Strategy optimization of proton exchange membrane fuel cell cold start

Abstract

<p indent="0mm">Under the background of “carbon peaking and carbon neutrality” goals, the proton exchange membrane fuel cell (PEMFC) vehicle attracts extensive attention due to its high energy conversion efficiency, long range and zero emission. However, the challenge of cold start in low temperature environments becomes a large obstacle to its commercialization and application. The current cold start performance of typical commercial fuel cell vehicles cannot reach the optimal target yet. Several problems such as the lack of complete mechanical systems of water transport and phase change and the absence of simulation models for on-board fuel cells at system level still exist. Thus, researchers have carried out a great number of experiments and simulations to study the mechanism of degradation, water transport, phase change and heat transfer as well as start-up strategy optimization of PEMFC cold start. By measuring the output performance, it is found that the degradation of performance is attributed to the formation of ice which covers the reaction active region, blocks the gas channel and increases the electrical contact resistance. Researchers also believe that the reduction of durability is owing to the volume change of water-ice phase change which leads to the damage of the structure by characterizing the microstructure of the fuel cell. With the help of transparent cells, neutron imaging and simulations of multiphase PEMFC models, the distribution, transport and phase change of water and ice during cold start have been studied. The results indicate that the electrochemical product water first saturates the PEM and the catalyst layer (CL) as membrane water. Then the water remains liquid in the form of supercooled water at low temperatures, and finally flows out of the cell or freezes suddenly. By studying the heat transfer process both in plane and through plane during cold start, researchers find that at central regions of the single cell and in the middle part of the stack, the temperature rises fastest. They also find that the irreversible reaction heat generated by cathodic oxygen reduction reaction (ORR) is the main source of heat generation. Based on the cold start mechanism of PEMFCs, researchers have developed various self-start and auxiliary start strategies. The start-up mode and control strategies have been optimized. The internal structure and materials of each part have been improved. And a series of auxiliary startup strategies such as gas purging, heater heating, reaction heating, gas heating as well as coolant heating have been proposed. A large number of simulations and experiments are carried out to verify the advantages of these strategies. Through these excellent cold start strategies, the commercialization and promotion process of PEMFC vehicles can be accelerated.