Quantum Correlation Functions Research Articles

Reconstructing the spatial structure of quantum correlations in materials

Quantum correlations are a fundamental property of quantum many-body states. Yet they remain experimentally elusive, hindering certification of genuine quantum behavior, especially in quantum materials. Here we show that the momentum-dependent dynamical susceptibility measured via inelastic neutron scattering enables the systematic reconstruction of a general family of quantum correlation functions, which express the degree of quantum coherence in the fluctuations of two spins at an arbitrary mutual distance. Using neutron scattering data for the compound KCuF3—a system of weakly coupled S=1/2 Heisenberg chains—and numerically exact quantum Monte Carlo data, we show that quantum correlations possess a radically different spatial structure with respect to conventional correlations. Indeed, they exhibit a different emergent length scale—the quantum coherence length—which is finite at any finite temperature (including when long-range magnetic order develops). Moreover, we show theoretically that coupled Heisenberg spin chains exhibit a form of quantum monogamy, with a trade-off between quantum correlations along and transverse to the spin chains. These results highlight real-space quantum correlators as an informative, model-independent means of probing the underlying quantum state of real quantum materials. Published by the American Physical Society 2024

Generalized quantum master equations can improve the accuracy of semiclassical predictions of multitime correlation functions

Multitime quantum correlation functions are central objects in physical science, offering a direct link between the experimental observables and the dynamics of an underlying model. While experiments such as 2D spectroscopy and quantum control can now measure such quantities, the accurate simulation of such responses remains computationally expensive and sometimes impossible, depending on the system’s complexity. A natural tool to employ is the generalized quantum master equation (GQME), which can offer computational savings by extending reference dynamics at a comparatively trivial cost. However, dynamical methods that can tackle chemical systems with atomistic resolution, such as those in the semiclassical hierarchy, often suffer from poor accuracy, limiting the credence one might lend to their results. By combining work on the accuracy-boosting formulation of semiclassical memory kernels with recent work on the multitime GQME, here we show for the first time that one can exploit a multitime semiclassical GQME to dramatically improve both the accuracy of coarse mean-field Ehrenfest dynamics and obtain orders of magnitude efficiency gains.

Projective measurements can probe nonclassical work extraction and time correlations

Quantum correlation functions are a natural way to encode multitime information, as they are ubiquitous in analysis from fluctuation theorems to information scrambling. Correlation functions can be identified with quasiprobabilities associated to quantum processes. In this work we show how these can be measured via error-cancellation techniques, using projective measurements only and no ancillae. The scheme is implemented in a nitrogen-vacancy center in diamond undergoing a unitary quantum work protocol. We reconstruct quantum-mechanical time correlations encoded in the Margenau-Hills quasiprobabilities by observing work extraction peaks five times those of sequential projective energy measurement schemes and in violation of newly derived stochastic bounds. We interpret the phenomenon via anomalous energy exchanges due to the underlying negativity of the quasiprobability distribution. Published by the American Physical Society 2024

Functional Formulation of Quantum Theory of a Scalar Field in a Metric with Lorentzian and Euclidean Signatures.

We study the Schrödinger equation in quantum field theory (QFT) in its functional formulation. In this approach, quantum correlation functions can be expressed as classical expectation values over (complex) stochastic processes. We obtain a stochastic representation of the Schrödinger time evolution on Wentzel-Kramers-Brillouin (WKB) states by means of the Wiener integral. We discuss QFT in a flat expanding metric and in de Sitter space-time. We calculate the evolution kernel in an expanding flat metric in the real-time formulation. We discuss a field interaction in pseudoRiemannian and Riemannian metrics showing that an inversion of the signature leads to some substantial simplifications of the singularity problems in QFT.

The mean square displacement of a ballistic quantum particle

A commonly used quantum mechanical formulation of the mean square displacement δ x 2 ( t ) is based on the quantum correlation function of the position operator. While this quantity yields the classically expected result δ x 2 ( t ) ∝ t 2 for a ballistic particle in the interval topology, it is found here to diverge at essentially all times, when evaluated on infinitely large rings. A somewhat different formulation of the mean square displacement in quantum mechanics was proposed in a previous work (R. Marquardt, Mol. Phys. 119, e1971315 (2021)) and yielded the result δ x 2 ( t ) ∝ t for the ballistic particle on an infinitely large ring. Here, it is shown analytically that that formulation yields δ x 2 ( t ) ≡ 0 for the ballistic particle on an infinitely long interval. The two formulations define two different, topology dependent quantities that have the dimension of an area and that could in principle be determined from the same experiment, following a measurement idea proposed in the aforementioned work. That idea is critically reviewed here.

Efficient formulation of multitime generalized quantum master equations: Taming the cost of simulating 2D spectra.

Modern 4-wave mixing spectroscopies are expensive to obtain experimentally and computationally. In certain cases, the unfavorable scaling of quantum dynamics problems can be improved using a generalized quantum master equation (GQME) approach. However, the inclusion of multiple (light-matter) interactions complicates the equation of motion and leads to seemingly unavoidable cubic scaling in time. In this paper, we present a formulation that greatly simplifies and reduces the computational cost of previous work that extended the GQME framework to treat arbitrary numbers of quantum measurements. Specifically, we remove the time derivatives of quantum correlation functions from the modified Mori-Nakajima-Zwanzig framework by switching to a discrete-convolution implementation inspired by the transfer tensor approach. We then demonstrate the method's capabilities by simulating 2D electronic spectra for the excitation-energy-transfer dimer model. In our method, the resolution of data can be arbitrarily coarsened, especially along the t2 axis, which mirrors how the data are obtained experimentally. Even in a modest case, this demands O(103) fewer data points. We are further able to decompose the spectra into one-, two-, and three-time correlations, showing how and when the system enters a Markovian regime where further measurements are unnecessary to predict future spectra and the scaling becomes quadratic. This offers the ability to generate long-time spectra using only short-time data, enabling access to timescales previously beyond the reach of standard methodologies.

The Nicolai-map approach to supersymmetry

In 1980 Hermann Nicolai proposed a characterization of supersymmetric theories that became known as the Nicolai map. This is a particular nonlocal and nonlinear field transformation, whose perturbative expansion is given by fermion-line trees with bosonic leaves. Quantum correlation functions can by evaluated using the inversely transformed fields in the free theory. After initial promise and excitement (fuelling the author’s PhD work!), the subject all but fell dormant for 35 years. Recently however, technical progress in the construction as well as a deeper insight into the nature of the map have been achieved, from quantum mechanics to super Yang–Mills in various dimensions. I will present the Nicolai map from this modern perspective and touch on some of the current developments.

ANALISIS FUNGSI KORELASI KLASIK DAN KUANTUM UNTUK MODEL CINCIN: SEBUAH REVIEW

A review of the journal entitled 'Classical And Quantum Correlation Functions For A Ring Model' has been carried out which discusses the solutions of classical and quantum correlation functions for the ring model. Classical and quantum correlation functions are derived for systems of non-interacting particles moving in a circle. demonstrated that the decay behavior of the classical expression for the correlation function can be recovered from a strictly periodic quantum mechanical expression by taking the limit ℏ→0, after the appropriate transformation. The aim of this study is to present clearly and in detail how the position correlation function for a system of particles moving in a circle having a certain average energy and written in a form which shows the nature of the transformation. Next, we examine the use of Poisson addition to represent F(z), and how the correlation function becomes identical to the form given by classical statistical mechanics, which exhibits Gaussian decay. The results of this study indicate that the positional correlation function for a system of particles moving in a circle, and having a certain average energy, can be written in a form which shows the nature of the transformation. Then using the Poisson addition formula to represent F(z), the expression is rewritten to enable the limit ℏ→0 to be taken. It was finally found that the correlation function became identical to the form given by classical statistical mechanics, which exhibits a Gaussian decay.

Witnessing Quantum Correlations in a Hybrid Qubit‐Qutrit System Under Intrinsic Decoherence

AbstractStudying qubit‐qutrit systems is crucial to harnessing their quantum advantages, especially in quantum secure technologies. In this regard, the present work consists of considering a qubit‐qutrit system under intrinsic decoherence. For this hybrid‐spin system, the relationship between negativity, local quantum uncertainty, and local quantum Fisher information is discussed. The results show that it is possible to generate and preserve the maximally correlated states by tuning the system parameters to certain fixed values. It is also demonstrated the occurrence of the sudden death/birth phenomenon by examining the behavior of quantum correlation functions.

BV quantization of dynamical fuzzy spectral triples

This paper provides a systematic study of gauge symmetries in the dynamical fuzzy spectral triple models for quantum gravity that have been proposed by Barrett and collaborators. We develop both the classical and the perturbative quantum BV formalism for these models, which in particular leads to an explicit homological construction of the perturbative quantum correlation functions. We show that the relevance of ghost and antifield contributions to such correlation functions depends strongly on the background Dirac operator around which one perturbs, and in particular on the amount of gauge symmetry that it breaks. This will be illustrated by studying quantum perturbations around (a) the gauge-invariant zero Dirac operator in a general -model, and (b) a simple example of a non-trivial in the quartic -model.

Computing quantum correlation functions by importance Sampling method based on path integrals

In this paper, an importance sampling method based on the Generalized Feynman–Kac (GFK) method has been used to calculate the mean values of quantum observables from quantum correlation functions for many-body systems with the Born–Oppenheimer approximation in the nonrelativistic limit both at zero and finite temperature. Specifically, the expectation values [Formula: see text], [Formula: see text], [Formula: see text] and [Formula: see text] for the ground state of the lithium and beryllium and the density matrix, the partition function, the internal energy and the specific heat of a system of quantum harmonic oscillators are computed, in good agreement with the best nonrelativistic values for these quantities. Although the initial results are encouraging, more experimentation will be needed to improve the other existing numerical results beyond chemical accuracies specially for the last two properties for lithium and beryllium. Also more work needs to be done to improve the trial functions for finite temperature calculations. Although these results look promising, more work needs to be done to achieve the spectroscopic accuracy at zero temperature and to estimate the finite temperature effects from the non-Born–Oppenheimer calculations. Also more experimentation will be needed to study the convergence criteria for the inverse properties for atoms at zero temperature.

Two loop ghost free quantisation of Wilson loops in [formula omitted] supersymmetric Yang-Mills

We report a perturbative calculation of the expectation value of the infinite straight line Maldacena-Wilson loop in N=4 supersymmetric Yang-Mills theory to order g6. Thus, we extend the previous perturbative result by one order. The vacuum expectation value is reformulated in terms of a non-linear and non-local transformation, the Nicolai map, mapping the full functional measure of the interacting theory to that of a free bosonic theory. The results are twofold. The perturbative cancellations of the different contributions to the Maldacena-Wilson loop are by no means trivial and seem to resemble those of the circular Maldacena-Wilson loop at order g4. Furthermore, we argue that our approach to computing quantum correlation functions is competitive with more standard diagrammatic techniques.

Enantiodiscrimination of chiral molecules via quantum correlation function.

We propose a method to realize enantiodiscrimination of chiral molecules based on quantum correlation function in a driven cavity-molecule system, where the chiral molecule is coupled with a quantized cavity field and two classical light fields to form a cyclic three-level model. According to the inherent properties of electric-dipole transition moments of chiral molecules, there is a π-phase difference in the overall phase of the cyclic three-level model for the left- and right-handed chiral molecules. Thus, the correlation function depends on this overall phase and is chirality-dependent. The analytical and numerical results indicate that the left- and right-handed chiral molecules can be discriminated by detecting quantum correlation function. Our work opens up a promising route to discriminate molecular chirality, which is an extremely important task in pharmacology and biochemistry.

Determination of uncertainties in parton densities

We review various methods used to estimate uncertainties in quantum correlation functions, such as parton distribution functions (PDFs). Using a toy model of a PDF, we compare the uncertainty estimates yielded by the traditional Hessian and data resampling methods, as well as from explicitly Bayesian analyses using nested sampling or hybrid Markov chain Monte Carlo techniques. We investigate how uncertainty bands derived from neural network approaches depend on details of the network training, and how they compare to the uncertainties obtained from more traditional methods with a specific underlying parametrization. Our results show that utilizing a neural network on a simplified example of PDF data has the potential to inflate uncertainties, in part due to the cross validation procedure that is generally used to avoid overfitting data.

Quantum trajectory theory and simulations of nonlinear spectra and multiphoton effects in waveguide-QED systems with a time-delayed coherent feedback

We study the nonlinear spectra and multi-photon correlation functions for the waveguide output of a two-level system (including realistic dissipation channels) with a time-delayed coherent feedback. We compute these observables by extending a recent quantum trajectory discretized-waveguide (QTDW) approach which exploits quantum trajectory simulations and a collisional model for the waveguide to tractably simulate the dynamics. Following a description of the general technique, we show how to calculate the first and second order quantum correlation functions, in the presence of a coherent pumping field. With a short delay time, we show how feedback can be used to filter out the central peak of the Mollow triplet or switch the output between bunched and anti-bunched photons by proper choice of round trip phase. We further show how the loop length and round trip phase effects the zero-time second order quantum correlation function, an indicator of bunching or anti-bunching. New resonances introduced through the feedback loop are also shown through their appearance in the incoherent output spectrum from the waveguide. We explain these results in the context of the waiting time distributions of the system output and individual trajectories, uniquely stochastic observables that are easily accessible with the QTDW model.

Application of the imaginary time hierarchical equations of motion method to calculate real time correlation functions.

We investigate the application of the imaginary time hierarchical equations of motion method to calculate real time quantum correlation functions. By starting from the path integral expression for the correlated system-bath equilibrium state, we first derive a new set of equations that decouple the imaginary time propagation and the calculation of auxiliary density operators. The new equations, thus, greatly simplify the calculation of the equilibrium correlated initial state that is subsequently used in the real time propagation to obtain the quantum correlation functions. It is also shown that a periodic decomposition of the bath imaginary time correlation function is no longer necessary in the new equations such that different decomposition schemes can be explored. The applicability of the new method is demonstrated in several numerical examples, including the spin-Boson model, the Holstein model, and the double-well model for proton transfer reaction.

Gravitational quantum collapse in dilute systems

Penrose has suggested that large fluctuations of the gravitational energy of quantum systems, resulting from fluctuations of its density in space, may induce a quantum collapse mechanism [1], but he did not propose a precise dynamics for this process. We use the GBC (Gravitational Bohmian Collapse) model [2], which provides such a dynamics. The effects of collapse in dilute quantum systems are investigated, both in ordinary 3D space and in configuration space. We first discuss how a single result appears during a quantum measurement. The GBC model predicts a continuous but very fast evolution of the state vector that, at the end of the measurement, reproduces the von Neumann projection postulate. This ensures that the model remains compatible with the relativistic nosignaling constraint. In the absence of any measurement, we study the spontaneous effects of the GBC process, which depend on the quantum correlation function of observables with the spatial density operator. If the selected observable is the local current of the density fluid, we show that the collapse term leads to modifications of the Newton force, in a scalar or tensor form.

A digital quantum simulation of the Agassi model

A digital quantum simulation of the Agassi model from nuclear physics is proposed and analyzed. The proposal is worked out for the case with four different sites. Numerical simulations and analytical estimations are presented to illustrate the feasibility of this proposal with current technology. The proposed approach is fully scalable to a larger number of sites. The use of a quantum correlation function as a probe to explore the quantum phases by quantum simulating the time dynamics, with no need of computing the ground state, is also studied. Evidence is given showing that the amplitude of the time dynamics of a correlation function in this quantum simulation is linked to the different quantum phases of the system. This approach establishes an avenue for the digital quantum simulation of useful models in nuclear physics.

Gauge-independent emission spectra and quantum correlations in the ultrastrong coupling regime of open system cavity-QED.

A quantum dipole interacting with an optical cavity is one of the key models in cavity quantum electrodynamics (cavity-QED). To treat this system theoretically, the typical approach is to truncate the dipole to two levels. However, it has been shown that in the ultrastrong-coupling regime, this truncation naively destroys gauge invariance. By truncating in a manner consistent with the gauge principle, we introduce master equations for open systems to compute gauge-invariant emission spectra, photon flux rates, and quantum correlation functions which show significant disagreement with previous results obtained using the standard quantum Rabi model. Explicit examples are shown using both the dipole gauge and the Coulomb gauge.

Super-Resolution Imaging by Computationally Fusing Quantum and Classical Optical Information

A high-speed super-resolution computational imaging technique is introduced on the basis of classical and quantum correlation functions obtained from photon counts collected from quantum emitters illuminated by spatiotemporally structured illumination. The structured illumination is delocalized—allowing the selective excitation of separate groups of emitters as the modulation of the illumination light advances. A recorded set of photon counts contains rich quantum and classical information. By processing photon counts, multiple orders of Glauber correlation functions are extracted. Combinations of the normalized Glauber correlation functions convert photon counts into signals of increasing order that contain increasing spatial frequency information. However, the amount of information above the noise floor drops at higher correlation orders, causing a loss of accessible information in the finer spatial frequency content that is contained in the higher-order signals. We demonstrate an efficient and robust computational imaging algorithm to fuse the spatial frequencies from the low-spatial-frequency range that is available in the classical information with the spatial frequency content in the quantum signals. Because of the overlap of low spatial frequency information, the higher signal-to-noise ratio (SNR) information concentrated in the low spatial frequencies stabilizes the lower SNR at higher spatial frequencies in the higher-order quantum signals. Robust performance of this joint fusion of classical and quantum computational single-pixel imaging is demonstrated with marked increases in spatial frequency content, leading to super-resolution imaging, along with much better mean squared errors in the reconstructed images.