A high performance humidity sensor for environmental and health monitoring was fabricated with a polymer–polymer composite sensing layer. PEDOT:PSS/PVA composite was synthesized by physically mixing PEDOT:PSS aqueous solution with PVA aqueous solution and was then sonicated and stirred at elevated temperatures. Sensors were fabricated by depositing the sensing layer on an IDT printed on a piezoelectric substrate. The sensors’ electrical characterizations were performed to find out the response toward varying humidity levels. The results showed that the composite's response toward humidity change is very stable and can effectively measure low humidity levels with fast response time. The AC capacitance and impedance of the sensor were measured between 0%RH and 80%RH. The maximum change in impedance was from 137kΩ to 110kΩ and for capacitance from 96pF to 124pF. The sensors were deployed in a real time humidity measurement and the readings were converted into corresponding %RH. The results indicated that the sensors show promising response with ±1% reading error. The response and recovery times of the sensor were measured to be 0.625s and 0.53s respectively showing excellent performance of the sensor toward increasing and decreasing humidity levels.