Changes In Provenance Research Articles

On-land evidence for subduction of the proto−South China Sea beneath northern Borneo and tectonic reconstruction of Southeast Asia during the early Permian–Oligocene

The development of the Mesozoic proto−South China Sea was closely related to the tectonic evolution of the Tethys and Paleo-Pacific domains and may have been a key driving mechanism for the opening of the South China Sea. Despite its importance, direct geologic evidence for the proto−South China Sea remains limited, and its development is debated between two primary models: intra-oceanic subduction and oceanic-continental subduction. Here, we present petrographic, geochronologic, and geochemical data from tuffs and Eocene−Pliocene sedimentary records in Sabah, northern Borneo. The results reveal that these tuffs, formed ca. 28 Ma, possess geochemical characteristics indicative of oceanic arc origins. Combined with changes in sediment provenance since the Oligocene and various subduction timelines around Borneo, we suggest that these tuffs resulted from the subduction of the proto−South China Sea. This oceanic arc, along with Eocene mid-ocean-ridge−like mafic rocks in Sabah, indicates that a younger oceanic basin had formed within the proto−South China Sea. This aligns with observations in Palawan, Philippines, illustrating the transition from an oceanic spreading center to a subduction zone and indicating the proto−South China Sea extended from eastern Sabah to Palawan. In addition, inherited zircons (ca. 280 Ma) in the tuffs exhibit geochemical signatures typical of continental arcs. Combined with the Permian−Cretaceous arc-related igneous rocks in Southeast Asia, this suggests that southern Sabah was part of the Paleo-Tethys Ocean before integrating into the Paleo-Pacific domain since the Triassic. By shedding light on these processes, our research provides critical insights into the existence, extent, and evolution of the proto−South China Sea and reconstructs the multiphase transitions between different tectonic domains in Southeast Asia.

Cross-checking OSL ages from different grain sizes to improve chronological reliability in deltaic environments: an example from the Yangtze River Delta

The Yangtze River Delta has experienced intricate sedimentary and environmental changes throughout the Holocene, driven by the interplay of fluvial and marine forcings. This study presents quartz optically stimulated luminescence (OSL) ages and luminescence sensitivity data from a Holocene sediment core MQ, analyzed across four grain-size fractions, ranging from silt to sand. The results reveal substantial variability in OSL ages and sensitivity among grain sizes, with the medium-grain (45–63 μm) fraction yielding the most consistent and reliable results. In contrast, finer and coarser grains tend to overestimate ages due to incomplete bleaching, with the accurate dating of coarser grains requiring more aliquots or single-grain measurements. The variability in luminescence sensitivity reflects changes in sediment provenance and depositional conditions between estuarine and deltaic environments. OSL ages indicate that the sedimentary evolution of the Yangtze River Delta progressed through distinct phases: rapid accumulation during the early Holocene (10–7 ka) driven by rising sea level and valley infilling; reduced sedimentation during the middle Holocene (7–3 ka) related to a dry climate in the catchment; and accelerated deposition in the late Holocene (3 ka–present) associated with enhanced fluvial input linked to intensified human activities. This study highlights the importance of selecting suitable appropriate grain sizes and carefully comparing different fractions in OSL analysis to reconstruct deltaic chronologies accurately. The finding that the medium-grain fraction yields more reliable OSL ages than finer and coarser fractions should be tested in similar settings elsewhere. The results provide valuable insights for future research on complex depositional environments and contribute to a better understanding of long-term environmental changes.

Multiple episodes of late Neoproterozoic rifting in the Tarim Craton during its separation from the supercontinent Rodinia

In this paper, we review and evaluate the magmatic history, regional stratigraphy, structural patterns and sedimentary provenance features of the Late Neoproterozoic Tarim Craton to elucidate the nature and different modes of extensional tectonics during the Latest Neoproterozoic, a critical time coinciding with the disintegration of the supercontinent Rodinia. New detrital zircon U–Pb ages and geochemical data acquired from quartz schists and spatially associated granites in the Tugerming anticline along the northern margin of the Tarim Craton have revealed Cryogenian ages, as opposed to Early Neoproterozoic and older ages as reported in previous studies. Granitic intrusions are dated at 656–637 Ma, which involved remelting of the ancient crust following the decline of the initial (Cryogenian) rift stage. They are unconformably overlain by terrestrial clastic deposits. Based on the available detrital zircons from the Late Neoproterozoic sedimentary rock assemblages, we identify a major change in the provenance of the basinal strata at the end of the Cryogenian period. This inferred provenance change, associated with basement exhumation, overlaps in time with resumed magmatic activities, basin inversion and uplift along the northern margin of the craton. The initial, Cryogenian rifting stage was facilitated by pure shear deformation that produced rift basins in and across the Tarim Craton. The subsequent rifting stage was facilitated by simple shear deformation, confined to the northern edge of the craton as the break-up of the supercontinent Rodinia further progressed. Episodic rifting of the Tarim Craton and its separation from Rodinia were aided by thermal weakening of its lithosphere owing to the periodic impingement of mantle upwelling beneath it throughout the Cryogenian and Ediacaran periods.

Sea level and low-latitude climate control on sedimentary provenance and paleoenvironmental evolution in the central Okinawa Trough since 19 cal. ka BP

This study utilizes AMS 14C dating, grain size analysis, and elemental composition to ascertain the provenance of sediments in core C01, thereby offering insights into the paleoenvironmental evolution of the Okinawa Trough since 19 cal. ka BP. Between 19.0 and 11.3 cal. ka BP, the sediments were predominantly derived from the Changjiang River, a phenomenon attributed to the river's seaward expansion during periods of low sea level. During this interval, the Kuroshio Current (KC) exhibited relative stability. However, the rise in sea level from 11.3 to 7.3 cal. ka BP resulted in a shift in sediment sources, incorporating contributions from the Changjiang River and/or the continental shelf post-deglaciation to Taiwan, alongside a significant intensification of the KC. This increase in KC intensity is likely correlated with heightened summer insolation in the low latitudes of the Northern Hemisphere and an enhanced East Asian summer monsoon. Additionally, volcanic activity occurring at 7.3 cal. ka BP played a critical role in modifying sediment composition. By 7.3 cal. ka BP, sea levels approximated contemporary conditions, with terrestrial sediments primarily sourced from Taiwan. Around 4.9 cal. ka BP, a marked decrease in KC intensity was observed, potentially influenced by the strengthening of the El Niño-Southern Oscillation, which disrupts subtropical circulation in the North Pacific. The sedimentary records from core C01 illustrate that low-latitude Pacific climate variability since the last deglaciation has significantly impacted changes in sedimentary provenance and environmental conditions in the Okinawa Trough.

Rapid India–Asia Initial Collision Between 50 and 48 Ma Along the Western Margin of the Indian Plate: Detrital Zircon Provenance Evidence

Constraining the collision timing of India and Asia requires reliable information from the coeval geological record along the ~2400 km long collisional margin. This study provides insights into the India–Asia collision at the westernmost margin of the Indian Plate using combined U-Pb geochronological data and sandstone petrography. The study area is situated in the vicinity of Fort Munro, Pakistan, along the western margin of the Indian Plate, and consists of the Paleocene Dunghan Formation and Eocene Ghazij Formation. The U-Pb ages of detrital zircons from the Dunghan Formation are mainly clustered between ~453 and 1100 Ma with a second minor cluster between ~1600 and 2600 Ma. These ages suggest that the major source contributing to the Dunghan Formation was likely derived from basement rocks and the cover sequence exposed mainly in Tethyan Himalaya (TH), Lesser Himalaya (LH), and Higher Himalayan (HH). Petrographic results suggest that the quartz-rich samples from the Dunghan Formation are mineralogically mature and have likely experienced log-distance transportation, which is possible in the case of an already established and well-developed river system delivering the sediments from the Craton Interior provenance. Samples of the overlying Ghazij Formation show a major detrital zircon age clustered at ~272–600 Ma in the lower part of the formation, comparable to the TH. In the middle part, the major cluster is at ~400–1100 Ma, and a minor cluster at ~1600–2600 Ma similar to the age patterns of TH, LH, and HH. However, in the uppermost part of the Ghazij Formation, ages of <100 Ma are recorded along with 110–166 Ma, ~400–1100 Ma, and ~1600–2600 Ma clusters. The <100 Ma ages were mainly attributed to the northern source, which was the Kohistan-Ladakh arc (KLA). The ~110–166 Ma ages are possibly associated with the TH volcanic rocks, ophiolitic source, and Karakoram block (KB). The Paleozoic to Archean-aged zircons in the Ghazij Formation represent an Indian source. This contrasting provenance shift from India to Asia is also reflected in the sandstone petrography, where the sample KZ-09 is plotted in a dissected arc field. By combining the U-Pb ages of the detrital zircons with sandstone petrography, we attribute this provenance change to the Asia–India collision that caused the provenance shift from the southern (Indian Craton) provenance to the northern (KLA and KB) provenance. In view of the upper age limit of the Ghazij Formation, we suggest the onset of Asian–Indian collision along its western part occurred at ca. 50–48 Ma, which is younger than the collision ages reported from central and northwestern segments of the Indian plate margin with 70–59 Ma and 56 Ma, respectively.

Timing and evolution of structures within the southeastern Greater Caucasus and Kura Fold-Thrust Belt from multiproxy sediment provenance records

Abstract The Greater Caucasus (GC) mountains are the locus of post-Pliocene shortening within the northcentral Arabia-Eurasia collision. Although recent low-temperature thermochronology constrains the timing of orogen formation, the evolution of major structures remains enigmatic—particularly regarding the internal kinematics within this young orogen and the associated Kura Fold-Thrust Belt (KFTB), which flanks its southeastern margin. Here we use a multiproxy provenance analysis to investigate the tectonic history of both the southeastern GC and KFTB by presenting new data from a suite of sandstone samples from the KFTB, including sandstone petrography, whole-rock geochemistry, and detrital zircon (DZ) U-Pb geochronology. To define source terranes for these sediments, we integrate additional new whole-rock geochemical analyses with published DZ results and geological mapping. Our analysis reveals an apparent discrepancy in up-section changes in provenance from the different methods. Sandstone petrography and geochemistry both indicate a systematic up-section evolution from a volcanic and/or volcani-clastic source, presently exposed as a thin strip along the southeastern GC, to what appears similar to an interior GC source. Contrastingly, DZ geochronology suggests less up-section change. We interpret this apparent discrepancy to reflect the onset of sediment recycling within the KFTB, with the exhumation, weathering, and erosion of early thrust sheets in the KFTB resulting in the selective weathering of unstable mineral species that define the volcaniclastic source but left DZ signatures unmodified. Using the timing of sediment recycling and changes in grain size together as proxies for structural initiation of the central KFTB implies that the thrust belt initiated nearly synchronously along strike at ~2.0–2.2 Ma.

Mio-pliocene evolution of deep-water channels on the northeastern Bengal fan: Records of signals of Himalaya uplift and South Asian Monsoon from source areas

Submarine channels, acting as major conduits for delivering terrestrial sediments into the deep sea, are sensitive to source-region uplift and climate variations. Using new 3D seismic data, previously published paleoenvironmental data, and IODP/ODP data, we characterize stratigraphic time changes in deep-water channels on the northeastern Bengal Fan and suggest that their long-term evolution relates to contemporaneous changes of Himalaya uplift and South Asian Monsoon. Our results show that around the boundary between the Miocene and Pliocene Epochs, the sedimentary characteristics of deep-water channels were changing at about the same time as decreased rates of Himalaya uplift and changes in the monsoonal climate. It is strongly suggested that environmental signals could successfully propagate from the Himalaya to the deep sea and play a dominant control on the long-term evolution of deep-water channels. During the late Miocene, orogen-wide and substantial Himalaya uplift and humid monsoonal climates (dominance of summer monsoon) generated a sediment supply with high fluxes, which allowed coarser-grained sediments to reach further into the basin and thus caused the formation of larger-scale, non-leveed erosional channels that have avulsion and confluence phenomena. After the Miocene, local and limited Himalaya uplift and arid monsoonal climates (dominance of winter monsoon) led to a sediment supply with low fluxes, during which only finer-grained sediments reached deep water and gave rise to smaller-scale, leveed aggradational channels that mainly have splay deposits. Between the late-Miocene and post-Miocene periods, detrital zircon U-Pb ages of Bengal Fan samples from IODP cores reflect a sediment provenance change from the mixing of Brahmaputra and Ganges Rivers to the end-member of Brahmaputra River, broadly coeval with the variations of Himalaya uplift and South Asian Monsoon. Moreover, Bengal Fan cores record a Mio-Pliocene decrease in sedimentation rates and maximum grain sizes and an increase in mudstone contents, consistent with the variations of sediment yield in the source catchments. Observations and interpretations from the current study, therefore, contribute to a better understanding of how the long-term evolution of submarine channels respond to tectonic and climatic perturbations in source areas and may help recognizing similar process-response relationships in other areas.

Tectonic evolution of the Qiangtang Basin (northern Tibet): Constraints from detrital zircon geochronology

The Mesozoic evolution of the Qiangtang Basin in the Tibetan Plateau, which potentially hosts oil and gas resources, is not fully understood, particularly in the context of the opening and closure of the Tethyan oceans. To better understand the tectonic evolution of the Qiangtang Basin and the history of sedimentation, we obtained 788 new U-Pb detrital zircon ages from 12 sandstone samples. Our results show that the provenance of the Mesozoic strata varies both in space and time. In the central part of the basin (Central Qiangtang), older sedimentary rocks are characterized by unimodal age spectra (300–233 Ma) that indicate a proximal arc source. Trace-element compositions of Permian to Triassic zircons from Lower Triassic strata are characteristic of crystallization in arc and backarc environments, thus supporting previous suggestions that the Qiangtang Basin formed as a backarc basin during subduction of the Paleo-Tethys oceanic lithosphere. Younger (Upper Triassic and Jurassic) strata in the Qiangtang Basin received detrital zircons from diverse sources that included Cambrian to Triassic magmatic rocks and Paleozoic strata in the Central Qiangtang, and Triassic flysch deposits in the Songpan-Garze Terrane. We suggest that this change in provenance — from a unimodal arc source that produced zircons in Lower–Middle Triassic rocks to the diverse provenance recognized in the Upper Triassic strata — marks the closure of the Paleo-Tethys Ocean during the Late Triassic. Jurassic sedimentation in the Qiangtang Basin occurred during the expansion of the Meso-Tethys Ocean (Early–Middle Jurassic) and the subsequent subduction of this ocean (since the Callovian). During the Early Cretaceous, the closure of the Meso-Tethys Ocean led to an uplift and a sedimentary hiatus that marked the end of marine sedimentation in the Qiangtang Basin.

Quaternary provenance changes in the loess deposits of the western Chinese Loess Plateau: Insights from U-Pb age spectra of detrital zircon

The western region of the Chinese Loess Plateau (CLP) on the western side of the Liupan Mountains connects the Tibetan Plateau with the deserts of the northern arid zones. This region is key for understanding of the coupled relationship between tectonic uplift and surface processes (erosion and climate) on the Tibetan Plateau; however, the variation of Quaternary wind-dust sources in the region remains uncertain, confounding analysis. In this paper, we conduct a source tracing investigation using detrital zircon U-Pb dating of 12 loess layers from the Huining aeolian sedimentary sequence of the western CLP, reconstruct the history of provenance changes during the Quaternary Period, and further explore driving mechanisms. Results show that aeolian dust from the western CLP is mainly from the northeastern margin of the Tibetan Plateau (NTP). At 1.8–1.66 Ma, the main source region was the NTP, which corresponds to the Episode C uplift event of the Tibetan Plateau. The dominant source area transitioned to the Gobi Altay Mountains (GAMs) around 1.5–1.4 Ma. This shift suggests that the tectonic uplift of the Tibetan Plateau had entered a period of stasis following the conclusion of Episode C, leading to increased transport of detrital material from the GAMs by the East Asian Winter Monsoon. After 1.24 Ma, the dominant source region abruptly changed from the GAMs to the NTP and lasted until 0.04 Ma. The topographic fluctuations caused by the Kunhuang Movement appears to have been the main reason for the sudden source change. Based on our results and evidence from previous studies, the source changes that occurred during the Quaternary Period were in response to a combination of tectonic events and climate change. Comparison of zircon age spectra between the eastern and western CLP further support the idea that the Plateau Winter Monsoon was the main transport system for aeolian dust in the western CLP.

Geochemistry of Quaternary sediments in the northwestern South China Sea: Sediment provenance and mid-Pleistocene transition

The Quaternary sediments in the northwestern South China Sea (NW-SCS) provide valuable information about provenance, climate and sea level changes. However, the correlation between the geochemical records in marine sediments and these influencing factors remains less understood in the NW-SCS. Two wells penetrated Quaternary sediments on the shelf and shelf margin of the NW-SCS and provide an excellent dataset. In this study, the major, trace, and rare earth elements in the sediments were analyzed to reveal the Quaternary provenance changes that correlate with the climatic Middle Pleistocene transition (MPT). These results indicate that the core sediments were mainly derived from felsic source rocks and the degree of chemical weathering in the source areas is relatively low (CIA averaged at 58). The Quaternary provenance of the NW-SCS did not undergo significant changes, recording mixed sedimentation from the Red River, Hainan Island, and central Vietnamese sources. The felsic source rocks and negative Eu anomaly indicated the shelf area received sediments primarily from the Red River and Hainan Island. However, a positive Eu anomaly on the shelf margin suggests additional contributions from mafic rocks sourced from central Vietnam. During the MPT (1.3–1.4 to 0.8–0.9 Ma), the dominant periodicity of climate cycles changed from a 40 kyr obliquity cycle to a 100 kyr eccentricity cycle; the cooling climate led to a slight weaking in chemical weathering and a minor decrease in sediment supply from terrestrial sources. After the MPT, the mixed sourced sediments in the shelf and shelf margin areas of the NW-SCS likely suffered from multiple hydrodynamic forces under the influence of the Pleistocene high-frequency and high-amplitude sea level fluctuations. These climate induced changes led to significant fluctuations in element content that provide new insights into Quaternary sources and climatic events in the NW-SCS.

Provenance evolution of the Fushan Sag (Hainan Island, Southern China): Constraints from U-Pb geochronology on detrital zircons

The Fushan Sag, situated on the southeast of the Beibuwan Basin in the northern Hainan Island, represents a semi-graben fault sag, characterized by a near NEE trend. In this study, we conducted LA-ICP-MS U-Pb age dating on detrital zircon from both the Liushagang and Weizhou formations in the Fushan Sag. By integrating our findings with previous research and considering the geological characteristics and bedrock conditions of the surrounding areas, we aimed to ascertain the provenance of the Fushan Sag. The obtained detrital zircon ages (1059 with 80% concordance) can be primarily categorized into three distinct age groups: Mesozoic (90–250 Ma), Paleozoic (250–450 Ma), and Proterozoic (450–2500 Ma). Specifically, detrital zircon grains from the Weizhou Formation reveal three prominent age peaks, approximately falling within the ranges of 100–150 Ma, 250–300 Ma, and 400–450 Ma. Conversely, the detrital zircon grains extracted from the Liushagang Formation predominantly exhibit two age peaks, approximately spanning 100–150 Ma and 200–300 Ma, with a weaker peak observed at 350–450 Ma in the second member, implying a potential change in provenance during this period. A comparative analysis of detrital zircon age characteristics strongly suggests that the primary provenance of the study area is Hainan Island, with the possibility of contributions from the YunKai Massif. Base on the preliminary geochronological data gathered, and in conjunction with extant scholarly research, an inference can be formulated regarding the paleogeographic evolution of the Beibuwan Basin spanning from the Eocene to the Oligocene. This analysis offers insights into the basin's geological history and dynamic changes over this extensive time frame.

Evidence for, and significance of, the Neoproterozoic Xuefeng Orogeny, South China

The recognition of unconformities is important for determining the long-term evolution of orogenic belts. We document an unconformity between Tonian and Cryogenian strata of the Nanhua Basin of South China. This stratigraphic break has previously been termed the Xuefeng Movement and is developed within the Yangtze Block and western Cathaysia Block. Deformation characteristics and detrital zircon U-Pb geochronology from rock units underlying and overlying the unconformity (i.e., the Niuguping and Gucheng formations, respectively) from the Anhua region of the northern Hunan Province in the southeastern Yangtze Block are documented. The Niuguping Formation displays a set of top-to-northwest imbricate thrust faults and related fault-propagation folds, NEE-plunging subparallel crenulation lineations, a foliation, and shows widespread greenschist facies metamorphism. In contrast, the overlying Gucheng Formation exhibits no obvious stratal deformation (apart from a mild inclination of bedding) and is unmetamorphosed. Detrital zircon age spectra of the samples from the Niuguping Formation are characterized by unimodal age peaks of ca. 750–730 Ma, while those of the samples from the Gucheng Formation yield a multimodal age distribution, with a few syn-sedimentary detrital zircons (<700 Ma), and much older zircons with age peaks of ca. 800 Ma, 2.1–1.9 Ga, and 2.6–2.3 Ga. Combining this data with previous geochronology indicates deposition of the Niuguping and Gucheng formations in the late Tonian (725–720 Ma) and Cryogenian (690–660 Ma), respectively. The time gap across the unconformity is some 30 Ma (720–690 Ma). The unconformity and associated structural and metamorphic break extend across the Yangtze Block and western Cathaysia Block, defining a major regional orogenic event. The significantly different detrital zircon spectra of strata across the unconformity suggest a dramatic change in the source due to the Xuefeng Orogeny in the Yangtze Block. Zircon U-Pb-Hf isotopic evidence indicates that detritus of the Niuguping Formation below the unconformity was derived from syn-depositional magmatic activity in the northern Yangtze Block, while a significant increase of Archean to Paleoproterozoic ages for the Gucheng Formation, suggests that the Xuefeng Orogeny resulted in crustal thickening and denudation in the northern Yangtze Block. These changes in provenance, along with changing deformational and metamorphic patterns, indicate evolution of the Nanhua Basin from a compressional to an extensional back-arc basin, which we infer is related to tectonic switching from an advancing to a retreating subduction system in the northern Yangtze Block at the time of the unconformity.

Provenance changes of the holocene deposits of Oga and Tsivolki bays (Novaya Zemlya archipelago) according to SR, ND, PB isotope data

The paper is devoted to the Sr-, Nd-, Pb-isotope data obtained for two cores of bottom sediments taken in the Oga and Tsivolki bays of the Severny Island of the Novaya Zemlya archipelago. The studied sequence of sediments from Oga Bay has been accumulated over the last thousand years. The 87Sr/86Sr ratio decreases from top to bottom down the section from 0.72225 to 0.71995, the value of εNd varies from –6.1 to –5.5. The Pb isotopic composition varies within narrow limits: the 206Pb/204Pb ratio from 19.107 to 19.139, the 207Pb/204Pb ratio from 15.632 to 15.635, and the 208Pb/204Pb ratio from 38.568 to 38.635. A rapid decrease in the 87Sr/86Sr ratio at a relatively stable neodymium and lead isotope composition indicates a change in the source of the clastogenic material. This can be explained by the fact that the material of the destruction of Permian clay shales, and then the Devonian-Silurian sedimentary carbonates, first entered the area of glacier abrasion and further, respectively, into the sedimentation zone. The sediment column from the Tsivolki Bay was formed over a little more than 10 thousand years. Based on the Sr, Nd, and Pb isotope ratios, these bottom sediments are divided into lower and upper parts: before and after 150 cm (or ~3500 years). In the lower part of the column, the 87Sr/86Sr ratio increases from 0.72055 to 0.72580, the value of εNd remains approximately the same and varies around –8.2. In the upper part, the 87Sr/86Sr ratio drops to 0.72049 in the near-surface layer; at the same time, the value of εNd increases to –6.4. At the boundary of these two units, the 206Pb/204Pb ratio abruptly changes from about 18.0 in the lower part to 19.3 in the upper part and 208Pb/204Pb from about 36.5 in the lower part to 38.7 in the upper part of the section. The change in the Sr, Nd, and Pb isotope characteristics is likely a reflection of changes in the composition of the rocks in the area where the basin was removed, which is now being eroded by the glacier. Comparison with modern sources supplying clastic material to the Kara Sea showed that the material inputs the Oga and Tsivolki bays only from Novaya Zemlya.

Provenance response to evolving palaeogeography recorded by Carboniferous sandstones in the northern Pennine Basin, UK

On the basis of a combination of heavy mineral data, provenance-sensitive heavy mineral indices, garnet major element chemistry, rutile trace element chemistry and zircon U–Pb geochronology, six major changes in sandstone provenance during Carboniferous deposition in the northern Pennine Basin, UK, have been recognised. These changes are a manifestation of both tectonic and climatic factors. The earliest Tournaisian sediment was supplied from the local Southern Uplands High, but the increasingly humid climate led to the establishment of the Pennine River system, which introduced northerly-derived sediment from farther afield in the mid Tournaisian. This system was operative until the mid Bolsovian, but shows stratigraphic variations due to changes in input from different parts of the Pennine River hinterland (East Greenland, northern Scotland, western Norway). These variations are believed to be at least partly related to tectonism, since the maximum supply from high-grade metamorphic sources in East Greenland in the Namurian was concurrent with a tectonically-driven change in drainage direction in this part of the northern sourcelands. In addition, at the base of the Visean, there was a temporary influx of mature sediment coincident with a climatically-driven regression and, at the base of the Duckmantian, sediment was briefly introduced from the west as a far-field manifestation of Alleghanian tectonism. Finally, continued uplift of the Variscan mountain belt to the south of the UK led to establishment of northward-directed transport systems that reached the northern Pennine Basin in the mid-Bolsovian, leading totermination of supply from the Pennine River.

U-Pb detrital zircon age determination and provenance of the lower Karoo succession from the Karoo Research Initiative (KARIN) borehole KWV-1, Eastern Cape Province, South Africa

Abstract In recent years, the maximum age of sedimentation and possible sources of detritus to the sedimentary successions of the Karoo Supergroup has received a lot of interest, with various authors presenting age data from across the main Karoo Basin (MKB). Our paper aims to contribute to this ever-growing geochronological database as we report weighted mean ages for the youngest zircons as well as detrital zircon age distributions for the lower Karoo Supergroup succession sampled from the Centre of Excellence for Integrated Mineral and Energy Resource Analysis (CIMERA)-Karoo Research Initiative (KARIN) drill core KWV-1. A total of 880 near concordant zircon ages were determined using Laser Ablation Quadrupole Inductively Coupled Plasma Mass Spectrometry (LA-Q-ICP-MS) from fifteen samples representing the Dwyka Group, the Collingham-, Ripon-, Fort Brown- and Waterford formations of the Ecca Group and the Koonap Formation of the Beaufort Group as intersected by this ~2 352 m deep research borehole drilled in the southeastern sector of the basin. The weighted mean ages for the youngest zircons calculated for the formations of the Ecca- and Beaufort groups compares with findings reported by other authors and with the ages reported for tuffaceous layers associated with these units. The weighted mean ages for the youngest zircons of the Dwyka Group reflect the age of the youngest source area and do not aid in constraining the maximum age of deposition. A significant change in detrital zircon age distribution was noted between the Dwyka Group and the overlying formations of the Ecca and Beaufort groups, which we interpret as a change in provenance. The major Meso-to Neoproterozoic detrital zircon age fractions present in the Dwyka Group are attributed to source areas located towards the north and northeast of the MKB, in line with regional ice flow directions. A significant late Carboniferous to Permian detrital zircon age fraction is however observed throughout the formations of the Ecca- and Beaufort groups, with a lesser fraction of older zircon ages. The prevailing youngest age fraction reflects ages associated with magmatic source areas in the Gondwanide Orogeny located towards the south of the MKB at the time of deposition, while the recycling of deformed sedimentary strata of the Cape Supergroup contained in the Cape Fold Belt is considered the source of older detritus. The source of detritus to the MKB remained unchanged during the deposition of the respective formations of the Ecca- and Beaufort groups, despite changes in the depositional environment brough on by regional tectonics.

Low variability of authigenic 10Be/9Be across the Holocene Po plain parasequences reveals suitability of dating method for highstand deltaic deposits

The authigenic 10Be/9Be dating method presents a valuable tool for reconstructing depositional chronologies in sedimentary environments, requiring only ubiquitous mud for sampling. Nevertheless, studies elucidating the variability of the 10Be/9Be record preserved in epicontinental successions are lacking, despite the essential nature of such knowledge for the application of authigenic 10Be/9Be in geochronology. In this study, we investigate the variability of measured natural 10Be/9Be ratios in sediment cores recovered from the Holocene Po River delta plain in Northern Italy, aiming to unveil the influence of changing sedimentary environments and provenance on the beryllium isotopic signature. We identified significant variations in the authigenic 10Be/9Be ratios across parasequences, which correlates with a provenance change from the Eastern Alps to the Po River. The observed variation would cause an age offset of ∼1 Myr if unrecognized in a dated succession. Our analysis revealed consistent ratios between the delta plain (primarily represented by swamp) and delta front consisting of proximal prodelta facies, suggesting a prevalent riverine signature in the proximal prodelta, likely maintained by hyperpycnal flow deposition. Statistical assessments based on random sampling and bootstrapping highlighted the importance of a sample size of n > 10. Furthermore, a standard deviation of the observed variability indicates a necessity of an additional 9% uncertainty in authigenic 10Be/9Be dating studies if the sample size is smaller. Overall, our findings emphasize that the normal regressive highstand settings of a deltaic system maintain relatively stable beryllium isotopic fluxes, which are favourable for the authigenic 10Be/9Be dating application, if provenance changes are known.

Provenance history of the eastern Pearl River Mouth Basin: Implications for the evolution of the South China margin

Abstract The provenance history of the Pearl River Mouth Basin is of great significance for understanding how the South China margin evolved from a Mesozoic Andean-type subduction margin into the present-day rifted passive margin. However, the long-term provenance history of continental margin basins in the northern South China Sea is poorly understood. Newly identified Mesozoic–Cenozoic successions from the Lufeng Sag in the eastern Pearl River Mouth Basin provide valuable records of the provenance history and related evolution of the South China margin. Here, we trace the provenance of the eastern Pearl River Mouth Basin using U-Pb ages of zircon and ZTR values (proportions of zircon, tourmaline, and rutile in all transparent heavy minerals) of heavy minerals, and determine the tectonic setting and crustal thickness using trace element ratios and Eu anomalies in zircon. The results show that from the middle Eocene strata—which have a U-Pb age spectrum similar to strata of the Upper Cretaceous—to the Miocene strata, the proportion of Mesozoic age populations gradually increases, while the proportion of Paleozoic age populations decreases. In addition, following the middle Eocene high values, the ZTR values decreased during the late Eocene and then increased during the early Oligocene. Based on the variations in zircon age populations and ZTR values, the middle Eocene sediment is interpreted to have been recycled from Upper Cretaceous to middle Eocene successions, followed by an early Oligocene provenance change from intrabasinal to extrabasinal sources. Moreover, the zircon trace element ratios and Eu anomalies indicate that a widespread Mesozoic continental magmatic arc formed before ca. 90 Ma along the South China margin, and the crust simultaneously thickened during this time. In accordance with the provenance history, the evolution of the South China margin is divided into three tectonic phases: the Paleo-Pacific, Proto-South China Sea, and South China Sea. During the transition from the Paleo-Pacific to the Proto-South China Sea tectonic phase, sediment was recycled from Upper Cretaceous to middle Eocene successions in the eastern Pearl River Mouth Basin. During the transition from the Proto-South China Sea to the South China Sea tectonic phases, the provenance changed from intrabasinal to extrabasinal sources.

Provenance of the late Jurassic to Cenomanian sedimentary succession of the Araripe Basin (NE Brazil) and implication for the geodynamic evolution of Western Gondwana

The separation of Gondwana was controlled by preexisting Proterozoic structures and by the development of rift aborted basins, of which the Araripe Basin (NE Brazil) is one of the best examples. Previous studies have focused on the presence and provenance of Aptian–Albian shallow-marine incursions in the Araripe Basin but to date, little attention has been given to its paleodrainage evolution during sedimentation stages. Understanding the paleodrainage evolution is crucial for determining sediment sources and how topographic changes relate to the geodynamic development of the northern part of South America during the fragmentation of Gondwana, and this study investigates the provenance of Mesozoic rift and post-rift sedimentary rocks in the Araripe Basin using a multi-proxy dataset comprising major and trace element concentrations, Sm–Nd isotopic composition, and detrital zircon U–Pb ages. The low Eu/Eu* ratios (0.3–0.9) and high Th/Sc ratios (>0.64) in the most of analyzed samples suggest a felsic and silicic source. The εNd(0) values (−12.3 to −23.7) and TDM ages (1.68 to 2.55 Ga) of analyzed samples suggest overall ancient crustal sources. The presence of oval and elongated zircon grains suggests a major contribution of first-cycle transport sediments. The presence of 2.3–1.8 Ga and 0.63–0.58 Ga U–Pb zircon ages further indicates the dominant contribution of the Borborema Province influenced by the Brasiliano cycle (650–520 Ma). The low contribution of Tonian (∼940 Ma) zircons to the U–Pb zircon age distribution of the rift-beginning stage sample associated with published paleocurrent direction suggests sources located in the northern and northwestern terranes of the Borborema Province. The increase of Tonian (0.9–1.0 Ga) zircon grains during the rift stage suggests a provenance change with a dominant source in the eastern terranes during the rift stage. During the post-rift I stage, the decrease of 1.2–0.72 Ga zircon ages suggests a change in the source areas, with the paleodrainage coming from northern Borborema Province, similar to that of the rift-beginning stage. The samples of the post-rift II stage exhibit dominant contributions of Paleoproterozoic and Neoproterozoic U–Pb ages related to the Albian to Cenomanian uplift of the Borborema plateau during the opening of Equatorial Atlantic Ocean. Together with previous published studies, these findings highlight the significant role played by the post-rift continental uplift to the paleodrainage of the northern part of South America.

Sediment provenance analysis of the early Permian reservoirs of the Perth Basin

The sediment provenance of Early Permian reservoirs (‘Kingia’ and High Cliff sandstones) of the onshore North Perth Basin is poorly understood. Bulk rock inorganic geochemistry, detrital zircon geochronology and heavy mineral data have been used to assess spatial and temporal changes in provenance in the vicinity of the Waitsia, Lockyer Deep, West Erregulla and Beharra Springs Deep discoveries. The geochemical data provides a chemostratigraphic framework for the Early Permian that can be confidently correlated throughout the basin. The detrital zircon and Raman data have recognised significant regional variabilities. The zircon data defines western and eastern regions that were separated and/or infilled by different depositional systems, likely defined by the Mountain Bridge Fault. Raman analysis demonstrates that the High Cliff and ‘Kingia’ sediments in the vicinity of Waitsia have different zircon age populations and heavy mineral assemblages, with the ‘Kingia sandstone’ dominated by apatite indicating access to a granitic source at this time. This is poorly represented by wells in the northern Dongara Terrace and Allanooka Terrace, where sediments are dominated by garnet. Analysis of Lockyer Deep and West Erregulla discovery wells in the northern Dandaragan Trough, also demonstrate only minor amounts of apatite, but also include a significant mafic component, the source of which is uncertain. The geochemical data demonstrates that the top of these reservoirs is defined by a highly consistent change in provenance, coincident with a switch to garnet-rich sediments and different dominant zircon age populations.

Climates and sea-level controls on chemical weathering in the northern shelf of the Okhotsk Sea in the past 23 ka

The Okhotsk Sea, a subarctic marginal sea with a wide shelf and abundant weathering products, provides ample information about the chemical weathering in the geological past. However, insufficient investigation in the Okhotsk Sea, especially in its shelf, limits our knowledge of the intensity of chemical weathering in high-latitudes. In this study, high-resolution geochemical elements compositions of the core LV87-54-1 were measured to reveal the provenance change in the Northern Okhotsk Sea Shelf since the Last Glacial Maximum (LGM) and to discuss the influential factors of the deep-sea weathering records. The elemental ratios suggested that the sediment provenance remained stable during 23–11.4 ka, mainly transported from the Okhotsk-Chukotka volcanic belt; whereas the sediment input from the Kamchatka Peninsula to the study area has been enhanced since 11.4 ka. During 23–14 ka, the chemical index of alteration (CIA) was observed to align with climatic changes in the Northern Hemisphere. Synchronized climatic deterioration (i.e., cooling and drying) in the Northern Hemisphere mainly contributed to the reduced alteration of the sediments eroded from the Okhotsk-Chukotka volcanic belt. During 14–11.4 ka, the reworking of older weathered sediments caused by sea-level rise overwhelmed climates in controlling silicate weathering, resulting in an increased alteration of sediments. During the Holocene, the core sediment witnessed a lower weathering degree, compared to the LGM–Deglaciation. We attribute this to an increased sediment input from the Kamchatka Peninsula that supplied more weaker weathered sediments to the study area.