Flame Propagation Research Articles

A new experimental method to study the flame inhibition performance of low concentration halogenated gas

The minimum fire extinguishing concentration is a key index for the development of next generation chemical clean fire extinguishing gases, which is usually got by the cup-burner. The fire suppression performance of low concentration of chemical gas is hard to be understood by the available methods. In this work, the fundamental acknowledgement of steady flame surface attacking mechanism by halon functional group is newly discussed by conducting a series of bench scale tests with a cylindrical channel under a varied fluorinated gases. The characteristics of flame propagation under differentiated air atmosphere environmental conditions is obtained. The influence of fluorine-containing gas flow rate on flame propagation speed is clarified. A dimensionless relationship including atomic radius, bond length, polarization degree, molar mass and molar volume are proposed to describe the influence of low concentration of fluorine-containing gas on flame propagation speed. It provides an insight for the understanding of the flame inhibition performance of low concentration halogenated gas.

The Hydrogen Vehicle in the Context of the Sustainable Development of the Green Road Transport System

Abstract The scientific work presents concrete research carried out by the authors to implement some concepts of technical and managerial nature, so that those interested in this field can get acquainted with a certain way of exposing the problems concerning the hydrogen-powered vehicle, in the context of the sustainable development of the ecological road transport system. At the moment, the car whose energy for propulsion is generated by means of hydrogen or hydrogen fuel cells does not enjoy a high popularity among users, due to the very high purchase price (where we have high technology, we also have a price to match - a fuel cell is more expensive than an electric battery), the reluctance of the population to use this type of fuel, defined by the danger of explosions and fires generated by hydrogen, and the lack of hydrogen refueling stations in Romania and in some European countries. The use of alternative fuels in internal combustion piston engines has the advantage of significantly reducing pollution due to combustion products. With regard to the direct use of hydrogen as a fuel in internal combustion piston engines, we can say that it has proved its inefficiency, because the hydrogen injected or sucked directly into the engine cylinders is unstable, produces uncontrolled burns and detonations, and in the liquid state it is very difficult to store, it requires special transport methods, hydrogen tanks must be armored with Kevlar because hydrogen in the event of a car accident can explode. For example, if we use it as a fuel in a diesel engine, hydrogen may not ignite itself because the self-ignition temperature in the cylinders of compression-ignition engines is high (600°C). However, at a normal stoichiometric ratio, hydrogen has a high flame rate, much higher than gasoline. This creates a thermodynamic cycle of the thermal engine almost perfectly, but ideally, let us not forget that in poor mixtures of air-hydrogen the flame propagation speed is considerably reduced. The compression ratio of the engine is of utmost importance because it is finally defining the thermal efficiency of the engine. In the following, we present a technical and managerial study with engineering nuances, through which readers can look and understand the stage of development, place and role of the vehicle propelled by hydrogen fuel cells. Finally, the conclusions and further directions of research and development in the field addressed are presented.

Effect of airflow velocity in vessel-pipelines on dust explosion during pneumatic conveying

In order to investigate the flame propagation and pressure characteristics of dust particles during airflow transportation, a dust explosion experimental apparatus simulating dust handling processes was designed. The system is supplied with a stable airflow by a high-pressure fan, capable of continuously transferring dust from the vessel to the pipeline at a controllable speed. Dust explosion experiments were meticulously executed by applying 1 kJ of ignition energy to the transported dust particles at airflow velocities of 5, 10, and 15 m/s. This study examines the effects of airflow velocity, pipe diameter, and ignition position on explosion characteristics and delves into the mechanisms of these effects through a detailed analysis of experimental results. For the maximum explosion pressure, an increase in airflow velocity causes the maximum explosion pressure to rise. As the pipe diameter increases, the maximum explosion pressure first rises and then falls. The maximum explosion pressure occurs in the case of bottom ignition. The range of maximum explosion pressure values is expected to provide a reference for explosion detection and explosion venting. For flame propagation, the flame undergoes five processes within the vessel, including ignition of dust particles, spherical flame development, flame stretching towards the mouth of the pipe, complete combustion of particles, and near exhaustion of particle combustion. The higher the airflow velocity and the larger the pipe diameter, the more pronounced the flame stretching and development towards the pipe opening become. Within the pipe, two distinct flame propagation behaviors were observed under conditions of high and low airflow velocities. Compared with the experimental results of high-pressure pneumatic powder spraying forming a dust cloud within a vessel-pipeline, this study measures the maximum explosion pressure at specific turbulence levels and establishes a quantitative relationship between airflow velocity and explosion characteristics. Utilizing this correlation can provide a reference for predicting industrial-grade dust explosion characteristics at different airflow velocity levels, thereby offering a more optimized design basis for the design and safety protection of industrial equipment.

A LES study on the instantaneous H2 jet-ignited combustion characteristics of H2/NH3 mixtures

This paper presents a Large Eddy Simulation (LES) study investigating jet flame ignition characteristics to achieve stable ammonia combustion for novel applications in gaseous ammonia/hydrogen-fueled engines with an active prechamber. The study investigated three cases with initial global equivalence ratios of 0.6, 0.8, and 1.0. Two main ignition modes were proposed, and five stages of coupled flame propagation processes were identified. The oscillation of supersonic hydrogen jet flame was investigated. The modes of flame-vortex interaction including vortex ring formation, along with the mechanism of highly reactive zone formation, were proposed. The effects of reactivity and turbulence transition on piloted ammonia flame were investigated to attain stable ammonia combustion and achieve a high heat release rate. The results showed that oscillations in the jet flame were strengthened at low global equivalence ratios with high hydrogen mass ratios. Enhancing propagation of initial and secondary vortex rings broadened highly reactive zones. Vorticity dissipated more rapidly at low equivalence ratios, leading to a stratified structure and enhanced piloted spherical flame. The Unsteady Flamelet Ignition Prediction (UFIP) sub-model of combustion was verified for the piloted ammonia flame, enabling a more comprehensive discussion of flame propagation tendencies.

Construction and combustion behavior of horizontal two-dimension combustion networks of boron-metal oxides

In order to break through the top-down combustion mode brought by the traditional pillars, it is explored to explore the exploration of delay composition array construction in two-dimensional dimensions. In this study, B-CuO, B-Bi2O3, B-Fe2O3 sticks and combustion networks with good forming properties were prepared with the help of a micro-pen direct ink writing device by dispersing the above materials in DMF with boron and metal oxides as the main body of the charge and F2602 as the binder. The sticks were thermally ignited using a nichrome wire, and the flame propagation behaviors of the sticks with different formulations, spacings and heights were tracked with a high-speed camera, and a series of combustion networks were designed on the premise of not leaping into flames. Results show that the B-CuO stick has the fastest ignition speed level (19.71–29.02 mm ·s−1) at equivalence ratios of 1.0–4.0, followed by B-Bi2O3 (5.99–16.01 mm ·s−1) and B-Fe2O3 is the slowest (1.91–4.94 mm ·s−1). The sticks burned best at an equivalence ratio of 1.0–1.5. A variety of combustion networks were constructed on 50 × 50 mm glass slides by selecting B-CuO, B-Bi2O3, and B-Fe2O3 at the equivalence ratios of 1.0, 1.5, and 1.5, respectively, among which B-CuO had the shortest combustion time (5.17 s), the shortest total combustion network length (252 mm), and 400 mm network could be realized for B-Bi2O3. Construction and 19.85 s, and B-Fe2O3 can realize 608 mm network length and 130.7 s combustion time. Through these studies, the two-dimensional combustion network construction of boron-metal oxides was realized, which provides a new idea for the delay action in small size.

Effects of partial fuel cracking on the forced ignition and spherical flame propagation in ammonia/air mixtures

As a zero-carbon fuel, ammonia has promising applications and thereby has received great attention recently. However, compared to traditional hydrocarbon fuels, ammonia has very low laminar flame speed and extremely high minimum ignition energy (MIE). A feasible method to promote ammonia combustion is partial fuel cracking, during which ammonia undergoes decomposition into hydrogen and nitrogen. This work reports a computational study on forced ignition and spherical flame propagation in partially cracked ammonia/air mixtures. The objective is to assess the effects of fuel cracking on the MIE and flame propagation. It is found that even a slight amount of ammonia cracking can significantly reduce the MIE and promote ignition. In addition, the influence of positive stretch rate on the spherical flame propagation speed, which is quantified by the Markstein length, is shown to be greatly affected by ammonia cracking. The mechanism of ignition promotion and change in spherical flame propagation by ammonia cracking is interpreted and discussed.

A comparative study on the combustion of lean NH3/H2/air ignited by pre-chamber turbulent jet ignition modes

Internal combustion engines fueled with mixtures of hydrogen (H2) and ammonia (NH3) are potential power devices for reducing carbon emissions. To improve the ignition and combustion performance of NH3/H2, turbulent jet ignition (TJI) can be used. This study aims to investigate NH3/H2/air combustion under TJI modes at low equivalence ratios. Considering that the adoption of the scavenging system is beneficial for improving the reactivity of the pre-chamber, the effect of active TJI with scavenging is also explored. The results show that injecting 1.2 times the initial mixture volume of air is optimal for scavenging, and the scavenging effect becomes significant as the NH3 fraction increases. Using conventional active TJI and active TJI with scavenging effectively improves ignition performance and flame propagation, reducing sensitivity to the equivalence ratio compared to passive TJI mode. Although the adoption of active TJI modes improves the lean flammability limit of NH3/H2, weak flame propagation may occur in the early stage of combustion under ultra-lean conditions. Appropriately increasing the injection of auxiliary H2 can effectively improve this phenomenon.

Experimental study on thermal runaway and flame eruption characteristics of NCM523 lithium-ion battery induced by the coupling stimulations of overcharge-penetration

The thermal runaway of lithium-ion batteries under extreme coupled abuse conditions has seriously hindered the sustainable development of lithium-ion new energy vehicles. To reveal the complex thermal runaway behavior mechanism of overcharged lithium-ion batteries induced and by nail penetration, In this paper, a coupled stimulated thermal runaway experimental platform was built, and experimental studies of overcharge-penetration coupled stimulated thermal runaway and flame eruption dynamics were carried out on 18650-type NCM523 lithium-ion batteries from macro and minutiae viewpoints, in which the states of charge (SOC) of the overcharged batteries were 100 %, 105 %, 110 %, 115 %, 120 %, 125 %, 130 %, 135 %, 140 %, 145 % and 150 %. The results showed that the maximum battery surface temperature during overcharging increased from 32.7°C at 100 % SOC to 66.1°C at 150 % SOC, an improvement of 102 %. The thermal runaway battery temperature increased from 529.0°C at 100 % SOC to 657.1°C at 150 % SOC, an increase of 24.2 %. The thermal runaway maximum flame temperature increases from 485.5°C at 100 % SOC to 983.9°C at 150 % SOC, an improvement of 102.6 %. The flame area of medium overcharged> high-level overcharged> low-level overcharged batteries and the flame area of thermal runaway increased by 22213.95 cm2 compared to the maximum of 100 % SOC, and the flame propagation speed of the batteries after thermal runaway showed that the greater the SOC, the stronger the intensity of the flame. The higher the degree of overcharging, the higher the danger of thermal runaway on the side of the battery and near the positive electrode, and the danger of thermal runaway in overcharged lithium-ion batteries increases with the increase of SOC.

Research on the flame oscillation characteristics of scramjet combustor equipped with strut fuel injector

The combustor is the core component of the scramjet engine, and stable combustion is the prerequisite for the efficient operation of the scramjet engine. This paper investigates combustion stability in a combustor with a thin strut for oxygen supplementation at the trailing edge. LES (Large eddy simulation) was carried out under the combustor inlet conditions of Ma= 2.8, Tt= 1680 K, and Pt= 1.87 MPa. The results show that as the amount of oxygen supplementation inside the combustor increases, the oscillation forward propagation characteristics of the flame front inside the combustor are formed. First, the combustion instability phenomenon of the flame inside the combustor is analyzed, and then the oscillation frequency of the flame is analyzed by FFT (Fast Fourier Transform) of the flame front and pressure and DMD (Dynamic Mode Decomposition) of the velocity field within one cycle. Finally, the flame forward propagation mechanism inside the combustor is analyzed by pressure-velocity-heat release distribution. The results show that the injection of excess oxygen inside the combustor forms a strong coupling phenomenon of flow and combustion, and the premixed gas downstream of the trailing edge of the strut forms a state of slow combustion to explosion, forming a flame propagation forward and periodic oscillation phenomenon.

Spontaneous ignition and flame propagation in hydrogen/methane wrinkled laminar flames at reheat conditions: Effect of pressure and hydrogen fraction

Direct numerical simulations (DNS) with detailed chemical kinetics and chemical explosive mode analysis (CEMA) are performed to investigate the effect of operating pressure and hydrogen–methane blending on laminar wrinkled flames at reheat combustion conditions. Building upon previous three-dimensional DNS datasets of reheat hydrogen flames, the present work considers two-dimensional configurations that render computationally-feasible simulations of high-pressure combustion and significantly more complex hydrocarbon chemistry. A geometrically-simplified representation of the reheat combustor is adopted and the thermodynamic states considered in the simulations are carefully chosen to mimic gas turbine operation conditions, which are constrained to achieve a target flame position and flame temperature. The two-dimensional DNS results are first assessed against the available three-dimensional data and then analyzed to extract the main trends exhibited by the reheat combustion process with respect to the fraction of the fuel consumed by spontaneous ignition and flame propagation, for increasing pressures and hydrogen fractions. Due to significant differences in the characteristic features of the velocity and thermal boundary layers between the three-dimensional and the two-dimensional configurations, a different global flame shape is observed (V-shaped flame vs W-shape flame) together with a ∼10% bias in the fraction of fuel consumed by spontaneous ignition. Crucially, results from the scaling studies reveal very clear trends with a significant decrease in the fuel consumption by spontaneous ignition for increasing pressures and hydrogen fractions, at the conditions investigated. Finally, this study highlights the important role that first-principle direct numerical simulations, even when conducted in computationally affordable two-dimensional simplified geometrical configurations, can play in obtaining detailed insights and quantitative trends useful for the characterization of complex reactive flows.Novelty and significanceThe reheat burners of the two-stage sequential gas turbine combustors are designed to stabilize flames primarily due to spontaneous ignition. However, prior numerical simulations revealed the presence of an additional assisted-ignition mode aided by recirculation zones. In this study, we used practically feasible two-dimensional direct numerical simulations of premixed hydrogen–air mixtures under lean conditions to quantify the roles of the two flame stabilization modes at different operating pressures. Achieving fundamental understanding of the effect of pressure and hydrogen fraction on flame stabilization is crucial to the development of two-stage sequential combustion and the present two-dimensional calculations provide important new insights. We show that at high pressures, both modes consume fuel to a similar extent. We also investigated the effect of methane blending on flame stabilization. This study also discusses how two-dimensional direct numerical simulations can be leveraged in the design optimization of reheat burners at low technology readiness levels.

Experimental study on ignition and flame propagation of premixed ammonia ignited by Direct-Injected diesel in an optical rapid compression Machine

Ammonia (NH3) is considered as one of the most promising zero-carbon fuels for internal combustion engines. Based on diesel engine modification, The ammonia/diesel dual-fuel mode with port injection of ammonia and in-cylinder direct injection of diesel has been proven to be the most feasible strategy. In this paper, the effects of ignition and flame propagation of premixed ammonia ignited by direct-injected diesel were studied based on an optical rapid compression machine (RCM). The results show that the spray and distribution of diesel play the key role in the ignition and flame propagation of NH3/diesel dual fuels combustion. For total excess air ratio (λT) of 1.0, the ignition delay of NH3/diesel with high energy ratio of ammonia (ER of 95 %) was much shorter than ER of 66 % which was mainly due to the low injection pressure of diesel. Under the same injection pressure, with the large nozzle diameter of diesel injector of 0.28 mm, the ignition delay of NH3/diesel will be shortened significantly. When the ER is low, the combustion process presents the characteristics similar to the multi-point compression combustion. When the ER rises to 83 %, the combustion process is mainly dominated by NH3 premixed combustion, and diesel mainly plays the role of ignition. Reducing the background pressure and temperature to 4 MPa and 887 K, respectively, NH3 is not able to be ignited by diesel.

Experimental study of NaHCO3/modified vermiculite composite powder for methane explosion suppression

Using a self-constructed experimental platform with 9.5 % methane as the explosive gas, the effects of various masses of NaHCO3, vermiculite, and NaHCO3/modified vermiculite composite powders on the explosion pressure, flame propagation shape, and flame propagation velocity of methane were investigated. The composite powders’ thermal stability and surface microstructure were examined, along with the mechanism of explosion suppression, using thermogravimetric analysis, XRD analysis, and particle size analysis. By comparing various data, 50 wt% NaHCO3/modified vermiculite composite powder with a mass of 360 mg showed the best detonation suppression effect, with Pmax and (dP/dt)max reduced by 53.3 % and 87.1 %, respectively, and Pmax arrival time extended by 142.9 %. The flame disappearance time reached 467 ms, which increased by 165.3 %, and the maximum flame propagation speed decreased by 40 %. Methane explosion suppression is achieved by adding NaHCO3/modified vermiculite composite powder, which prevents flame propagation and breaks the methane explosion chain reaction by chemical and physical suppression of methane explosion.

A facile and effective strategy for modifying combustion of Zr/KClO4 via adding Si

As a commonly applied ignition composition, Zr/KClO4 has attracted various interests and plenty of efforts have been made to improve the combustion performance. In this study, Si nanoparticles were incorporated into Zr/KClO4 by sonication. Around 2.5× peak pressure and 9.2× reactivity were achieved by Si/50%Zr/KClO4 when compared to Zr/KClO4. In addition, the peak pressure and pressurization rate of Si/Zr/KClO4 ternary systems are all superior to ones of both Zr/KClO4 and Si/KClO4 binary systems. The synergetic effect of Si/Zr/KClO4 is a combination of shorter ignition delay of Zr/KClO4 and more gas production of Si/KClO4, which is also reflected on the higher flame propagation rate of Si/Zr-based thermites than composites with pure Si or Zr as the fuel. Meanwhile, the heat release during the redox reaction has been measured. The results show ∼700–1000 J/g higher energy release than Zr/KClO4, and higher combustion efficiency can be attained by ternary systems than binary ones. Thus, adding Si powders is an effective way to improve the energetic behavior of Zr/KClO4 ignition composition, and Si/Zr/KClO4 ternary composites can be a promising candidate for application in pyrotechnics.

Energy release effect of micro-nano self-assembled aluminum powders and application in composite explosives

Nano aluminum powder effectively enhances reactivity, thereby improving energy-containing materials' performance. To investigate micro-nano self-assembled aluminum powders' energy output and their application in composite explosives, we tested the heat of combustion and ignition characteristics (ignition delay, ignition energy, flame propagation speed) using oxygen bomb calorimetry and Hartmann tube. Results showed that the combustion heat decreased with increasing nano aluminum powder content. The addition of nano aluminum powders substantially decreased ignition delay and energy, enhancing the combustion rate and reactivity of aluminum powder dust. The ranking of reactivity among the five aluminum powders was as follows: μ@n-Al-10 % > μ@n-Al-5% > μ/n-Al-10 % > μ/n-Al-5% > μAl. Assessing explosives containing various aluminum powders showed that the self-assembled 5 % content sample had the highest heat of detonation at 8490 kJ/kg. Mechanical sensitivity increased with higher nano aluminum powder content, with explosives containing 5 % nano content exhibiting the highest safety performance.

Effect of vent size on vented H2/N2/air deflagration

In this work, the coupling of explosion venting (vent size) and inerting (N2) on H2/air deflagration was investigated. Experiments were carried out in a vertical rectangular duct with an upper opening at an initial temperature and pressure of 280 K and 101 kPa, and a vent coefficient Kv was employed to replace the vent size to elucidate its effect on pressure buildup and flame propagation during H2/N2/air deflagration. In the present study, the internal pressure profile is monitored by three pressure sensors, PS1-3, which are installed at the bottom, center, and top of the duct, respectively, and the external pressure profile is obtained by PS4. The results show that the maximum internal overpressure (pmax) recorded by PS1-3 all increase with increasing Kv, but pmax obtained from PS2 and PS3 tend to increase linearly. For a given Kv, the maximum and minimum amplitudes of pmax are measured by PS1 and PS3, respectively. Specifically, the greater the distance between the pressure sensor and the upper opening, the greater the amplitude of pmax. The relationship between the maximum reduced explosion pressure (pred) and Kv is investigated, where pred is defined as the highest pmax for a specific Kv. As Kv increases from 2.2 to 11.9, pred increases from 26.25 kPa to 88 kPa. The maximum external flame velocity (Vext) increases from 83 m/s to 454 m/s with increasing Kv from 2.2 to 11.9. The amplitude of the maximum external overpressure (pext) first increases and decreases with an increase in Kv from 2.2 to 11.9. The formation time (Δt) of pext decreases and then increases and finally decreases with increasing Kv from 2.2 to 11.9. When Kv is increased from 2.2 to 4.1, all external fireballs are presented as mushroom shapes, but the external fireballs are gradually transformed into jet shapes for Kv ≥7.8. Two pressure oscillations, including Helmholtz oscillations and acoustic oscillations, are found. Acoustic oscillations are found in all tests, but Helmholtz oscillations are only observed for Kv ≤ 4.1.

Experimental Study on the Influence of Ignition Position on the Overpressure of Hydrogen Jet Flame.

The accidental leakage of hydrogen poses a significant barrier to the widespread adoption and development of hydrogen energy due to the potential risks of fire, explosion, and jet fire hazards. Experimental investigations have been conducted on the process of jet fires formed by igniting hydrogen jet streams after accidental releases in scenarios such as high-pressure hydrogen gas storage tanks and hydrogen transmission pipelines. These experiments utilized a release pipe with a diameter of 10 mm and a length of 0.75 m, along with three pressure sensors, to study the influence of release pressure and ignition position on jet flame overpressure and flame propagation. Extensive tests at 1.5 MPa yielded a hydrogen flammability map containing two nonflammable zones and one flammable zone, along with a graph illustrating the relationship between overpressure and ignition points. Furthermore, experiments conducted at ignition positions of 0.05, 0.5 and 1.0 m under release pressures ranging from 6 to 10 MPa revealed that release pressure had no significant effect, while ignition position notably influenced the waveform and peak of the shockwave. Additionally, a peak shockwave reaching 30 kPa was observed at the downstream of the pipe outlet when ignited at 0.05 m, far exceeding the threshold of 24 kPa associated with fatalities. This research aims to provide valuable insights for safety design and protection distance considerations in scenarios involving hydrogen release and ignition.

Effects of Fuel Bed Slope and Wind Direction on Flame Spread Characteristics Over a Bed of Pinus Silvestris Needles

ABSTRACT Important factors influencing the flame characteristics over a bed of dry pine needles from Siberian Boreal forests (Pinus silvestris) in lab-scale is provided. Factors such as slope of the fuel bed, wind velocity, and direction of spread (concurrent flow or opposed flow), which play significant roles in determining the flame spread rate, have been investigated. Systematic lab-scale experiments have been carried out in a wind tunnel with varying air velocities and on an inclined fuel bed in still air. Numerical simulations have been carried out using a three-dimensional physics-based flame spread model available in Fire Dynamics Simulator, and the results are validated against a wide range of measured flame characteristics. The validated numerical model is then used to simulate concurrent flow and opposed flow flame spread over a sloping fuel bed in the presence of wind. Gas phase temperature on and above the bed surface and total and radiative heat flux measurements for concurrent flow and opposed flow flame spread under the influence of wind as well as for upslope flame spread in still air are presented. A stationary flame propagation mode is observed for a flat fuel surface. Predicted temperature, flow, and species concentration fields have been reported for selected cases to understand the flow and flame dynamics in gas phase and within the fuel beds. These data serve as a validation of the numerical model used for simulating the experimental cases. Further, it can be used to validate popular fire models such as Fire Foam and Fire-Star 3D.

Optical study on spray mixing, flame propagation and jets evolution within visible methanol active pre-chamber for turbulent jet ignition

Methanol spray impingement, mixing, flame propagation and jet evolution within the narrow-confined active pre-chamber (APC) with complex walls were experimentally observed by optical method for the first time. The effects of injection pressure and duration was investigated on an actual-geometry optical APC assembled in constant volume combustion chamber (CVC). Exploration on APC internal processes within static environments forms the basis for optimization of APC and analysis of jet formation. Mie scattering coupled with flame natural luminosity imaging were used to record spray mixing and combustion. The results show that in the APC with narrow-confined space, methanol spray undergoes three wall impingements, inducing a tumble that promotes mixing. High injection pressure enhances rapid spray tip penetration, while long injection duration slows methanol diffusion. In longer injection duration cases, the spray tip after the third impingement interferes with subsequent sprays. For higher injection pressure, this interference occurs in the APC cone section due to a larger spray cone angle, whereas for lower pressure, it happens in the APC duct section. Higher injection pressure also causes more spray to impact the APC bottom after the first wall impingement, hindering flame acceleration in the duct section. Irregular flame propagation is observed in the APC cone section due to wider space and uneven mixture conditions, while the convergent geometry from the APC throat to the duct section significantly accelerates flame propagation. The APC jet appears due to the pressure difference between the APC and the main chamber, with the brightness and length of the visible flame jet increasing with APC flame luminosity and pressure difference. A Mach ring structure is observed initially, but the jet velocity decreases as the Mach ring disappears during the APC inner flame extinguishing process. Through this study, the actual spraying and combustion process in APC is experimentally captured and revealed, which are an important contribution for APC optimization and development.

Study on the combustion characteristics and reaction mechanism of aluminum/alcohol-based nanofluid fuel

Enhancing the volumetric energy density of fuels is a crucial approach in the exploration of efficient energy sources. As a commonly used high-energy additive, Aluminum nanoparticles (Al NPs) holds broad application prospects. This study delves into the effects of Al NPs on the combustion characteristics of methanol and ethanol fuels through in-depth analysis of single droplet combustion and spray combustion experiments involving alcohol-based nanofluid fuels. The experiments revealed that adding Al NPs significantly enhances fuel combustion efficiency, shortening both the combustion life and ignition delay time. Spray combustion tests demonstrated that adding 2 wt% Al NPs increased the maximum and average flame propagation speeds of ethanol fuel spray by 48.93 % and 47.94 %, respectively, while the maximum explosion pressure rose from 0.66MPa to 0.83MPa, with a reduced time to reach peak explosion pressure by 106ms. Based on the SEM and XRD characterization results of the combustion residues and the analysis of flame morphology, a physical model of the alcohol-based nanofluid fuel spray combustion flame was established. Numerical simulations of the gas-phase kinetics model showed that the generation rates of radicals such as H, O, and OH were significantly increased with the addition of Al NPs, intensifying the combustion reaction. The findings provide a theoretical basis for future fuel design and combustion performance optimization.

The effect of jet disturbance on flame propagation characteristics of multi-component natural gas/hydrogen mixed fuel

Gas explosions mostly occur in turbulent environments in practical situations. Meanwhile, the current research on the explosion characteristics of hydrogen-doped natural gas is mostly methane/hydrogen mixed fuel, ignoring the influence of other components of natural gas on the explosion characteristics of the actual situation. Therefore, the effects of different jet intensities (Pjet), hydrogen-doping ratios (XH2) and equivalence ratios (φ) on the explosion characteristics of multi-component natural gas/hydrogen mixed fuel are experimentally investigated in cylindrical tanks of 30 L. Additionally, it extensively explored the dual influence of jet disturbance and gas inerting effect on the flame propagation characteristics of multi-component natural gas/hydrogen mixed fuel. With the increase of Pjet, both Pmax and (dp/dt)max initially increase and then decrease, while τ continuously decreases. When Pjet = 0.4 MPa, the promotion effect on Pmax and (dp/dt)max is most significant. The lifting of XH2 leads to a gradual increase in Pmax and decreasing τ. (dp/dt)max exhibits a trend of initially increasing and then decreasing with the elevation of XH2, reaching its maximum at XH2 = 40%. The introduction of jet flow significantly reduces the promotion or inhibition effect on explosions of high hydrogen blending ratio mixtures. Furthermore, the introduction of jet flow is more effective in promoting the explosive performance of multi-component natural gas/hydrogen mixed fuel with high equivalence ratios and low hydrogen doping ratios under rich fuel conditions. This study can provide a key reference for the explosion hazard assessment during the practical application of natural gas/hydrogen mixed fuel.