Proton Exchange Membrane Fuel Cell Cold Research Articles

Order reduction, simplification and parameters identification for cold start model of PEM fuel cell

The cold-start of proton exchange membrane fuel cell (PEMFC) has been one of the leading technical challenges for fuel cell vehicle commercialization. It is essential to understand the mechanism and process of a cold start to improve the cold start ability of the PEM fuel cell. In this study, a one-dimensional cold start transient model of PEMFC was developed for transfer species, heat, charge and water phase change during the cold start process. Based on the 1-D spatially distributed model, a reduced nonlinear cold-start model of the PEMFC is presented. Then the parameter identification is conducted to validate the model accuracy based on the experiment data. The identification result shows that the reduced model captures the detailed model's multiplicity behaviours, and good agreement is observed during cold start simulation with experiment results. In contrast, the computation time is reduced significantly. Thus, the proposed order reduction model can be used to investigate real-time estimation and develop model-based control strategies for automotive PEMFC cold start.

Strategy optimization of proton exchange membrane fuel cell cold start

<p indent="0mm">Under the background of “carbon peaking and carbon neutrality” goals, the proton exchange membrane fuel cell (PEMFC) vehicle attracts extensive attention due to its high energy conversion efficiency, long range and zero emission. However, the challenge of cold start in low temperature environments becomes a large obstacle to its commercialization and application. The current cold start performance of typical commercial fuel cell vehicles cannot reach the optimal target yet. Several problems such as the lack of complete mechanical systems of water transport and phase change and the absence of simulation models for on-board fuel cells at system level still exist. Thus, researchers have carried out a great number of experiments and simulations to study the mechanism of degradation, water transport, phase change and heat transfer as well as start-up strategy optimization of PEMFC cold start. By measuring the output performance, it is found that the degradation of performance is attributed to the formation of ice which covers the reaction active region, blocks the gas channel and increases the electrical contact resistance. Researchers also believe that the reduction of durability is owing to the volume change of water-ice phase change which leads to the damage of the structure by characterizing the microstructure of the fuel cell. With the help of transparent cells, neutron imaging and simulations of multiphase PEMFC models, the distribution, transport and phase change of water and ice during cold start have been studied. The results indicate that the electrochemical product water first saturates the PEM and the catalyst layer (CL) as membrane water. Then the water remains liquid in the form of supercooled water at low temperatures, and finally flows out of the cell or freezes suddenly. By studying the heat transfer process both in plane and through plane during cold start, researchers find that at central regions of the single cell and in the middle part of the stack, the temperature rises fastest. They also find that the irreversible reaction heat generated by cathodic oxygen reduction reaction (ORR) is the main source of heat generation. Based on the cold start mechanism of PEMFCs, researchers have developed various self-start and auxiliary start strategies. The start-up mode and control strategies have been optimized. The internal structure and materials of each part have been improved. And a series of auxiliary startup strategies such as gas purging, heater heating, reaction heating, gas heating as well as coolant heating have been proposed. A large number of simulations and experiments are carried out to verify the advantages of these strategies. Through these excellent cold start strategies, the commercialization and promotion process of PEMFC vehicles can be accelerated.

Study on the Degradation Mechanism of the Proton Exchange Membrane Fuel Cell Based on a Constant Voltage Cold Start Mode

Abstract The constant voltage cold start of the proton exchange membrane fuel cell (PEMFC) is usually operated at a low start-voltage in order to ensure high heat generation, which can shorten the process of the PEMFC cold start. However, the effect of constant voltage cold start on the durability of PEMFC is still unclear. Thus, in this work, the PEMFC is tested repeatedly at a low start-voltage to simulate its actual operating state in the vehicle. Then, the effect of the PEMFC durability under constant voltage cold start is investigated by polarization curve, cyclic voltammetry, electrochemical impedance spectroscopy, transmission electron microscope, and ion chromatography. After the repeatedly cold start, the output performance of the PEMFC decreases significantly. According to the characterization results, the degradation mechanism of the PEMFC at the constant voltage cold start is demonstrated to be that the PEMFC start-up repeatedly at low start-voltage leads to the decomposition of membrane polymer structure and promotes the crossover of H2. Meanwhile, the PEMFC start-up repeatedly at low start-voltage also leads to the agglomeration of catalysts, which reduces the active area of catalysts and ultimately results in the degradation of fuel cell performance. Above all, this study proves that the durability of PEMFC can be shortened by the constant voltage cold start at 0.1 V, which provides a reference for the development of the PEMFC cold start control strategy.

Enabling real-time optimization of dynamic processes of proton exchange membrane fuel cell: Data-driven approach with semi-recurrent sliding window method

The reliability of proton exchange membrane fuel cell (PEMFC) tightly depends on the suitable operating conditions during dynamic operations. This study proposes an optimization framework to determine the optimal control strategy for PEMFC cold starts underpinned by a novel artificial intelligence method, to improve cold-start capacity and shorten the start-up time. The effects of constant and dynamic currents on PEMFC cold starts under various initial temperatures are studied. The numerical results from a developed PEMFC dynamic model show that the constant current slope strategy (CCSS) is more efficient than the constant current strategy (CCS) in respect of the cold-start time. In the CCSS study, a too-large current slope can lead to a voltage undershoot and then cause a failed cold start, but a too-small current slope can result in a long start-up process in the investigated range of the operating conditions. A data-driven model is developed for dynamic prediction and real-time optimization during the cold start by a semi-recurrent sliding window (SW) method coupled with artificial neural networks (NN) with the simulation data. Based on this NN-SW model, the specific safety–critical operating condition curve under the CCSS has been identified. A real-time adaptive control strategy (RACS) is further proposed to optimize the operating current during the PEMFC cold starts with various initial temperatures. Compared to the optimal CCSS, RACS proves to be more robust and efficient for PEMFC cold-start startups. Based on RACS, the start-up time for an initial temperature of −20 °C can be cut down by 26.7%. Furthermore, the ice predictions by the NN-SW model are also tested and the results are satisfying with an average R2 = 0.9773.

Numerical study of subfreezing temperature cold start of proton exchange membrane fuel cells with zigzag-channeled flow field

An automotive proton exchange membrane fuel cell (PEMFC) engine needs to be capable of surviving from sub-freezing temperatures. Cold starting up a PEMFC engine presents great technical challenge due mainly to the intra-electrode ice formation that is closely related to the involved multi-physical transport. The flow field configuration to some extent dictates the reactants and product transport and is thus of important influence on PEMFC cold start performance. The present work carefully analyzes the cold start process of PEMFCs with zigzag-channeled flow field (ZZFF). A transient three-dimensional numerical model is established and experimentally validated first, and then we make comparisons of cold-start performance between zigzag and straight channel flow-field PEMFCs to reveal the effects of ZZFF. It is found that the ZZFF better distributes the reactants/product and current density in the PEMFC as it enhances the transport along the flow direction in-between the under-land and under-channel regions inside the cell. The process of cold starting the ZZFF PEMFC is found to generate slightly less heat, which is not good to cold start. Therefore, the ZZFF enhances the survivability of PEMFC engine cold starting from subfreezing temperatures, whereas it slightly degrades the quick self-startup ability of PEMFC engine. Case study with PEMFCs of more zigzagged flow fields further corroborates the effects of ZZFF configuration on PEMFC cold start performance.

An Online Self Cold Startup Methodology for PEM Fuel Cells in Vehicular Applications

This paper puts forward an adaptive cold start strategy for a proton exchange membrane fuel cell (PEMFC) based on maximum power mode. The proposed strategy consists of a water evacuation process after PEMFC shutdown and a self-heating process at PEMFC cold startup. To maximize the performance of the suggested strategy, an optimal operating condition for the cold start procedure is sought first. In this respect, an experimental parametric study is performed to explore the impact of fan velocity, micro-short circuit, anode pressure, and purge procedure on the PEMFC cold start performance. After laying down the proper conditions, the proposed cold start procedure is implemented on a test bench for experimental validations. The self-heating process is based on an online adaptive algorithm that maximizes the PEMFC's internal heat depending on its operating parameters’ variation. In fact, this algorithm attempts to keep the current density at high levels, leading to PEMFC's performance improvement achieved by membrane hydration and temperature increase. The experimental results confirm the effectiveness of the proposed strategy, which presents a fast and cost-effective PEMFC's cold start.

Numerical study of cold start performance of proton exchange membrane fuel cell with coolant circulation

It has been well recognized that cold start is one of the key issues of proton exchange membrane fuel cell (PEMFC) used as the engine of vehicles. Coolant circulation is usually launched synchronously with the fuel cell during cold start to avoid sudden large temperature variation, which greatly increases the cell thermal mass, lowers the heating rate, and worsens the cell performance. Considering the flow and heat transfer of coolant circulation, a three-dimensional, transient, multi-disciplinary model for cold start is built up. The numerical results agree reasonably well with experimental data, indicating that the model can be used for the investigation of PEMFC cold start processes. The analysis of circulation parameter effects shows that increasing the coolant flow rate or coolant tank capacity has little influence on the cell voltage, but will increase the non-uniformity of temperature distribution along flow direction. At lower start-up temperature, this non-uniformity is more obvious. With higher coolant flow rate, although the distribution of current density becomes more evenly, the ice formation amount increases and its distribution and location are greatly affected.

A Comprehensive Review of Solutions and Strategies for Cold Start of Automotive Proton Exchange Membrane Fuel Cells

Proton exchange membrane fuel cell (PEMFC) can be a significant eco-friendly alternative power source for vehicles. However, under subfreezing conditions, cell degradation and irreversible performance decay can occur because of ice formation and repetitive thaw/freeze cycles. These problems have limited the further commercialization of PEMFC in cold weather countries. Thus, many improvements have been made to repair the freeze protection and rapid cold startup problems in PEMFC vehicles. In this paper, a comprehensive review dedicated to engineers of the recent research progress on the PEMFC cold start problems is presented. Systems and methods for fuel cell shutdown are summarized and classified into two categories: purge solution and material to avoid freezing. Regarding the system and solutions for PEMFC cold startup, different heating solutions are classified into two main groups depending on their heating sources and categorized as internal and external heating methods. This paper concludes with a detailed review of cold startup strategies based on an exhaustive survey of journal papers and patents.