Properties Of Hybrid Polymer Composites Research Articles

Preparation and characterization of functional material based on hybrid polymer composites

The microstructures and properties of hybrid polymer composites based on polyaniline (PANi)/γ-Fe2O3 nanoparticles/TiO2/carbon have been investigated for multifunctional applications such as heavy metal removal and initial study for radar absorbing material application. γ-Fe2O3 nanoparticles with spherical shape were synthetized by a coprecipitation method from iron sand. By activating the polyethylene glycol (PEG-400) coated carbon of coconut shell, the homogenous shape and size of carbon was achieved. Then, γ- Fe2O3, TiO2, and carbon were mixed with PANi by an in situ polymerization method at low temperature 0-5 oC. Characterization process involved XRD, SEM, FTIR, VSM, and DC conductivity measurements. For radar absorber application, the functionalized polymer composites showed good electrical conductivity 0.45 S/cm to absorb the incoming electromagnetic energy. An efficient and effective reduction of Pb2+ ion from the water has been achieved by using this material.

Analysis on the Durability of Hybrid Polymer Composites for Power FGD System

The corrosion condition of flue gas desulfurization (FGD) equipment for the coal-fired power plant was defined as the strong corrosion grade. The lining system of hybrid polymer composite was used in internal cylinder of steel chimney, and a corrosion-resistant and heat-resistant protective layer was formed on the metal surface. The corrosion-resistant and ageing-resistant properties of hybrid polymer composite prepared at low temperature after four years of practical use were investigated by differential scanning calorimeter (DSC), scanning electron microscopy (SEM) and measurement of gravimetric variation, contact angle, abrasion resistance, bonding strength and tensile strength. The properties of hybrid polymer composites prepared at 25℃ and –15℃ were comparatively analyzed in the paper.

Preparation, Structure, and Properties of Hybrid Polymer Composites Containing Silver Clusters and Nanoparticles

The major methods for the preparation of silver-containing polymer composite nanosystems and the formation of their hybrid structure are examined. Special attention is focused on a new class of silver-containing hybrid systems, namely, organic–inorganic coordination polymers, obtained by the self-assembly of silver complexes. The effect of intercomponent interaction on the structure and properties of these hybrid composites was examined.

AC-impedance and dielectric properties of hybrid polymer composites

The AC-impedance and dielectric properties of hybrid polymer composites made up of epoxy (diglycidyl ether of bisphenol-A) matrix filled with various zinc oxide concentrations (0, 4.9, 9.9, 14.9 and 19.9 wt%) and reinforced with conductive carbon black nanoparticles (0.1 wt%) have been investigated as a function of fillers concentrations, applied frequency in the range from 20 kHz to1 MHz and temperature in the range from 30℃ to 110℃. The observed data were analyzed using the dielectric permittivity and electric modulus formalisms (i.e. the inverse quantity of complex permittivity). The dielectric constant of the composites increases with increasing temperature and filler concentrations, and this case can be explained by hopping and tunneling processes. The AC-conductivity is apparently enhanced with increasing frequency, temperature, zinc oxide and carbon black fillers. The observed increase in the AC conductivity was explained based on the concept of conductive paths and connections between the zinc oxide–particles and the conductive carbon black–nanoparticles. The activation energy has been estimated from fitting the AC conductivity–temperature data and it was found that it is decreased by the addition of the zinc oxide content in the epoxy matrix reinforced with carbon black, which means that the composites have better electrical conduction. The scanning electron microscopy images revealed that the dispersed zinc oxide-particles and carbon black-nanoparticles were randomly distributed within the epoxy matrix with some paths and surface contacts between the fillings. It was found that the addition of carbon black nanoparticles to epoxy/zinc oxide composites enhances the electrical conduction due to the electronic and impurity contributions.