Dependence Properties Research Articles

Enhancement of atmospheric nucleation precursors on formic sulfuric anhydride induced nucleation: Theoretical mechanism

As an intermediate formed by H2SO4 (SA), formic sulfate anhydride (FSA) has been hypothesized to play a role in the nucleation of atmospheric aerosols. It is the first time that the clusters (SA)x(A)y(W)n and (FSA)x(A)y(W)n (x = 1–2; y = 1–2; n = 0–4) were systematically studied in theory on the structures, thermodynamics, intermolecular interactions, humidity dependence, atmospheric dependence and optical properties. FSA is predicted to be more stronger to promote the clustering with ammonia (A) than SA, suggesting that substituent group enhances nucleation capability of FSA. Whereas, the substituent group does not influence the humidity sensitivity of hydrated clusters. The clusters trend to form small hydrated clusters (nwater≦3). The study on atmospheric dependence indicates that the stability of the clusters depends more on temperature other than pressure. Moreover, FSA shows a stronger ability on reducing atmospheric visibility than A, SA and water molecules. This finding aims to draw attention to FSA about atmospheric nucleation.

Development of Flexible Hydrophobic Polypropylene/SPCB/GNP Hybrid Nanocomposite Films With Excellent EMI Shielding and Mechanical Properties

ABSTRACTThe demand for effective electromagnetic interference (EMI) shielding materials has driven the development of novel and facile approach for fabrication of conductive polymer nanocomposites. In this study, a polypropylene (PP)‐based hybrid nanocomposite was prepared by incorporating Super P conductive carbon black (SPCB) and graphene nanoplatelets (GNP) via latex technology. A simplistic method of fabrication was adopted where the nanofillers were stirred into the PP latex at room temperature, ensuring the proper dispersion of fillers within the matrix. Hybridizing the nanocomposite by the usage of two different fillers has resulted in a substantial improvement in EMI shielding performance of the material along with its mechanical and thermal properties. The samples were fabricated and tested in three different thicknesses to ensure that EMI shielding effectiveness (EMI SE) is a thickness dependent property and also the studies were carried out over a broad range of microwave frequency. A high electrical conductivity of 7.6 S m−1 was obtained and exceptional EMI SE of 65 dB (X band), 69.76 dB (Ku band), and 72.38 dB (K band) was showcased by 2 mm thickness composites. The optical images of PP latex incorporated with the fillers gave a clear understanding about the formation of conducting networks within the polymer matrix at percolation threshold. The addition of SPCB and GNP also showed a significant increase in hardness and tensile strength of the composite and helped in protecting the polymer matrix against photo radiation. The fillers also aided in the enhancement of the hydrophobicity of the films. The thermal stability, crystallization temperature (TC) and melting temperature (TM) of the composites were also improved when compared to that of neat The works aims at fabricating a hydrophobic and low‐density polymer nanocomposite showing excellent absorption dominant EMI SE.

Acetaminophen effects upon formalin-evoked flinching, postformalin, and postincisional allodynia and conditioned place preference.

We explored in mice, the analgesic, tolerance, dependency, and rewarding effects of systemic acetaminophen (APAP). Studies employed adult mice (C57Bl6). (1) Intraplantar formalin flinching + post formalin allodynia. Mice were given intraperitoneal APAP in a DMSO (5%)/Tween 80 (5%) or a water-based formulation before formalin flinching on day 1 and tactile thresholds assessed before and after APAP at day 12. (2) Paw incision. At 24 hours and 8 days after hind paw incision in male mice, effects of intraperitoneal APAP on tactile allodynia were assessed. (3) Repeated delivery. Mice received daily (4 days) analgesic doses of APAP or vehicle and tested upon formalin flinching on day 5. (4) Conditioned place preference. For 3 consecutive days, vehicle was given in the morning in either of 2 chambers and in each afternoon, an analgesic dose of morphine or APAP in the other chamber. On days 5 and 10, animals were allowed to select a "preferred" chamber. Formalin in male mice resulted in biphasic flinching and an enduring postformalin tactile allodynia. Acetaminophen dose dependently decreased phase 2 flinching, and reversed allodynia was observed postflinching. At a comparable APAP dose, female mice showed similarly reduced phase 2 flinching. Incision allodynia was transiently reversed by APAP. Repeated APAP delivery showed no loss of effect after sequential injections or signs of withdrawal. Morphine, but not APAP or vehicle, resulted in robust place preference. APAP decreased flinching and allodynia observed following formalin and paw incision and an absence of tolerance, dependence, or rewarding properties.

Dependence Modeling for Tsunami and Earthquake Disasters in the Indonesian Megathrust Zones using Copula Models

The megathrust earthquake parameters that are related to the number of tsunami disasters (𝑍) are the number of earthquakes (𝑋) and the maximum earthquake magnitude (𝑌). The dependence property of these three random variables is stochastic due to the uncertainty of each event. This study provides the stochastic dependence model of (𝑋, 𝑍) and (𝑌, 𝑍) based on the historical data of tsunami and megathrust earthquake disasters occurring from 1905 to 2022 in five megathrust zones of Indonesia, namely the Sumatra, Java, Bali, Sulawesi and Papua zones. In this study, the stochastic dependence models applied are bivariate Copula models that are flexible under rigid assumptions. The data source is taken from the U.S. Geological Survey catalog. The results show that each megathrust zone has various responses to the earthquake and tsunami mechanisms; it can be seen from the probability functions of three random variables in each megathrust zone that they are significantly different. Furthermore, according to stochastic dependence modeling results, it is found that the Copula model selected for each zone varies in type and parameters. Moreover, the selected bivariate Copula models for each megathrust zone have better agreement with the data modeled than the conventional bivariate discrete models.

Neural dynamics of grouping explain properties of serial dependence in orientation

Neural dynamics of grouping explain properties of serial dependence in orientation

Thickness dependence and crystallization properties of amorphous GeTe thin films on silicon dioxide

Radio frequency magnetron sputtering was used to prepare the amorphous GeTe thin films on silicon dioxide and the thickness effects on the crystallization behavior were investigated. With the film thickness reducing, the crystallization temperature, crystallization activation energy, amorphous and crystalline resistance increase remarkably, indicating the great improvement in thermal stability and power consumption. Ozawa’s model was used to estimate the crystallization kinetics of GeTe thin films, it shows that nucleation and grain growth occur simultaneously, and grain growth dominates ultimately. XRD analysis demonstrated that the grain size can be reduced and the crystallization process of GeTe thin film can be inhibited with the film thickness decreasing. Furthermore, the thinner film has smaller resistance drift index and surface roughness, which are beneficial to improve the reliability of storage device. T-type phase change memory devices based on 25 nm GeTe thin film were fabricated by 0.13 μm CMOS technology, and the current–voltage and resistance-voltage characteristics demonstrate the excellent electrical performance, including the fast resistance switching between SET and RESET processes, low threshold current and voltage. All the results proved the strong dependency relationships between the crystallization properties and film thickness of GeTe thin film, which paves the way for developing high-density phase change memory in the fields of big data and artificial intelligence.

The optical properties of nano-structural α-Fe2O3 dependence on the shape.

Three different crystal morphologies of α-Fe2O3, including uniform hexagonal, square, and rhombic shapes, were prepared according to the aqueous-thermal reaction. The hexagonal-shaped α-Fe2O3 was enclosed by the 104 plane, while the square and rhombic structures were enclosed by the 110 plane. Two absorption peaks at 455 and 532 cm-1 were found for the perpendicular (⊥) modes, and one absorption peak at 650 cm-1 appeared for the parallel (||) mode for hexagon-shaped α-Fe2O3 during analysis by Fourier-transform infrared spectroscopy. However, the peaks of square- and rhombic-shaped α-Fe2O3 for perpendicular (⊥) mode blueshifted, and the former two peaks merged together forming a broad band at approximately 480 cm-1. For Raman spectra determination, the peaks arose from the Brillouin zone center, and two additional peaks were observed at 660 and 1320 cm-1, belonging to 1 longitudinal optical (1LO) and 2 longitudinal optical (2LO) modes. All three materials exhibited higher intensities when excited at a wavelength of 633 cm-1. Furthermore, in the polarization state, the centers of all peak positions slightly shifted for hexagon-shaped α-Fe2O3, but all peak positions for square-shaped and rhombic-shaped α-Fe2O3 exhibited a significant blueshift. The structure of hexagon-shaped α-Fe2O3 was relatively tolerant regarding the polarization properties of vibration modes; however, the symmetry of crystal square-shaped and rhombic-shaped α-Fe2O3 changed, subsequently revealing different optical properties. RESEARCH HIGHLIGHTS: The hexagon-shaped, square-shaped, and rhombic-shaped α-Fe2O3 enclosed by different planes were synthesized. The Fourier Transform Infrared spectrometer peaks of α-Fe2O3 depended on their hexagon, square and rhombic shapes. Compared with hexagon-shaped α-Fe2O3, the Raman peaks for square and rhombi ones significantly shifted. The hexagon-shaped α-Fe2O3 is relatively tolerant regarding the polarization properties.

Dependence properties of stochastic volatility models

The concepts of physical dependence and approximability have been extensively used over the past two decades to quantify nonlinear dependence in time series. We show that most stochastic volatility models satisfy both dependence conditions, even if their realizations take values in abstract Hilbert spaces, thus covering univariate, multi‐variate and functional models. Our results can be used to apply to general stochastic volatility models a multitude of inferential procedures established for Bernoulli shifts.

Scientific logic and spatio-temporal dependence in analyzing extreme-precipitation frequency: negligible or neglected?

Abstract. Statistics is often misused in hydro-climatology, thus causing research to get stuck on unscientific concepts that hinder scientific advances. In particular, neglecting the scientific rationale of statistical inference results in logical and operational fallacies that prevent the discernment of facts, assumptions, and models, thus leading to systematic misinterpretations of the output of data analysis. This study discusses how epistemological principles are not just philosophical concepts but also have very practical effects. To this aim, we focus on the iterated underestimation and misinterpretation of the role of spatio-temporal dependence in statistical analysis of hydro-climatic processes by analyzing the occurrence process of extreme precipitation (P) derived from 100-year daily time series recorded at 1106 worldwide gauges of the Global Historical Climatology Network. The analysis contrasts a model-based approach that is compliant with the well-devised but often neglected logic of statistical inference and a widespread but theoretically problematic test-based approach relying on statistical hypothesis tests applied to unrepeatable hydro-climatic records. The model-based approach highlights the actual impact of spatio-temporal dependence and a finite sample size on statistical inference, resulting in over-dispersed marginal distributions and biased estimates of dependence properties, such as autocorrelation and power spectrum density. These issues also affect the outcome and interpretation of statistical tests for trend detection. Overall, the model-based approach results in a theoretically coherent modeling framework where stationary stochastic processes incorporating the empirical spatio-temporal correlation and its effects provide a faithful description of the occurrence process of extreme P at various spatio-temporal scales. On the other hand, the test-based approach leads to theoretically unsubstantiated results and interpretations, along with logically contradictory conclusions such as the simultaneous equi-dispersion and over-dispersion of extreme P. Therefore, accounting for the effect of dependence in the analysis of the frequency of extreme P has a huge impact that cannot be ignored, and, more importantly, any data analysis can be scientifically meaningful only if it considers the epistemological principles of statistical inference such as the asymmetry between confirmatory and disconfirmatory empiricism, the inverse-probability problem affecting statistical tests, and the difference between assumptions and models.

A note on incorrect inferences in non-binary qualitative probabilistic networks

Qualitative probabilistic networks (QPNs) combine the conditional independence assumptions of Bayesian networks with the qualitative properties of positive and negative dependence. They formalise various intuitive properties of positive dependence to allow inferences over a large network of variables. However, we will demonstrate in this paper that, due to an incorrect symmetry property, many inferences obtained in non-binary QPNs are not mathematically true. We will provide examples of such incorrect inferences and briefly discuss possible resolutions.

Bias-dependent photoresponse of Td-WTe2 grown by chemical vapor deposition

The type-II Weyl semimetal Td-WTe2 is one of the wonder materials for high-performance optoelectronic devices. We report the self-powered Td-WTe2 photodetectors and their bias-dependent photoresponse in the visible region (405, 520, 638 nm) driven by the bulk photovoltaic effect. The device shows the responsivity of 15.8 mAW−1 and detectivity of 5.2 × 109 Jones at 520 nm. Besides, the response time of the WTe2 photodetector shows the strong bias-voltage dependent property. This work offers a physical reference for understanding the photoresponse process of Td-WTe2 photodetectors.

Max-convolution processes with random shape indicator kernels

In this paper, we introduce a new class of models for spatial data obtained from max-convolution processes based on indicator kernels with random shape. We show that these models have appealing dependence properties including tail dependence at short distances and independence at long distances. We further consider max-convolutions between such processes and processes with tail independence, in order to separately control the bulk and tail dependence behaviors, and to increase flexibility of the model at longer distances, in particular, to capture intermediate tail dependence. We show how parameters can be estimated using a weighted pairwise likelihood approach, and we conduct an extensive simulation study to show that the proposed inference approach is feasible in relatively high dimensions and it yields accurate parameter estimates in most cases. We apply the proposed methodology to analyze daily temperature maxima measured at 100 monitoring stations in the state of Oklahoma, US. Our results indicate that our proposed model provides a good fit to the data, and that it captures both the bulk and the tail dependence structures accurately.

Advanced Excitation Symmetry Analysis Method (ESAM) for improved automated ultrasonic testing of polished materials

One of the strategic plans of the international NDT community is to define standards for developing advanced and digitalized non-destructive testing for automated set-up in mass production [1,2]. Excitation Symmetry Analysis Method (ESAM) are new coded signal processing tools exploring symmetry properties [3]. ESAM method aims to extract the nonlinearity from an ultrasound output by studying the property of symmetry of the transfer function. More precisely, the extraction of nonlinearity is done using basis function associated to a group which is associated to an a priori transfer function. As soon as the linear tomography uses the invariant properties of amplitude dependence, nonlinear tomography should exploit the invariance properties (or symmetry properties) of the complex system. Consequently, the invariance of the stationary properties of a complex medium would be supposed to be associated to a signature of the degradation, that will be extracted with advanced signal processing tools. The idea remains the same: studying the symmetry and more precisely the time reversal one and the inversion. A signal processing is used to measure discrepancies in the autocorrelation function (output signal called chirp coda) for two inputs: a signal and its inversion (pulse inversion). The experiments were done on different sample with and without cracks. It has been shown that when the nonlinearities are extracted from the chirp coda amplitude are non- negligible in crack area and nonlinearities are out of phase. Then, mixing symmetries like time reversal and pulse inversion enable the detection of defect that are difficult to detect with conventional ultrasound method. Indeed, for such crack a destructive mechanical analysis called Jomini is done where the material is polished and examined with microscope. The sensitivity improvement of chirp-coded signal processing has been validated in various domains. Coded excitation techniques, used in communication systems such as radar and sonar provide improved SNR without increasing the amplitude of excitation. The typical test equipment consists of a preamplifier Juvitek TRA-02 (0.02 - 5 MHz) connected to a computer, an amplifier ENI model A150 (55 dB at 0.3-35 MHz), a shear wave transducer Technisonic (2.25 MHz), and a longitudinal wave transducer Panametrics V155 (5 MHz). The experimental device was tested with the V3 calibration block, improved, and specially scaled in order to access to a wide range of multivalued parameters: mechanical properties, ultrasonic parameters (celerity and attenuation) and local geometric data.

Structural, morphological, mechanical, and thermal insulation properties of multiple-phase magnesium silicate ceramic fibers electrospun from dual-precursor sols

As the research for advanced materials suitable for high-temperature uses continues, the need for oxide ceramic micro-nanofibers with outstanding mechanical and thermal properties becomes increasingly important. By incorporating two types of magnesium sources, specifically Mg(CH3COO)2·4H2O and MgCl2·6H2O, into the precursor, a range of fibers made of magnesium silicate ceramics was produced through electrospinning. X-ray diffraction (XRD) analysis verified that the resulting multiple phases included MgO, MgSiO3, Mg2SiO4, and amorphous SiO2, with the phase composition being affected by the diffusion reaction of Mg ions. The fibers produced using the dual-precursor method maintained a stable morphology with a uniform and compact structure after undergoing high-temperature treatments ranging from 1000 to 1200 °C. This study is the first to report the tensile strength of magnesium silicate fibrous membranes, which was found to be 1.54 ± 0.27 MPa and 1.21 ± 0.73 MPa after heat treatment at 800 °C and 1000 °C, respectively. Furthermore, these fibrous membranes demonstrated dependable thermal insulation properties within the testing range of 500–1000 °C, along with a low thermal conductivity at room temperature of 0.0301–0.0306 W m−1·K−1. Characterized by their impressive mechanical strength and high temperature stability, magnesium silicate ceramic micro-nanofibers show significant potential for various applications in the targeted field.

Non-locality as a regularization mechanism in elastodynamics

It is well known that the solutions to the elastodynamic problem do not satisfy continuous dependence properties on the initial values, and/or supply terms, when the elastic tensor fails to be positive. In fact, the behavior of the solutions can be very explosive since the elements of the spectrum can go to infinite. Therefore, it is very relevant to identify thermomechanical mechanisms regularizing the behavior of the solutions. So, the main aim of this note is to show, from an analytical point of view, how the non-locality, in the sense of Eringen, is a mechanism satisfying this property of regularization of the solutions. It is worth noting that such system has not been previously studied from an analytical point of view. We firstly obtain the existence of the solutions to this problem, even when we do not assume any positivity on the elastic tensor. This result is proved with the help of the linear semigroups theory; however, even with these regularizing effects, the solutions to this problem are unstable. A particular easy one-dimensional problem is also considered. The extension of the existence and instability results to the thermoelastic case is pointed out later. Finally, we also study the spatial behavior of the solutions to the problem in the case that the region is a semi-infinite cylinder, and we obtain a Phragmen–Lindelöf alternative of the exponential type. This result is also relevant because a similar result, without considering regularizing terms, is unknown if the elastic tensor is not positive definite.

Vibrations characteristics analysis of metal composite 17–4PH material extrusion additively manufactured parts under amplitude dependence property

The ultra-fuse 17–4 PH stainless-steel filament has emerged as a promising new material in the 3D printing field during this past decade. Since the introduction recently of the 17–4 PH stainless-steel filament in the material extrusion process, extensive research has been carried out on the mechanical performance (tensile strength, plasticity, and surface roughness) of the metal composite 17–4 PH stainless-steel material extrusion additively manufactured parts, however few of them mainly focused on the dynamic performance of the 17–4 PH stainless-steel material extrusion additively manufactured parts thus leaving a slight void, therefore to fill this gap a dynamic linear model of a metal composite filament ultra-fuse 17–4 PH stainless-steel material extrusion additively manufactured parts has been established in this study considering the amplitude dependence. Material extrusion additively manufactured plates have been built in x and z-direction, and based on the Jones-Nelson model an investigation of the natural frequency and response and damping ratio of ultra-fuse metal composite 17–4 PH metal composite material extrusion specimens has been completed. Equations of the proposed dynamic model have been solved by the combination of the orthogonal polynomial method and energy method. The Newton-Raphson iteration has been employed to predict the natural frequencies and responses of the ultra-fuse 17–4 PH stainless-steel material extrusion manufactured parts. The results indicate that the predicted damping characteristics of the ultra-fuse metal composite 17–4 PH metal composite material extrusion parts have a good consistency with the experimental ones, meanwhile, when amplitude vibration increases from [0.25 g…2.00 g], the response of the ultra-fuse 17–4 PH metal composite material extrusion parts increase as well both for x and z-direction samples.

On the prediction of power outage length based on linear multifractional Lévy stable motion

In the power system, failure interruption hugely compromises the power system reliability. Therefore, an efficient method to correctly predict how long the power outage last would significantly improve the efficiency. To address this problem, we propose a method based on a suitable stochastic motion. First, we introduce linear multifractional Lévy stable motion (LMLSM). Then, by computing the global and local fractal characteristics we show that the LMLSM is multifractal and possesses the long-range dependence (LRD) property. Besides, the non-Gaussian characteristics of the LMLSM are analyzed, which means it can better describe the constant peak values in the stochastic time series. Furthermore, a discrete iterative prediction model is derived with fractional Black-Scholes differential equation. At last, a case study is provided based on the real failure interruption duration (FID) dataset in the power grid, by illustrating the validity of the proposed prediction method for power grid reliability.

Construction of New Bivariate Semilinear Copulas Based on the Ali–Mikhail–Haq, Farlie–Gumbel–Morgenstern and Plackett Families

Copulas are quite a popular, flexible, and useful tool for multivariate modeling in many fields of applications, including finance and insurance, actuarial sciences, biomedical studies, geostatistics, and hydrology. In this paper, we use the concept of diagonal function to build new bivariate copulas based on the well known and important Ali–Mikhail–Haq (AMH), Farlie–Gumbel–Morgenstern (FGM) and Plackett families. We also study some dependence properties of the newly constructed semilinear copulas, namely, the Spearman’s [Formula: see text] coefficient. In particular, we find that the range of this rank correlation coefficient varies between weak and moderate values for the transformed AMH and FGM families, although it varies between moderate and strong values for the transformed Plackett families. Moreover, in all cases, the Spearman’s [Formula: see text] coefficient reaches negative and positive values. Finally, we present a synthetic data generation algorithm, as well as a classical method of estimation of the copula association parameter [Formula: see text] for each of the six transformed bivariate families.

Advances in exploration of photoinduced electron transfer reactions involving small molecules probed by magnetic field effect

The review focuses on photoinduced electron transfer (PET) reactions between small molecules and various kinds of chemical and biological systems using a weak external magnetic field (MF). Laser flash photolysis is a competent tool to characterize the intermediates which are formed due to PET. A weak MF, very close to the hyperfine interaction of the system, has the potential to inhibit or enhance reaction channels for singlet and triplet states, which eventually effects the product distribution. At first, well-documented examples of PET involving small molecules like derivatives of phenazines, carbazoles and acridines with classical electron donors in varying homogeneous and heterogeneous media have been discussed and the influence of a weak MF on the dynamics of PET is highlighted. Secondly, utilization of magnetic field effect (MFE) to probe PET in protein pockets has been described. Thirdly, an extensive discussion on PET involving nucleobases, nucleosides, nucleotides and nucleic acids and subsequent MFE on such reactions has been reported. Next, MFE has been exploited to study PET involving nanomaterials. Finally, some very recent studies of MFE have been discussed. Thus, this review is an attempt to unravel various aspects of PET in a large number of systems of varying dimensions by means of several facets of MFE like B1/2 parameter, its capability to authenticate the initial spin state and distance dependence property.

Minimal coverage of generalized typed inclusion dependencies in databases

The paper discusses the theory and algorithms necessary to construct a minimal covering of generalized typed inclusion dependencies. Traditionally, the construction of minimal covering is used for all types of dependencies in order to obtain a non-redundant and consistent database design. Generalized inclusion dependencies correspond to referential integrity constraints, when several main and several external relations are involved in one constraint, which corresponds to an ultragraph edge. In previous work, based on a study of the properties of dependencies, a system of axioms was presented with proof of consistency and completeness. In this work, the closures were studied for generalized typed inclusion dependencies. An algorithm for constructing closures has been developed and its correctness has been proven. The results obtained are further used to develop an algorithm for constructing a minimal covering. At the end of the article, examples are presented that demonstrate the operation of the algorithms.