Properties Of Coatings Research Articles

Expanding Chemical Space in the Synthesis of Gold Bipyramids

AbstractGold bipyramids (AuBPs), despite having superior properties compared to their spectroscopically similar counterparts, gold nanorods, have found comparatively limited applications. This discrepancy is primarily due to the lack of protocols to tailor their dimensions. Typically, the concentration of Au seeds is virtually the sole factor that determines the aspect ratio and thus, the optical properties of AuBPs. As a result, varying the volumes of AuBPs while incurring minimal changes to their optical spectra remains a synthetically non‐trivial task. Here, the chemical space in the seeded growth of AuBPs, is expanded by exploiting the interplay between bromide, silver ions, and seed concentration for tuning the final dimensions and optical properties of AuBPs. Specifically, a 6 fold change in volumes of AuBPs is achieved while maintaining the fixed plasmon band position. Further overgrowth of as‐prepared bipyramids broadens the realizable dimensions without compromising quality and initial morphology. Overall, the results expand the chemical toolbox in the wet‐chemistry synthesis of anisotropic gold nanoparticles, which is relevant for health, colorimetric sensors, and energy applications.

Influence of Finishing Process Parameters of HDF Boards on Selected Properties of Coatings in Modern UV Lines and Their Relation to Energy Consumption

This study analyzes the influence of energy generated by emitters on the adhesive properties of varnish coatings in multilayer UV systems. The experimental material, in the form of a cell board finished with UV varnish products, was prepared on a prototype line under the conditions of Borne Furniture in Gorzów Wielkopolski. The roughness and wettability were measured using a OneAttension tensiometer integrated with a topographic module, taking into account the Wenzel coefficient. The adhesion of the examined systems was verified using the PositiTest AT-A automatic pull-off device. Energy consumption by the prototype production line was compared to the standard line, utilizing mercury emitters and mercury emitters with added gallium. Energy consumption was calculated for selected variants. The influence of the Wenzel coefficient on the wettability angle was observed. Significant differences between contact angles (CA and CAc) were noted for coatings formed with sealers (stages I and II). The largest discrepancies, reaching up to 30 degrees, were recorded at the lowest UVA and UVV doses of 26 mJ/cm2. In adhesion tests, values below 1 MPa were obtained. Insufficient energy doses in the curing process of UV systems led to delamination between the coatings. Five variants were selected where delamination within the substrate predominated (˃90% A) and were characterized by the lowest energy consumption in the processes. Topographic images helped identify the presence of various surface microstructures at different stages of the production cycle. The greatest energy savings, up to 50%, were achieved in stages III and IV of the technological process.

Influence of Plasma Arc Current and Gas Flow on the Structural and Tribological Properties of TiN Coatings Obtained by Plasma Spraying

This study investigates the development of TiN-based coatings using plasma spraying technology, focusing on how plasma arc current and working gas flow rate affect the coatings’ structural-phase composition and mechanical–tribological properties. The research highlights the potential and effectiveness of plasma spraying for TiN coatings. Results from scanning electron microscopy and nanoindentation tests show that the TiN coatings have a dense microstructure with strong adhesion. Tribological testing demonstrated that coatings deposited at a 250 A arc current displayed the lowest coefficient of dry friction and the lowest porosity (2.13%) compared to those deposited at 350 A and 450 A arc currents, which exhibited higher porosity (up to 10.45%).

The Anti/Deicing Performance of the Low Interfacial Toughness Coating Is Enhanced: Induced Ice Crack Generation and Its Extension.

The low interfacial toughness of the material surface is important for crack initiation and expansion of the ice layer as it remains an effective method for large-scale deicing. However, there are challenges, such as a large critical icing size and incomplete shedding of the ice layer. Adjusting the interfacial forces to make the ice more prone to cracking, expanding, and shedding is advantageous in addressing the problem of anti-icing failure in materials with low interfacial toughness. Therefore, we propose a deicing strategy that combines porous PDMS (polydimethylsiloxane) coatings with low interfacial toughness and piezoelectric vibration. A series of hydrophobic porous PDMS coatings with different porosities were prepared on the surface of an aluminum alloy substrate through curing and phase separation. The elastic modulus of the coatings decreased from 1465 to 509 kPa as the coating porosity increased, revealing the mechanism behind the improvement in mechanical properties. The key to promoting ice fracture on porous PDMS coatings lies in the synergistic effect of the out-of-plane shear stress and microcracks at the solid-ice interface. This work focuses on exploring the characteristics of interfacial forces by combining the intrinsic mechanical properties of coatings with external forces, providing new insights for designing low interfacial toughness anti-icing materials.

Optimizing Fe-N-C Electrocatalysts for PEMFCs: Influence of Constituents and Pyrolysis on Properties and Performance

Proton exchange membrane fuel cells (PEMFCs) are promising alternative technologies with applications in stationary power systems, vehicles, and portable electronics due to their low temperature operation, fast start-up, and environmental advantages. However, the high cost of platinum-based catalysts, in particular for the oxygen reduction reaction (ORR) of the cathode side, prevents their widespread incorporation. Fe-N-C electrocatalysts have emerged as viable alternatives to platinum. In this study, different precursor components were investigated for the way that they affect the pyrolysis process, which is crucial for tailoring the final catalyst properties. In particular, carbon allotropes such as carbon Vulcan, Ketjenblack, and carbon nanotubes were selected for their unique structures and properties. In addition, various sources of iron (FeCl2, FeCl3, and K[Fe(SCN)4]) were evaluated. The influence of the pyrolysis atmosphere on the resulting Fe-N-C catalyst structures was also assessed. Through an integrated structure and surface chemistry analyses, as well as electrochemical tests with rotating disk electrode experiments in acidic media, the ORR performance and stability of these catalysts were defined. By examining the relationships between carbon sources and iron precursors, this research provides valuable information for the optimization of Fe-N-C catalysts in fuel cell applications.

A Study of the Features of Coating Deposition on a Carbide Substrate Using Preliminary Etching with Glow-Discharge Plasma

The properties of coatings obtained using two surface preparation methods were compared: heating and etching by ion bombardment with plasma generation by arc evaporators and heating and etching by a glow discharge. A Ti-TiN-(Ti,Cr,Al)N coating was deposited. The use of a glow discharge provides better resistance of the coating to destruction during the scratch test and wear resistance of metal-cutting tools when turning steel. As the cutting speed increases, the advantage in wear resistance of the coating deposited using a glow discharge increases. During the process of heating and etching by ion bombardment with metal ions, a nanolayer rich in cobalt and tooling elements (iron, molybdenum) is formed in the area of the interface of the coating and the carbide substrate. When heated and etched by a glow discharge, such a layer does not form. When using both methods, there is identical diffusion of tungsten into the coating and diffusion of chromium and possibly titanium into the substrate. Thus, the glow-discharge heating and etching method can be effectively used in the process of PVD coating deposition.

3d Mapping Of Stiffness Evolution Of Hardening Concrete With Saps Using Elastic Wave Tomography

Phenomena occurring during the delicate phase of concrete curing can have a strong influence on the final mechanical properties. Therefore, monitoring the changes during hydration can provide meaningful information on the material properties. Lately, non-destructive techniques have received great attention for monitoring earlyage concrete. This paper aims to assess the ultrasonic velocity and stiffness development of hardening concrete during various curing stages using the Elastic Wave Tomography (EWT) technique. The monitoring of the curing process starts as soon as seven hours after casting and lasts up to seventy hours. A three-dimensional (3D) wave velocity map is created, and conventional concrete is compared to concrete containing SuperAbsorbent Polymers (SAPs), a novel admixture used for shrinkage mitigation by providing internal curing in the cementitious matrix. However, SAPs have been proven to reduce compressive strength when added to concrete, due to the increased porosity they induce. This porosity may also result in the reduction of the wave velocity. However, the internal curing provided by the SAPs can promote the formation of new hydration products in the matrix and thus (partly) compensate for the strength loss making the uniformity of the internal curing another important point of concern. EWT can provide global information on the homogeneity of the influence of the SAPs in the cementitious matrix as opposed to the wave velocity of a single wave path that is usually examined in practice. In addition, the determination of the early-age stiffness evolution can be connected to the final mechanical properties of the material. The dynamic Young’s Modulus is calculated and compared to the static Young’s modulus at 28 days. Predictions towards the static Young’s modulus are also made, showing good agreement.

Sintering behaviour of buffered UO2 fuel doped with niobium oxides

An innovative nuclear fuel doped with a redox buffer is being developed to control the partial oxygen pressure (pO2) within the reactor and thereby limit stress corrosion cracking of the cladding. The selected redox buffer couple is Nb2O5/NbO2. The doping of the fuel affects its densification and final properties. Therefore, a study is being conducted on the densification behavior of this type of fuel and the influence of dopant concentration. The dopant was mixed with UO2, and the powder was then pressed into pellets, sintered under a reducing atmosphere. The linear shrinkage and oxygen release from the pellet were monitored during sintering. This method highlighted the reduction of niobium oxides during sintering, which causes oxygen release, influencing the densification behavior and microstructure of the doped fuel.

Production and Characterization of Biosurfactants from Lactic Acid Bacteria in Dadiah for Strawberries Edible Coating

Biosurfactants are amphiphilic components applied in various fields, one of which is preserving agricultural products. Biosurfactants can be used as additives in edible coatings to prevent microbial adhesion by reducing surface tension on the fruit surface. They also play a role in increasing the moisture barrier and slowing down the physiological changes of fruit. Nonetheless, biosurfactants were often produced by non-GRAS bacteria. GRAS biosurfactant-producing bacteria are urgently needed for application in food products. This study aims to isolate and characterize biosurfactant-producing strains of lactic acid bacteria from Dadiah and evaluate their efficacy in reducing microbial adhesion on strawberries. From four selected isolates found in Dadiah, Lactiplantibacillus plantarum was the best candidate, producing biosurfactant with index emulsification (EI24) of 64.48±0.37% with a CMC of 1 g/l. LC-MS and FT-IR characterized the biosurfactants as glycolipids. The rate of antibacterial and anti-adhesive tests on Escherichia coli ATCC 8739 were 18.79±5.23% and 55.26±0.02%, while on Staphylococcus aureus ATCC 6738 were 31.60±2.63% and 74.63±0.00% at a concentration of 3000 mg/l. However, no anti-fungal activity against Rhizopus stolonifer and Aspergillus niger was observed at the same concentration. Compared to SDS, biosurfactants demonstrated non-toxicity with an LC50 value of 2.94 x 108 mg/l. A combination of 1% chitosan reduced the number of fungal cells by 29.76±3.25% on 125 mg/l biosurfactant and bacterial cells by 31.91±5.06% on 1000 mg/l biosurfactant after ten days, indicating their potential to reduce fruit spoilage and enhance microbial anti-adhesive properties of edible coatings.

Effects of Ta on the strengthening mechanism of microstructure and corrosion resistance of underwater wet laser cladding 17-4PH coating

Underwater wet laser cladding has gradually become the key technology for online repair of marine engineering materials. This work successfully prepared a Ta-reinforced 17-4PH coating on a 20Cr substrate using this technique. The study primarily examined how varying levels of tantalum (Ta) influence the microstructure, phase composition, microhardness, immersion corrosion, and electrochemical properties of underwater cladding coatings. Additionally, a detailed analysis of the corrosion mechanism was conducted. The experimental findings demonstrated that incorporating Ta can greatly enhance the forming quality and overall performance of coatings. When the Ta addition was 10 %, the forming quality was the best, and there were no porosity or depressions. The 10 % Ta coating had the best densification with a minimum porosity of 0.05 %. The average microhardness of the T10 coating was 594.1 ± 5.9 HV0.2, an increase of about 13 % over the original T0 coating. Additionally, when the Ta content reached 10 %, the formation of Ta2O5 on the surface played a crucial role in enhancing the coating's resistance to immersion corrosion. The T10 coating demonstrates the highest polarization resistance and superior corrosion resistance among the coatings tested. The corrosion mechanism of the original unadded Ta coating involved severe intergranular corrosion and pitting; The corrosion mechanism observed in the T10 coating involved local crevice corrosion and minor pitting. This study reveals the strengthening mechanism of Ta on the organizational properties of the underwater laser cladding layer, which can provide meaningful guidance for the future development of underwater laser cladding technology.

Optimizing Glass Foam Production from Recycled Sources: Influence of Variation in Cullet Color and Spent Alkaline Battery Components

Glass foams present a compelling opportunity for upcycling glass waste, offering a favorable combination of low weight, thermal insulation, and mechanical strength. Prior works demonstrated the feasibility of producing glass foams from glass waste and foaming agents sourced from synthetic textile waste, manganese oxides, and spent alkaline battery cathodes. This work explores the optimization of the process, investigating the impact of glass composition of differently colored glasses on final properties and incorporating entire alkaline batteries, encompassing both cathode and anode components. By carefully adjusting the composition, foaming agent content, and process temperature, customizable properties are achieved. Increasing foaming agent content or utilizing transparent glass improves insulation but lowers density and mechanical properties. Lowering foaming agent content or using brown/green glass enhances density and strength at the expense of insulation. Temperatures beyond 900 °C increase crystalline content, boosting mechanical performance without affecting density. This innovative approach not only offers a pathway to sustainable insulation materials but also underscores the potential for minimizing environmental impact through the efficient upcycling of glass waste.

Effect of Pulse Electrodeposition Mode on Microstructures and Properties of Ni-TiN Composite Coatings

Mild steel is a kind of material commonly used in the chemical industry and to manufacture machinery, farm tools, and other parts in order to improve the surface performance of the parts and prolong their service life. The Ni-TiN composite coating was fabricated through ultrasonic electroplating using a Ni-based sulfamic acid bath with added nano-TiN particles. The effects of three distinct current modes, direct current (DC), positive pulse current (PC), and positive–negative pulse current (PNPC), on various aspects of the coating, including surface morphology, TiN content and distribution, interface bonding strength, microhardness, friction and wear properties, as well as corrosion resistance, were investigated. The findings demonstrated that, in comparison to DC electroplating, PC electrodeposited Ni-TiN composite coatings yielded finer grains, smoother surfaces, reduced surface cracks, increased interface bonding strength, and enhanced corrosion resistance. Furthermore, PNPC electrodeposited Ni-TiN composite coatings showed higher interface bonding strength than those of PC electrodeposited Ni-TiN coatings and had the densest structure, leading to the best corrosion resistance. Pulse current electroplating enhanced the incorporation of nano-TiN particles, with a higher deposition rate observed in positive–negative pulse current electroplating compared to positive pulse current electroplating. Furthermore, the PNPC electrodeposited coating displayed improved microhardness and demonstrated the best friction and wear properties, while the DC electroplated coating displayed the least favorable performance in these aspects.

The effect of Mg17Al12 intermetallic compound on dynamic recrystallization of cast-forged AZ80 magnesium alloy

An asymmetric I-crossbeam geometry is produced by cast-forging of the AZ80 magnesium alloy at two different casting cooling conditions and three different forging temperatures. Samples are extracted from two different locations from each component, representing different deformation conditions, for microstructure study. This paper presents a detailed investigation into the relationship between the Mg17Al12 intermetallic compound and dynamic recrystallization in the cast-forging process. The eutectic, lamellar, discontinuous, and continuous morphologies of the Mg17Al12 phase are observed in the produced components, and their evolution during the cast-forging process is investigated. Depending on the forging condition, dissolution and re-precipitation of the Mg17Al12 phase might occur before or after the forging stage and influence the extent, distribution, and grain size of DRX. It is shown that the eutectic, lamellar, and discontinuous morphologies of the Mg17Al12 phase effectively promote dynamic recrystallization. On the other hand, the continuous morphology is only effective when the particles are broken as a result of high deformation. This study provides a better understanding of the effect of Mg17Al12 intermetallic compound on the hot deformation behavior of the AZ80 alloy, which can be used to tailor the cast material in order to improve the forgeability and final mechanical properties of the magnesium-based structural components.

Advancements in Biofiller-Reinforced PLA Composites for 3D Printing: A Review

Additive manufacturing is key in realizing highly complex and high-performance composite materials. Among all the various kinds of functionality that could be added to a composite component, continuous fiber-reinforced composites have been drawing much attention because of their attractive combination of properties. The comprehensive spectrum of knowledge that ranges from the basics concerned with structure, morphology, synthesis, physical, and chemical properties finally reaches to this analytical study of advanced composites. Most generally, such a composite is structured on a thermoplastic or thermoset polymer matrix that embeds the load-carrying reinforcing fibers; probably best known are carbon, glass, and aramid fibers. These composites, which involve fibers continuously reinforcing, have high strength relative to their weight. They are also anisotropic, meaning they have qualities that vary from one direction to another – something which might be customisable for specific load cases. They warp and shrink less during their life in an outside environment than conventionally made bioplastics due to a fact that short fibers can provide reinforcement to them. This 3-D printing object is manufactured by special additive manufacture technology during the manufacturing process after compounding and extruding the fiber-reinforced composite filament. The final properties of 3D printed parts could be tailorable through changing variables such a fiber type, fiber length, volume fraction, polymer matrix material, orientation of fibers, and printing process parameters. These continuous fiber-reinforced 3D printed composites could achieve tensile strengths up to one GPa, have stiffness values reaching even a rating of countless Gpa, and have ad thicknesses in the range from about 1.4–1.8 g/cm³. This finding could be applied in basically all major industries, from aerospace and the automotive industry to sports gear. Such conclusions from the analysis may be useful in the selection of appropriate materials and techniques while even guiding the development of new applications with respect to such advanced composite materials.

Correlation analysis of composition, microstructure, and final properties of porcelain tiles: an experimental study

Abstract This study deals with the intricate relationship between composition, microstructure and the final properties of porcelain tiles namely bulk density, water absorption, thermal expansion coefficient, strength, and Young's modulus. In order to achieve this, a comprehensive set of 16 experimental trials were carried out, involving the preparation of eight distinct formulations characterized by varying Seger values and ratios which were subsequently subjected to sintering at two distinct firing temperatures. The analysis was conducted through a comprehensive correlation matrix, revealing significant relationships between composition, phase content and the final properties. The glassy phase emerges as a key contributor, positively influencing bulk density, reducing water absorption and linear shrinkage, and enhancing Young's modulus. The coefficient of thermal expansion correlates positively with residual quartz and inversely with mullite content, highlighting their impact on this property. Strength is positively correlated with mullite content, while quartz, albite, and anorthite phases exhibit negative correlations due to their intricate influence on the overall microstructure. These findings provide essential insights into the complex interplay between composition, microstructure and properties, contributing to the advancement of materials engineering for tailored porcelain tiles.

Effect of NaCl replacement by other salt mixtures on myofibrillar proteins: Underlining protein structure, gel formation, and chewing properties.

The protein structure, gel changes, and chewing properties of low-sodium myofibrillar protein (MP) prepared by compound chloride salts (KCl/MgCl2, KCl/CaCl2, and KCl/MgCl2/CaCl2) and different substitution degrees (10%, 25%, and 40%) at same ionic strength (0.6M) were investigated. The results revealed that the low-sodium MP gels containing CaCl2 manifested more liquid loss and less moisture content accompanied by obvious morphological shrinkage, while KCl/MgCl2 contributed to the gel juiciness. At high substitution degree of 40%, KCl/CaCl2 substitution rendered the gel with dense structure and highest strength, but worse water retention capacity. Using other compound chloride salts influenced the chewing efficiency, and CaCl2 substitution made the gel relatively hard to chew. The inhomogeneous structure accompanied by cluster blocks in KCl/CaCl2-substituted MP gel accelerated the overall fracture rate. During heating process, more proteins in CaCl2-substituted MP did not participate in gel formation, intervening the final gel properties. The chloride salt mixtures containing MgCl2, rather than CaCl2, avoided or alleviated the liquid loss and shrinkage of low-sodium MP gel within the substitution degree of 10%-40%, and substitution degree not exceeding 25% was more reasonable for the controlled qualities.

Improving melt pool depth estimation in laser powder bed fusion with metallic alloys using the thermal dose concept

Laser-matter interactions in laser powder bed fusion for metals (LPBF-Ms) significantly impact the final properties of the fabricated components. Critical process parameters, such as the linear energy density (LED), the ratio of laser power to scan speed, modify the energy input and consequently modify the melt pool geometry. LED strongly influences the melt pool cross-sectional profile, which dictates the thermal effects, microstructure, and mechanical properties of the finished part. Recognizing the crucial role of the melt pool in additive manufacturing, researchers have developed predictive models to estimate its dimensions and morphology. These models aid in tailoring part properties, optimizing process parameters, and reducing the number of experimental trials. However, existing models are either computationally expensive or analytically overly simplified for general LPBF-M applications. This study proposes an improved model that incorporates the Rosenthal equation as described by Tang to increase the accuracy of melt pool depth prediction. By using the thermal gradient per unit time, termed the “thermal dose” in this paper, corresponding to the LED value that produces experimental near-semicircular melt pool shapes for each studied material, we can improve the melt pool depth estimation. The trend revealed a good fit across the LED range compared with experimental measurements, suggesting the model’s effectiveness.

Impact of Carbon Source on Bacterial Cellulose Network Architecture and Prolonged Lidocaine Release

The biosynthesis of bacterial cellulose (BC) is significantly influenced by the type of carbon source available in the growth medium, which in turn dictates the material’s final properties. This study systematically investigates the effects of five carbon sources—raffinose (C18H32O16), sucrose (C12H22O11), glucose (C6H12O6), arabinose (C5H10O5), and glycerol (C3H8O3)—on BC production by Komagataeibacter hansenii. The varying molecular weights and structural characteristics of these carbon sources provide a framework for examining their influence on BC yield, fiber morphology, and network properties. BC production was monitored through daily measurements of optical density and pH levels in the fermentation media from day 1 to day 14, providing valuable insights into bacterial growth kinetics and cellulose synthesis rates. Scanning electron microscopy (SEM) was used to elucidate fibril diameter and pore size distribution. Wide-angle X-ray scattering (WAXS) provided a detailed assessment of crystallinity. Selected BC pellicles were further processed via freeze-drying to produce a foam-like material that maximally preserves the natural three-dimensional structure of BC, facilitating the incorporation and release of lidocaine hydrochloride (5%), a widely used local anesthetic. The lidocaine-loaded BC foams exhibited a sustained and controlled release profile over 14 days in simulated body fluid, highlighting the importance of the role of carbon source selection in shaping the BC network architecture and its impact on drug release profile. These results highlight the versatility and sustainability of BC as a platform for wound healing and drug delivery applications. The tunable properties of BC networks provide opportunities for optimizing therapeutic delivery and improving wound care outcomes, positioning BC as an effective material for enhanced wound management strategies.

Shrouding Gas Plasma Deposition Technique for Developing Low-Friction, Wear-Resistant WS2-Zn Thin Films on Unfilled PEEK: The Relationship Between Process and Coating Properties

In this study, tungsten disulfide–zinc (WS2-Zn) composite films were generated on polyether ether ketone (PEEK) disks by an atmospheric pressure plasma jet (APPJ) equipped with a shrouding attachment. The friction and wear properties of the WS2-Zn coatings were intensively investigated by using a rotational ball-on-disk setup under dry sliding and ambient room conditions. In order to gain more information about the lubrication mechanism, the coating areas as deposited and the worn areas (i.e., in the wear track) were analyzed with a scanning electron microscope (SEM) with regard to their chemical composition in depth by energy-dispersive X-ray spectroscopy (EDS). X-ray photoelectron spectroscopy (XPS) was conducted to obtain precise chemical information from the surface. The results indicated that WS2-Zn coatings significantly improved the tribological properties, exhibiting a coefficient of friction (COF) of <0.2. However, the tribological performance of the coatings is strongly dependent on the plasma process settings (i.e., plasma current, dwell time of the powder particles in the plasma jet), which were tuned to reduce the oxidation by-products of WS2 to a minimum. The COF values achieved of the dry lubricant films were significantly reduced in contrast to the uncoated PEEK by a factor of four.

Mechanical and high-temperature steam oxidation properties of Cr coatings deposited via high-power impulse magnetron sputtering

Applying protective coatings to Zr alloy cladding surfaces is one of the better methods to design fuel tolerant materials. In this study, the surface of a Zr-4 alloy was coated with Cr using high-power impulse magnetron sputtering. Furthermore, the mechanisms by which bias voltages affect the mechanical characteristics, resistance to high-temperature steam oxidation, and coating structure were elucidated. The coating exhibits a strong (200) weave structure with coarse grains at a bias voltage of -100 V. With increasing bias, the energy of deposited particles increases, grains continue to grow, (200) preferential growth orientation disappears, and the coating exhibits a (110) crystal orientation. The growth structure of the coating first shows a tendency to be dense and then loose. For the Cr coating with a (200) crystal orientation, a dense oxide layer is preferentially formed after oxidation, which can effectively block the internal diffusion of O. With increasing oxidation time, coarse Cr grains can effectively block the external diffusion of Zr. Furthermore, the Cr coating exhibiting a (110) crystal orientation was severely oxidized after oxidation, resulting in the formation of cracks at the film base; this accelerated the outward diffusion of Zr.