Quantum Entropy Production Research Articles

Thermodynamic uncertainty relation for quantum entropy production.

In quantum thermodynamics, entropy production is usually defined in terms of the quantum relative entropy between two states. We derive a lower bound for the quantum entropy production in terms of the mean and variance of quantum observables, which we refer to as a thermodynamic uncertainty relation (TUR) for the entropy production. In the absence of coherence between the states, our result reproduces classic TURs in stochastic thermodynamics. For the derivation of the TUR, we introduce a lower bound for a quantum generalization of the χ^{2} divergence between two states and discuss its implications for stochastic and quantum thermodynamics, as well as the limiting case where it reproduces the quantum Cramér-Rao inequality.

Quantum relative entropy uncertainty relation.

For classic systems, the thermodynamic uncertainty relation (TUR) states that the fluctuations of a current have a lower bound in terms of the entropy production. Some TURs are rooted in information theory, particularly derived from relations between observations (mean and variance) and dissimilarities, such as the Kullback-Leibler divergence, which plays the role of entropy production in stochastic thermodynamics. We generalize this idea for quantum systems, where we find a lower bound for the uncertainty of quantum observables given in terms of the quantum relative entropy. We apply the result to obtain a quantum thermodynamic uncertainty relation in terms of the quantum entropy production, valid for arbitrary dynamics and nonthermal environments.

Upper bound for quantum entropy production from entropy flux.

Entropy production is a key quantity characterizing nonequilibrium systems. However, it can often be difficult to compute in practice, as it requires detailed information about the system and the dynamics it undergoes. This becomes even more difficult in the quantum domain and if one is interested in generic nonequilibrium reservoirs, for which the standard thermal recipes no longer apply. In this paper, we derive an upper bound for the entropy production in terms of the entropy flux for a class of systems for which the flux is given in terms of a system's observable. Since currents are often easily accessible in this class of systems, this bound should prove useful for estimating the entropy production in a broad variety of processes. We illustrate the applicability of the bound by considering a three-level maser engine and a system interacting with a squeezed bath.

Entropy production and the role of correlations in quantum Brownian motion

We perform a study on quantum entropy production, different kinds of correlations, and their interplay in the driven Caldeira-Leggett model of quantum Brownian motion. The model, taken with a large but finite number of bath modes, is exactly solvable, and the assumption of a Gaussian initial state leads to an efficient numerical simulation of all desired observables in a wide range of model parameters. Our study is composed of three main parts. We first compare two popular definitions of entropy production, namely the standard weak-coupling formulation originally proposed by Spohn and later on extended to the driven case by Deffner and Lutz, and the always-positive expression introduced by Esposito, Lindenberg and van den Broeck, which relies on the knowledge of the evolution of the bath. As a second study, we explore the decomposition of the Esposito et al. entropy production into system-environment and intra-environment correlations for different ranges of couplings and temperatures. Lastly, we examine the evolution of quantum correlations between the system and the environment, measuring entanglement through logarithmic negativity.

Reconstructing quantum entropy production to probe irreversibility and correlations

One of the major goals of quantum thermodynamics is the characterization of irreversibility and its consequences in quantum processes. Here, we discuss how entropy production provides a quantification of the irreversibility in open quantum systems through the quantum fluctuation theorem. We start by introducing a two-time quantum measurement scheme, in which the dynamical evolution between the measurements is described by a completely positive, trace-preserving (CPTP) quantum map (forward process). By inverting the measurement scheme and applying the time-reversed version of the quantum map, we can study how this backward process differs from the forward one. When the CPTP map is unital, we show that the stochastic quantum entropy production is a function only of the probabilities to get the initial measurement outcomes in correspondence of the forward and backward processes. For bipartite open quantum systems we also prove that the mean value of the stochastic quantum entropy production is sub-additive with respect to the bipartition (except for product states). Hence, we find a method to detect correlations between the subsystems. Our main result is the proposal of an efficient protocol to determine and reconstruct the characteristic functions of the stochastic entropy production for each subsystem. This procedure enables to reconstruct even others thermodynamical quantities, such as the work distribution of the composite system and the corresponding internal energy. Efficiency and possible extensions of the protocol are also discussed. Finally, we show how our findings might be experimentally tested by exploiting the state of-the-art trapped-ion platforms.

Entropy production and thermalization in the one-atom maser

In the configuration in which two-level atoms with an initial thermal distribution of their states are sent in succession to a cavity sustaining a single mode of electromagnetic radiation, one atom leaving the cavity as the next one enters it (as in the one-atom maser), Jaynes and Cummings showed that the steady state of the field, when many atoms have traversed the cavity, is thermal with a temperature different than that of the atoms in the off-resonant situation. Having an interaction between two subsystems which maintains them at different temperatures was then understood as leading to an apparent violation of energy conservation. Here we show, by calculating the quantum entropy production in the system, that this difference of temperatures is consistent with having the subsystems adiabatically insulated from each other as the steady state is approached. At resonance the insulation is removed and equilibration of the temperatures is achieved.

Quantum Fokker-Planck-Kramers equation and entropy production.

We use a canonical quantization procedure to set up a quantum Fokker-Planck-Kramers equation that accounts for quantum dissipation in a thermal environment. The dissipation term is chosen to ensure that the thermodynamic equilibrium is described by the Gibbs state. An expression for the quantum entropy production that properly describes quantum systems in a nonequilibrium stationary state is also provided. The time-dependent solution is given for a quantum harmonic oscillator in contact with a heat bath. We also obtain the stationary solution for a system of two coupled harmonic oscillators in contact with reservoirs at distinct temperatures, from which we obtain the entropy production and the quantum thermal conductance.

On the von Neumann entropy of a bath linearly coupled to a driven quantum system

The change of the von Neumann entropy of a set of harmonic oscillators initially in thermal equilibrium and interacting linearly with an externally driven quantum system is computed by adapting the Feynman–Vernon influence functional formalism. This quantum entropy production has the form of the expectation value of three functionals of the forward and backward paths describing the system history in the Feynman–Vernon theory. In the classical limit of Kramers–Langevin dynamics (Caldeira–Leggett model) these functionals combine to three terms, where the first is the entropy production functional of stochastic thermodynamics, the classical work done by the system on the environment in units of kBT, and the second and the third other functionals which have no analogue in stochastic thermodynamics.

Quantum entropy production in phase space

A fluctuation theorem for the nonequilibrium entropy production in quantum phase space is derived, which enables the consistent thermodynamic description of arbitrary quantum systems, open and closed. The new treatment naturally generalizes classical results to the quantum domain. As an illustration the harmonic oscillator dragged through a thermal bath is solved numerically. Finally, the significance of the new approach is discussed in detail, and the phase space treatment is opposed to the two-time energy measurement approach.

A CYCLE DECOMPOSITION AND ENTROPY PRODUCTION FOR CIRCULANT QUANTUM MARKOV SEMIGROUPS

We propose a definition of cycle representation for Quantum Markov Semigroups (QMS) and of Quantum Entropy Production Rate (QEPR) in terms of the ρ-adjoint. We introduce the class of circulant QMS, which admit non-equilibrium steady states but exhibit symmetries that allow us to compute explicitly the QEPR, gain a deeper insight into the notion of cycle decomposition and prove that quantum detailed balance holds if and only if the QEPR equals zero.

Generalized Clausius Inequality for Nonequilibrium Quantum Processes

We show that the nonequilibrium entropy production for a driven quantum system is larger than the Bures length, the geometric distance between its actual state and the corresponding equilibrium state. This universal lower bound generalizes the Clausius inequality to arbitrary nonequilibrium processes beyond linear response. We further derive a fundamental upper bound for the quantum entropy production rate and discuss its connection to the Bremermann-Bekenstein bound.

Quantum entropy production as a measure of irreversibility

We consider conservative quantum evolutions possibly interrupted by macroscopic measurements. When started in a nonequilibrium state, the resulting path-space measure is not time-reversal invariant and the weight of time-reversal breaking equals the exponential of the entropy production. The mean entropy production can then be expressed via a relative entropy on the level of histories. This gives a partial extension of the result for classical systems, that the entropy production is given by the source term of time-reversal breaking in the path-space measure.

Quantum jumps and entropy production

The irreversible motion of an open quantum system can be represented through an ensemble of state vectors following a stochastic dynamics with piecewise deterministic paths. It is shown that this representation leads to a natural definition of the rate of quantum entropy production. The entropy production rate is expressed in terms of the von Neumann entropy and of the numbers of quantum jumps corresponding to the various decay channels of the open system. The proof of the positivity and of the convexity of the entropy production rate is given. Monte Carlo simulations of the stochastic dynamics of a driven qubit and of a $\ensuremath{\Lambda}$ configuration involving a dark state are performed in order to illustrate the general theory.