Prograde Metamorphism Research Articles

West Siberian sedimentary basin. Crustal subsidence caused by rock contraction in its lower part due to prograde metamorphism

The history of the crustal subsidence in the Mesozoic and Cenozoic in the West Siberian Basin – the largest sedimentary basin in the world – is considered. Most researchers associate its formation with post-rift subsidence of the crust, which followed an episode of strong lithospheric stretching about 250 million years ago near to the Permian to the Triassic transition. A characteristic feature of post-rift subsidence is a decrease in its rate in time. During the Mesozoic-Cenozoic history, in Western Siberia the rate of crustal subsidence should have slow down by an order of magnitude. However, the analysis of long (700–900 km) seismic profiles in the north of Western Siberia and in the Southern Kara Sea shows that since the beginning of the Mesozoic in these regions, on average, there has been an acceleration of the crustal subsidence. Under such circumstances, lithospheric stretching in them could be responsible for only a small part of the total subsidence of the crust of 6–7 km. In Western Siberia, the Earth’s crust is close to the isostatic equilibrium. Then, in the absence of strong stretching, the accumulation of thick sedimentary sequences in the basin could only have been caused by rock contraction in the lower crust due to prograde metamorphic reactions. To obtain the above results, we used, for the first time, some simple methods to analyze the structure of the sedimentary cover in the West Siberian Basin. Detailed seismic profiles have been published for many other deep basins on all the continents. The methods of their interpretation implemented in this paper can be easily applied to determine the role of lithospheric stretching in the formation of deep sedimentary basins on the global scale.

Polymetamorphism and metastability in Paleozoic schists of the central Appalachian Baltimore Terrane, USA

Metapelitic assemblages are often considered highly reactive during prograde metamorphism, such that they effectively record a history of tectono-metamorphic processes. Across eastern North America, metamorphosed rift-to-drift stratigraphy has been central to disentangling the terminal history of Appalachian convergence. We report results from a single metapelitic outcrop in the Loch Raven Schist of Maryland's Baltimore Terrane, where regional metamorphism is historically interpreted to have derived only from the Ordovician Taconic orogeny. An aluminum-rich litho-horizon alludes to two phases of metamorphism: an early, low/medium-pressure (P) sillimanite-stabilizing phase largely overprinted by a subsequent medium/high-P kyanite-stabilizing event, terminating at c. 391–383 Ma. This provides evidence of substantial crustal disturbances in the central Appalachians during Avalonian collision of comparable timing to equivalent events in the north. In a subordinate and aluminum-poor litho-horizon, large (2–3.5 cm) garnet provides geochronological evidence only for a protracted phase of metamorphism at 440–424 Ma. We interpret this age as recording the early, low/medium-P phase of metamorphism that either: (a) extends the duration of the Taconic event; or (b) provides new evidence for metamorphism associated with Silurian tectonism and/or extension in the Central Appalachians. However, this assemblage appears to have been metamorphically unresponsive during Devonian overprinting, despite peak metamorphic conditions of ∼670 °C and ∼8 kbar. We suggest that a potential combination of the paucity of fluid, limited strain accumulation, and coarse refractive assemblages stabilized a kinetically sluggish and metastable composition.

Ca–Zn isotope fractionation during fluid–rock interaction in subduction zones and its implication for deep carbon cycle

Subducting slabs transport Earth's surface carbon into the deep mantle, with a portion of this carbon potentially recycled through volcanic eruptions at mid-ocean ridges or ocean islands. Non-traditional stable isotopes such as calcium (Ca) and zinc (Zn) are increasingly used to trace this deep carbon cycle. However, the potential for Ca and Zn isotope fractionation in the subduction zone, critical for the successful application of these tracers, remains insufficiently explored. In this study, we investigate high-pressure carbonated metamafic rocks and enclosed vein systems from a Paleo-oceanic subduction complex (SW Tianshan) to explore the possible fractionation of Ca and Zn isotope during subduction-related metamorphism and fluid–rock interaction. The δ44/40Ca (0.77 ‰–0.90 ‰) and δ66Zn isotope compositions (0.20 ‰–0.39 ‰) of greenschist-, blueschist- and eclogite-facies metabasites are consistent with their protoliths (OIBs and MORBs). We observe no systematic fractionation of either Ca and Zn isotopes across prograde metamorphism and associated dehydration. However, the precipitation of carbonate in surrounding rock along fluid pathways leads to an increase in the δ44/40Ca of residual fluids (>0.90 ‰). More significantly, we find detectable Zn isotope fractionation (ΔA-H = ẟ66Znaltered - ẟ66Znhost of 0.06–0.10 ‰) during fluid-mediated metasomatism of some blueschists/eclogites. Light Zn isotopes are preferentially released into the infiltrating fluid, resulting in an elevated δ66Zn isotope composition in the immediate carbonated eclogites along the vein. The modified slab fluids during migration are likely charactered by heavy δ44/40Ca and light δ66Zn compositions, which may play a crucial role in determining the low δ66Zn values found in some arc lavas. However, the MORB-like δ44/40Ca compositions observed in global arc magmatic rocks suggest that the slab-released Ca (possibly along with some carbon) is probably sequestered and stored along the migration path of the fluid, thereby hindering the slab–arc carbon recycling. Our study emphasizes that intraslab fluid–rock interaction results in similar δ44/40Ca and δ66Zn signature in carbonate-bearing eclogites compared to sedimentary carbonates. Consequently, deeply subducted carbonate-bearing eclogites –not necessarily sedimentary carbonates– might carry light δ44/40Ca and heavy δ66Zn signatures into the deep mantle, potentially influencing the corresponding Ca-Zn isotope compositions of some mantle-derived basalts.

The Permian Watershed tungsten deposit (northeast Queensland, Australia): fluid inclusion and stable isotope constraints

The Watershed scheelite deposit is located in an extinct fore-arc basin in the Mossman Orogen of North Queensland. This fore-arc region comprises multiply deformed, Ordovician–Silurian metasedimentary rocks of the Hodgkinson Formation, and it was intruded by Carboniferous–Permian granites of the Kennedy Igneous Association. At Watershed, the Hodgkinson Formation includes strongly deformed skarn-altered conglomerate, psammite and slate units, which record four deformation events that evolved from ductile (D1–3) to brittle–ductile (D4). Early, D1–2 scheelite mineralisation in Carboniferous monzonite and skarn-altered conglomerate formed during regional prograde metamorphism, which reached upper greenschist to lower amphibolite facies conditions. Permian, D4 scheelite mineralisation was deposited in transtensional, shear-related veins, vein haloes and skarn-altered conglomerate during retrograde, lower greenschist facies metamorphism. During D4, four stages of retrograde alteration (retrograde stages 1–4) affected the rocks. Fluid inclusion assemblages in retrograde stage 2, vein scheelite and quartz are characterised by a low-salinity H2O–NaCl ± CH4 fluid (XCH4 <0.01, 1.4–8.0 wt% NaCleq). The fluid inclusions show evidence for fluid mixing between a low (∼0 wt% NaCleq) and a medium (<8 wt% NaCleq) saline fluid. Scheelite mineralisation P–T conditions were determined at ∼300 °C and 1–1.8 kbar (i.e. a depth of 3.7–6.7 km), indicative of a high geothermal gradient (35–75 °C/km), which was likely caused by the heat from the Permian granites. The presence of pyrrhotite and arsenopyrite in D4 veins (retrograde stage 4), plus graphite and methane in the fluid inclusions in scheelite, indicates reduced mineralisation conditions. Oxygen isotope compositions (δ18OVSMOW) of retrograde stage 2 scheelite (+3.8 to +7.3‰), plagioclase (+7.0 to +11.8‰) and quartz (+12.6 to +15.5‰) indicate a fluid temperature of 306 ± 56 °C with δ18OVSMOW values between +4.7 and +8.3‰. Retrograde stage 3 muscovite δDVSMOW (−73.4 to −62.7‰) and δ18OVSMOW (+11.5 to +13.2‰) values were used to calculate the O–H isotopic compositions of the fluids in equilibrium with the minerals at various possible temperatures (250–300 °C). The results are consistent with a metamorphic origin for the mineralising fluid. Sulfur isotope compositions (δ34SCDT between −2.5 and +2.8‰) for vein-hosted, retrograde stage 4 sulfides indicate that sulfur could have come from seawater or seawater sulfate, which is consistent with the local geology, even though this range overlaps with magmatic sulfur isotope compositions. Metamorphic fluids probably originated from devolatilisation reactions in the Hodgkinson Formation during prograde metamorphism. Permian intrusions acted as heat source enhancing metamorphic fluid flow and metal transport.

Petrofabric and Raman microspectroscopy study of the Mina Afortunada gneiss dome: Mapping its thermal gradient

Black quartzites and migmatitic orthogneisses from the Mina Afortunada dome have been analysed through quartz and graphite petrofabric analysis and Raman microspectrometry on graphitized carbonaceous material. The results permit us to recognize a deformation temperature increase from the dome envelope towards its core marking the transition from basal-<a> to rhomb-<a> quartz intracrystalline slip systems at maximum T of 475 °C, and from rhomb-<a> to prism-<a> at maximum T of 515 °C. The complementary petrofabric and Raman study on graphite discloses a change from basal to prismatic <a> slip systems at maximum T of ca. 470 °C, accompanied by a strengthening of its structural order.The Raman study of large graphite grains revealed a non-random crystallinity organization in them, with domains of weaker lattice structural order (reflecting lower formation T) in core areas and higher crystallinity sectors (higher formation T) at the rims. This finding might reflect a shielding effect during prograde metamorphism, the rim material preventing grain core material from reorganization and increase in its crystallinity. This study shows also that graphite can be a good candidate for pressure-temperature-time path reconstruction in metamorphosed organic-rich rocks.

Evidence for isotopically light Fe mobility under oxidising conditions in subduction zone fluids: A record of Monviso meta-serpentinites, Western Alps

The isotopically light Fe signature of arc magmas relative to mid-oceanic ridge basalts (MORB) is expected to be related to the redox state of their source. This implies a link between Fe mobility and redox variations across subduction zones. Here we address slab chemical variations during prograde metamorphism through a comprehensive geochemical study, including major, trace elements and Fe stable isotope (δ56Fe) analyses, of meta-serpentinites composing the eclogitic meta-ophiolite of the Monviso massif (Western Alps, Italy). These rocks partly preserve mantle related geochemical heterogeneities, as supported by negative correlations between fluid immobile elements (High Field Strong Elements) and LREE/HREE (Light – Heavy Rare Earth Elements) ratios. They are however characterized by large Cs enrichments relative to U or alkali elements suggesting that abyssal fluid mobile elements signature was overprinted by subduction related processes. Meta-serpentinites display large δ56Fe variations, from -0.20 ± 0.05 ‰ to +0.09 ± 0.03 ‰. Mineral separate analyses of olivine bearing veins show low Δ56Fe between olivine and magnetite (∼ 0.4 ‰), which according to Fe isotope thermometry correspond to high temperature equilibration, estimated between 530 and 550 °C, compatible with Monviso metamorphic climax (520–570 °C and 2.6–2.7 GPa). These results, in combination with geochemical modelling, confirm a reset of δ56Fe signature of abyssal serpentinites during prograde metamorphism in subduction zones. The bulk rock δ56Fe values of Monviso meta-serpentinites are negatively correlated with their Fe3+/∑Fe and As concentrations (a redox-sensitive and fluid mobile element). These correlations can be attributed to a metasomatism by external fluids derived from slab serpentinites during subduction. It also concords with the oxygen fugacity (fO2) record in meta-serpentinites, with meta-serpentinites equilibrated at high fO2 displaying the lowest δ56Fe values while samples equilibrated at low fO2 display mantle like δ56Fe signatures. These results highlight that oxidising conditions during serpentinite dehydration are likely to boost isotopically light Fe mobility in slab derived fluids.

METAMORPHISM AND DEFORMATION OF GOLD-BEARING NEOPROTEROZOIC WONAKA SCHIST BELT, NORTHWEST-NIGERIA.

The role of metamorphism and deformation is indispensable in the occurrences of gold mineralization worldwide. In this work, deformation and metamorphic conditions for gold-bearing Neoproterozoic Wonaka Schist Belt; located around Kutcheri town of Tsafe Local Government of Zamfara State, was investigated. This is achieved using metamorphic litho-minerals obtained from ternary plots via X-Ray fluorescence (XRF) geochemical data, and directly using minerals phases from X-Ray Diffraction (XRD) technique. Index minerals identified from petrographic analysis previously suggest low to medium-grade metamorphism (M1). XRD analysis indicates quartz, albite, oligoclase, microcline, chlorite, and biotite, suggesting greenschist to lower amphibolite facies (M2). Sillimanite, andalusite, kyanite, staurolite, chlorite, biotite, and garnet were identified from the ternary plots using XRF major oxides, indicating upper amphibolite to granulite facies metamorphism (M3). This is typical of prograde metamorphism, granulite facie metamorphic grade is indicated. Na2O/Al2O3 versus K2O/Al2O3 for petrogenetic character suggests shale provenance, while the trace elements spider diagram indicates Wonaka litho-units as co-genetic compositionally, as high concentrations of V and Cr linked the petrogenetic affinity to mafic sources. Three circles of deformations are indicated; ductile deformation (D1) of the paleosome Schist producing foliations and lineation, brittle type (D2) in mid Pan-African and was accompanied by several fractures and felsic intrusions. Late Pan-African (D3) involves the folding of banded orthogneisses, the development of boudinage as well as intense shearing (ductile fault). Geospatial analysis of the fractures suggests that they represent regional Pan-African sutures cross-cutting Nigeria into the Atlantic and up to South American plate. The research therefore concludes that Au-fluid emanating through this regional event, utilizes D2 as channel ways and loci. D3 with M3 engulfed the entire structures repositioning the geometry to its present disposition.

Simulation of microtextural evolution in omphacite: Ordering transformation kinetics as unexplored archives of slab eclogitization

Earth's subduction zone processes and surface environments are intricately governed by mass transfer phenomena at plate convergent boundaries. The determination of their rates and timings from high-pressure metamorphic rocks (e.g., eclogite), or remnants of ancient convergent boundaries, remains an ongoing challenge. Here, we proposed the potential and versatility of ordering transformation kinetics of omphacite, an essential mineral found in eclogite, as a dynamic recorder of the metamorphic history. Through macroscopic phase-field simulation, we explored the growth of antiphase domains (APDs) in metastable disordered omphacite, discussing the feasibility of constraining metamorphic reaction kinetics based on the size and morphology of omphacite APDs in eclogitized oceanic crust. Our simulation corroborated that omphacite nucleating later during the prograde metamorphism can exhibit an incompletely ordered state with sparsely distributed ordered domains, which suggests their usefulness in estimating the recrystallization timing of the omphacite. Additionally, we confirmed that the APD formation dynamics are significantly influenced by the initial cation configuration of the disordered matrix. This implies the APD morphology in natural omphacite under slab-surface conditions may reflect their precipitation kinetics. These findings provide valuable insights into the microtextural evolution of omphacite due to its ordering transformation, thereby enhancing our ability to interpret morphological features.

Abiotic synthesis of graphitic carbons in the Eoarchean Saglek-Hebron metasedimentary rocks

Graphite in metasedimentary rocks of the Eoarchean Saglek-Hebron Gneiss Complex (Canada) is depleted in 13C and has been interpreted as one of the oldest traces of life on Earth. The variation in crystallinity of this oldest graphitic carbon could possibly confirm the effect of metamorphism on original biomass, but this is still unexplored. Here, we report specific mineral associations with graphitic carbons that also have a range of crystallinity in the Saglek-Hebron metasedimentary rocks. Petrographic, geochemical and spectroscopic analyses in the Saglek-Hebron banded iron formations suggest that poorly crystalline graphite is likely deposited from C-H-O fluids derived from thermal decomposition of syngenetic organic matter, which is preserved as crystalline graphite during prograde metamorphism. In comparison, in the Saglek-Hebron marble, disseminations of graphite co-occur with carbonate and magnetite disseminations, pointing to abiotic synthesis of graphitic carbons via decarbonation. Our results thus highlight that variably crystalline graphitic carbons in the Saglek-Hebron metasedimentary rocks are potential abiotic products on early Earth, which lay the groundwork for identifying the preservation of prebiotic organic matter through metamorphism on Earth and beyond.

Mesozoic orogenic gold metallogenesis at the Bangong–Nujiang suture belt, central Tibet: Constraints from pyrite textures, composition and sulfur isotope of the Shangxu gold deposit

Pyrite is a good carrier to provide gold within a hydrothermal mineralization system. Under prograde metamorphism, recrystallization of sedimentary and diagenetic pyrite and transformation of pyrite into pyrrhotite in a metamorphic terrane lead to the release of trace elements from the pyrite carrier into an upward migrating liquid phase carrier. In this case study, we report the in situ trace element and δ34S compositions of the pyrite from four different stages, which chronologically comprise sedimentary Py1, diagenetic Py2, metamorphic Py3a, Py3b and hydrothermal Py4a, Py4b, Py5, and the dominant sulfides from the hydrothermal stage at Shangxu, an Early Cretaceous turbidite-hosted orogenic gold deposit in the middle Bangong–Nujiang suture belt (BNSB) in central Tibet, in order to decipher the ore-forming material source and the metallogenesis of the Mesozoic orogenic gold mineralization in the BNSB. Concentrations of trace elements, i.e., Au, Co, Cu, Zn, Mo, Ag, Sb, Te, Hg, Tl, Pb and Bi, that are easy to dissolve during pyrite recrystallization, show a general progressive decline from Py1 to Py4b (excepting in Py3b and Py4a, which have a sudden rise in trace element composition) and a plunge in Py5, indicating that Py1 and Py2 supply the parent source minerals for mineralization, and that the main ore-forming stage are contemporary with the deposition of Py3b and Py4a, ending up with the precipitation of Py5. The δ34S values of pyrite narrow from −46.7 ‰–19.3 ‰ (Py1, Py2), through −7.6 ‰–0.2 ‰ (Py3a, Py3b), to − 3.6 ‰–5.7 ‰ (Py4a, Py4b) and −7.7 ‰–5.6 ‰ (Cp, Gn), indicating that a probable coeval seawater sulfate sulfur source for Py1 and Py2 (by bacterial sulfate reduction), and an inherited sulfur source from Py1 and Py2 for Py3 and Py4. We highlight that contributions from the magmatic materials to the hydrothermal gold mineralization are limited at Shangxu, and the widely distributed Lower–Middle Jurassic pyrite-rich turbidite of the Mugagangri Group is a highly potential primary source rock for the regional gold mineralization.

Timing and origin of gold mineralization in the Neoproterozoic Xixano Complex, Mozambique Belt, northeastern Mozambique: Case study of the Nanlia and Makorongo prospects

The metallogeny of gold in northeastern Mozambique is still debated, with the main point of contention being the timing of mineralization with respect to regional tectonism, metamorphism, and magmatism. In this study, we applied Re–Os sulfide geochronology to constrain the age of gold mineralization in the Nanlia and Makorongo prospects hosted by the Xixano Complex, in the southern part of the Mozambique Belt. In addition, chemical analyses of host rocks and sulfides complement the discussion on the genesis of mineralization. Single-mineral Re–Os model ages of pyrite and pyrrhotite in quartz veins constrain the occurrence of gold mineralization in the Nanlia and Makorongo prospects between ca. 580 and ca. 560 Ma. This mineralization age interval postdated the timing of peak metamorphism of the host rocks established at ca. 631–607 Ma and is contemporaneous with the metamorphism of basement rocks between ca. 607 and ca. 564 Ma, during the thrusting of tectonic nappes in the last stage of the Pan-African orogeny. In addition, the strike of the veins in the Nanlia and Makorongo prospects is parallel to the local orientation of the thrust fault that separated the overlying rocks from the basement rocks and the dominant S1 foliation of the host rocks. These geochronological and structural data indicate a close relationship between auriferous veins in the study area and the Pan-African thrust fault associated with the emplacement of the tectonic nappes. We propose a metamorphic model for the gold mineralization in the Nanlia and Makorongo prospects, in which the mineralizing fluids were sourced mainly from dehydration of basement rocks, as a result of prograde metamorphism triggered by the juxtaposition of the Neoproterozoic tectonic nappes, including the Xixano Complex, during the last stage of the Pan-African orogeny. The mineralizing fluids ascended through the Pan-African thrust faults and structures to the overlying rocks, where the gold was deposited along the S1 foliation.

Orogen‐scale uniformity of recorded granulite facies conditions due to thermal buffering and melt retention

AbstractGranulite facies metapelitic gneisses collected over a km exposed area of the Kakamas Domain of the Namaqua–Natal Metamorphic Province in southern Namibia all contain similar garnet–sillimanite–cordierite–biotite–quartz–K‐feldspar–ilmenite plagioclase magnetite mineral assemblages. These assemblages are interpreted to have equilibrated at suprasolidus retrograde conditions, and most samples contain distinct biotite‐ or sillimanite‐free peak assemblages. Pseudosection modelling constrains extremely uniform residuum solidus conditions of kbar and °C for the entire Kakamas Domain. Estimated peak metamorphic conditions overlap with these but are more smeared out at between 4 and 7 kbar at 760°C to potentially more than 900°C. The uniformity of residuum solidus conditions is not coincidental, but is a consequence of retrograde re‐equilibration due to minor melt retention after peak metamorphism. Re‐equilibration could only stop once all retained melt had crystallized, which required the concomitant growth of a hydrous mineral to account for its H2O component. Biotite is the most stable hydrous mineral in these rocks, such that the residuum – conditions in the Kakamas Domain reflect the upper‐ stability of biotite, and also corresponds to the intersection of the well‐known biotite–sillimanite melting reaction that consumed all biotite during prograde metamorphism. The calculated melt fertility of the sample suite indicates that the variable amounts of heat consumed to overcome the latent heat of fusion could have caused a 25°C spread in the peak temperature achieved by the most and least fertile samples. Peak temperature in the Kakamas Domain may have been as much as 100°C higher than residuum solidus conditions for specific samples but cannot be confidently constrained as it is obscured by the effects of both thermal buffering during prograde metamorphism and melt retention during retrograde metamorphism. Both processes are an inescapable part of the evolution of all granulite facies rocks, but their effects are most pronounced in fertile rocks like metapelites that are traditionally the preferred lithology for quantifying the – history of exhumed terranes.

Petrogenesis and Geodynamic Evolution of the Archean Shawmere Anorthosite Complex and Associated Gneisses, Kapuskasing Uplift, Superior Province, Canada

Abstract In this study, we integrated extensive field, petrographic, whole-rock major and trace element, and Nd–Pb–Sr–O isotope, and zircon U–Pb ages, trace element and Lu–Hf isotope data from the Neoarchean Shawmere Anorthosite Complex and surrounding gneisses to unravel their petrogenetic origin and tectonic history. The ~2765 Ma Shawmere Anorthosite Complex is interpreted to have been emplaced into a sequence of interlayered greywacke and basalt deposited in an intra-continental arc rift system above a north-dipping subduction zone. The complex consists mainly of anorthosite, leucogabbro, gabbro, and hornblendite that were emplaced as several batches of magmas and crystal mushes originating from sub-arc mantle sources. In contrast to the previous studies, our field and petrographic data suggest an igneous origin for the most hornblende in the complex, implying hydrous parental magmas. A hydrous magma origin is also consistent with the high-anorthite content (mostly 70–90%) of the plagioclase in the complex. Percolation of hydrous basaltic melts through gabbroic cumulates in crustal magma chambers led to extensive (&amp;gt;50%) replacement of igneous clinopyroxene by igneous hornblende. Continued subduction resulted in the closure of the intra-arc rift system and the intrusion of the complex by tonalite, granodiorite and diorite between 2765 and 2680 Ma in an Andean-type margin. The complex and surrounding gneisses underwent hornblende granulite-facies metamorphism mainly between 2680 and 2620 Ma, overlapping with mid-crustal east-west extension between 2660 and 2640 Ma. The granulite-facies metamorphism is recorded by the replacement of hornblende, plagioclase and clinopyroxene by garnet and the development of a garnet-orthopyroxene-plagioclase metamorphic assemblage with a granoblastic texture. Tectonic rebounding of mid-crustal rocks to upper crustal levels after 2620 Ma led to the formation of an extensive network of extensional fractures and retrograde metamorphism. Migration of CO2-rich hydrous fluids along the extensional fractures and grain boundaries resulted in the precipitation of many metasomatic minerals mainly at the expense of hornblende and plagioclase, including epidote, clinozoisite, tremolite, actinolite, paragonite, margarite, titanite, quartz, calcite, sillimanite, dolomite, and chlorite. Prevalent replacement of hornblende by garnet during prograde metamorphism and metasomatic replacement of hornblende and plagioclase by retrograde mineral assemblages disturbed the Sm–Nd, U–Th–Pb, and Rb–Sr isotope systems.

Dating prograde metamorphism: U–Pb geochronology of allanite and REE-rich epidote in the Eastern Alps

We use U–Pb dating of allanite and REE-rich epidote in three polymetamorphosed units from the Eastern Alps to constrain the timing of prograde metamorphism. All three units (Ennstal, Wölz and Rappold Complex) record several metamorphic cycles (Variscan, Permian and Eoalpine) and presently define an Eoalpine (Cretaceous) metamorphic field gradient from lower greenschist to amphibolite facies. For U–Pb data, a method is introduced to test the magnitude of 230Th disequilibrium and potentially approximate the Th/U ratio of the reservoir out of which allanite and REE-rich epidote grew. We also show that the modelled stability of epidote-group minerals in the REE-free MnNCKFMASH and MnNCKFMASHTO systems and REE-bearing systems is nearly identical. By combining the stability fields of (clino-)zoisite and epidote modelled in REE-free systems with known geothermal gradients for the region, REE-rich epidote growth is constrained to 200–450 °C and 0.2–0.8 GPa during prograde metamorphism. In the Rappold Complex, allanite cores yield a Variscan age of ca. 327 Ma. In the Ennstal and Wölz Complex, allanite growth during the Permian event occurred at ca. 279–286 Ma. Importantly, recrystallized allanite laths and REE-rich epidote overgrowths in samples from all three units yield prograde Eoalpine ages of ca. 100 Ma, even though these units subsequently reached different peak conditions, most likely at different times. This suggests that all units were buried roughly at the same time during the onset of Eoalpine continental subduction. This interpretation leaves room for the model proposing that diachronous peak metamorphic conditions reported for the field gradient may be related to the inertia of thermal equilibration rather than tectonic processes.

Altered spinels act as a mirror of multi-episodic fluid metasomatism in the forearc mantle: An example from the Minhe ophiolite in Qilian Orogen, NW China

Forearc mantle peridotites commonly undergo complex melt/fluid metasomatism, which inevitably has a considerable influence on their geochemical compositions at the whole-rock scale. Serpentinites predominantly comprise the Minhe ophiolite, which is a fragment of the Proto-Tethys Ocean that outcrops in the Qilian Orogen in NW China. These serpentinites contain zoned spinels that vary compositionally from the centers to the margins, with a spinel core overgrown by ferritchromite layer and magnetite at the outermost rim. The mineral chemistry of the spinel cores (i.e., Cr#, Mg#, Cr2O3, and Al2O3) suggests that the protolith of the serpentinites was an oceanic mantle remnant in a forearc setting. Moreover, the ferritchromite exhibited increases in Fe, Mn, Sc, and Ni contents and decreases in Mg, Cr, Al, V, Zn, and Ga contents. Considering the linear correlation among elements (e.g., Co, Ni, and Zn) and the absence of mineral inclusions, the ferritchromite likely formed through ionic substitutions induced by slab fluids. The magnetite was enriched in Cr, Ni, V, Zn, Co, and Cu, but did not have a magmatic origin owing to low V concentrations. All evidence indicates that the peridotites underwent at least two episodes of fluidic metasomatism in the subduction zone. During early slab subduction, aqueous fluids released from the dehydration of the subducted slab directly serpentinized the forearc mantle peridotites, thereby altering the olivine and orthopyroxene to lizardite/chrysotile. During this process, certain mobile elements (e.g., Fe, Ni, and Mn) in the fluids and/or olivine serpentinization were incorporated into existing spinels, favoring ferritchromite growth. The second fluidic episode was dependent on prograde metamorphism at greater depths in the subduction channel, which not only produced antigorite via the recrystallization of lizardite and chrysotile, but also drove the fluids towards a more oxidizing state, thereby facilitating the growth of Cr-magnetites. Subsolidus re-equilibration controlled by fluid infiltration further promoted the inter-diffusion of elements (e.g., Cr, V, Co, Ni, Cu, and Zn) in the zoned spinels.

Pressure-temperature-time evolution of the Milin pelitic schists: Implications for the tectonic evolution of the eastern Indus-Yarlung suture zone, eastern Himalaya

We report an integrated comprehensive dataset composed of petrography, pressure-temperature (P-T) calculations, monazite U-Th-Pb ages, and trace-element data from pelitic schists in the eastern Indus-Yarlung suture zone in the Milin area of the eastern Himalaya. These rocks represent the exposure of subduction-related rocks within the eastern Indus-Yarlung suture zone accretionary complex. The dominant mineral assemblages of the pelitic schists are garnet + kyanite + staurolite + biotite + quartz and garnet + kyanite + staurolite + biotite + paragonite + sillimanite with quartz, plagioclase, and ilmenite assemblages. Phase equilibrium modeling of sillimanite-bearing pelitic schists yielded peak P-T conditions of ∼670−680 °C at ∼8.6 kbar, similar to that of kyanite-bearing schists (∼670 °C, ∼8.8 kbar). Monazite grains with complex internal structures retained variable ages ranging from 28 Ma to 15 Ma, which correlate systematically with changes in the concentrations of Y, Th, U, and heavy rare earth elements and ratios of Th/U. Combined with petrologic analysis, we conclude that the pelitic schists experienced a long-lived prograde metamorphism from ca. 28 Ma to ca. 22 Ma. Peak metamorphism occurred in the period 22−21 Ma, followed by quasi-isothermal decompression until 15 Ma. The discrepancies among metamorphic P-T-t paths in the eastern Indus-Yarlung suture zone indicate the presence of not only collision-related regional metamorphism at medium P-T conditions, but also subduction-related high-pressure−low-temperature terranes in the Milin region. These two domains experienced different P-T evolution and tectonic histories and were juxtaposed in the early Neogene during the India-Asia continental collision.

Devonian Andean‐type convergence in the southern Dunhuang block (NW China): Petro‐structural, metamorphic P–T and geochronological constraints

AbstractArchean to Palaeoproterozoic basement rocks exposed in the Dunhuang block in NW China were affected by Palaeozoic crustal reworking, as constrained by previous zircon U–Pb geochronological investigations. However, relationships between the Palaeozoic metamorphic ages, P–T evolution and deformational history of the region remain ambiguous. In order to address this issue, P–T–t–D paths of paragneisses from the basement of the Hongliuxia belt in the southern Dunhuang block were investigated. Inclusions in garnet and kyanite from the paragneisses are considered as vestiges of Palaeozoic M1 metamorphism corresponding to initiation of the prograde evolution. The earliest continuous metamorphic fabric is an originally steep N–S striking foliation S2. This fabric was reworked by vertical folds F3 associated with the development of a ubiquitous steep, mainly south‐dipping, E‐W striking axial planar foliation S3. The S2 foliation in paragneisses is mainly associated with Grt–St–Ky–Sil–Bt–Ms–Pl–Qz–Rt assemblages in samples from the western domain and with Grt–Ky–Sil–Bt–Kfs–Pl–Qz–Rt assemblages in samples from the northeastern domain of the Hongliuxia belt. The S3 foliation is associated with Grt–Sil–St–Bt–Ms–Pl–Qz–Ilm assemblages in the western domain and with Grt–Sil–Bt–Ms–Pl–Qz–Kfs–Ilm assemblages in the northeastern domain, followed by growth of chlorite in both domains. Early prograde stage (M1) from 4.0–6.5 kbar and 540–560°C to metamorphic peak (M2a) at 9–10 kbar and ~650–675°C is mainly recorded by paragneisses from the western domain. Subsequent decompression is initially accompanied by heating (M2b) constrained to 6.5–7 kbar and 675–710°C in the western domain, and to 6–6.5 kbar and ~730°C in the northeastern domain, followed by cooling (M3) through 4–6.5 kbar and 550–650°C till late chloritization (late M3). In situ U–Pb dating of monazite combined with monazite trace‐element compositions suggests that prograde evolution (M1) most likely started at c. 406 Ma, peak‐P conditions (M2a) were reached at 400–394 Ma, decompression associated with heating (M2b) took place at 393–391 Ma, and cooling (M3) during exhumation probably lasted from 380 to 354 Ma. The prograde metamorphism probably reflects burial during underthrusting of neighbouring continental basement (the Alxa block or an equivalent) below the Dunhuang block. This event culminated in pure shear thickening (D2a) of the whole supra‐subduction margin followed by minor heating and exhumation (D2b). The D3‐M3 event is interpreted as reflecting exhumation during orthogonal shortening of the system, possibly in response to an independent orogenic cycle. Combined with the available regional data, this study reveals the existence of a complex tectono‐metamorphic evolution for the Dunhuang block characterized by two distinct orogenic phases with (i) the thickening of a previously thinned arc‐back‐arc crust recorded in the northern and central belts at 420–410 Ma in the pro‐wedge side of the active margin (Sanweishan phase), followed by (ii) the 410–390 Ma thickening in the retro‐wedge side (Hongliuxia phase). Such a tectonic evolution of the whole Dunhuang block resembles Andean‐type migration of crustal thickening from the convergent front to hinterlands. The D3‐M3 event, potentially responsible for the juxtaposition of rocks from different geological occurrences and depths, is seemingly independent from this Andean‐type orogenic cycle.

Halogen (F, Cl, Br, and I) Devolatilization During Prograde Subduction: Insights From Western Alps Ophiolites

AbstractIn order to examine the progressive chemical evolution of halogens (F, Cl, Br, I) in altered ocean crust (AOC) during prograde subduction, this study compares bulk and in situ halogen concentrations in mafic samples from three petrogenetically related exhumed terrains in the Western Alps (the Chenaillet ophiolite, the Queyras ophiolites of the Schistes Lustrés, and the Monviso ophiolite). Samples from the Chenaillet ophiolite represent oceanic crust unaffected by metamorphic halogen loss and define a protolith halogen content (122 μg/g F, 29 μg/g Cl, 82 ng/g Br, and 98 ng/g I). Samples from the Queyras ophiolites experienced blueschist facies conditions, undergoing recrystallization and halogen loss (74 μg/g F, 19 μg/g Cl, 70 ng/g Br, and 63 ng/g I). Eclogite facies samples from the Monviso meta‐ophiolite exhibit markedly reduced Cl (8 μg/g Cl) and Br (42 ng/g Br) contents relative to samples from Chenaillet and Queyras. Using electron probe microanalysis (EPMA), F and Cl host minerals (e.g., amphibole, chlorite, epidote) are identified and characterized in selected samples, showing a broad distribution of F and Cl, lending support to the view that halogen devolatilization in the subducting slab occurs continuously and is not dependent on the breakdown of a particular phase. In situ Cl concentrations decrease significantly between sub‐greenschist and blueschist assemblages. Fluorine is retained within subducting AOC and is decoupled from the heavy halogens (Cl, Br, I), which undergo continuous devolatilization during prograde metamorphism.

Role and origin of water-fluxed melting in the generation of High Himalayan leucogranites

Knowledge of the role water has played in the evolution of Earth’s continents is crucial for improving our understanding of how its layers (e.g. crust and mantle) interact with each other and co-evolved. Orogenic belts are the preferred pathway for material circulation, heat transfer, and water cycling. The Himalayan orogen preserves a large number of syn- and post-collisional rocks, of which the Himalayan leucogranites are key to studying the role of water in crustal reworking. Although some geochemical proxies support water-fluxed melting in the source of Himalayan leucogranites, the timing of water addition, the scale of water-fluxed melting, and how water affects or controls the chemical and physical properties of the partial melts are not well constrained. Here, we filtered the published data on High Himalayan leucogranites to ensure that they represent the geochemical characteristics of primary melts. Our results show that the primary leucogranites with high Th/U and low Rb/Sr ratios were produced by water-fluxed melting as a result of the dissolution of monazite, melting of plagioclase, and formation of peritectic K-feldspar. Furthermore, thermodynamic modeling demonstrates that water-fluxed melting generates a high water content and a large volume of felsic water-unsaturated melt with chemical compositions similar to those of the High Himalayan leucogranites. We suggest that the external water is released by the breakdown of hydrous crustal minerals during dehydration melting and prograde metamorphism.

Dehydration‐driven deformation of eclogite: Interplay between fluid discharge and rheology

AbstractAqueous fluids released during dehydration of a subducting slab have a large effect on the rheology of the subduction interface. While high‐pressure experiments and natural‐case studies link deformation with critical dehydration reactions during eclogitization, the exact interplay between these processes remains ambiguous. To investigate fluid–rock interaction and associated deformation at high‐pressure, we studied a suite of eclogites from the Tsäkkok Lens of the Scandinavian Caledonides that record prograde metamorphism within an Early Palaeozoic cold subduction zone. Our results show that in‐situ dehydration during the blueschist to eclogite facies transition produces fluid fluxes leading to rheological weakening and densification, consequently promoting ductile‐brittle deformation. Petrographic evidence, supported by thermodynamic modelling and thermobarometry, attest to a prograde passage from lawsonite‐blueschist to peak eclogite facies of ~2.5 GPa and ~620°C. Phengite‐bearing eclogites imply interaction with an externally‐derived fluid, whereas rare phengite‐free, kyanite‐eclogites only record internally‐derived fluid production. Models predict that prograde breakdown of chlorite, lawsonite and amphibole between 500 and 610°C lead to progressive dehydration and release of up to 4.6 wt.% of aqueous fluid. Microstructural data reveal elongated shapes of highly strained omphacite porphyroblasts, displaying minor yet gradual changes in misorientation towards the grain boundaries. Occasionally, these intragranular structures form subgrain cells that have similar sizes to those of neoblasts in the rock matrix. These observations point to the potential onset of dynamic recrystallization processes via dislocation creep. Moreover, the omphacite neoblasts and rutile show non‐random crystallographic preferred orientations (CPOs), which are characterized by the subparallel alignment of point‐like maxima in rutile [001] and [100] axes to those of [001] and (010) of omphacite neoblasts, respectively. Additionally, the [001] axes of these minerals are also subparallel to the weak stretching mineral lineation, and the (100) of rutile and the (010) of omphacite neoblasts are distributed in the plane of the foliation. This suggests that the development of their CPOs was coeval and structurally controlled. Garnet microfractures normal to the foliation are dilated and sealed predominantly by omphacite. The lack of obliquity between CPO and foliation plane, as well as the systematic orientation of garnet microfracture orientations, are consistent with coaxial deformation at peak‐pressure conditions. Unlike other studies, we show that neither an external fluid source nor channelized fluid flow is needed to facilitate a ductile‐brittle deformation of eclogite in a subduction setting.