Pulsed Laser Ablation Research Articles

Laser-driven synthesis of functional materials for advanced energy applications: A short review

Since the initial exploration of synthesis possibilities at a liquid–solid interface through pulsed laser irradiation of iron in water, the pulsed laser ablation in liquid media (PLAL) process has garnered significant attention for constructing various nanostructures due to its simple, ultrafast, and clean methodology that avoids byproduct formation. Recent advances in functionalized heterostructures via the PLAL process suggest a broad range of applications for energy- conversion systems, including water splitting and energy harvesting. This review surveys recent advancements in PLAL for energy applications, with a specific focus on its applications in oxygen evolution reaction (OER) electrocatalysts and energy harvesting devices. The review discusses the synthesis mechanisms, advantages, challenges, and future research directions of PLAL, aiming to provide a comprehensive understanding of its potential and limitations.

Synthesis of Au/Co3O4/PVA hybrid nanocomposites via eco-friendly method based on pulsed laser ablation process for water treatment

A portable nanostructured nanocomposite film, based on cobalt oxide and gold nanoparticles (NPs) embedded in a polyvinyl alcohol structure (PVA), Au/Co3O4/PVA, was prepared via a novel way based on pulsed laser ablation to be applied as an effective catalytic degradation material for a hazardous chemical structure as nitro compounds. Au/Co3O4/PVA was investigated by the techniques of UV–Vis, FT-IR, SEM, and XRD. From XRD, the decrease in crystallinity of PVA is attributed to the intermolecular hydrogen bonding between PVA and Au/Co3O4. In addition, there are five interplanar peaks, with three shared peaks by both phases and one unique peak for each phase of Au and Co3O4. From FT-IR, the modes observed at a 500–1200 cm-1 wavenumber range correspond to the stretching vibration modes of Au/Co3O4. From UV–VIS, as the embedding of Co3O4 on Au-PVA structure increases, the energy band gap is shifted to a lower value. This is due to the embedding of Co3O4 NPs. From SEM, in the case of embedding PVA with Au NPs, the bright semi-spherical shape of the nanostructured materials has a bright semi-spherical light area. Moreover, in the case of the embedded PVA with Co3O4 NPs, the faint semi-spherical form of the nanostructured materials is discernible. Besides, the catalytic activity performance is tested for the degradation of 4-nitrophenol, which reveales that the reaction followed first-order kinetics, as indicated by linear regression analysis. The results shows that the sample completely convertes 4-nitrophenol to 4-aminophenol within 6 min.

Effect of magnetic field on the structural, optical, and electrical properties of CdS nanoparticles in distilled water by using pulsed laser ablation

In this study, we investigated the impact that the incorporation of a magnetic field has on the properties of cadmium sulfide CdS nanoparticles as well as the performance of an n-CdS/p-Si heterojunction photodetector that was developed by the use of the pulsed laser ablation in a liquid method. Nd:YAG laser pulses (1.064 μm, 550 mJ) were utilized to ablate cadmium sulfide CdS nanoparticles in water. The synthesized nanoparticles were shown to have a polycrystalline hexagonal structure, as evidenced by the findings of the X-ray diffraction experiment, the crystallite size for cadmium sulfide CdS decreased from 4.611 nm to 4.518 nm. The lattice constants of cadmium sulfide CdS nanostructures were determined to be a = 4.1302, c = 6.702, and c/a=1.622. The strain and dislocation density of cadmium sulfide CdS exhibited an increase. Images taken from a field emission scanning electron microscope demonstrated the formation of spherical nanoparticles on the surface. A magnetic field was applied, increasing the CdS film's crystallinity. As a consequence of this enhancement, the particle size of the CdS decreased from 25.18 nm to 12.17 nm. A comparison was made between this and the size of the crystallites that appeared when no magnetic field was present. The EDS spectrum of magnetically prepared cadmium sulfide CdS films indicates the presence of Cd and S, and the weight percentage ratios [Cd]/[S], increase from 3.72 to 3.80. The transmission electron microscopy (TEM) pictures of CdS samples that were generated using a magnetic field contained particles of small size with a mean of 10.10 nanometers. From the FT-IR spectra of cadmium sulfide CdS prepared using a magnetic field within 400–4000 cm−1, the peaks (bands) of cadmium sulfide CdS at 617 cm−1 represent the bending vibration of Cd-S. As a result of the influence of a magnetic field, the optical energy gap of CdS nanoparticles increased from 2.30 eV to 2.72 eV, as indicated by the UV-Vis study. From PL emission spectra the values of the energy band gap of cadmium sulfide CdS increased from 2.45 eV at 505.7 to 2.47 eV when a magnetic field was applied. CdS NP films produced under the influence of a magnetic field were identified as having n-type characteristics by Hall effect assessments, Particle mobility was influenced by particle size. The effect of applying a magnetic field on the efficiency of the n-CdS/p-Si photodetector was investigated and analyzed. When a magnetic field was applied during ablation, the responsivity of n-CdS/p-Si heterojunction photodetectors increased from 0.498 A/W to 0.830 A/W at 510 nm. This was the result of the application of the magnetic field.

The effect of laser energy on the size of WS2 quantum dots synthesized by pulsed laser ablation in liquid

The effect of laser energy on the size of WS2 quantum dots synthesized by pulsed laser ablation in liquid

Geometrical modeling of ultrashort pulse laser ablation with redeposition and analysis of the influence of spot size and shape

Ultrashort-pulse lasers are an established technology for micromachining and have a great future. A major challenge remains the search for suitable laser parameters and a scanning strategy. To date, this has been achieved mainly by conducting experiments and measuring the resulting surfaces. The use of modeling methods for this purpose is not yet practical for industrial processing. In this work, the recently introduced geometric modeling method for pulsed laser ablation is applied to ultrashort laser ablation and extended to consider the power dependence of the process footprint and the pointing stability during ablation. This work highlights this modeling method to cover a wide range of process parameters in a time-saving manner and to simulate laser micromachining in real time. Furthermore, the influence of the processing height compared to the focal height on oxygen-free copper and steel 1.4034 was investigated. For both the ablation depth is decreased while simultaneously increasing the ablation width. For oxygen-free copper, the ablated volume is insensitive to changes in the processing height, which is not the case for steel 1.4034. The results also show the influence of the pulse repetition rate on the change in the shape of material removal and its influence on process stability.

Diverse energy laser ablation in liquid for indium oxide nanoparticles on porous silicon: enhancing photodetector performance

Abstract The fabrication and analysis of a photodetector using copper oxide nanoparticles (In2O3-NPs) embedded in a porous silicon (PS) structure are detailed in this study. One method used to create In2O3 NPs was pulsed laser ablation in ethanol (PLAL), while another was photo-assisted electrochemical etching to create a porous silicon substrate. The optical, structural, and electrical features of In2O3-NPs/PS devices are investigated, with a particular emphasis on their variations with laser energy. After successfully applying In2O3 nanoparticles onto PS, the X-ray diffraction analysis revealed the presence of distinct peaks that correlate to a copper cubic structure. Using field emission scanning electron microscopy, the researchers determined that the particles had a spherical shape. Absorption increased with increasing laser intensity, and the In2O3-nanocolloids showed clear surface plasmon resonance peaks between 570 and 590 nm in wavelength range. Band gaps of 3.5, 3.4, 3.2, and 3.1 eV were found for the In2O3-NPs generated at 500, 600, 700, and 800 mJ of laser energy, according to the optical properties. According to the optoelectronic properties of the In2O3-NPs/PS photodetector, it was built with an energy level of 700 mJ and had a maximum responsivity of 0.2766 A/W at 650 nm. The In2O3NPs/PS devices discussed in this study have excellent photodetecting performance because they integrate In2O3-NPs with PS.

Accelerating the Hydrogen Evolution Kinetics with a Pulsed Laser-Synthesized Platinum Nanocluster-Decorated Nitrogen-Doped Carbon Electrocatalyst for Alkaline Seawater Electrolysis.

Efficient and durable electrocatalysts for the hydrogen evolution reaction (HER) in alkaline seawater environments are essential for sustainable hydrogen production. Zeolitic imidazolate framework-8 (ZIF-8) is synthesized through pulsed laser ablation in liquid, followed by pyrolysis, producing N-doped porous carbon (NC). NC matrix serves as a self-template, enabling Pt nanocluster decoration (NC-Pt) via pulsed laser irradiation in liquid. NC-Pt exhibits a large surface area, porous structure, high conductivity, N-rich carbon, abundant active sites, low Pt content, and a strong NC-Pt interaction. These properties enhance efficient mass transport during the HER. Remarkably, the optimized NC-Pt-4 catalyst achieves low HER overpotentials of 52, 57, and 53mV to attain 10mA cm-2 in alkaline, alkaline seawater, and simulated seawater, surpassing commercial Pt/C catalysts. In a two-electrode system with NC-Pt-4(-)ǀǀIrO2(+) as cathode and anode, it demonstrates excellent direct seawater electrolysis performance, with a low cell voltage of 1.63mV to attain 10mA cm-2 and remarkable stability. This study presents a rapid and efficient method for fabricating cost-effective and highly effective electrocatalysts for hydrogen production in alkaline and alkaline seawater environments.

Effect of surface charge on laser-produced silver nanoparticles for dye reduction and surface-enhanced Raman spectroscopy

Silver nanoparticles (Ag NPs) are widely used in biological, chemical, and physical fields due to their distinct properties. However, the effect of surfactants with different polarities on the catalytic and surface-enhanced Raman spectroscopy (SERS) performance of Ag NPs has not been thoroughly studied. Here, we tailor the surface charge of laser-synthesized Ag NP without changing their morphology and investigate their catalytic and SERS capabilities. The surfactant-free silver nanoparticles (NPBare), synthesized via pulsed laser ablation in liquid (PLAL), are subsequently coated with ionic surfactants sodium dodecyl sulfate (NPSDS) and cetyltrimethylammonium bromide (NPCTAB). The synthesis and morphology of Ag NPs are confirmed using UV-Vis absorption spectroscopy and scanning electron microscopy. The surface charge of fabricated NPs is determined using zeta potential (ZP) measurements. The ZP values of NPBare, NPSDS, and NPCTAB are determined to be -17 mV, 28.7 mV, and 5.58 mV, respectively. The catalytic activity of bare and coated Ag NPs was tested against the cationic and anionic dyes, Methylene blue (MB) and Methyl orange (MO) respectively. The reduction rate of both dyes was highest when using NPBare. However, in the case of coated nanoparticles, the rate of MB and MO reduction depends on the difference between the ZP of the dye and nanoparticles: the rate of reduction increases with the difference between the zeta potentials of the dye and coated nanoparticles increases. The SERS capability of bare and coated NPs was evaluated for anionic (MO) and cationic (MB, Rhodamine B, and Crystal Violet) dyes. The SERS intensity of dyes strongly enhanced with the increase in ZP difference between the dye molecules and NPs. Surface charge modified NPs shown excellent SERS sensitivity with detection limit up to nanomolar for dye molecules as well as the homogeneity of NPs demonstrated in Raman mapping results with relative standard deviation of 17%. The results suggest that the electrostatic interaction between the nanoparticles and dye molecules plays a dominant role in SERS enhancement. These findings highlight the significance of surface charge in improving the catalytic and sensing properties of noble metal nanoparticles.

Research on Textured Polishing Wheel (TPW) patterns for polishing dental ceramic materials in anhydrous environments

Abstract Dental ceramics commonly utilize high-hardness fused silica materials for the fabrication of inlays, crowns, and artificial dental implants, with their processing efficiency and surface roughness (Ra) directly influencing manufacturing costs and product quality. This study presents the development of a Textured Polishing Wheel (TPW) featuring three distinct surface patterns (spiral, linear, and radial), achieved through single-point diamond and pulsed laser processing techniques. It investigates the effects of these patterns on the removal rate and surface roughness (Ra) of dental ceramics during the polishing process. Results indicate that while TPW demonstrates comparable material removal depth to non-textured polishing wheels, it marginally increases surface roughness (Ra). Moreover, TPW significantly reduces burning and wear on the wheel surface during polishing. Pulsed laser ablation of TPW leads to further improvement in surface roughness, thereby enhancing the processing of dental ceramics. Experimental findings highlight the superior performance of spiral TPW, achieving a material removal rate of 4.2 μm/h and a surface roughness (Ra) of approximately 2.2 nm , thus meeting the manufacturing and functional requirements of dental ceramics.

Pulsed Laser Ablation of Oxygen deficiency Enriched Superlattice Vanadium Pentoxide (V2O5) Ultrathin Nextrode aiming for Flexible Binder-less Tandem Energy Harvesting Devices.

For the initial instance, oxygen deficiency-enriched vanadium pentoxide (O─V2O5@500) thin film electrodes are tuned by the Pulsed Laser Ablation technique. The O─V2O5@500 thin film electrode shows remarkable electrochemical performances confirming the greater potential window of -0.4 to 0.9V versus Hg/HgO in an alkaline electrolyte; also, the O─V2O5@ 500 thin film electrode exhibits a noteworthy volumetric capacity of 167.7 mAh cm-3 (areal capacity of 73.3 µAh cm-2). Additionally, Density Functional Theory (DFT) theory calculations are carried out for oxygen-deficient V2O5. From the partial density of states (pDOS) and partial charge density analysis, it is clear that oxygen vacancy improves the electrical conductivity due to the higher degree of electron delocalization of V─O─V near the vacancy and enhances the redox properties due to the formation of in-gap states. Further, it is reported that a O─V2O5@ 500 ||PVA-KOH|| Bi2O3 A-650 thin film supercapbattery (TFSCB) device attains an exceptional discharge volumetric capacitance of 182.85 F cm-3 (equal volumetric capacity of 124.5 mAh cm-3). Furthermore, the TFSCB device exhibits an extraordinary maximum volumetric energy (power) density of 14.28 mWh cm-3 (1.66W cm-3); TFSCB succeeds in supreme capacity retention of 86% with outstanding coulombic efficiency of 94.4% after 21 000 cycles.

Photodetector application of CuO nanoparticles on porous silicon fabricated by laser ablation in liquid at diverse laser energies

Abstract This paper describes the synthesis and analysis of a photodetector made of copper oxide nanoparticles (CuONPs) embedded in a porous silicon (PS) matrix. CuONPs were generated utilizing pulsed laser ablation in ethanol (PLAL), while a porous silicon-(PS) substrate was created via photo-assisted electrochemical etching. An investigation is conducted on the optical, structural, and electrical characteristics of CuONPs/PS devices, with a focus on their dependence on laser energy. The X-ray diffraction analysis reveals the presence of distinct peaks associated with a copper cubic structure, demonstrating the successful synthesis of CuONPs that have been deposited onto PS. The study using field emission scanning electron microscopy revealed that the particles exhibited spherical form. The CuO-nanocolloids exhibited a linear relationship between laser power and absorption, and their surface plasmon resonance peaks were clearly visible at 570–590 nm. Band gaps of 1.70, 1.61, 1.81, and 1.90 eV were found for CuONPs produced at 500, 600, 700, and 800 mJ of laser energy, respectively, according to the optical characteristics. The greatest responsivity of the CuO-NPs/PS photodetector, manufactured at an energy level of 700 mJ, was 0.135345 A/W at 450 nm, as determined by the optoelectronic characteristics. As a result of combining PS with CuONPs, the devices shown in this work have the ability to function as highly efficient photodetectors.

Comparative Studies of Nanoparticles Formed by Pulsed Laser Ablation of WSe2 in Water and Alcohol

Comparative Studies of Nanoparticles Formed by Pulsed Laser Ablation of WSe2 in Water and Alcohol

Synthesis of trigonal selenium rods, wires and fibers by pulsed laser ablation in ethanol

Elongated stuctures, needle-like type, of trigonal selenium were synthesized successfully by pulsed laser ablation in ethanol. The aspect-ratio was controlled by tuning the repetition rate of the laser beam from 0.1 kHz to 19.9 kHz. Five minutes irradiation followed up by one day of aging inside the colloid was required to achieve the needle-like structure in ethanol.

Nickel oxide nanoparticles embedded in polymer-matrix nanocomposite prepared by nanosecond laser ablation method for optoelectronic applications

The polymeric PVA structure embedded with nickel oxide nanoparticles (NiO NPs) was synthesized using nanosecond pulsed laser ablation in liquid media technique for optoelectronic applications. A comprehensive investigation was conducted on the optical and electrical characteristics of the fabricated films to demonstrate the proficiency of the proposed nanocomposite film in that particular domain. Different weights of NiO nanoparticles were generated by embedding them in PVA film using different ablation durations. It was shown that as the concentration of NiO embedded in PVA increased in correlation with the ablation period, the absorption peak changed to a longer wavelength, and the absorption edge of PVA changed towards lower photon energy with a reduction in the band gap density. Followed by the increase in disorder degree through the addition of NiO NPs, while an average value of the dispersion energy is identical, and the nonlinear parameters (χ(3) and n2) increase. Also, the results emphsies that the dielectric characteristics were affected as the concentration of NiO NPs increased due to the rise in the density of states, which resulted in the generation of polarization. Due to the creation of the charge transfer complex, the optical conductivity of the produced nanocomposites rises as the concentration of NiO NPs increases. Therefore, the optical and electrical characteristics of PVA are significantly affected by the incorporation of NiO nanocomposites.

An interior damage free approach for nanosecond pulsed laser ablation of single crystal diamond via metal film induced self-maintaining graphitization

When laser ablation was conducted on an uncoated single-crystal diamond (SCD) substrate, interior damage and random ablation were observed. Metal film-induced self-maintaining graphitization (MISG) was proposed as a generic approach to solve this problem. MISG was realized through coating a ∼ 100-nm-thick metal film on an SCD substrate. Experiments involving laser irradiation of metal films, such as Au-, Al-, Ti-, and Pt-coated SCD substrates, revealed that the material removal depths were the same when the output power was the same and that the surface was covered by graphite after laser irradiation. In addition, the laser-induced damage to the upper or lower surface in the case of the uncoated SCD substrate disappeared. A semitransparent model based on Beer-Lambert law and an opaque model based on modified Level-Set method were built to simulate laser irradiation on uncoated and metal–coated SCD substrates. In the case of the uncoated sample, the laser energy was largely absorbed by the areas with high-concentration defects, leading to preferential graphitization. In the case of the metal-coated sample, a graphite layer was thermally induced on the SCD surface via heat transition during the period of laser irradiation of the metal film. Subsequently, the graphite layer was self-maintaining, and the material removal acted like a graphite piston sinking to the interior of the SCD substrate. This study demonstrates the feasibility of MISG as a universal approach for avoiding interior damage during laser ablation of SCD substrates.

Promising antibiofilm formation: Liquid phase pulsed laser ablation synthesis of Graphene Oxide@Platinum core-shell nanoparticles.

The increasing prevalence of multi-drug resistance in pathogenic bacteria has rendered antibiotics ineffective, necessitating the exploration of alternative antibacterial approaches. Consequently, research efforts have shifted towards developing new antibiotics and improving the efficacy of existing ones. In the present study, novel core shell graphene oxide@platinum nanoparticles (GRO@Pt-NPs) and their unchanging form have been synthesized using the two-step pulsed laser ablation in liquid (PLAL) technique. The first step involved using the graphene target to create graphene nanoparticles (GRO-NPs), followed by the ablation of GRO-NPs inside platinum nanoparticles (Pt-NPs). To characterize the nanoparticles, various methods were employed, including UV-VIS, transmission electron microscopy (TEM), energy dispersive X-ray (EDX), mapping tests, and X-ray diffraction (XRD). The anti-bacterial and anti-biofilm properties of the nanoparticles were investigated. TEM data confirm the creation of GRO@Pt-NPs. The average particle size was 11 nm for GRO-NPs, 14 nm for Pt-NPs, and 26 nm for GRO@Pt-NPs. The results demonstrate that the created GRO@Pt-NPs have strong antibacterial properties. This pattern is mostly produced through the accumulation of GRO@Pt-NPs on the bacterial surface of Klebsiella pneumoniae (K. pneumoniae) and Enterococcus faecium (E. faecium). The inhibition zones against K. pneumoniae and E. faecium when GRO-NPs were used alone were found to be 11.80 mm and 11.50 mm, respectively. For Pt-NPs, the inhibition zones of E. faecium and K. pneumoniae were 20.50 mm and 16.50 mm, respectively. The utilization of GRO@Pt-NPs resulted in a significant increase in these values, with inhibitory rates of 25.50 mm for E. faecium and 20.45 mm for K. pneumoniae. The antibacterial results were more potent in the core-shell structure than the GRO-NPs alone or Pt-NPs alone. The current work uses, for the first time, a fast and effective technique to synthesize the GRO@Pt-NPs by PLAL method, and the preparation has high clinical potential for prospective use as an antibacterial agent.

Au/ZnO nanocomposites based on simple laser ablation method for water treatment

A binary heterostructure of Au/ZnO nanocomposite is prepared in a novel way based on successive pulsed laser ablation of the two targets in an aqueous solution with varied pulse time. The development of the method allows generating a noble metal (Au) and metal oxide (ZnO) one after one to produce a novel heterostructure with a tunable shell applicable as a catalytic degradable material. The nanocomposite samples are tested to study their optical, morphological, and structural properties. The photocatalytic degradation study demonstrates a significant decrease in the absorbance intensity of Rohdamin B (RhB) dye as the irradiation time increases. It indicates a reduction in dye concentration with a remarkable improvement in contact time. Besides, the degradation percentage against pH value is investigated. It reveals an increasing trend as the pH value rises with a maximum percentage at pH 10. The study is also concerned with the influence of the initial concentration of RhB dye on the degradation efficiency of the nanocomposite. Higher initial concentrations of the dye lead to a decrease in the degradation efficiency of the catalysts. Finally, the kinetic analysis of RhB photodegradation reveals that the Langmuir-Hinshelwood first-order kinetic model accurately describes RhB's adsorption onto the nanocomposites.

Laser-synthesized TiN-based nanoparticles as novel efficient electrostatic nanosorbent for environmental water cleaning

Abstract Dyes used in industries such as textile, paper, and leather are known to be harmful to both human health and aquatic ecosystems, which makes critically important the search of effective and sustainable methods for their removal from wastewater in order to mitigate the detrimental pollution effects. Here, we show that titanium nitride nanoparticles (TiN NPs) synthesized by scalable methods of pulsed laser ablation in liquid ambient (water, acetone and acetonitrile) can serve as extremely efficient sorbents for water decontamination from dye molecules (methylene blue, crystal violet, and malachite green). Our tests show that adsorption of TiN NPs is associated with the electrostatic effect due to a strong negative charge of laser-synthesized TiN NPs and the presence of pores in the NPs. Comprehensive characterization using scanning and transmission electron microscopy, along with Raman spectroscopy, evidenced that the appearance of surface charge is related to the formation of under-stoichiometric TiN (TiN1-x), associated with the predominance of nitrogen vacancies. This study identifies an optimal configuration of vacancy defects that maximizes dye adsorption, with TiN NPs synthesized in water exhibiting superior performance, achieving a dye sorption capacity of 136.5 mg/g at room temperature for methylene blue, which corresponds to best earlier reported values for nanomaterials. This study not only extends the utility of TiN NPs to environmental remediation but also highlights the critical influence of synthesis conditions on their functional properties, offering a pathway towards the design of more effective materials for pollution control.

The ablation behavior of diamond/Cu composites by infrared nanosecond pulsed laser

This paper investigates the material removal behavior of diamond/Cu composites by multi-passes infrared nanosecond pulsed laser ablation, focusing on the formed surface cracks, periodic ripples, profile evolution and deposition. Combining nanosecond laser ablation experiments with simulations based on thermophysical properties is then undertaken to effectively reduce the maximum thermal stress and inhibit crack initiation and propagation. Three types of cracks were identified in nanosecond laser ablation, which were influenced by the diverse thermophysical properties of the material and the temperature gradient. The periodic ripples of 300–1800 nm on the sidewalls of the machined groove on diamond grains were induced when the laser fluence approached the ablation threshold, which did not even appear on the copper matrix as the thermal effects dominate. The groove profile showed a limited change as the ablation passes further increase to be over 40 due to the plasma shielding effect inside the groove, the laser defocusing phenomenon and the increased difficulty of sputtering the molten material. In addition, the different ablation mechanisms of diamond and copper resulted in the formation of overlapping deposition layers with changed surface characteristics at varying laser energy densities. The uneven island-like recast layer affected the uniformity of the ablated grooves, which was dependent on the material microstructure and accumulated laser energy.

Cooperative aggregation of gold nanoparticles on phospholipid vesicles is electrostatically driven.

Gold nanoparticles (AuNP) are known to aggregate on the surface of lipid vesicles, yet the molecular mechanism behind this phenomenom remains unclear. In this work, we have investigated the binding behaviour of AuNPs, synthesized with pulsed laser ablation, to phospholipid vesicles under varying conditions of ionic strength (KCl concentration) and NP to vesicle ratios. Our observations reveal a strong influence of electrolyte concentration on AuNP aggregation mediated by vesicles. Notably, cluster formation is observed even at less than one AuNP per vesicle ratio at low enough ionic strengths. These results evidence a binding mechanism governed by electrostatic attraction with a distinct cooperative behaviour at very low salt concentrations, resulting in a significant increase in nanoparticle clustering. This behaviour is quantitatively analysed through a model that incorporates the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory, considering the electrical double layer attraction between dissimilar, non-oppositely charged objects. This study not only provides insight into the fundamental understanding of nanoparticle-vesicle interactions but also suggests potential strategies for controlling nanoparticle assembly in biological and synthetic systems by tuning the ionic strength.