The solar cell-secondary battery energy system has been widely used as decentralized power generation and energy-storage system to reduce reliance on fossil fuel-based generation and mitigate fluctuations in solar cell energy supply. This typically involves power conversion by connecting two energy devices through charge controllers such as maximum power point tracker (MPPT) and pulse width modulator (PMW), which are technically mature and ensure reliable energy conversion and storage within the system. In the era of the fourth industrial revolution, characterized by the hyper-connectivity and hyper-mobility of the internet of things and wearable devices, solar-based integrated energy systems are emerging as a promising independent power source. To make devices more cost-effective, miniaturized, and energy efficient, many researchers are developing integrated energy devices that directly connect two energy devices without relying on a charge controller, a so-called "monolithic" form. However, most integrated devices reported to date still utilize a simple four-electrode structure. While this may visually resemble a monolithic device, it is functionally and structurally limited in its integration capabilities. To maximize the benefits expected from monolithic integrated devices, such as reduced process costs, miniaturization, and increased efficiency, it is essential to implement energy devices with three-electrode structures that share core components such as the electrode of the devices. In this regard, studies have been reported to realize a three-electrode energy device by utilizing the anode (or cathode) of a solar cell, which is a power generation device, as the electrode of an energy storage device, but there is a limitation that the energy density per unit area is low due to the use of a supercapacitor as the storage device, and the overall efficiency of the integrated device is low.In this study, we report on the design and implementation of a three-electrode integrated energy device sharing an electrode to improve the performance (e.g., areal capacity, energy efficiency). This integrated device uses an organic solar cell as the power generation device and a silver-zinc secondary battery as the energy storage device, and they share a silver electrode with each other. The shared silver electrode acts as a multifunctional layer that simultaneously serves as the positive electrode of the solar cell, the electrical connection between the solar cell and the secondary battery, and the cathode active material of the secondary battery. On the device perspective, by using a secondary cell instead of a capacitor, we have significantly increased the areal capacity. In order to further improve the efficiency of the integrated energy device, we applied the following three design strategies to the battery design. First, through the composition design of active ions in the electrolyte, the operating voltage of the secondary battery was matched to the same level as the maximum output voltage of the solar cell. This allows the solar cell to operate at its maximum power conversion efficiency when it charges the battery. Second, we improved the fast-charging characteristics of silver-zinc battery by ensuring that the area near the silver electrode surface is supersaturated with silver anion species during battery operation. This allows the secondary battery to accept the high-power density supplied by the solar cell at a low overvoltage, improving the efficiency of the integrated device. Finally, by applying a gel electrolyte with an optimized ratio of electrolyte components (gelling agent, hardener, salt, and plasticizer), we prevented the failure of the solar cell due to the penetration of electrolyte components and ensured the stable operation of the secondary battery. In conclusion, the aforementioned design improvements enabled the high-performance silver-zinc battery to be recharged near the maximum power point of the solar cell, achieving the highest photo conversion-storage efficiency (PSE) of any organic solar cell-based integrated energy system to date. In this presentation, the design and implementation of a solar cell-battery integrated energy device in a three-electrode configuration sharing a silver electrode will be presented in detail. In addition, secondary battery design strategies will be discussed to maximize the efficiency of the integrated device during high-power charging from solar cells.
Read full abstract