In recent years, there has been significant interest in the development of self-compacting concrete (SCC). This study views SCC as a two-phase composite material and introduces a new aggregate spacing coefficient model based on the concept of Fullman’s mean free path and stereological theory. The validity of the aggregate spacing coefficient model was verified. The relationship between the fine and coarse aggregate coefficients and the properties of SCC are revealed. The results show that the slump and slump flow of SCC increase as the fine and coarse aggregate coefficients increase. The coarse aggregate spacing coefficient has a significant influence on the compressive strength and drying shrinkage of SCC. A significant linear relationship between the coarse aggregate spacing coefficient and SCC dry shrinkage properties is revealed. Compared to the conditional mixing proportion method, which considers the aggregate volume as a control factor, the aggregate spacing coefficient takes into account the aggregate volume and gradation, which can more accurately reflect the characteristics of the aggregate. Meanwhile, this new perspective on the macroscopic composition of SCC provides insights into the controlling factors of its performance.
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