This paper proposes a new algorithm that can simultaneously measure the two-dimensional temperature distribution and absorption coefficient distribution of a pulverized-coal-fired (PCF) boiler furnace. On the base of optimal estimation of the uniform absorption and scattering coefficients as well as 2-D temperature distribution from the color radiation images of the flame by the Tikhonov regularization algorithm, the product of the absorption coefficient and the absolute blackbody emission intensity forms a new unknown distribution of emission source, which is also reconstructed from the color radiation images of the flame by the Tikhonov method. Then the distribution of absorption coefficient can be obtained from the new distribution of emission source as the 2-D temperature distribution has been known. Experimental investigation has been conducted on a 660 MWe four corner, tangentially firing, PCF boiler. In the flame detectors, a three-band pass filter is added in the CCD industrial camera to improve the monochromaticity of the original flame image. The temperature and absorption coefficient distributions of the cross-sections at three detection layers under a load of 330 MW and at the highest layer under a load of 500 MW are obtained. In order to verify the reliability of the algorithm, the flame radiation intensity images calculated from the 2-D distributions of temperature and absorption coefficient reconstructed at the highest layer under the load of 330 MW are taken as measurement data, the algorithm is repeated and the results show that the 2-D temperature distribution reconstructed is similar to the input one, with relative error less than 1% between their mean temperatures, and relative error less than 10% between the reconstructed and input mean values of absorption and scattering coefficients. It demonstrates that the algorithm and technology proposed in this paper have important application prospects in the monitoring, diagnosis and control of PCF combustion processes.