The pumping-power dependence of the time decay of the long-lived photoinduced midgap absorption has been studied in an MX chain compound $[{\mathrm{Pt}(\mathrm{en})}_{2}]{[\mathrm{Pt}(\mathrm{en})}_{2}{\mathrm{Cl}}_{2}{](\mathrm{B}\mathrm{F}}_{4}{)}_{4},(\mathrm{en})$ being ethylenediamine. The 476.5 nm light of a cw Ar-ion laser is used as the pumping light source. In addition to an extremely nonexponential time decay, the life time of the midgap band is found to vary as ${K}_{0}^{\ensuremath{-}2}$ with the absorption intensity ${K}_{0}$ induced by the laser pumping. This decay behavior is explained well in terms of the Torney-McConnell survival-probability function, $S(\ensuremath{\zeta}{)=e}^{8\ensuremath{\zeta}}\mathrm{erfc}\sqrt{8\ensuremath{\zeta}}$ with $\ensuremath{\zeta}{=A}_{0}^{2}Dt,$ peculiar to the geminate coalescence of unequilibrated states in one dimension, where ${A}_{0},$ D, and t are the initial density of the unequilibrated states, diffusion coefficient, and time, respectively. The observed midgap states are confirmed from this finding to collapse through diffusion-limited mutual collisions in locally disordered PtCl chains. Our previous data on temperature and sample dependencies are reviewed within the framework of this collisional geminate coalescence model.
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