Pure SnSe Research Articles

Low temperature co-pyrolysis of hexabenzylditinsulfide and selenium. an alternate route to Sn(S xSe1−x)

Benzyl-substituted tin chalcogenides (Bn 3Sn) 2S (1) and (Bn 3Sn) 2Se (2) yield polycrystalline-phase pure SnS and SnSe in good ceramic yields when pyrolyzed with S and Se, respectively, at 275°C. Heating mixtures of (1) and elemental selenium produce solid solutions of the formula Sn(S xSe 1−x). Combustion analysis showed less than 1% residual carbon in all ceramic products. This methodology allows the complete conversion of tin to tin chalcogenides and eliminates the need to synthesize organosulfur and organoselenium intermediates.

Electrical Properties of Stannous Selenide

The electrical resistivity, Hall coefficient and thermoelectric power were investigated over the temperature range from 100° K to 800° K on pure and impurity-doped SnSe crystals. An anomalous hump of the Hall coefficient was found to occur at about 200°C in most of the as-grown crystals and this seems to make the conventional analysis based on a simple semiconductor model impossible. Anisotropies in the resistivity and Hall coefficient were also studied on single crystals and the observed anisotropy in the resistivity seems to be ascribed to an anisotropy in the effective mass of holes. Hole mobility varies as T -2.0 at high temperatures and its discrepancy from T -1.5 law is explained on the assumption of both optical and acoustical mode scatterings. Further investigation was made of the anomalous Hall coefficient on heating the specimen at various temperatures in vacuum. This anomalous phenomenon was found to depend on the heat-treatment history of the crystal and the experimental results were analysed on such a simple model that acceptors are introduced into SnSe by impurity diffusion above 200°C and caused to disappear on heating at lower temperatures. General features observed seem to be in fair agreement with the proposed model.