Dilational Properties Research Articles

Methodological approach to characterize the interfacial and foaming properties of carbonated beverages

The adjustment and control of specific product characteristics, e.g., foaming behavior of carbonated beverages, requires an understanding of influencing factors along with reliable analytical methods. However, due to the overlay of different phenomena, i.e., release of CO2 and action of surface-active molecules contained in such beverages, it is difficult to assess their respective contribution to foam appearance and stability. This study aimed at evaluating a new methodological approach to investigate the interfacial and foaming properties of carbonated beverages. Using beer as an example, it was attempted to establish a correlation between interfacial properties and foaming behavior. To ensure a comprehensive dataset, surface tension, interfacial dilatational rheology, and foaming properties including foam structural characteristics of six different German beers of three different types (i.e., Pils, wheat beer and Koelsch), which are known to exhibit distinct foaming behavior, were measured. While foams prepared with CO2 as sparging gas did not show any differences in foam aging, use of air for foaming enabled differentiation based on beer type. Differences observed in foam structural characteristics and stability could not be related to dynamic surface tension but might be linked to interfacial dilatational properties. Overall, the presented multiscale approach can be seen as promising concept for further experimental studies on carbonated beverages.

In Silico Evaluation and Experimental Validation of Interfacial Properties in 3-5 Residue Peptides.

Predicting the interfacial properties of peptides is important for replacing oil-derived surfactants in cosmetics, oil, and agricultural applications. This work validated experimentally the estimations of surface tension at the critical micelle concentration (STCMC) of six peptides performed through a random forest (RF) model in a previous contribution. In silico interfacial tensions of the peptides were obtained in the system decane-water, and dilational experiments were applied to elucidate the foaming potential. The RF model accurately classified the peptides into high and low potential to reduce the STCMC. The simulations at the decane-water interface correctly identified peptides with high, intermediate, and low interfacial properties, and the dilational rheology allowed the estimation of the possible potential of three peptides to produce foams. This study sets the basis for identifying surface-active peptides, but future work is necessary to improve the estimations and the correlation between dilational properties and foam stabilization.

Dilational rheological properties of extended anionic surfactants at decane-water interface

The dynamic interfacial dilational properties of extended surfactants octadecyl-(polypropylene oxide)m-(polyethylene oxide)n-carboxylic sodium (C18POmEOnC) with different numbers of polypropylene oxide (PO) and polyethylene oxide (EO) groups at the decane–water interface were investigated by means of oscillating drop method. The influences of interface ageing time, dilational frequency, bulk concentration and interfacial pressure on the dilational properties were investigated. The experimental results demonstrate that, at low concentrations, the adsorption film is predominantly influenced by diffusion exchange, while intermolecular interactions at the interface play a more significant role at high concentrations. Beyond the critical micelle concentration (CMC), the primary relaxation process in the adsorption film is driven by the formation of micellar structures. Additionally, the weak hydrophobic PO groups exhibit compressibility and extensibility, facilitating the formation of spring-like helical structures at the decane–water interface. As a result, the dilational modulus increases and the phase angle decreases in low concentration with the increase of PO number. With increasing concentration, the weak hydrophilic EO chains gradually transition from a partially flat state to an upright orientation toward the aqueous phase, forming sublayer structures through polar interactions. At this stage, the increase in EO group chain length has a more pronounced impact on the elastic modulus compared to PO groups. These experimental findings suggest the existence of a mechanistic model for the extended surfactant adsorption films.

Experimental study and model evaluation on BFRP tube-confined RAC cylinders under monotonic axial compression

Using concrete waste as recycled aggregate (RA) in engineering structures can generate great ecological and economic benefits. To enhance the compressive properties of RA concrete (RAC), basalt fiber reinforced polymer (BFRP) tubes were used to provide lateral confinement in this study. Monotonic axial compressive tests were carried out on BFRP tube-confined RAC using 36 cylindrical specimens. Detailed test results were presented, including the failure mode, stress-strain curve, compressive strength, axial strain, and dilation property. The influences of the RA replacement ratio and the number of BFRP layers were analyzed. The test results indicated that BFRP tube-confined specimens exhibited strain hardening behavior in all of their stress-strain curves even if only a single layer of BFRP was used, and the failure was due to BFRP rupture along the hoop direction. The ultimate strength and deformability of RAC were significantly enhanced using BFRP confinement, with the confinement effect becoming more pronounced with increasing RA replacement ratios and BFRP layers. Compared to the unconfined specimens, the maximum enhancements in the ultimate strength and axial strain reached 2.8 times and 18.1 times, respectively, after BFRP confinement. Three typical theoretical models of FRP-confined concrete were employed to predict the ultimate conditions and axial stress-strain curves of the specimens. Finally, an improved model was formulated based on the test data to predict the ultimate conditions of BFRP tube-confined RAC cylinders. The proposed model was proven to predict the axial stress-strain curves, ultimate strength, ultimate axial strain with reasonable accuracy.

Enhanced rare earth element recovery with cross-linked glutaraldehyde-lanthanide binding peptides in foam-based separations

HypothesisLanthanide Binding Tag (LBT) peptides that coordinate selectively with lanthanide ions can be used to replace the energy intensive processes used for the separation of rare earth elements (REEs). These surface-active biomolecules, once selectively complexed with the trivalent REE cations, can adsorb to air/aqueous interfaces of bubbles for foam-based REEs recovery. Glutaraldehyde, an organic compound that is a homobifunctional crosslinker for proteins and peptides, can be used to enhance the adsorption and interfacial stabilization of lanthanide-bound peptides films. ExperimentsThe stability of the interfacial cross-linked films was tested by measuring their dilational and shear surface rheological properties. Surface activity of the adsorbed species was analyzed using pendant drop tensiometry, while surface density and molecular arrangement were determined using x-ray reflectivity and x-ray fluorescence near total reflection. FindingsGlutaraldehyde cross-linked REE-peptide complexes enhance the adsorption of lanthanides to air-water interfaces, resulting in thicker interfacial structures. Subsequently, these thicker layers enhance the dilational and shear interfacial rheological properties. The interfacial film stabilization and REEs extraction promoted by the cross-linker presented in this work provides an approach to integrate glutaraldehyde as a substitute of common foam stabilizers such as polymers, surfactants, and particles to optimize the recovery of REEs when using biomolecules as extractants.

Durability performance of BFRP-confined coal gangue concrete exposed to the sulfate-rich mine environment

The combination of basalt fiber reinforced polymer (BFRP) confinement and coal gangue concrete (CGC) is an economical and innovative approach for serving as a supporting structure in the underground mine. Nevertheless, the sulfate-rich mine water and mist exist in the mine environment, which may cause the performance deterioration of structures. Thus, the long-term behavior of BFRP-confined CGC in the sulfate-rich environment was systematically explored, based on the sulfate durability investigation of BFRP sheets and CGC. The tensile test of BFRP sheets and the compressive test of CGC were first carried out to evaluate their deterioration laws and mechanism in different sulfate environment. More importantly, axial compression test of FRP-confined concrete cylindrical specimens after sulfate attack were conducted, considering the effect of inner concrete, FRP layer, sulfate concentration and corrosion time on the stress-strain response and dilation properties. The results indicate that the tensile strength of BFRP sheet declined to a small extent with the extension of sulfate corrosion due to the degradation of epoxy resin and matrix-fiber interface. Additionally, the compressive strength of CGC exhibits a first increase and then decrease trend as the secondary hydration occurs and the sulfate ions react with the hydrated production to form expansive gypsum and ettringite crystals. The strength and ductility of CGC were improved by FRP confinement regardless of sulfate attack or not, whereas sulfate corrosion degraded the improvement ratio, especially the deformation capacity. Most importantly, the sulfate degradation coefficients were introduced into ultimate strength and strain models for sulfate-attacked BFRP-confined CGC, providing a basis for its design and life cycle assessment in the underground mine.

Analysis-oriented stress-strain model for concrete in steel tubed geopolymer concrete (STGC) columns

To alleviate the brittleness of geopolymer concrete and further promote its engineering application for environmental benefits, a novel type of column, i.e., steel tubed geopolymer concrete (STGC) column, has been proposed recently. Note that an accurate axial stress-strain model is necessary for a comprehensive understanding of the compressive behavior of STGC columns. However, the existing analysis-oriented models are all developed for the conventional concrete-filled steel tube (CFST) columns, and the confinement mechanism of steel tubed concrete columns is significantly different from that of concrete-filled steel tube columns since the axial deformation of steel tube and core concrete is not synchronized for steel tubed concrete columns during the loading process due to the discontinuous steel tube. Furthermore, the dilation properties of STGC columns at the initial loading are significantly overestimated by the existing lateral-axial strain models. Besides, steel-confined geopolymer concrete (GPC) experiences a more remarkable softening behavior resulting from the more significant brittleness of GPC than that of ordinary concrete. Thus, the deformation models are proposed in this study and the active-confinement base model is also developed for GPC based on the mechanical characteristics of STGC columns under axial compression. Then a new analysis-oriented model is proposed for steel tubed geopolymer concrete. Comparisons between the theoretical calculations and the test results indicate that the proposed model can provide reasonable predictions for both steel stress evolution and the stress-strain relationship of STGC.

Electro-fluid-dynamics (EFD) of soft-bodied organisms swimming through mucus having dilatant, viscous, and pseudo-plastic properties

The sperm propelling mechanism has been proposed as a possible resource for soft micro-robots in confined spaces, with potential applications in biomedical engineering. Human sperm cells essentially swim through the non-Newtonian liquid (cervical mucus) to reach their target. Thus, sperm cells swimming through non-Newtonian fluids is not vital only for physiology, but also for the fabrication of swimming micro-robots. Inspired by these remarkable applications, we examine the basic mechanics of spermatozoa motility using an undulating sheet model. This undulating sheet is bounded between two rigid walls which is self-propeling in the negative axial direction. The liquid around the spermatozoa is taken as Carreau fluid with electro-osmotic properties. The application of the lubrication approximation results in the reduction of momentum equations. The resulting ODE is solved numerically via the finite difference method and MATLAB’s built-in routine bvp5c. The unknowns that are present in the boundary conditions are refined by the root-finding algorithm. Power losses, cell speed, flow rate, velocity of the fluid, and streamline pattern are visualized by graphs. The findings of this study have important implications for the designing and optimization of electrically controlled microswimmers.

Dilatational and Shear Interfacial Properties of Pea Protein Isolate Systems with Transglutaminase at the Air–Water Interface

Dilatational and Shear Interfacial Properties of Pea Protein Isolate Systems with Transglutaminase at the Air–Water Interface

Effect of aggregate sizes on dilation properties and stress−strain behavior of FRP-confined recycled aggregate concrete

Aggregate size plays a crucial role in determining the mesoscale uniformity and compactness of concrete, directly influencing its dilation characteristics. This dilation behavior, especially under axial load, has significant implications for the tri-axial stress conditions when the concrete undergoes passive confinement using Fiber-Reinforced Polymer (FRP). This study focuses on comprehensively investigating the stress−strain behavior and dilation properties of FRP-confined recycled aggregate concrete (RAC), with a specific emphasis on the effects of recycled aggregate (RA) sizes. A series of compression tests were conducted to examine the stress−strain response of FRP-confined RAC, shedding light on how the dilation properties are influenced by varying RA sizes. The results revealed notable differences in the physical properties (crushing index and water absorption ratio) of RA compared to natural aggregates, with these differences significantly impacting the unconfined concrete strength. Although, an increase in aggregate size demonstrated an improvement in FRP confinement efficiency, it did not bring about a change in the ultimate strength of FRP-confined concrete due to the interaction between the weakening of unconfined concrete strength and the increase in confinement efficiency. In addtion, the transition stress on the stress−strain curve proved highly dependent on both aggregate size and FRP confinement efficiency to RAC. Consequently, a new modified transition stress model, accounting for the effect of aggregate size and FRP confinement, was introduced. Incorporating this newly proposed transition stress model into the existing stress−strain expression yielded predicted stress−strain curves that closely matched the experimental results for FRP-confined RAC with varying RA sizes.

A simple gradation-state-dependent model for granular materials

This paper proposes a gradation-state-dependent constitutive model to capture the granular materials' mechanical behaviours considering the granular crushing's influence. Firstly, a gradation evolution law is developed to reflect the change in grain size distribution (GSD) with the growth of stress levels, and then, based on the evolution law, the elastic compliance matrix is modified to reflect the effects of particle breakage. Secondly, as the critical state line (CSL) exhibits gradation dependence, a novel method is developed to describe the family of CSLs under different fixed gradations. Subsequently, by combining the gradation evolution law with the CSL equation, the paper explains the steepening of the slope of the critical state line when the crushing is activated. With the improvement of CSL, the material's shear dilatancy and contraction properties are better reflected, assisting in establishing a plastic compliance matrix. Employing the derived elastic and plastic compliance matrix, the elastic–plastic model reflecting the influence of gradation and state effects is established and verified with a series of experimental and discrete element method (DEM) simulation results.

The effect of aromatic side chains on the dilational rheological properties of N-acyltaurate amphiphiles at water-decane interfaces.

To elucidate the effect of aromatic side chains on dilational rheological properties of N-acyltaurate amphiphiles at the decane-water interface, the interfacial rheological properties of sodium N-2-(2-naphthoxy)-tetradecanoyltaurinate (12+N-T) and sodium N-2-(p-butylphenoxy)-tetradecanoyltaurinate (12+4B-T) were investigated utilizing the drop shape analysis method. The effects of adsorption time, interfacial pressure, oscillating frequency, and bulk concentration on the interfacial dilational modulus and phase angle were explored. The results show that the 12+4B-T molecule with a longer hydrophobic chain shows a higher ability for reducing the interfacial tension (IFT). In addition, the interfacial films of both 12+N-T and 12+4B-T are dominated by diffusion exchange at high concentrations. The rigidity of molecules controls the diffusion exchange at low concentrations, while the molecular hydrodynamic radius determines the diffusion exchange at high concentrations. Thus, at low concentrations, the stronger intermolecular interaction between 12+4B-T molecules results in higher dilational modulus values than 12+N-T. When approaching the CMC (critical micelle concentration) value, the rapid diffusion exchange of 12+4B-T between the sublayer micelles and the interface causes a significant decrease in the dilational modulus, while the relatively rigid structure of 12+N-T enables a higher dilational modulus than 12+4B-T. What's more, the longer hydrophobic chain allows 12+4B-T molecules to escape from the interface more easily, resulting in a higher phase angle at low concentrations. However, the diffusion exchange of 12+4B-T is slower than that of 12+N-T, which results in lower phase angles for 12+4B-T than 12+N-T at high concentrations. In general, the introduction of a rigid naphthalene ring in the molecular structure gives the interfacial film greater strength at high concentration. The research results in this paper provide a new technique for the strength regulation of interfacial surfactant adsorption films.

Modulation of Lipid Digestion by Nanoarchitectonics of Complex Interfacial Structures with Tween 80 and Lecithin.

In recent years, there has been a growing interest in regulating lipid digestion through the construction of various interfacial structures. In the present work, a series of complex interfacial structures were designed by combining Tween 80 in the aqueous phase and lecithin in the oil phase at different concentration ratios. The emulsification properties, the roles in regulating lipid digestion, and the interfacial dilatational rheological properties of the composite emulsifying systems were characterized. The results showed that the combination of Tween 80 and lecithin at different ratios could effectively modulate the rate of lipid digestion. The polyoxyethylene chains of Tween 80 formed a network, that provided a spatial obstacle for the adsorption of bile salts and lipases. Thus, Tween 80 significantly delayed the lipid digestion. The introduction of lecithin gradually replaced Tween 80 molecules at the interface, thus providing space for the adsorption of bile salts and lipases. In addition, as the ratio of lecithin concentration to Tween 80 increased, lecithin gradually became the dominant factor in the interfacial properties. As a result, the rate of lipid digestion was accelerated. Therefore, by compounding different ratios of lecithin and Tween 80, a series of emulsions with different lipid digestion rates were obtained. This research provides a basis for rationally designing food emulsions according to specific needs.

G-frame generator sets for projective unitary representations

<abstract><p>Frames with special structures play a crucial role in various industrial applications, such as medical imaging, quantum communication, recognition and identification software, and so on. In this paper, we will discuss a more general setting, i.e., a g-frame induced by the projective unitary representation. We show some new results on the dilation property for g-frame generator sets for unitary groups and projective unitary representations. In particular, by using complete wandering operators, several properties of g-frame generators for projective unitary representations have been obtained. Moreover, we explore some characterizations of the g-frame generator dual pairs.</p></abstract>

Theoretical model for spontaneous combustion gangue coarse aggregate concrete filled steel tube stub columns

Spontaneous combustion gangue coarse aggregate concrete filled steel tube (SCGCA-CFST) provides a possibility for the structural application of spontaneous combustion gangue coarse aggregate (SCGCA) concrete. To establish an accurate stress-strain model for SCGCA-CFST, 12 SCGCA-CFST specimens and 18 SCGCA concrete specimens were tested under monotonic axial compression with steel tube thickness and SCGCA replacement ratio (0%, 50%, 100%) as variables. The experimental results demonstrated that as the SCGCA replacement ratio increased, the elastic modulus of SCGCA concrete decreased by 6.65%–11.65%, the cylinder compressive strength decreased by 11%–21.95%, and the axial strain at peak axial stress increased by 7.1%–14.27%. Furthermore, the crack extension forms and dilation properties of the core concrete in SCGCA-CFST differed significantly from those of normal coarse aggregate concrete filled steel tube (NCA-CFST). The incorporation of SCGCA reduces the effectiveness of steel tube confinement, which causes the existing stress-strain models of NCA-CFST overestimate the enhancement effect of steel tube confinement on the strength and deformability of core SCGCA concrete. Based on this, the analysis-oriented stress-strain model for NCA-CFST was modified to be applicable for SCGCA-CFST by incorporating the influence of aggregate characteristics, and the accuracy of that was verified.

Effects of molecular weight of polyethylene glycol with size and ratio of fumed silica on rheological behavior of shear thickening fluid

The rheological models of shear thickening fluids (STFs), which have recently been used in many fields, are estimated using a statistical method in this study. Although research has been carried out to predict the rheological properties of STFs, the variation of the basic parameters affecting the rheological properties has not been studied much in these estimations. To produce shear thickening fluids, silica nanoparticles have been dispersed in polyethylene glycol (PEG). To make the rheological model estimation correctly, nanoparticle ratios (10 wt%, 15 wt%, 20 wt%, 25 wt%), the particle sizes (9 nm, 12 nm, and 14 nm), and the molecular weight of the liquid mediums are produced by changing three different sample set is used. At high shear rates, mixtures of fumed silica (aerosil) and PEG display shear thickening behavior. In the low shear rates (0-200 s-1), this mixture exhibits shear thinning property, while in the high shear rates (200-1000 s-1), shear thickening behavior. Fumed silica-PEG suspensions show pseudoplastic behavior in the first region and dilatant properties in the second region. Equations from theory are used to model the outcomes of the experimental data. Non-Newtonian models are used, and the best model is chosen based on the rheological behavior of the mixes. Herschel-Bulkley is discovered to be the most suitable non-Newtonian model in the first and second regions.

Dilations and information flow axioms in categorical probability

AbstractWe study the positivity and causality axioms for Markov categories as properties of dilations and information flow and also develop variations thereof for arbitrary semicartesian monoidal categories. These help us show that being a positive Markov category is merely an additional property of a symmetric monoidal category (rather than extra structure). We also characterize the positivity of representable Markov categories and prove that causality implies positivity, but not conversely. Finally, we note that positivity fails for quasi-Borel spaces and interpret this failure as a privacy property of probabilistic name generation.

Discrete Element Simple Shear Test Considering Particle Shape

The particle shape has significant effects on the slip and rotation of particles in the shear of geomaterials, which is an important factor in the deformation and strength of geomaterials. This paper employed particle flow code (PFC3D) to simulate the simple shear test, and ellipsoidal particles with different aspect ratios were prepared to study the effects of particle shape on the mechanical behavior and fabric evolution of granular materials under complex stress paths. The numerical results show that the particle shape has a significant effect on the peak strength, dilatancy, non-coaxiality, and other mechanical properties of granular materials. The contact fabric evolves from orthotropy to transverse isotropy under the principal stress axes rotation. This paper will provide a reference for natural granular materials with different shapes in the study of mechanical behavior and the micro-constitutive model.

A Circular Approach to Finished Tanned Leather: Regeneration by Cryogenic Technology.

Finished tanned leather is usually covered by a thin polymeric layer. This layer has the scope to change the morphological aspect of the last leather layer as well as improve the impermeabilization properties. Often, the finished product is refused by the final client, and tanneries must restore significant quantities of materials. Therefore, it is very important to remove this finished polymeric layer, recover the underneath tanned leather, and predispose it to a new finishing. The bonding between the polymeric film and leather is so strong that, today, only a blade shaving process can perform this separation at the expense of also removing a layer of tanned leather and consequently reducing the leather thickness. Here, a novel separation method was developed based on the significant difference in the dilation properties between the tanned hide and the polymeric film at low temperatures. The use of cryogenic fluids, in particular the direct application of liquid nitrogen, can freeze the polymeric layer below the glass transition temperature, inducing brittle behavior. The result is an easy separation without any alteration of the tanned leather layer; for a demonstration of that, some techniques were used, such as FTIR, SEM, Tensile strength evaluation, DSC, and TGA. By this last analysis, it is possible to check how a decrease of weight to 90% happened for the polymeric layer at about 400 °C against the complete blank at about 600 °C. A similar great distance of results exists in the case of tensile strength, where an average value of 34.5% is the deformation stress for blank samples, against 34.8% for processed samples. Thus, the process here developed allows the reuse of the tanned leather towards a new life in respect of the principles of the circular economy.

Interfacial moduli at large strains and stability of emulsions stabilised by plant proteins at high bulk shear rates

For several commercial plant-protein stabilisers, we investigated how surface shear and dilatational properties affect dynamic emulsion stability under high bulk shear conditions. Potato protein isolates Potato-1 (rich in patatin) and Potato-2 (rich in protease inhibitors) showed a stiffer, more solid-like response than soy and pea protein isolates in large amplitude oscillatory surface shear. Soy protein isolates had the weakest interfaces and showed a more liquid-like behaviour. Potato-2 had the highest stiffness and most brittle interface in large amplitude oscillatory dilatational deformations. It also showed more significant softening, evident from both the shear and dilatational Lissajous plots. Only the Potato-1-stabilised emulsion was stable against coalescence at high bulk shear (although that emulsion was unstable against flocculation because of its low zeta potential). The low stiffness imparted to the interface by the pea and soy protein isolates was not suitable for preparing emulsions with high dynamic stability. In the linear regime, both Potato-1 and Potato-2 produced interfaces with similar surface shear moduli, and in dilatation, Potato-2 gave a higher modulus. The lower stability of the Potato-2 emulsions appears to be linked to the higher brittleness and stronger softening effect for increasing deformation amplitude. Both in surface shear and dilatation, the maximum linear strain for the Potato-1-stabilised interface is larger. The lower maximum linear strain and stronger softening effect at high deformations for Potato-2 may have resulted in more disruption of the interfacial microstructure, and this induced (partial) coalescence.