Background: Over 4 million people live within one mile of an unconventional oil and gas (UOG) well. Quantitative environmental monitoring data and models are needed to advance understanding of the complex inter-relationships between UOG activity, water and air quality, and human exposures.Methods: In a preliminary exposure study of 66 homes in Belmont County, Ohio, we measured the volatile organic compounds (VOCs) benzene, ethylbenzene, and toluene in air inside and outside homes with passive charcoal badges. We analyzed drinking water samples for 13 UOG-related VOCs, gasoline-range organics (GRO), and diesel-range organics. Using UOG well coordinates from the Ohio Department of Natural Resources, we calculated several metrics capturing residential proximity to multiple UOG wells.Results: Detection rates were low for the air samples; no associations between well proximity metrics and air VOC detection or concentrations were observed. Distance to nearest well was negatively correlated with drinking water concentrations of GRO, toluene, and certain disinfection byproducts linked with UOG wastewater.Research underway: To advance upon this work, we are formulating a model quantifying groundwater vulnerability to UOG contamination by augmenting proximity information with hydrological data. We are collecting water samples from hundreds of homes across Pennsylvania and Ohio and analyzing them for a range of inorganic and organic compounds using new analytical chemistry techniques to aid in source attribution.Conclusions: Low detection rates impeded air monitoring inferences; more sensitive techniques are needed at a greater number of homes. Our new water vulnerability model could be used to prioritize monitoring or assign exposures in epidemiologic studies. Our inter-disciplinary approach (hydrogeology, chemistry, exposure science) to UOG environmental monitoring has the potential to provide important insights into human exposure potential via the drinking water pathway.
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