The mechanism of charge generation and charge transport is not well understood in high polymers. This leads to qualitative uncertainties in the interpretation of thermally stimulated currents in these materials. In order to clarify the situation, we have undertaken experiments using optical detrapping (photon stimulated currents, PSC) in polyethylene terepthalate (PET) and low-density polyethylene (LDPE). To make the evaluation as straightforward as possible, we have chosen to study depolarisation currents in short circuit. The measurement configuration is such that external photocurrents can be ignored. We find that there is little connection between the dark depolarisation current and the optically stimulated current, in agreement with previous work. At room temperature, we see evidence that long U.V. wavelengths (λ > 315 nm) cause a reduction in the trapped charge density. Illumination at shorter wavelenghts results in carrier generation and trapping which can, under appropriate conditions, give rise to a sign reversal (and, hence, anomalous behaviour) in subsequent longer wavelength depolarisations. The effects observed do not seem to be due to the thermal expansion of the sample. While the full range of response as a function of temperature and wavelenghts remains to be studied, it is already clear that the anomalous behaviour arises from injection from the electrodes (at the longer wavelenght) and the effects of bulk generation (or possibly photoinjection of carriers of the opposite sign) at the shorter wavelengths. The spectral ranges of these processes overlap, and competition occurs in the region where they are both operative. We shall give a tentative model to account for our results.
Read full abstract