Pure Methane Research Articles

Adsorption and separation of carbon dioxide and methane on carbonaceous adsorbents

AbstractAdsorption and separation of carbon dioxide and methane on different carbonaceous adsorbents were analyzed and compared. Coconut shell‐based activated carbon has the highest adsorption capacity for two gases. Sips model describes the adsorption isotherms best. The separation factor on coconut shell‐based activated carbon is the highest under various conditions, reaching about 3.8. The adsorption capacity of the two gases is closely related to the specific surface area and micropore volume of the adsorbent. The adsorbed amount of each component in the mixture is less than that of the pure component under the same condition, indicating that there is a competition in the adsorption process. The total adsorbed amount of the two gases decreases as the proportion of carbon dioxide decreases, implying that the adsorption process is dominated by carbon dioxide adsorption. Additionally, the separation factor decreases with increasing temperature. Understanding the adsorption behaviors of pure and binary carbon dioxide and methane is important in treating biomass gas using carbonaceous adsorbents.

Effect of steam addition and distance between inlet nozzles on non-catalytic POX process under MILD combustion condition

Moderate or intensive low-oxygen dilution (MILD) combustion is a novel combustion technology with high efficiency and low emissions. Few studies have been performed on the application of this technology for partial oxidation processes. In this research, a Computational Fluid Dynamics study for the effect of different parameters on the natural gas partial oxidation under MILD combustion conditions has been carried out. The combustion chamber was in the form of cylinder with a diameter of 300 mm and a length of 1500 mm. The effect of parameters such as different kinetic mechanisms, adding ethane and propane to methane (shale gas feed), adding steam to the feed and distance (interval) between methane and oxygen nozzles were investigated. Results showed that addition of ethane and propane to methane increased the mole fraction of CO and C2H2 so that, in the case of mixed methane with ethane and propane compared to the case of pure methane, an increase of 18.75% and 12.93% was observed for CO and C2H2, respectively. In addition, with increasing the percentage of steam in the inlet feed at a constant flow rate, methane conversion increased so that it in the case of 30% inlet steam was 77.17%, which showed 11% promotion compared to the pure methane case. Also, increasing the distance between the fuel and oxidizer nozzles led to an increase in the maximum temperature in the combustion chamber.

Modeling of Turbulent Premixed CH4/H2/Air Flames Including the Influence of Stretch and Heat Losses

Abstract This paper presents a Reynolds averaged Navier Stokes turbulent combustion model for CH4/H2/air mixtures which includes the effect of heat losses and flame stretch. This approach extends a previous model concept designed for methane/air mixtures and improves the prediction of flame stabilization when hydrogen is added to the fuel. Heat loss and stretch effects are modeled by tabulating the consumption speed of laminar counterflow flames in a fresh-to-burnt configuration with detailed chemistry at various heat loss and flame stretch values. These computed values are then introduced in the turbulent combustion model by means of a turbulent flame speed expression which is derived as a function of flame stretch, heat loss, and H2 addition. The model proposed in this paper is compared to existing models on experimental data of spherical expanding turbulent flame speeds. The performance of the model is further validated by comparing computational fluid dynamics predictions to experimental data of an atmospheric turbulent premixed bluff-body-stabilized flame fed with CH4/H2/air mixtures ranging from pure methane to pure hydrogen.

Analysis of Auto-Ignition Chemistry in Aeroderivative Premixers at Engine Conditions

Abstract The minimization of auto-ignition risk is critical to the design of premixers of high power aeroderivative gas turbines as an increased use of highly reactive future fuels (for example, hydrogen or higher hydrocarbons) is anticipated. Safety factors based on ignition delays of homogeneous mixtures are generally used to guide the choice of a residence time for a given premixer. However, auto-ignition chemistry under aeroderivative conditions is fast (0.5–2 ms) and can be initiated within typical premixer residence times. The analysis of what takes place in this short period necessarily involves the study of low-temperature auto-ignition precursor chemistry, but precursors can change with fuel and local reactivity. Chemical explosive modes (CEMs) are a natural alternative to study this as they can provide a measure for auto-ignition risk by considering the whole thermochemical state in the framework of an eigenvalue problem. When transport effects are included by coupling the evolution of the chemical explosive modes to turbulence, it is possible to obtain a measure of spatial auto-ignition risk where both chemical (e.g., ignition delay) and aerodynamic (e.g., local residence time) influences are unified. In this article, we describe a method that couples large eddy simulation (LES) to newly developed, reduced auto-ignition chemical kinetics to study auto-ignition precursors in an example premixer representative of real life geometric complexity. A blend of pure methane and di-methyl ether (DME), a common fuel used for experimental auto-ignition studies, was transported using the reduced mechanism (38 species/238 reactions) under engine conditions at increasing levels of DME concentrations until exothermic auto-ignition kernels were formed. The resolution of species profiles was ensured by using a thickened flame model where dynamic thickening was carried out with a flame sensor modified to work with multistage heat release. This paper is outlined as follows: First, a reduced mechanism is constructed and validated for modeling methane as well as DME auto-ignition. Second, sensitivity analysis is used to show the need for chemical explosive modes. Third, the thickened flame model modifications are described and then applied to an example premixer at 25 bar/890 K preheat. The chemical explosive mode analysis closely follows the large thermochemical changes in the premixer as a function of DME concentrations and identifies where the premixer is sensitive and flame anchoring is likely to occur.

Study on Hydrate Phase Equilibrium Diagram of Methane Containing System Based on Thermodynamic Model

Natural gas hydrate is a potential energy source in the future, which widely occurs in nature and industrial activities, and its formation and decomposition are identified by phase equilibrium. The calculation of multicomponent gas phase equilibrium is more complex than that of single component gas, which depends on the accurate model characterized by enthalpy and free energy. Based on the Kvamme-Tanaka statistical thermodynamic model, theoretical and experimental methods were used to predict and verify the phase equilibrium of pure methane hydrate and carbon dioxide hydrate in the temperature range of 273.17–289.05 K. The phase equilibrium curves of methane-containing gases such as CH4+CO2,CH4+C2H6,CH4+H2S and CH4+CO2+H2S under different mole fractions were drawn and analyzed, and the decomposition or formation enthalpy and free energy of hydrate were calculated. The results show that, the phase equilibrium curves of the methane containing systems is mainly related to the guest molecule type and the composition of gas. The evolution law of phase equilibrium pressure of different gases varies with composition and temperature, and the phase splitting of CO2at the quadruple point affects the phase equilibrium conditions. Due to the consideration of the interaction between the motion of guest molecules and the vibration of crystal lattice, the model exhibits a good performance, which is quantified in terms of mean square error (MSE) with respect to the experimental data. The magnitudes of MSE percent are respectively 1.2, 4.8, 15.12 and 9.20 MPa2for CH4+CO2, CH4+C2H6, CH4+H2S and CH4+CO2+H2S systems, and the values are as low as 3.57 and 1.32 MPa2for pure methane and carbon dioxide, respectively. This study provides engineers and researchers who want to consult the diagrams at any time with some new and accurate experimental data, calculated results and phase equilibrium curves. The research results are of great significance to the development and utilization of gas hydrate and the flow safety prediction of gas gathering and transportation.

Effects of hydrogen-enriched methane combustion on latent heat recovery potential and environmental impact of condensing boilers

Decarbonization has received significant interest from the energy sector in recent years. In particular, hydrogen enrichment of fuels has been analyzed by several researchers. A side effect of hydrogen enrichment is that it increases the water vapor content in the resulting flue gas. Although this is an undesirable phenomenon in non-condensing energy systems, the higher water vapor content is an advantage in condensing boilers as more energy can be harnessed through condensation. This study analyzes the carbon emission mitigation and latent heat recovery potential of condensing boilers using a mixture of methane and hydrogen as fuel. Accordingly, analyses were performed considering hydrogen volumetric fractions ranging from 0% (pure methane) to 100% (pure hydrogen). The maximum concentrations of CO2 and CO in the flue gas were calculated using the Ostwald diagram. The characteristics of the hydrogen–methane fuel mixture, namely the partial pressure of the water vapor inside the flue gas and the dew point temperature, were investigated as well. The fuel consumption and overall energy saving potential due to the water vapor inside the flue gas were calculated considering a condensing boiler with a gross heat input of 25 kW. As NOx emissions are correlated to the adiabatic flame temperature, the latter was investigated as well. In addition to carbon emission mitigation, the results demonstrated that the condensing boiler efficiency in terms of the higher heating value increased by 1.3%, owing to the additional latent energy saved as the hydrogen volumetric fraction increased from 0% to 80%.

Gas adsorption and separation in metal-organic frameworks by PC-SAFT based density functional theory.

In this work, we examine the theoretical performance of perturbed-chain statistical associating fluid theory based density functional theory (DFT) in predicting gas adsorption and separation in metal-organic frameworks by using simulation and experimental data as the benchmark. Adsorption isotherms of methane and ethane in pure gas and mixtures and selectivities for ethane/methane mixtures are calculated. The predicted isotherms by DFT are in excellent agreement with simulation and experimental data for pure methane and ethane, whereas for the mixture, DFT is in semi-quantitative accordance with simulation results. For fast and high-throughput screening of material purpose, three algorithms including Picard iteration with line search, Anderson mixing, and Picard-Anderson-hybrid algorithm are proposed to calculate the three dimensional density distribution of confined gases. The advantages and limitations of the three algorithms under various conditions are discussed.

A Molecular Dynamics Investigation on Methane Flow and Water Droplets Sliding in Organic Shale Pores with Nano-structured Roughness

Roughness of surfaces significantly influences how methane and water flow in shale nanopores. We perform molecular dynamics simulations to investigate the influence of surface roughness on pore-scale transport of pure methane as well as of two-phase methane–water systems with the water sliding as droplets over the pore surface. For single-phase methane flow, surface roughness shows a limited influence on bulk methane density, while it significantly reduces the methane flow capacity. In methane–water systems, the mobility of water is a strong function of surface roughness including a clear transition between immobile and mobile water droplets. For cases with mobile water, droplet sliding speeds were correlated with pressure gradient and surface roughness. Sliding water droplets hardly deform, i.e., there is little difference between their advancing and receding contact angle with structured roughness.

Syngas biomethanation: effect of biomass-gas ratio, syngas composition and pH buffer

The concept of syngas biomethanation is attractive, however, it still needs improvement in optimizing the operational conditions. In the present study, syngas fermentations under different carbon monoxide (CO), carbon dioxide (CO2) and hydrogen (H2) compositions were conducted under two different biomass-gas ratio (BGR) systems. The results showed that high BGR enhanced the CO consumption rate, achieving a 60% enhancement with CO as the sole substrate. Stoichiometric H2 addition could successfully convert all the CO and CO2 to pure methane, however, higher H2 partial pressure might decline the CO consumption due to pH inhibition from consumption of bicarbonate. Microbial analysis showed different syngas composition could affect the bacteria community, while, archaea community was only slightly affected with Methanothermobacter as the dominant methanogen. This study provided strategy for efficient syngas biomethanation and deeper insight into effect of H2 addition on CO conversion under different BGR systems.

Implementation of packed column for biogas purification as fuel for motorcycle injection systems for performance improvement

The use of gasoline for primary energy consumption can reduce crude oil, contained in the earth. The development of alternative fuels such as biogas and biofuel is very critical to overcoming this problem. Biogas requires purification to remove some contaminant particles that interfere with the combustion process. The packed column is generally applied to absorb and separate gas and liquid mixture. It is more efficient due to the liquid flows down the column of steam naturally without the supply of energy from outside the system. This study focuses on determining the effect of the packed column biogas purification process. Biogas is applied as an alternative fuel in spark-ignition engines (SIE). The test is carried out using a chassis dynamometer to obtain power and torque data. The use of the packed column for biogas fuel purification can produce higher performance compared to unrefined biogas. The unrefined biogas still contains impurities that can interfere with the combustion process. This condition is proven by measuring the power and torque of the vehicle on the chassis dynamometer, where the filtered biogas produces higher power and torque. Tests were carried out both using the packed column and without the packed column. Variations from speed to torque, to power, to SFC and BMEP are considered. In this study, validation is in good agreement with previous studies. Overall, the results show that the average error between using the packed column and without the packed column for torque, power, SFC and BMEP is increased by approximately 7 %. Purification of biogas using the packed column using Ca(OH)2 can bind CO2 and obtain pure methane gas with a higher heating value. In conclusion, the packed column for biogas purification as fuel for motorcycle injection systems can be applied

Selection of methanotrophic platform for methanol production using methane and biogas

To develop biotechnological process for methane to methanol conversion, selection of a suitable methanotrophic platform is an important aspect. Systematic approach based on literature and public databases was developed to select representative methanotrophs Methylotuvimicrobium alcaliphilum, Methylomonas methanica, Methylosinus trichosporium and Methylocella silvestris. Selected methanotrophs were further investigated for methanol tolerance and methanol production on pure methane as well as biogas along with key enzyme activities involved in methane utilization. Among selected methanotrophs M.alcaliphilum showed maximum methanol tolerance of 6% v/v along with maximum methanol production of 307.90mg/L and 247.37mg/L on pure methane and biogas respectively. Activity of methane monooxygenase and formate dehydrogenase enzymes in M.alcaliphilum was significantly higher up to 98.40nmol/min/mg cells and 0.87 U/mg protein, respectively. Biotransformation trials in 14 L fermentor resulted in increased methanol production up to 418 and 331.20mg/L, with yield coefficient 0.83 and 0.71mg methanol/mg of pure methane and biogas respectively. The systematic selection resulted in haloalkaliphilic strain M.alcaliphilum as one of the potential methanotroph for bio-methanol production.

Reactive structures and NOx emissions of methane/hydrogen mixtures in flameless combustion

Methane/hydrogen combustion represents a concrete solution for the energy scenario to come. Indeed, the addition of hydrogen into the natural gas pipeline is one of the solutions foreseen to reduce CO2 emissions. Nevertheless, the replacement of methane by hydrogen will enhance the reactivity of the system, increasing NOx emissions. To overcome this issue, non-conventional combustion technologies, such as flameless combustion represent an attractive solution. This study aims to improve our understanding of the behaviour of methane/hydrogen blends under flameless conditions by means of experiments and simulations. Several experimental campaigns were conducted to test fuel flexibility for different methane/hydrogen blends, varying the injector geometries, equivalence ratio and dilution degree. It was found that a progressive addition of hydrogen in methane enhanced the combustion features, reducing the ignition delay time and loosing progressively the flameless behaviour of the furnace. Reducing the air injector diameter or increasing the fuel lance length were found to be efficient techniques to reduce the maximum temperature of the system and NOx emissions in the exhausts, reaching values below 30 ppm for pure hydrogen. MILD conditions were achieved up to 75%H2 in molar fraction, with no visible flame structures. Additionally, RANS-based simulations were also conducted to shed further light on the effect of adding hydrogen into the fuel blend. A sensitivity study was conducted for three different fuel blends: pure methane, an equimolar blend and pure hydrogen. The effect of chemistry detail, mixing models, radiation modeling and turbulence models on in-flame temperatures and NOx emissions was also studied. In particular, it was found that the usage of detailed chemistry for NOx, coupled with an adjustment of the PaSR model, filled the gap between experiments and predictions. Finally, a brute-force sensitivity revealed that NNH is the most important route for NOx production.

On the sustainability of small-scale expansion-based natural gas liquefaction: Supersonic separator, Joule-Thomson, and turbo-expander

Expansion-based liquefaction technologies are prime candidates for small scale offshore natural gas liquefaction, aiding in reducing NG chain logistical costs, due to their compactness. This study assesses the sustainability and profitability of three expansion-based small-capacity natural gas liquefaction technologies: the rigid-geometry supersonic separator, the Joule-Thomson valve and the turbo-expander. The rigid-geometry supersonic separator was simulated for liquefaction of nearly pure methane via a thermodynamically rigorous steady-state modeling. Supersonic separator inlet conditions were optimized via a response-surface predictor of its critical flowrate in terms of temperature and pressure. Such optimum inlet conditions were found to be T = -15.79°C, P = 80 bar for a maximum 2.5 Mach. With these conditions a multi-criteria analysis was conducted combining sustainability metrics to heuristic criteria into a single one-dimensional index, the Sustainability Degree. Turbo-expander was unveiled as the most sustainable process as it has the highest SD = 11.39 due to its lowest power intensity (0.78 kWh/kgLNG), highest net present value (15.89 MMUSD) and minimal carbon emissions. Single unit supersonic separator has a medium performance (SD = 3.5), weighed down by the large natural gas recycle needed, while Joule-Thomson is the worst process due to the largest power consumption (1.66 kWh/kgLNG) and the lowest net present value (4.4 MMUSD).

Air-induced collisional parameters in the [formula omitted] band of methane

Air broadening and shift coefficients together with narrowing and first order line mixing parameters were measured for 166 lines belonging to J″ manifolds of the P (J″=2−11), Q (J″=1−12) and R (J″=0−11) branches of the ν3 band of 12CH4 near 3.3 μm. These measurements were carried out using a non-linear multispectrum least squares fitting technique. A hard collision Dicke narrowed line shape model including Rosenkranz line mixing was applied. Five high resolution Fourier transform spectra were recorded at room temperature, one at low pressure with pure methane and four at pressures up to 904 hPa with mixtures of methane and air. The measured parameters are compared with data available in the literature.

Carbon natural gas storage performance as predicted by multiscale modeling

Adsorbed natural gas (ANG) technology could help to facilitate the transition to environmentally friendly automobiles. Limits on total energy storage and the accumulation of higher hydrocarbons (C3+) present in natural gas are factors that restrict ANG broad application. Because experimental bed deactivation studies are extremely time-consuming, we propose a multiscale technique to study tank deactivation involving a mathematical model capable of predicting compositions of ANG tank cycles. The model is based on multicomponent ideal adsorption solution theory calculation and molecular simulation of the monocomponent adsorption equilibrium data using the representative pore method. We expect that this approach will save experimental effort and bring new insight to understanding the property-structure relation in activated carbons. The technique is validated using literature experimental data from tanks filled with activated carbons. Two target limits for the charge and discharge pressures (35–1 bar and 65–5.8 bar) are tested. The pressure range of 65–5.8 bar shows the best energy delivery for the three commercial carbons examined. The simulation shows that the amount of energy delivered is maximized for a pore size of 18.5 Å, larger than the 11.5 Å pore previously suggested for storage of pure methane. Maxsorb activated carbon showed similar performance to the metal-organic framework (MOF) NU-125 after approximately 100 charge and discharge cycles. In general, activated carbons are less expensive and more stable than MOFs. By accelerating bed deactivation assessment, the technique will allow the synthesis community to produce more efficient carbonaceous materials and facilitate ANG technology feasibility.

Cation Ordering and Exsolution in Copper-Containing Forms of the Flexible Zeolite Rho (Cu,M-Rho; M=H, Na) and Their Consequences for CO2 Adsorption.

The flexibility of the zeolite Rho framework offers great potential for tunable molecular sieving. The fully copper‐exchanged form of Rho and mixed Cu,H‐ and Cu,Na‐forms have been prepared. EPR spectroscopy reveals that Cu2+ ions are present in the dehydrated forms and Rietveld refinement shows these prefer S6R sites, away from the d8r windows that control diffusion. Fully exchanged Cu‐Rho remains in an open form upon dehydration, the d8r windows remain nearly circular and the occupancy of window sites is low, so that it adsorbs CO2 rapidly at room temperature. Breakthrough tests with 10 % CO2/40 % CH4 mixtures show that Cu4.9‐Rho is able to produce pure methane, albeit with a relatively low capacity at this pCO2 due to the weak interaction of CO2 with Cu cations. This is in strong contrast to Na‐Rho, where cations in narrow elliptical window sites enable CO2 to be adsorbed with high selectivity and uptake but too slowly to enable the production of pure methane in similar breakthrough experiments. A series of Cu,Na‐Rho materials was prepared to improve uptake and selectivity compared to Cu‐Rho, and kinetics compared to Na‐Rho. Remarkably, Cu,Na‐Rho with >2 Cu cations per unit cell exhibited exsolution, due to the preference of Na cations for narrow S8R sites in distorted Rho and of Cu cations for S6R sites in the centric, open form of Rho. The exsolved Cu,Na‐Rho showed improved performance in CO2/CH4 breakthrough tests, producing pure CH4 with improved uptake and CO2/CH4 selectivity compared to that of Cu4.9‐Rho.

Hydrogen and propane implications for reactivity controlled compression ignition combustion engine running on landfill gas and diesel fuel

A detailed investigation of employing landfill gas together with additives such as hydrogen or propane or both as a primary low reactivity fuel in a reactivity controlled compression ignition combustion of a diesel engine is conducted. A 3401E caterpillar single-cylinder diesel engine with a bathtub piston bowl profile is utilized to execute the study. The engine is operated at various intake pressures of 1.6, 1.9, and 2.2 bar, and runs at a fixed engine speed of 1300 rpm. For verification purposes, the conduct of the present engine running on pure methane as a low reactivity fuel is compared to that of the same engine available in the literature. Next, a numerical simulation is made to assess the performance of the present engine running on landfill gas plus the additives. Based on the obtained results, injecting either hydrogen or propane or a combination of both up to a total amount of 10% by volume to the premixed of landfill gas and air, and advancing diesel fuel injection timing of about 20–30 deg. crank angle, render the landfill gas utilization quite competitive with using methane alone. Applying an enriched landfill gas in a reactivity controlled compression ignition diesel engine, as a power generator, drastically reduces the greenhouse gas emission to the atmosphere. Also, the CO and UHC mole fraction in the exhaust gas can be eliminated by either advancing the start of diesel injection or using hydrogen or propane or both as additives. In addition, utilizing hydrogen or propane or a combination of both with the primary fuel improves the peak pressure to about 16% in comparison with that of landfill gas alone.

Numerical Simulation of an Internal Reforming Solid Oxide Fuel Cell Unit Fueled with Hydrogen-Natural Gas Mixtures

Blending hydrogen into natural gas grid can effectively reduce carbon emissions and promote the development of the hydrogen economy. Utilizing hydrogen-natural gas mixtures through internal reforming solid oxide fuel cells (SOFCs) can convert the chemical energy of the fuels direct into electricity, which is a promising technology for combined heat and power systems. In this study, a three-dimensional model for an internal reforming solid oxide fuel cell unit is developed coupling chemical and electrochemical reactions, mass, momentum and heat transfer processes. The influences of the hydrogen addition on the distributions of temperature, gas compositions, and current density are studied by changing the hydrogen ratios in the inlet gas mixtures. The simulation results show that the addition of hydrogen affects the coupling of the endothermic reforming reactions and exothermic electrochemical reactions, which leads to improved temperature uniformity and lower fuel utilization of the SOFC unit compared with pure methane feeding. In order to further enhance the heat transfer between the exothermic and endothermic regions, a heat-pipe enhanced interconnect is introduced in the model. The introduction of the heat pipe is demonstrated to have the ability to decrease the temperature gradient and increase the electrochemical performance.

Estimation of Heat Flow Using a Bottom Simulating Reflection Based on 3D Seismic Data, West Africa

DOI:10.17014/ijog.8.3.297-311A Bottom Simulating Reflection (BSR) has been identified using 3D seismic data from the Cameroon continental slope margin. The BSR covers an area of c. 350 km2 in water depths ranging between 940 m to 1,750 m across an area characterized by high- and low-gradient slopes, gullies, scours, and fans. The thickness of the Gas Hydrate Stability Zone (GHSZ) is ~100 - 250 m, assuming an average velocity of 1,800 m/s. Pockmarks are intensively developed across the slope and most of them are observed in the BSR area. Geothermal estimation is based on hydrate stability conditions for pure methane - seawater system, hydrostatic pressure model, and a range of P-wave velocity models for the GHSZ, ranging from 1,600 -1,800 to 2,000 - 2,200 m/s. Geothermal gradient is calculated showing the range and distribution of thermal gradients in the BSR area from 0.046 C/m to 0.094 oC/m with assumed GHSZ velocity of 1,800 m/s. Thermal gradient anomalies have been observed in association with gullies, vertically stacked channels and in some individual pockmarks. The highest anomalies of 0.08 C/m – 0.094 C/m are found in the depression areas of pockmark trains, within seafloor gullies. These positive anomalies are most likely controlled by active or recently active fluid advection and expulsion through the Cameroon slope.

Modelling of the gas hydrate potential in Svalbard’s fjords

Large amounts of methane are trapped as natural gas hydrate (NGH) in the sediments of the Arctic. Unlike NGH provinces offshore west of Svalbard (Vestnesa Ridge), NGH potential in Svalbard’s fjords and near-shore environment is poorly constrained. In this study we modelled the NGH stability zone (GHSZ) to determine the NGH formation potential within the fjords of Svalbard. We applied a nearest neighbour interpolation method to dynamically derive statistical bottom-water temperature (BWT) trends from available CTD data. The BWT trends along with available geothermal gradient data constrained Svalbard-wide sub-bottom thermobaric models suitable for GHSZ modelling in the near subsurface. Analyses of source rock and fluid seepage data in Isfjorden, including 15 newly identified acoustic gas flares, indicate an active petroleum system with fluid migration reaching the seafloor with significant contributions of higher-order hydrocarbons to the gas feed. A GHSZ is predicted for most fjords at mean BWT conditions and 95:5 methane:ethane gas compositions. Suitable conditions for pure methane NGH formation are only met in the deepest parts of Isfjorden, Hinlopenstretet, Kross- and Kongsfjorden, and Rijpfjorden. Temporal constraints implemented along the well-defined Isfjorden transect indicated a notable negative response to water column warming. The predicted GHSZ across Svalbard’s fjords is likely to disappear over the next few decades.