Pu Ratio Research Articles

Experiments on Criticality and Reactivity Worths in the FCA-XXII-1 Assembly Simulating Highly Enriched MOX Fueled Tight Lattice LWR Cores

A series of integral experiments were conducted at the fast critical assembly (FCA) of the Japan Atomic Energy Agency, simulating light water reactor cores with a tight lattice cell of highly enriched mixed-oxide (MOX) fuel containing >15% fissile plutonium (Pu). The three experimental configurations of the FCA-XXII-1 assembly were constructed using foamed polystyrene with different void fractions (45%, 65%, and 95%) to clarify the prediction accuracy of neutronics calculation codes and nuclear data libraries among various neutron spectra. The hydrogen-to–nuclear fuel atomic ratio varied from 0.1 to 0.8. The nuclear characteristics measured in the experiments were criticality (keff), moderator void reactivity worths, and sample reactivity worths using boron carbide (20%, 60%, and 90% 10B enrichment) and Pu (92%, 81%, and 75% fissile Pu ratio). Preliminary analyses on experiments were conducted using a deterministic calculation code system conventionally used for fast reactors and the Japanese evaluated nuclear data library of JENDL-4.0. The calculated keff values overestimated the experiments beyond the experimental uncertainties. However, most reactivity worth calculations agreed well with the experimental values. Even beyond the experimental uncertainties, discrepancies between the calculation and the experiment were <13%. Specifically in the reactivity worth analyses of the softer neutron spectra configurations, the treatment of ultrafine energy groups obviously improved the prediction accuracy of the deterministic calculations. Furthermore, reference calculations for criticality and large reactivity worths were performed with the Monte Carlo calculation code MVP3 by modeling the experimental configurations in detail, confirming that the deterministic calculations closely agreed with the reference values.

Understanding deforestation impacts on soil erosion rates using 137Cs, 239+240Pu, and 210Pbex and soil physicochemical properties in western Iran

To investigate the effects of converting forests into vineyards typical to Zarivar Lake watershed, Iran, which occurred mainly in the 1970s and 80s, on soil erosion,137Cs and 210Pbex, being mid-and-long-term soil loss tracers, were applied. In Chernobyl-contaminated areas like those found in some parts of Europe and Asia, the proportion of 137Cs Chernobyl fallout needs to be determined to convert 137Cs inventories into soil erosion rates. To do so, Pu radioisotopes were applied for the first time in Iran. The soil samples were gathered from two adjacent, almost similar hillslopes under natural forest (slope length: 250 m; slope gradient: 20%) and rainfed vineyard (slope length: 200 m; slope gradient: 17%). 137Cs/239+240Pu ratios indicated that 49.8 ± 10.0% of 137Cs originated from Chernobyl. The net soil erosion rates derived by 137Cs, and 210Pbex approaches were 5.0 ± 1.1 and 5.9 ± 2.9 Mg ha−1 yr−1 in the forested hillslope, and 25.9 ± 5.7 and 32.5 ± 14.5 Mg ha−1 yr−1 in the vineyard hillslope, respectively. Both 137Cs and 210Pbex highlighted that deforestation increased soil erosion by around five times. Moreover, the impacts of deforestation on soil physicochemical properties were investigated in surface and subsurface soils. Compared to forested hillslope, soil organic carbon stock in the upper 40 cm of the vineyard reduced by 14 Mg C ha−1 (29%), 8 Mg C ha−1 of which was removed by erosion within 35 years, and the remaining have likely been lost via emissions (6 Mg C ha−1). The vineyard topsoil experienced the most dramatic drops in percolation stability (PS), sealing index, and organic matter by about 55, 51, and 49%, respectively. Among all measured physicochemical properties, PS showed the greatest sensitivity to land-use change. Overall, the present study's findings confirmed that deforestation for agricultural purposes triggered soil loss, deteriorated soil quality and possibly contributed to the reduction of the lake's water quality and climate change.

Evidence of an oxidation induced phase transformation for a delta phase plutonium-gallium alloy

The oxidation of an ~1.5 at% Ga plutonium metal alloy in dry air as a function of time was studied using a combination of FIB-SEM, AES, and XRD. Analysis of SEM images of FIB cross-sections of the oxide allowed for direct measurement of the oxide thickness as well as determination of heterogeneity in the extent of the oxide. AES analysis performed on cross-sections of the oxide allowed for quantitative analysis of the atomic composition and semi-quantitative analysis of the chemical composition. Initial preparation of the sample was found to induce a martensitic transformation to α`-Pu with an average thickness of 233 nm. Electropolishing was found to be sufficient to fully remove the α` layer with creation of only a minimum oxide layer. Growth of the oxide in dry air was found to initially follow parabolic kinetics, with a parabolic rate constant orders of magnitude higher than expected for δ-Pu but in-line with values extrapolated to room temperature for α-Pu. Following complete oxidation of the initial α` layer, further regions of plutonium metal depleted in gallium were observed to form at the oxide / metal interface. However, gallium, as Ga2O3, was found to be enriched at the surface and present in the oxide in an amount comparable to the relative Ga:Pu ratio of the bulk metal alloy. The results presented here serve to bridge a diverse array of previous experimental and theoretical data and provide the first comprehensive view of the fate of the δ-stabilizer during formation of an oxide. Data availabilityThe raw/processed data required to reproduce these findings cannot be shared at this time as the data also forms part of an ongoing study.

Temporal variability of Pu signatures in a 210Pb-dated Sphagnum peat profile from the Northern Ural, Russian Federation

The peat archives are one of the stratigraphic records revealing clearly physical, chemical and biological signals of human influence on the Earth System since the 1950s, at least. The presented study was aimed mainly to identify the level and origin of anthropogenic radionuclides such as 238, 239, 240Pu in a 210Pb-dated peat profile derived from the Northern Ural, Russian Federation. As stated, the vertical variability of 240Pu/239Pu isotopic compositions reflects the nuclear weapons testing history with the maximum in the 1960s and small regional impact most likely of high-yielded tests in the 1950s as well as Chinese detonations in the 1970s. Peat accumulations rates were similar to those obtained in adjacent areas, whereas 210Pb flux slightly exceeded the reference level established for adequate latitude belt.

Utilizing neutronics modelling to predict changing Pu ratios in UO2 in the presence of Th

The isotopic fractions of plutonium produced in a reactor are of significant value as nuclear forensic signatures, and the mechanisms of their production and alteration should be investigated thoroughly. A series of neutronics calculations were made on a typical UO2 PWR setup, introducing (Th, U)O2 MOX rods gradually, to investigate how the presence of Th affects the 240Pu/239Pu and 242Pu/239Pu ratios in the remaining UO2 fuel rods. A relationship is found that links the percentage change in these ratios, with the burnup and Th content in the configuration. In an extreme case, it was found that the presence of Th may increase the ratio of 242Pu/239Pu by as much as 3.5% at low burnup.

Measurement of the Ratio of Cumulative Spectra of Beta Particles from $${}^{{235}}$$U and $${}^{{239}}$$Pu Fission Products for Solving Problems of Reactor-Antineutrino Physics

The first cycle of measurements of the ratio of cumulative spectra of beta particles originating from the isotopes $${}^{235}$$ U and $${}^{239}$$ Pu undergoing thermal-neutron-induced fission was performed. It is found that the curve obtained from our present measurement of the $${}^{235}$$ U $$/^{239}$$ Pu ratio of beta-particle spectra lies 5 $${\%}$$ lower than the analogous curve following from the measurement of a group from Institute Laue–Langevin (ILL). The present analysis reveals that this is due to an erroneous 5 $${\%}$$ overestimation of the $${}^{235}$$ U beta-particle spectrum measured by the ILL group. As a consequence, the results obtained for the $${}^{235}$$ U $$\bar{{\nu}}_{e}$$ spectrum at the production instant via a reconstruction from the cumulative spectrum of beta particles from $${}^{235}$$ U also turned out to be overestimated by 5 $${\%}$$ . These data explain the effect of the reactor antineutrino anomaly.

Source, Spatial Distribution and Migration of &lt;sup&gt;239+240&lt;/sup&gt;Pu in Chinese Soils

The source, spatial distribution, typical vertical distribution and migration of 239+240 Pu in Chinese 647 surface soils and 66 soil cores are investigated in this study. To provide a complete spatial distribution of 239+240 Pu in Chinese surface soil, an overall pattern of and mechanism for 239+240 Pu migration in Chinese core soil, we summarize and analyze the 239+240 Pu surface and vertical distributions in literature. Comprehensive statistical analysis suggests four typical distributions in Chinese soil cores. It is found that the 239+240 Pu vertical distribution is closely related to the soil type and the 239+240 Pu migration. The result indicates that global fallout is the major source of 239+240 Pu in Chinese soils, with the average 240 Pu/ 239 Pu atom ratios around 0.18. Abnormally low 240 Pu/ 239 Pu ratios are detected in Jiuquan region and northern Xinjiang province in Northwest China, which can be attributed to nuclear weapons tests. To further investigate the migration behaviors of 239+240 Pu in soil cores in China, we apply the Convection Dispersion Equation (CDE) model and find that 239+240 Pu apparent convection velocities ranges from 0.00032±0.00031 cm/a to 0.473±0.083 cm/a. As shown in four typical vertical 239+240 Pu activity distribution soil cores, the deepened 239+240 Pu activity maximum value position implies a fast 239+240 Pu migration rate or apparent convection velocity. This study for the first time suggests a significant linear correlation ( R 2 =0.847) between depth of 239+240 Pu maximum value (cm) and apparent convection velocity (v, cm/a), and we speculate that v usually does not exceed 0.5 cm/a. A significant linear correlation is also identified between apparent dispersion coefficient (D, cm 2 /a) and v 2 in Chinese soil cores.

Distribution and settling behavior of americium-241 in the tropical East Pacific

The distribution of the anthropogenic radionuclide 241Am, a decay product of 241Pu discharged from atmospheric tests of nuclear weapons, was investigated to resolve its horizontal and vertical migration in the Tropical East Pacific. We analyzed 241Am concentrations in seawater samples collected in 2003. On comparing the 241Am concentrations with the previously determined concentrations of 239+240Pu in the same samples, the vertical profiles of 241Am were found to be similar to those of 239+240Pu. At some stations, the maximum concentration of 241Am occurred 100–200 m deeper than that of 239+240Pu. The 241Am/239+240Pu ratios in the North Pacific and South Pacific were comparable to one another, and were the typical ratio for the Pacific. The 241Am distribution was influenced by the water mass at depths below 400 m. The 241Am data support the view there is a current flowing at depths of 400–3000 m from the North Pacific through the Equator to the South Pacific. In addition, the 241Am vertical profile was explained by using a 1-D scavenging model that considers the decay of 241Pu and adsorption and scavenging by suspended particles. The different depths for the maximum concentrations of 241Am and 239+240Pu observed at some stations were well explained by the model and by the distribution of CaCO3 particles. The residence time of 241Am in the Pacific was also estimated by using the model.

U-Pu Mixed Oxide Particle Analysis by NAUTILUS and Implications for Next-Generation Verification Challenges.

Precise and accurate measurement of U and Pu isotopes from micrometer-sized particles represents new verification challenges for the International Atomic Energy Agency. The U and Pu isotopes and U-Pu elemental ratio provide valuable information about the intended use, the production process, and the purification process of Pu and mixed oxide (MOX) fuels. We demonstrate the ability to directly measure U and Pu isotopes from MOX fuel particles using the U.S. Naval Research Laboratory's Naval Ultra-Trace Isotope Laboratory's Universal Spectrometer (NAUTILUS). Reactor-grade MOX reference materials with well-characterized U and Pu isotopic composition (e.g., UKMOX10 and UKMOX100) were prepared using standard sample preparation methods for large geometry-secondary ion mass spectrometry (LG-SIMS). The results show that the NAUTILUS can discriminate the 238U1H+ signal from 239Pu+, enabling the accurate measurement of the 240Pu/239Pu ratio for MOX particles within 2σ of the certificate value for U-Pu ratios from 3:1 to 300:1. The accuracy of previously reported LG-SIMS measurements was limited to U-Pu ratios <15:1. Using the NAUTILUS, the 234U/238U, 235U/238U, 236U/238U, 240Pu/239Pu, and 242Pu/239Pu ratios for UKMOX10 and UKMOX100 can all be measured accurately within 2σ of the reference values, directly, without correction. The application of the NAUTILUS to the accurate and precise determination of the elemental and isotopic composition of MOX particles in environmental samples may unravel some emerging verification challenges in international safeguards.

Diffusion behavior of hydrogen in oxygen saturated and unsaturated plutonium dioxide: An ab initio molecular dynamics study

As the plutonium (Pu) oxides are the crucial issue of the Pu surface and corrosion science and some impurities like hydrogen (H) are virtually impossible to exclude from them in realistic environments, understanding the dynamical behaviors of hydrogen (H) in Pu oxides is essential for the protections and applications of Pu. Here we perform systematic ab initio molecular dynamics (AIMD) calculations to reveal the diffusion behaviors of impurity H in the oxygen saturated (OS) and oxygen unsaturated (OU) Pu dioxide (PuO 2 ). The considered variation ranges of the concentration of interstitial H (θ: H to Pu ratio), the concentration of oxygen vacancy (OV) (n ov : OV to O ratio), and the temperature were 1 32 ∼ 14 32 , 0 ∼ 8 64 , and 300 ∼ 800 K, respectively. The root mean square displacements, radial distribution functions, Bader charge, electronic density of states, and the three-dimensional diffusion coefficients were extracted and analyzed in detail. Results indicate that the H diffusion is inhibited mainly due to the formation of hydroxyl with the host O both in the OS and OU PuO 2 . In the OU PuO 2 the O atoms will transport due to the presence of large concentration of H. The octahedral interstitial site in the OS PuO 2 and the OV in the OU PuO 2 provide a metastable and favorable capturing effect to the interstitial H, respectively. The diffusion coefficient in the OU PuO 2 is smaller than that of in the OS PuO 2 and decreases with n ov essentially as the OV plays the role of a trap for H diffusion. Our conclusions may provide potential guidance for Pu surface and corrosion science. • The mechanisms of inhibit hydrogen diffusion in different plutonium dioxides were confirmed. • Two different capturing effects to hydrogen in saturated and unsaturated PuO 2 were found. • The diffusion coefficients of hydrogen in different plutonium dioxides were obtained. • The variation tendencies of the hydrogen diffusion coefficients were discussed.

COMPRESSIBLITY OF PEAT SOIL IMPROVED WITH POLYURETHANE

This research investigated the compressibility of natural peat soil and peat soil improved with polyurethane foam. High natural moisture content, high compressibility, low bearing capacity and medium to low permeability is a problem and characteristic of a peat soil. This problem can be solved by reducing the compressibility of the peat soil. The objective of this study is mainly to prove whether the presence of polyurethane foam as a lightweight material on peat soil can reduce the compressibility of peat soil or otherwise. Fifteen samples of peat soil taken from Johan Setia, Klang were tested using Oedometer test with load is doubled at each increment until it reaches the maximum required load which is 10kPa, 20kPa, 40kPa, 80kPa, 160kPa, 320kPa and 640kPa. Polyurethane foam is a lightweight material, therefore reduces the overburden pressure to the underlying soil, hence future settlement can be minimized to a tolerable settlement value. Based on the data obtained from analysis of Oedometer test, the compressibility parameters including void ratio, compression index and swelling index of the peat soil alone are very high which denoted extremely poor condition of the peat soil. The compressibility parameters improved significantly with the PU foam stabilization as PU act as a void filler for peat soil. A slight increase in the compressibility parameters are recorded with higher ratio of isocyanate. However, the maximum pre-consolidation pressure recorded was with PU ratio of 1:1. Therefore, the optimum ratio for PU peat stabilization is in the ratio of 1:1.

COMPRESSIBLITY OF PEAT SOIL IMPROVED WITH POLYURETHANE

This research investigated the compressibility of natural peat soil and peat soil improved with polyurethane foam. High natural moisture content, high compressibility, low bearing capacity and medium to low permeability is a problem and characteristic of a peat soil. This problem can be solved by reducing the compressibility of the peat soil. The objective of this study is mainly to prove whether the presence of polyurethane foam as a lightweight material on peat soil can reduce the compressibility of peat soil or otherwise. Fifteen samples of peat soil taken from Johan Setia, Klang were tested using Oedometer test with load is doubled at each increment until it reaches the maximum required load which is 10kPa, 20kPa, 40kPa, 80kPa, 160kPa, 320kPa and 640kPa. Polyurethane foam is a lightweight material, therefore reduces the overburden pressure to the underlying soil, hence future settlement can be minimized to a tolerable settlement value. Based on the data obtained from analysis of Oedometer test, the compressibility parameters including void ratio, compression index and swelling index of the peat soil alone are very high which denoted extremely poor condition of the peat soil. The compressibility parameters improved significantly with the PU foam stabilization as PU act as a void filler for peat soil. A slight increase in the compressibility parameters are recorded with higher ratio of isocyanate. However, the maximum pre-consolidation pressure recorded was with PU ratio of 1:1. Therefore, the optimum ratio for PU peat stabilization is in the ratio of 1:1.

Performance Enhancing Effect of Metabolic Pre-conditioning on Upper-Body Strength-Endurance Exercise.

High systemic blood lactate (La) was shown to inhibit glycolysis and to increase oxidative metabolism in subsequent anaerobic exercise. Aim of this study was to examine the effect of a metabolic pre-conditioning (MPC) on net La increase and performance in subsequent pull-up exercise (PU). Nine trained students (age: 25.1 ± 1.9 years; BMI: 21.7 ± 1.4) performed PU on a horizontal bar with legs placed on a box (angular hanging) either without or with MPC in a randomized order. MPC was a 26.6 ± 2 s all out shuttle run. Each trial started with a 15-min warm-up phase. Time between MPC and PU was 8 min. Heart rate (HR) and gas exchange measures (VO2, VCO2, and VE) were monitored, La and glucose were measured at specific time points. Gas exchange measures were compared by area under the curve (AUC). In PU without MPC, La increased from 1.24 ± 0.4 to 6.4 ± 1.4 mmol⋅l−1, whereas with MPC, PU started at 9.28 ± 1.98 mmol⋅l−1 La which increased to 10.89 ± 2.13 mmol⋅l−1. With MPC, net La accumulation was significantly reduced by 75.5% but performance was significantly increased by 1 rep (4%). Likewise, net oxygen uptake VO2 (50% AUC), pulmonary ventilation (VE) (34% AUC), and carbon dioxide VCO2 production (26% AUC) were significantly increased during PU but respiratory exchange ratio (RER) was significantly blunted during work and recovery. MPC inhibited glycolysis and increased oxidative metabolism and performance in subsequent anaerobic upper-body strength-endurance exercise.

The Role of PU Ratio on the Dielectric Properties of EP/PU Blends

Electrical A.C conductivity Epoxy/polyurethane EP/PU blends with different blend ratio were synthesized and characterized. A.C conductivity measurements of EP/PU blends were studied in the frequency and temperature ranges (4x104Hz) and (293-373K) respectively. Effect of PU loading levels and temperature on dielectric properties was investigated. The EP/PU blends were diagnosed using FTIR. The results showed that AC conductivity σA.C to be proportionate to ωs. The behavior of the exponent s explained in terms of the correlated barrier hopping and small polaron models. The value of dielectric constant 29723 and dielectric loss 705 of neat epoxy were exhibit to decrease with frequency and increase with temperature. The dependence of activation energy and conduction behavior on the blend ratio also studied. The results showed that the estimated activation energy varied with PU content. The polarizability (α) decreases with increase of PU content and temperature which refer to weaken the intermolecular forces. The addition of PU to EP was responsible about the increase of charge carriers.

Deposition of artificial radionuclides in sediments of Loch Etive, Scotland

The nuclear fuel reprocessing plants on the Sellafield site (UK) have released low-level effluents into the Irish Sea under authorisation since 1952. This has led to the labelling of nearby offshore sediments with a range of artificial radionuclides. In turn, these sediments act as a long-term secondary source of both soluble and particle-associated radionuclides to coastal areas. These radionuclides are of interest both in assessing possible environmental impacts and as tracers for marine processes. Here we present results from a study of the geochemistry of natural (234, 238U) and artificial (137Cs, 241Am, 238Pu, 239+240Pu, and 236U) radionuclides and their accumulation in sediments from Loch Etive, Scotland. The data are interpreted in the context of the historical radioactive discharges to the Irish Sea and biogeochemical processes in marine sediments. Loch Etive is divided into two basins; a lower, seaward basin where the sedimentation rate (∼0.6 cm/yr) is about twice that of the more isolated upper basin (∼0.3 cm/yr). These accumulation rates are consistent with the broad distribution of 137Cs in the sediment profiles which can be related to the maximum Sellafield discharges of 137Cs in the mid-1970s and suggest that 137Cs was mainly transported in solution to Loch Etive during that period. Enrichments of Mn, Fe, and Mo in sediment and porewater from both Loch Etive basins result from contemporary biogeochemical redox processes. Enrichments of 238U and 234U in the lower basin may be a result of the cycling of natural U. By contrast, the Sellafield-derived artificial isotope 236U does not seem to be affected by the redox-driven reactions in the lower basin. The 238Pu/239,240Pu ratios suggest contributions from both historical Sellafield discharges and global fallout Pu. The uniform sediment distributions of Pu and Am, which do not reflect Sellafield historical discharges, suggest the existence of a homogenous secondary source. This could be the offshore ‘mud patch’ in the vicinity of Sellafield from which the supply of radionuclides reflects time-integrated Sellafield discharges. This source could also account for the continuing supply of Cs to Loch Etive, even after substantial reductions in discharge from the Sellafield site.

Analysis of the Daya Bay Reactor Antineutrino Flux Changes with Fuel Burnup.

We investigate the recent Daya Bay results on the changes in the antineutrino flux and spectrum with the burnup of the reactor fuel. We find that the discrepancy between current model predictions and the Daya Bay results can be traced to the original measured ^{235}U/^{239}Pu ratio of the fission β spectra that were used as a base for the expected antineutrino fluxes. An analysis of the antineutrino spectra that is based on a summation over all fission fragment β decays, using nuclear database input, explains all of the features seen in the Daya Bay evolution data. However, this summation method still allows for an anomaly. We conclude that there is currently not enough information to use the antineutrino flux changes to rule out the possible existence of sterile neutrinos.

Inventory and vertical distribution of 137Cs, 239+240Pu and 238Pu in soil from Raivavae and Hiva Oa, two French Polynesian islands in the southern hemisphere

Atmospheric nuclear weapons tests carried out by the United States, the former Soviet Union, the United Kingdom, France and China between 1945 and 1980 resulted in radioactive fallout over the earth's surface of long-lived radionuclides, such as 137Cs, 239+240Pu and 238Pu that could be detected more than 50 years after their production. In addition, the burnup in the upper atmosphere of a thermoelectric generator fueled by 238Pu, SNAP-9A, contributed to the inventory of 238Pu deposited on the ground. In order to estimate the deposition densities of 137Cs, 239+240Pu and 238Pu in French Polynesia, we collected undisturbed soil samples up to 30 cm deep at eight sites in two islands (Hiva Oa, 139°W - 10°S and Raivavae, 148°W - 24°S) in 2015–2016. The top 0–10 cm of the soil cores were sliced into five 2-cm layers and the bottom 10–30 cm into four 5-cm layers for gamma spectrometry and alpha spectrometry measurements. We found that more than 50% of the radioactive inventories are still contained within the first 10 cm and that the average vertical migration velocities of 137Cs and Pu are less than 0.2 cm y−1. The average accumulated depositions, deduced from the profile measurements, are 236 ± 11 Bq.m−2 and 313 ± 39 Bq.m−2 for 137Cs, 12.1 ± 1.5 Bq.m−2 and 22.1 ± 1.7 Bq.m−2 for 239+240Pu, and 1.23 ± 0.46 Bq.m−2 and 1.58 ± 0.60 Bq.m−2 for 238Pu, in Hiva Oa and Raivavae, respectively. The 238Pu/239+240Pu ratios are 0.102 ± 0.050 at Hiva Oa and 0.072 ± 0.033 at Raivavae. Both values are higher than the ratio in nuclear weapons tests fallout estimated to be 0.016 in 2016 (Hardy et al., 1973), because of the contribution of 238Pu fallout from SNAP-9A, which is latitude dependent. The 137Cs/239+240Pu ratios, 19.5 ± 3.2 at Hiva Oa and 14.2 ± 2.8 at Raivavae are in the lower part of the range of values observed in other regions of the world.

Developing Diagnostic Tools for Low-Burnup Reactor Samples

We test common fluence diagnostics in the regime of very low burnup natural uranium reactor samples. The fluence diagnostics considered are the uranium isotopics ratios $^{235}$U/$^{238}$U and $^{236}$U/$^{235}$U, for which we find simple analytic formulas agree well with full reactor simulation predictions. Both ratios agree reasonably well with one another for fluences in the mid $10^{19}\,\mathrm{n/cm^2}$ range. However, below about $10^{19}\,\mathrm{n/cm^2}$ the concentrations of $^{236}$U are found to be sufficiently low that the measured $^{236}$U/$^{235}$U ratios become unreliable. We also derive and test diagnostics for determining sample cooling times in situations where very low burnup and very long cooling times render many standard diagnostics, such as the $^{241}$Am/$^{241}$Pu ratio, impractical. We find that using several fragment ratios are necessary to detect the presence of systematic errors, such as fractionation.

Pacific Proving Grounds radioisotope imprint in the Philippine Sea sediments

Radionuclide concentrations were studied in sediment cores taken at the continental slope of the Philippine Sea off Mindanao Island in the equatorial Western Pacific. High resolution deposition records of anthropogenic radionuclides were collected at this site. Excess 210Pb together with excess 228Th and anthropogenic radionuclides provided information about accumulation rates. Concentrations of Am and Pu isotopes were detected by gamma spectrometry, alpha spectrometry and ICP-MS. The Pu ratios indicate a high portion (minimum of 60%) of Pu from the Pacific Proving Grounds (PPG). This implies that the transport of PPG derived plutonium with the Mindanao Current southward is similarly effective as the previously known transport towards the north with the Kuroshio Current. The record is compared to other studies from northwest Pacific marginal seas and Lombok basin in the Indonesian Archipelago. The sediment core top was found to contain a 6 cm thick layer dominated by terrestrial organic matter, which was interpreted as a result of the 2012 Typhoon Pablo-related fast deposition.

Variations in Pu isotopic composition in soils from the Spitsbergen (Norway): Three potential pollution sources of the Arctic region

Although the polar regions have not been industrialised, numerous contaminants originating from human activity are detectable in the Arctic environment. This study reports evidence of 240Pu/239Pu atomic ratios in the tundra and initial soils from different parts of west and central Spitsbergen and recognizes possible environmental inputs of non-global fallout Pu.The average atomic ratio of 240Pu/239Pu equal to 0.179 (ranging between 0.129 and 0.201) in tundra soils are comparable to the characteristic ratio for global fallout (0.180). However, the 240Pu/239Pu atomic ratios in the initial soils from proglacial zone of glaciers change within wide range between 0.1281 and 0.234 with the mean value of 0.169. By combining alpha and mass spectrometry, the three-sources model was used to identify the Pu sources in initial soils. Our study indicated that the main source of Pu is nuclear tests and that a second source with lower Pu ratio may come from weapons grade Pu (unexploded weapons grade Pu ie. material from bomb which didn't undergo nuclear explosions for example for security tests). Additionally, we found samples with high 238Pu/239+240Pu activity ratios and with typical global fallout 240Pu/239Pu atomic ratios, which are associated with separate sources of pure 238Pu from the SNAP-9A satellite burn up in the atmosphere.