl groups. These groups are found to enhance the electron density at the amino group significantly, thereby facilitating the formation of stronger C···N tetrel bonds. The insights provided into how the interaction strength is modulated by the geometries of amines are deemed essential for the design of more effective CO2 adsorption materials, thus advancing carbon capture technologies.

Tuning Intermolecular Interactions for Chiral Analysis: The Microwave Spectra and Molecular Structures of the Chiral Tag Candidates cis- and trans-2-Fluoro-3-(trifluoromethyl)oxirane and Their Gas-Phase Heterodimers with the Argon Atom.

The cis and trans isomers of the chiral tagging candidate molecule, 2-fluoro-3-(trifluoromethyl)oxirane, as well as the lowest energy gas-phase heterodimer of each with the argon atom, are characterized via quantum chemistry calculations and microwave rotational spectroscopy from 5 to 18 GHz and their ground state, vibrationally averaged structures, are determined. Apart from the cis/trans nature of the ring substitution and small differences in the dihedral angle specifying the rotation of the trifluoromethyl group, the two oxirane molecules and their respective argon complexes each have remarkable structural similarity. In contrast, the binding mode of argon to the oxirane, while similar for the two complexes here, is distinct from those modes observed in previous argon-fluorooxirane species. The ability to tune the preferred mode of binding with differing levels of fluorine substitution may prove advantageous in applications of chiral tagging to a wide variety of analytes.

Self-sustained optomechanical state destruction triggered by the Kerr nonlinearity

Cavity optomechanics implements a unique platform where moving objects can be probed by quantum fields, either laser light or microwave signals. With a pump tone driving at a frequency above the cavity resonance, self-sustained oscillations can be triggered at large injected powers. These limit-cycle dynamics are particularly rich, presenting hysteretic behaviors, broad comb signals, and especially large motion amplitudes. All of these features can be exploited for both fundamental quantum research and engineering. Here we present low-temperature microwave experiments performed on a high-Q cavity resonance capacitively coupled to the flexure of a beam resonator. We study the limit-cycle dynamics parameter space as a function of pump parameters (detuning, power). Unexpectedly, we find that in a region of this parameter space the microwave resonance is irremediably destroyed: Only a dramatic power reset can restore the dynamics to its original state. The phenomenon can be understood as an optical instability linked to the Kerr nonlinearity of the cavity. A theory supporting this claim is presented, reproducing almost quantitatively the measurement. This remarkable feature might be further optimized and represents a new resource for quantum microwave circuits. Published by the American Physical Society 2024

Heralding entangled optical photons from a microwave quantum processor

Exploiting the strengths of different quantum hardware components may increase the capabilities of emerging quantum processors. Here we propose and analyze a quantum architecture that leverages the nonlocal connectivity of optics, along with the exquisite quantum control offered by superconducting microwave circuits, to produce entangled optical resource states. In contrast to previous proposals on optically distributing entanglement between superconducting microwave processors, we use squeezing between microwaves and optics to produce microwave-optical Bell pairs in a dual-rail encoding from a single microwave quantum processor. Moreover, the microwave quantum processor allows us to deterministically entangle microwave-optical Bell pairs into larger cluster states, from which entangled optical photons can be extracted through microwave measurements. Our scheme paves the way for small microwave quantum processors to create heralded entangled optical resource states for optical quantum computation, communication, and sensing using imperfect microwave-optics transducers. We expect that improved isolation of the superconducting processor from stray optical fields will allow the scheme to be demonstrated with currently available hardware. Published by the American Physical Society 2024

Demonstration of microwave single-shot quantum key distribution

Security of modern classical data encryption often relies on computationally hard problems, which can be trivialized with the advent of quantum computers. A potential remedy for this is quantum communication which takes advantage of the laws of quantum physics to provide secure exchange of information. Here, quantum key distribution (QKD) represents a powerful tool, allowing for unconditionally secure quantum communication between remote parties. At the same time, microwave quantum communication is set to play an important role in future quantum networks because of its natural frequency compatibility with superconducting quantum processors and modern near-distance communication standards. To this end, we present an experimental realization of a continuous-variable QKD protocol based on propagating displaced squeezed microwave states. We use superconducting parametric devices for generation and single-shot quadrature detection of these states. We demonstrate unconditional security in our experimental microwave QKD setting. The security performance is shown to be improved by adding finite trusted noise on the preparation side. Our results indicate feasibility of secure microwave quantum communication with the currently available technology in both open-air (up to ~ 80 m) and cryogenic (over 1000 m) conditions.

Determination of the ground-state hyperfine splitting of trapped 171Yb+ ions

We present the determination of the ground-state hyperfine splitting (νHFS) in laser-cooled 171Yb+ ions using our microwave quantum frequency standard (QFS). Employing Ramsey spectroscopy in a closed-loop measurement configuration, we have achieved a νHFS value of 12 642 812 118 469.0(8) mHz with a fractional uncertainty of 6.6×10−14. This result aligns with previously reported values and represents the highest accuracy reported to date for such measurements conducted in a single-shot closed-loop configuration, without averaging over multiple dates. The development of this accurate 171Yb+ microwave QFS holds promise as a transportable time-frequency reference for satellite navigation systems.

Microwave radiation of space and prospects for its use in quantum propulsors

Using the original approach developed in recent years – supramolecular physics of the environment, the results of considering the contribution of physical optics processes to the formation of induced microwave radiation are presented.The two most powerful cosmic thermal sources: the background (relict) flux in the absolute millimeter maximum of the spectrum, and the mm-wave radio flux from Sun are considered. The postulate of A. Einstein about the emergence of an induced emission quantum in a medium with established thermal equilibrium is taken into account. This made it possible to quantitatively substantiate, based on the principles of the similarity theory of G.S. Golitsyn, a scheme for the use of microwave energy of the interstellar/interplanetary medium during space flights. Based on the physics of collisions, in the proton transfer reaction of the main simple hydrides in interstellar/interplanetary molecular clouds, it is proposed to take into account the possibility of the manifestation of an additional channel for the maser effect in such a medium (first considered by V.A. Ambartsumian in 1979) due to the close location of electronically excited Rydberg levels for molecules in these clouds. The pioneering work of N.S. Kardashev on the study of Rydberg transitions during the emission of recombination radio lines was taken into account. Due to the efforts of astronomers from the Lebedev Physical Institute and the State Astronomical Observatory of the Russian Academy of Sciences (at Pulkovo), this work led to the discovery of the microwave flux from deep space objects. Real energy and schemes for using a microwave quantum propulsor device with the ability to choose the direction of flights are discussed.

Versatile quantum microwave photonic signal processing platform based on coincidence window selection technique

Versatile quantum microwave photonic signal processing platform based on coincidence window selection technique

New Opportunities for Organic Synthesis with Superheated Flow Chemistry.

ConspectusFlow chemistry has brought a fresh breeze with great promises for chemical manufacturing, yet critical deterrents persist. To remain economically viable at production scales, flow processes demand quick reactions, which are actually not that common. Superheated flow technology stands out as a promising alternative poised to confront modern chemistry challenges. While continuous micro- and mesofluidic reactors offer uniform heating and rapid cooling across different scales, operating above solvent boiling points (i.e., operating under superheated conditions) significantly enhances reaction rates. Despite the energy costs associated with high temperatures, superheated flow chemistry aligns with sustainability goals by improving productivity (process intensification), offering solvent flexibility, and enhancing safety.However, navigating the unconventional chemical space of superheated flow chemistry can be cumbersome, particularly for neophytes. Expanding the temperature/pressure process window beyond the conventional boiling point under the atmospheric pressure limit vastly increases the optimization space. When associated with conventional trial-and-error approaches, this can become exceedingly wasteful, resource-intensive, and discouraging. Over the years, flow chemists have developed various tools to mitigate these challenges, with an increased reliance on statistical models, artificial intelligence, and experimental (kinetics, preliminary test reactions under microwave irradiation) or theoretical (quantum mechanics) a priori knowledge. Yet, the rationale for using superheated conditions has been slow to emerge, despite the growing emphasis on predictive methodologies.To fill this gap, this Account provides a concise yet comprehensive overview of superheated flow chemistry. Key concepts are illustrated with examples from our laboratory's research, as well as other relevant examples from the literature. These examples have been thoroughly studied to answer the main questions Why? At what cost? How? For what? The answers we provide will encourage educated and widespread adoption. The discussion begins with a demonstration of the various advantages arising from superheated flow chemistry. Different reactor alternatives suitable for high temperatures and pressures are then presented. Next, a clear workflow toward strategic adoption of superheated conditions is resorted either using Design of Experiments (DoE), microwave test chemistry, kinetics data, or Quantum Mechanics (QM). We provide rationalization for chemistries that are well suited for superheated conditions (e.g., additions to carbonyl functions, aromatic substitutions, as well as C-Y [Y = N, O, S, C, Br, Cl] heterolytic cleavages). Lastly, we bring the reader to a rational decision analysis toward superheated flow conditions. We believe this Account will become a reference guide for exploring extended chemical spaces, accelerating organic synthesis, and advancing molecular sciences.

Microwave quantum illumination: enhanced azimuth detection with cavity magnonics.

Most current microwave quantum illumination techniques rely on hybrid quantum systems to detect the presence of targets. However, real-world radar tasks are considerably more intricate than this simplistic model. Accurately determining physical attributes such as object speed, position, and azimuth is also essential. In this study, we explore azimuth detection using a quantum illumination approach based on a cavity-optomagnonics system and analyze the accuracy of azimuth detection in this framework. Our results indicate that this approach significantly outperforms classical microwave radar in azimuth detection within the parameters of current existing experiments. Additionally, we investigate the impact of Kerr nonlinearity of the YIG sphere on azimuth detection accuracy, revealing a clear improvement with the incorporation of Kerr nonlinearity.

Tailoring Coherent Microwave Emission from a Solid-State Hybrid System for Room-Temperature Microwave Quantum Electronics.

Quantum electronics operating in the microwave domain are burgeoning and becoming essential building blocks of quantum computers, sensors, and communication devices. However, the field of microwave quantum electronics has long been dominated by the need for cryogenic conditions to maintain delicate quantum characteristics. Here, a solid-state hybrid system, constituted by a photo-excited pentacene triplet spin ensemble coupled to a dielectric resonator, is reported for the first time capable of both coherent microwave quantum amplification and oscillation at X band via the masing process at room temperature. By incorporating external driving and active dissipation control into the hybrid system, efficient tuning of the maser emission characteristics at ≈9.4GHz is achieved, which is key to optimizing the performance of the maser device. The work not only pushes the boundaries of the operating frequency and functionality of the existing pentacene masers but also demonstrates a universal route for controlling the masing process at room temperature, highlighting opportunities for optimizing emerging solid-state masers for quantum information processing and communication.

Boundary measurement tomography of the Bose Hubbard model on general graphs

Correlated quantum many-body phenomena in lattice models have been identified as a set of physically interesting problems that cannot be solved classically. Analog quantum simulators, in photonics and microwave superconducting circuits, have emerged as near-term platforms to address these problems. An important ingredient in practical quantum simulation experiments is the tomography of the implemented Hamiltonians—while this can easily be performed if we have individual measurement access to each qubit in the simulator, this could be challenging to implement in many hardware platforms. In this paper, we present a scheme for tomography of quantum simulators which can be described by a Bose-Hubbard Hamiltonian while having measurement access to only some sites on the boundary of the lattice. We present an algorithm that uses the experimentally routine transmission and two-photon correlation functions, measured at the boundary, to extract the Hamiltonian parameters at the standard quantum limit. Furthermore, by building on quantum enhanced spectroscopy protocols that, we show that with the additional ability to switch on and off the on-site repulsion in the simulator, we can sense the Hamiltonian parameters beyond the standard quantum limit. Published by the American Physical Society 2024

Range Limitations in Microwave Quantum Radar

Range Limitations in Microwave Quantum Radar

Radiatively cooled quantum microwave amplifiers

Superconducting microwave amplifiers are essential for sensitive signal readout in superconducting quantum processors. Typically based on Josephson junctions, these amplifiers require operation at milli-Kelvin temperatures to achieve quantum-limited performance. Here, we demonstrate a quantum microwave amplifier that employs radiative cooling to operate at elevated temperatures and maintain near quantum-limited added noise. This kinetic-inductance-based parametric amplifier, patterned from a single layer of relatively high-Tc NbN thin film, maintains a high gain and meanwhile enables low added noise of 1.3 quanta when operated at 1.5 K. Remarkably, this represents only a 0.2 quanta increase compared to the performance at a base temperature of 0.1 K. Based on our findings, we also discuss the practicality of such an operating scheme for various quantum applications. By uplifting the parametric amplifiers from the mixing chamber without compromising readout efficiency, this work represents an important step toward more scalable microwave quantum technologies.

The Heavy Atom Structure, "cis effect" on Methyl Internal Rotation, and 14N Nuclear Quadrupole Coupling of 1-Cyanopropene from Quantum Chemical and Microwave Spectroscopic Analysis.

The microwave spectrum of 1-cyanopropene (crotonitrile) was remeasured using two pulsed molecular jet Fourier transform microwave spectrometers operating from 2.0 to 40.0 GHz. The molecule exists in two isomer forms, E and Z, with respect to the orientation between the methyl and the cyano groups. The spectrum of the Z isomer is more intense. Due to internal rotation of the methyl group, doublets containing A and E torsional species were found for all rotational transitions. Hyperfine splittings arising from the 14N nuclear quadrupole coupling were resolved. The heavy atom structure of the Z isomer was determined by observation of 13C and 15N isotopologue spectra in natural abundances. The experimental results were supported by quantum chemistry. The complex spectral patterns were analyzed and fitted globally, and the barriers to methyl internal rotation are determined to be 478.325(28) cm-1 and 674.632(76) cm-1 for the Z and E isomers, respectively. The non-bonded intramolecular electrostatic attraction between the methyl group and the 1-cyano substituent overcomes steric hindrance, leading to higher stability of the Z isomer. The consequence is a slight opening of 3.2° of the C(1)-C(2)-C(3) angle and a radical decrease of the methyl torsional barrier in the Z isomer due to steric repulsion.

Design of a Dual-Frequency Electric Field Local Enhancement Structure for Quantum Microwave Measurements

Design of a Dual-Frequency Electric Field Local Enhancement Structure for Quantum Microwave Measurements

Terahertz phonon engineering with van der Waals heterostructures.

Phonon engineering at gigahertz frequencies forms the foundation of microwave acoustic filters1, acousto-optic modulators2 and quantum transducers3,4. Terahertz phonon engineering could lead to acoustic filters and modulators at higher bandwidth and speed, as well as quantum circuits operating at higher temperatures. Despite their potential, methods for engineering terahertz phonons have been limited due to the challenges of achieving the required material control at subnanometre precision and efficient phonon coupling at terahertz frequencies. Here we demonstrate the efficient generation, detection and manipulation of terahertz phonons through precise integration of atomically thin layers in van der Waals heterostructures. We used few-layer graphene as an ultrabroadband phonon transducer that converts femtosecond near-infrared pulses to acoustic-phonon pulses with spectral content up to 3 THz. A monolayer WSe2 is used as a sensor. The high-fidelity readout was enabled by the exciton-phonon coupling and strong light-matter interactions. By combining these capabilities in a single heterostructure and detecting responses to incident mechanical waves, we performed terahertz phononic spectroscopy. Using this platform, we demonstrate high-Q terahertz phononic cavities and show that a WSe2 monolayer embedded in hexagonal boron nitride can efficiently block the transmission of terahertz phonons. By comparing our measurements to a nanomechanical model, we obtained the force constants at the heterointerfaces. Our results could enable terahertz phononic metamaterials for ultrabroadband acoustic filters and modulators and could open new routes for thermal engineering.

Coupled internal rotations and 14N quadrupole hyperfine structure of 2,4-dimethylpyrrole investigated by microwave spectroscopy and quantum chemistry.

The microwave spectrum of 2,4-dimethylpyrrole was investigated using a Fourier-transform microwave spectrometer in a supersonic expansion. Torsional splittings arising from two inequivalent methyl internal rotors in combination with hyperfine splittings due to the nuclear quadrupole coupling of the 14N nucleus were observed. The experiments were accompanied by quantum chemical calculations. A total of 1561 rotational lines were assigned and fitted in global fits using the programs XIAM and BELGI-Cs-2Tops-hyperfine, both achieved the measurement accuracy of 4kHz. Local separate fits were also performed to verify the correctness of the assignment. Accurate experimental molecular and internal rotation parameters could be deduced and compared to the calculated ones. The barrier to internal rotation of the 2-methyl rotor was determined to be 277.830(26) cm-1, essentially the same as the value of about 280cm-1 found for 2-methylpyrrole but lower than the value of 317cm-1 found for 2,5-dimethylpyrrole. The torsional barrier value of the 4-methyl rotor is 262.210(27) cm-1, slightly higher than the value of 246cm-1 found for 3-methylpyrrole. Benchmarking the rotational constants for 2,4- and 2,5-dimethylpyrrole revealed that the MP2/6-31G(d,p) level could be helpful to guide the assignment of microwave spectra of pyrrole derivatives.

High-Speed Electro-Optic Modulators Based on Thin-Film Lithium Niobate.

Electro-optic modulators (EOMs) are pivotal in bridging electrical and optical domains, essential for diverse applications including optical communication, microwave signal processing, sensing, and quantum technologies. However, achieving the trifecta of high-density integration, cost-effectiveness, and superior performance remains challenging within established integrated photonics platforms. Enter thin-film lithium niobate (LN), a recent standout with its inherent electro-optic (EO) efficiency, proven industrial performance, durability, and rapid fabrication advancements. This platform inherits material advantages from traditional bulk LN devices while offering a reduced footprint, wider bandwidths, and lower power requirements. Despite its recent introduction, commercial thin-film LN wafers already rival or surpass established alternatives like silicon and indium phosphide, benefitting from decades of research. In this review, we delve into the foundational principles and technical innovations driving state-of-the-art LN modulator demonstrations, exploring various methodologies, their strengths, and challenges. Furthermore, we outline pathways for further enhancing LN modulators and anticipate exciting prospects for larger-scale LN EO circuits beyond singular components. By elucidating the current landscape and future directions, we highlight the transformative potential of thin-film LN technology in advancing electro-optic modulation and integrated photonics.

Microwave quantum memcapacitor effect

Developing the field of neuromorphic quantum computing necessitates designing scalable quantum memory devices. Here, we propose a superconducting quantum memory device in the microwave regime, termed a microwave quantum memcapacitor. It comprises two linked resonators, the primary one is coupled to a Superconducting Quantum Interference Device, which allows for the modulation of the resonator properties through external magnetic flux. The auxiliary resonator, operated through weak measurements, provides feedback to the primary resonator, ensuring stable memory behavior. This device operates with a classical input in one cavity while reading the response in the other, serving as a fundamental building block toward arrays of microwave quantum memcapacitors. We observe that a bipartite setup can retain its memory behavior and gains entanglement and quantum correlations. Our findings pave the way for the experimental implementation of memcapacitive superconducting quantum devices and memory device arrays for neuromorphic quantum computing.