Profiles Of Mg Research Articles

Out‐Diffusion and Uphill‐Diffusion of Mg in Czochralski‐Grown (100) β‐Ga2O3 Under High‐Temperature Annealing and Its Influence on Lateral MOSFET Devices

AbstractIn this work, the out‐diffusion and uphill‐diffusion of Mg inside (100) β‐Ga2O3 epilayers and substrates are reported. The Mg accumulates toward the (100) surface upon annealing under an oxidizing environment, whereas the concentration profile changes with annealing temperatures and durations. Furthermore, the out‐diffusion of Mg from the substrate into the epilayer is observed at temperatures above 800 °C, which continues during the film growth. The substitutional‐interstitial‐diffusion (SID) mechanism is suggested to be the driving mechanism for the former, and the latter is related to the diffusion of mobile Mg interstitials. The accumulation profile of Mg can be used to identify the interface between the epilayer and the substrate. Furthermore, significant differences in device performance are observed for power transistors fabricated on annealed and non‐annealed epitaxial β‐Ga2O3 wafers. Increased breakdown voltages of annealed samples are attributed to the Mg diffusion into the first few nanometers of the epitaxial layer close to the interface to the semi‐insulating substrate, leading to compensation of residual dopants (donors) in that region.

The diversity of spectral shapes of hydrogen Lyman lines and Mg II lines in a quiescent prominence

Context. Broad sets of spectroscopic observations comprising multiple lines represent an excellent opportunity for diagnostics of the properties of the prominence plasma and the dynamics of their fine structures. However, they also bring significant challenges when they are compared with synthetic spectra provided by radiative transfer modeling. Aims. In this work, we provide a statistical spectroscopic analysis of a unique dataset of coordinated prominence observations in the Lyman lines (Lyα to Lyδ) and the Mg II k and h lines. The observed data were obtained by the Solar Ultraviolet Measurements of Emitted Radiation (SUMER) spectrograph on board of the Solar and Heliospheric Observatory (SoHO) satellite and the Interface Region Imaging Spectrograph (IRIS) on 22 October 2013. Only a few similar coordinated datasets of Lyman and Mg II k and h observations have ever been obtained in prominences and we present here the first analysis using these two sets of spectral lines. Moreover, for the first time, we assess the influence of noise on the statistical properties of the studied profile characteristics. Methods. We focus on the following profile characteristics: the shape of the observed line profiles based on the number of distinct peaks, the integrated line intensity, the center-to-peak ratio describing the depth of the reversal of two-peaked profiles, and the asymmetry of these peaks. Results. We show that the presence of noise has a negligible effect on the integrated intensity of all observed lines, but it significantly affects the classification of spectral profiles using the number of distinct peaks, the reversal depth, and also the peak asymmetry. We also demonstrate that by taking the influence of noise into account, we can assess which profile characteristics in which spectral lines are suitable for diagnostics of different properties of the observed prominence. For example, we show that the subordinate peaks (peaks below error bars) in the Lyman line profiles are mostly caused by noise, which means that only the dominant peaks should be used for statistical analyses or comparisons with synthetic spectra. On the other hand, in the Mg II k and h profiles, the key role in the distinction between the multi-peaked profiles with low peaks and the profiles with deep reversals is played by the dynamics of multiple fine structures located along a line of sight. The complex, multi-peaked profiles are observed in places where multiple fine structures with different line-of-sight velocities are crossing the line of sight, while the profiles with deep reversals likely correspond to instances when we observe single fine structures or more fine structures but with similar line-of-sight velocities. Conclusions. This study allows us to conclude that if we are interested in the diagnostics of the dynamics of prominence fine structures, the best approach is to use a combination of profile asymmetry in the Lyman lines together with the complex profiles of Mg II k and h lines. On the other hand, if we want to diagnose the temperature and pressure properties of individual prominence fine structures, we need to focus on the deeply reversed Mg II k and h lines in combination with the Lyman lines and to analyze the depth of the central reversal and the integrated intensities.

Two-horn quiescent prominence observed in Hα and Mg II h&k lines with THEMIS and IRIS

Context. Prominences are large magnetic structures in the corona filled by cool plasma with fast evolving fine structure. Aims. We aim to better understand the plasma conditions in the fine structure of a quiescent prominence including two transient horns observed at the bottom of the cavity using the high resolution Interface Region Imaging Spectrograph (IRIS) and the MulTi-Raies (MTR) spectrograph of the Télescope Heliographique pour l’Etude du Magnétisme et des Instabilités Solaires (THEMIS) in the Canary Islands. Methods. We analysed the spectra obtained in Hα by THEMIS and Mg II by IRIS and compare them with a grid of 23 940 1D radiative transfer models which include a prominence-to-corona transition region (PCTR). The full observed profiles of Mg II in each pixel are fitted completely by synthesised profiles with ×RMS (Cross RMS; an improved version of the rolling root mean square (rRMS) method). When the RMS is below a certain threshold value, we recover the plasma conditions from the parameters of the model best fitting the observed line profile. This criterion is met in two regions (the horns and edge of the prominence) where the line profiles can generally be described as single peaked. Results. The 1D models suggest that two different kinds of model atmospheres correspond to these two regions. The region at the edge is found to be fitted mainly with isothermal and isobaric models, while the other area (the horns) is seen to be fitted with models with a PCTR that have optical thicknesses of less than 5. In the prominence edge, the theoretical relationship between the integrated intensities in Hα and Mg II is verified and corresponds to low emission measure values. In these regions the electron density is around 1010 cm−3, while it is one order of magnitude less in the horn regions around 109 cm−3. Conclusions. In the horns, we find some profiles are best fitted with models with high mean temperatures. This suggests that the hot PCTR found in the horns could be interpreted as prominence plasma in condensation phase at the bottom of the coronal cavity.

Cooling rate of clinopyroxene reveals the thickness and effusion volume of Chang'E-5 basaltic flow units

China's Chang'E-5 mission landed in the northern Oceanus Procellarum and sampled the youngest mare basaltic regolith (1.9–2.0 Ga) to date. The returned samples enable us to gain new insights into the thickness and eruption volume of the basaltic flow unit, i.e., Em4, the fourth Eratosthenian-aged mare unit at the landing region. In this study, 1D bottom-up and top-down cooling and top-down-only cooling thermophysical models have been constructed for the emplacement of the Chang'E-5 flow unit in order to constrain its minimum thickness through the cooling rates. Based on the zoning profiles of Mg–Fe diffusion in clinopyroxene, the cooling rate of the coarsest-grained sample is constrained to be 0.000025–0.00055 K/h, corresponding to a flow unit with a minimum vertical dimension of 21–118 m. The minimum effusion volume of a single flow unit at the Em4 area is calculated to be 777–3626 km3, which indicates that the Em4 region where Chang'E-5 landed is mainly formed in one major effusion event. The large volume of the Chang'E-5 mare flow suggests that the mantle source of Chang'E-5 basalts in the Procellarum KREEP Terrane was warm enough to produce significant amounts of melt.

Visualization of depletion layer in AlGaN homojunction p–n junction

We analyzed the p–n junction of an aluminum gallium nitride (AlGaN) homojunction tunnel junction (TJ) deep-ultraviolet light-emitting diode by phase-shifting electron holography. We clearly obtained a phase image reflecting the band alinement of the p–n homojunction and derived a depletion layer width of approximately 10 nm. In addition, the observed depletion layer width for the AlGaN TJ was in good agreement with the simulated one reflecting the diffusion profile of Mg and Si, thus enabling a discussion on the electrical conduction mechanism for an AlGaN p–n junction.

Magnesium Based Hybrid Nanocomposites: An Insight into Nanoparticle Effects on the Microstructure and Mechanical Properties

Aims: The primary aim of this research is to understand the effects of type of nanoparticles on the microstructure and mechanical properties of Mg-based hybrid nanocomposites. For this reason, new Mg-based hybrid nanocomposites containing 2.2 vol.% Ti and 1.1 vol.% nano-Al2O3 or nano B4C particles were synthesized and their properties were studied in comparison with Mg-Ti and pure Mg. Background: Magnesium with excellent weight-saving potential is ideal for automotive and aerospace applications. But its use in pure Mg is restricted due to inherent limitations such as poor absolute strength, elastic modulus, deformability, and corrosion susceptibility. While most of these limitations can be circumvented by the judicious addition of micron-sized ceramic reinforcements, ductility is often compromised. One of the promising ways for ductility enhancement involves the use of nano-length scale reinforcements. Similar ductility improvements were also reported when hybrid reinforcements were introduced into the Mg matrix. While the role of hybrid reinforcement preparation, the particle size distribution, and volume fraction of hybrid reinforcements were studied extensively in the past, no detailed investigation on the effects of type of nanoparticles has been conducted so far. Objective: The objectives of this research include the successful synthesis and property characterization of Mg-based hybrid nanocomposites containing hybrid (Ti+Al2O3 or Ti+B4C) reinforcements. Result: While both hybrid nanocomposites displayed fine grains when compared to pure Mg and Mg-Ti, there was no noticeable difference between the grain size distribution profiles of Mg- (Ti+Al2O3) and Mg-(Ti+B4C) hybrid composites. The results of property measurements indicated an improvement in dimensional stability, indentation, tension, and compression properties of Mg due to the addition of either individual Ti or hybrid (Ti+Al2O3) or Mg-(Ti+B4C) particles. Among the hybrid composites, Mg-(Ti+B4C) containing hybrid (Ti+B4C) reinforcement exhibited a better combination of strengths and ductility. While the inherent strengthening contribution from B4C and Al2O3 reinforcements resulted in slightly different strength properties, the ductilization benefits of boron compounds enhanced the tensile fracture strain of Mg-(Ti+B4C). Conclusion: Since the particle size distribution and volume fraction of (Ti+Al2O3) and (Ti+B4C) are similar, the difference in strength values between Mg-(Ti+Al2O3) and Mg-(Ti+B4C) can be attributed to the matrix strengthening contribution from reinforcement type.

The Effect of Nanometer‐Scale V‐Pit Layer on the Carrier Recombination Mechanisms and Efficiency Droop of GaN‐Based Green Light‐Emitting Diodes

The effects of nanometer‐scale V‐pits layer with different parameters on the carrier recombination mechanisms and efficiency droop of GaN‐based green light‐emitting diodes (LEDs) are investigated. Under optimized growth conditions, the threading dislocations (TDs) are surrounded by V‐pits layer with six (10–11) side wall facets. The V‐pits layer contains sidewall multiple quantum wells (MQWs) with bandgap several hundred millielectronvolts higher than that of c‐plane MQWs. This higher bandgap acts as a barrier for carriers and prevents them from reaching the dislocations, which can effectively suppress the nonradiative recombination. Analysis suggests that the V‐pits enhance hole injection into deeper MQWs, which is confirmed by the secondary ion mass spectroscopy profiles of Mg and Al. With the aid of the V‐pits layer, holes can be injected into deeper MQWs, which reduce the carrier concentration within individual QWs. Therefore, the Auger‐related efficiency droop can be suppressed. The results show that LED with 200 nm LT‐GaN + 40 nm n‐GaN V‐pits layer is able to deliver an improvement in the light output power by 189% as compared with reference LED without V‐pits layer. At 200 mA, the efficiency droop for LED with200 nm LT‐GaN + 40 nm n‐GaN V‐pits is 25.9%, which is much smaller than 34.7% for reference LED without V‐pits.

Quiet-Sun Mg ii h and k Line Profiles Derived from IRIS Full-Sun Mosaics. I. Reference Profiles and Center-to-limb Variation

Abstract We derived high-precision reference profiles of the Mg ii h and k lines that represent the quiet Sun during a minimum of the solar activity. To do so, we used the broad catalog of full-Sun mosaics obtained by the Interface Region Imaging Spectrograph (IRIS). To minimize the influence of the local variations due to the on-disk solar features and to achieve low levels of uncertainties, we used 12 IRIS full-Sun mosaics without sunspots or other significant signs of solar activity. These mosaics were obtained between 2019 April and 2020 September in the near-ultraviolet spectral range. In this paper, we present the disk-averaged reference profiles of Mg ii h and Mg ii k lines, together with a series of reference profiles spanning the distance between the disk center and the solar limb. These series of profiles offer a detailed representation of the center-to-limb variation of both Mg ii h and Mg ii k lines. The reference Mg ii h and k line profiles provided in this paper can be used as the incident radiation boundary condition for radiative-transfer modeling of prominences, spicules, and other coronal and chromospheric structures.

Doppler shift oscillations of a sunspot detected by CYRA and IRIS

Context. The carbon monoxide (CO) molecular line at around 46655 Å in solar infrared spectra is often used to investigate the dynamic behavior of the cold heart of the solar atmosphere, i.e., sunspot oscillation, especially at the sunspot umbra. Aims. We investigated sunspot oscillation at Doppler velocities of the CO 7-6 R67 and 3-2 R14 lines that were measured by the Cryogenic Infrared Spectrograph (CYRA), as well as the line profile of Mg II k line that was detected by the Interface Region Imaging Spectrograph (IRIS). Methods. A single Gaussian function is applied to each CO line profile to extract the line shift, while the moment analysis method is used for the Mg II k line. Then the sunspot oscillation can be found in the time–distance image of Doppler velocities, and the quasi-periodicity at the sunspot umbra are determined from the wavelet power spectrum. Finally, the cross-correlation method is used to analyze the phase relation between different atmospheric levels. Results. At the sunspot umbra, a periodicity of roughly 5 min is detected at the Doppler velocity range of the CO 7-6 R67 line that formed in the photosphere, while a periodicity of around 3 min is discovered at the Doppler velocities of CO 3-2 R14 and Mg II k lines that formed in the upper photosphere or the temperature minimum region and the chromosphere. A time delay of about 2 min is measured between the strong CO 3-2 R14 line and the Mg II k line. Conclusions. Based on the spectroscopic observations from the CYRA and IRIS, the 3 min sunspot oscillation can be spatially resolved in the Doppler shifts. It may come from the upper photosphere or the temperature minimum region and then propagate to the chromosphere, which might be regarded as a propagating slow magnetoacoustic wave.

Determination of the nutrient profile in plant materials using laser-induced breakdown spectroscopy with partial least squares-artificial neural network hybrid models.

Nutrient profile determination for plant materials is an important task to determine the quality and safety of the human diet. Laser-induced breakdown spectroscopy (LIBS) is an atomic emission spectrometry of the material component analytical technique. However, quantitative analysis of plant materials using LIBS usually suffers from matrix effects and nonlinear self-absorption. To overcome this problem, a hybrid quantitative analysis model of the partial least squares-artificial neural network (PLS-ANN) was used to detect the compositions of plant materials in the air. Specifically, fifty-eight plant materials were prepared to split into calibration, validation and prediction sets. Nine nutrient composition profiles of Mg, Fe, N, Al, B, Ca, K, Mn, and P were employed as the target elements for quantitative analysis. It demonstrated that the prediction ability can be significantly improved by the use of the PLS-ANN hybrid model compared to the method of standard calibration. Take Mg and K as examples, the root-mean-square errors of calibration (RMSEC) of Mg and K were decreased from 0.0295 to 0.0028 wt.% and 0.2884 to 0.0539 wt.%, and the mean percent prediction errors (MPE) were decreased from 5.82 to 4.22% and 8.82 to 4.12%, respectively. This research provides a new way to improve the accuracy of LIBS for quantitative analysis of plant materials.

Hydraulic and geochemical interactions between surface water and sediment pore water in seasonal hypersaline Maharlu Lake, Iran

AbstractStudy of interactions between surface‐water and pore‐water in lakes is complicated due to spatio‐temporal heterogeneities in flow condition across the sediment–water interface. In this study, seasonal hypersaline Maharlu Lake was investigated by collecting surface‐water and pore‐water samples from four nests of multilevel piezometers installed at different distances from the inflow of rivers to the lake. The hydraulic heads in the piezometers as well as vertical profiles of Mg+2, Na/Cl, and Br/Cl were used to investigate both hydraulic and geochemical interactions between surface‐water and pore‐water in the lake. Depletion of lake surface water and pore water with respect to B, Br, Li+, K+, Mg2+ and the absence of Mg‐K chlorides and sulphates in the lake bed sediments is probably due to leakage of highly evaporated residual brine from the lake. Hydraulic gradients in the multilevel piezometric nests indicate that a general downward flow from surface‐water to pore‐water occurs across sediment–water interface. Vertical profiles of Br/Cl, Mg2+, and Na/Cl showed that the maximum flow rate was more than 1 m/yr close to the mouth of the inflowing rivers. The downward vertical flow was limited in the area far from the inflowing rivers due to the presence of an impermeable confining halite layer which interrupts the hydraulic connection between shallow pore water (less than 50 cm deep) and deeper zones. The hydraulic and geochemical interactions between surface‐water and pore‐water across sediment–water interface in the Maharlu Lake are of interest to find out the fate of pollutants and their distribution in the lake.

Integration of Optimal Time-of-Use Pricing in Stochastic Programming for Energy and Reserve Management in Smart Micro-grids

In this paper, the optimal operation problem of smart micro-grids integrated with the pricing of Time-of-Use (TOU) demand response (DR) program is modeled as a two-stage stochastic programming problem with the aim of minimizing the cost of MG operation and running TOU in the presence of renewable resources and incentive-based DR programs. Here, TOU as the most common type of time-based DR programs is implemented using a linear function based on the concept of self- and cross-price elasticity of load demand. In the presented model, the forecasting errors of generation of renewable resources are modeled by probability density functions. The operator of MG decides on two stages for optimal management of its network; the first stage refers to the operation of base condition of MG and the second one is pertaining to after the realization of different scenarios for generation of renewable resources. The base condition of MG refers to the situation in which the active power productions of renewables are equal to the predicted values. The proposed model is solved by Particle Swarm Optimization algorithm. A typical MG is employed to investigate and analyze the different features of the method. By varying the demand response potential of MG consumers, TOU tariffs are determined, and their impact on the results of energy and reserve cost as well as voltage and load profiles of MG are analyzed. Numerical results show the efficiency of DR in reducing costs as well as covering the uncertainty resulting from renewables.

Determination of electronic band structure by electron holography of etched-and-regrown interfaces in GaN p-i-n diodes

The electrostatic potential variation across etched-and-regrown GaN p-i-n diodes for power electronics has been studied using electron holography in a transmission electron microscope. The potential profiles have been correlated with the composition profiles of Mg, Si, and O obtained by secondary ion mass spectroscopy. Electronic charges obtained from the potential profiles correlate well with the presence of Si and O impurities at regrown interfaces. The overlap of Mg and Si when Mg doped GaN is grown directly over an etched undoped GaN surface results in the formation of a highly doped p-n junction. The introduction of a thin undoped layer over the etched GaN surface prevents the formation of such a junction as the regrowth interface is moved away from the Mg-doped GaN, and results in diodes with improved reverse leakage currents, close to the best values of continuously grown p-i-n diodes. Potential profiles of continuously grown (not etched) p-i-n diodes are compared to those of etched-and-regrown diodes.

Broad Emission and Absorption Line Outflows in the Quasar SDSS J163345.22+512748.4

Abstract We present a detailed study of the optical and near-infrared (NIR) emission and absorption line spectrum of the quasar SDSS J163345.22+512748.4. We discovered on the newly acquired NIR spectrum a highly metastable neutral helium broad absorption line (BAL) He i* λ10830 with a width of ∼2000 km s−1 and a blueshift of ∼7000 km s−1 in the velocity space. The BAL system is also significantly detected in Mg ii and He i* λ3889. We estimate a column density of (5.0 ± 1.7) × 1014 cm−2 for the He i*(2 3S) level and infer an ionization parameter of U A = 10−1.9±0.2 for the BAL outflow, assuming that the BAL region is thick enough for a full development of an ionization front. The total column density of the BAL outflow is constrained in the range N H ∼ 1021–1021.4 cm−2. We also found that the bulk of both Mg ii and UV Fe ii, as well as of Hα broad emission lines (BELs), are blueshifted with a velocity of ∼2200 km s−1 with respect to the quasar systemic redshift. We constrain the blueshifted BEL region to have a covering factor C f ≈ 16%, density n H ∼ 1010.6–1011.3 cm−3, column density N H ≳ 1023 cm−2, and ionization parameter U E ∼ 10−2.1–10−1.5. The outflow gas is located at ∼0.1 pc away from the central ionization source, at a scale comparable to the broad-line region. A toy kinetic model has been proposed to reproduce the profile of Mg ii BEL well if a partial obscured axisymmetric geometry of the outflow with a radial velocity as observed from the BALs is assumed.

Structure and Dynamics of Cool Flare Loops Observed by the Interface Region Imaging Spectrograph

Abstract Flare loops were well observed with the Interface Region Imaging Spectrograph (IRIS) during the gradual phase of two solar flares on 2014 March 29 and 2015 June 22. Cool flare loops are visible in various spectral lines formed at chromospheric and transition-region temperatures and exhibit large downflows which correspond to the standard scenario. The principal aim of this work is to analyze the structure and dynamics of cool flare loops observed in Mg ii lines. Synthetic profiles of the Mg ii h line are computed using the classical cloud model and assuming a uniform background intensity. In this paper, we study novel IRIS NUV observations of such loops in Mg ii h and k lines and also show the behavior of hotter lines detected in the FUV channel. We obtained the spatial evolution of the velocities: near the loop top, the flow velocities are small and they are increasing toward the loop legs. Moreover, from slit-jaw image (SJI) movies, we observe some plasma upflows into the loops, which are also detectable in Mg ii spectra. The brightness of the loops systematically decreases with increasing flow velocity, and we ascribe this to the effect of Doppler dimming, which works for Mg ii lines. Emission profiles of Mg ii were found to be extremely broad, and we explain this through the large unresolved non-thermal motions.

An Explanation of Remarkable Emission-line Profiles in Post-flare Coronal Rain

Abstract We study broad redshifted emission in chromospheric and transition region lines that appears to correspond to a form of post-flare coronal rain. Profiles of Mg ii, C ii, and Si iv lines were obtained using IRIS before, during, and after the X2.1 flare of 2015 March 11 (SOL2015-03-11T16:22). We analyze the profiles of the five transitions of Mg ii (the h and k transitions, and three lines belonging to the transitions). We use analytical methods to understand the unusual profiles, together with higher-resolution observational data of similar phenomena observed by Jing et al. The peculiar line ratios indicate anisotropic emission from the strands that have cross-strand line center optical depths (k line) of between 1 and 10. The lines are broadened by unresolved Alfvénic motions whose energy exceeds the radiation losses in the Mg ii lines by an order of magnitude. The decay of the line widths is accompanied by a decay in the brightness, suggesting a causal connection. If the plasma is ≲99% ionized, ion–neutral collisions can account for the dissipation; otherwise, a dynamical process seems necessary. Our work implies that the motions are initiated during the impulsive phase, to be dissipated as radiation over a period of an hour, predominantly by strong chromospheric lines. The coronal “rain” we observe is far more turbulent than most earlier reports have indicated, with implications for plasma heating mechanisms.

Intermittent generation of mafic enclaves in the 1991–1995 dacite of Unzen Volcano recorded in mineral chemistry

Mafic enclaves in the 1991–1995 dacite of Unzen volcano show chemical and textural variability, such as bulk SiO2 contents ranging from 52 to 62 wt% and fine- to coarse-grained microlite textures. In this paper, we investigated the mineral chemistry of plagioclase and hornblende microlites and distinguished three enclave types. Type-I mafic enclaves contain high-Mg plagioclase and low-Cl hornblende as microlites, whereas type-III enclaves include low-Mg plagioclase and high-Cl hornblende. Type-II enclaves have an intermediate mineral chemistry. Type-I mafic enclaves tend to show a finer-grained matrix, have slightly higher bulk rock SiO2 contents (56–60 wt%) when compared with the type-III mafic enclaves (SiO2 = 53–59 wt%), but the overall bulk enclave compositions are within the trend of the basalt–dacite eruptive products of Quaternary monogenetic volcanoes around Unzen volcano. The origin of the variation of mineral chemistry in mafic enclaves is interpreted to reflect different degree of diffusion-controlled re-equilibration of minerals in a low-temperature mushy dacitic magma reservoir. Mafic enclaves with a long residence time in the dacitic magma reservoir, whose constituent minerals were annealed at low-temperature to be in equililbrium with the rhyolitic melt, represent type-III enclaves. In contrast, type-I mafic enclaves result from recent mafic injections with a mineral assemblage that still retains the high-temperature mineral chemistry. Taking temperature, Ca/(Ca + Na) ratio of plagioclase, and water activity of the hydrous Unzen magma into account, the Mg contents of plagioclase indicate that plagioclase microlites in type-III enclaves initially crystallized at high temperature and were subsequently re-equilibrated at low-temperature conditions. Compositional profiles of Mg in plagioclase suggest that older mafic enclaves (Type-III) had a residence time of ~100 years at 800 °C in a stagnant magma reservoir before their incorporation into the mixed dacite of the 1991–1995 Unzen eruption. Presence of different types of mafic enclaves suggests that the 1991–1995 dacite of Unzen volcano tapped mushy magma reservoir intermittently replenished by high-temperature mafic magmas.

Iron Availability Compromises Not Only Oligodendrocytes But Also Astrocytes and Microglial Cells.

When disrupted, iron homeostasis negatively impacts oligodendrocyte (OLG) differentiation and impairs myelination. To better understand myelin formation and OLG maturation, in vivo and in vitro studies were conducted to evaluate the effect of iron deficiency (ID) not only on OLG maturation but also on astrocytes (AST) and microglial cells (MG). In vivo experiments in an ID model were carried out to describe maturational events during OLG and AST development and the reactive profile of MG during myelination when iron availability is lower than normal. In turn, in vitro assays were conducted to explore proliferating and maturational states of each glial cell type derived from control or ID conditions. Studies targeted NG2, PDGFRα, CNPAse, CC1, and MBP expression in OLG, GFAP and S100 expression in AST, and CD11b, ED1, and cytokine expression in MG, as well as BrDU incorporation in the three cell types. Our results show that ID affected OLG development at early stages, not only reducing their maturation capacity but also increasing their proliferation and affecting their morphological complexity. AST ID proliferated more than control ones and were more immature, much like OLG. Cytokine expression in ID animals reflected an anti-inflammatory state which probably influenced OLG maturation. These results show that ID conditions alter all glial cells and may impact myelin formation, which could be regulated by a mechanism involving a cross talk between AST, MG, and oligodendrocyte progenitors (OPC).

Dissolution of dehydroxylated lizardite at flue gas conditions: III. Near-equilibrium kinetics

The near-equilibrium dissolution kinetics of partially dehydroxylated lizardite was investigated at conditions relevant for ex situ CO2 mineralization, namely 30°C⩽T⩽90°C and pCO2<1atm. Batch experiments were carefully designed to explore a wide range of operating conditions without precipitating any secondary phases, namely amorphous silica or magnesium carbonates. The operational range included solutions whose compositions were very close to solubility of the dissolving silicate species. Expressions for specific dissolution rates were developed in order to describe the experimentally measured near-equilibrium, non-steady state dissolution profiles. The near-equilibrium kinetic model was able to describe the evolution of the concentration profiles of Mg(aq) and SiO2(aq) with good accuracy. A small enhancement in the dissolution rates of forsteritic silicate was observed in the presence of high concentrations of bicarbonate ions. The presence of Mg2+ ions and SiO2(aq) in the solution were found to affect the specific dissolution rates of the different silicate species present in dehydroxylated lizardite.

Influence of Quench Rate on the Artificial Ageing Response of an Al-8Si-0.4Mg Cast Alloy

The aim of the study is to present the influence of quench rate on the artificial ageing response of Al-8%Si-0.4%Mg cast alloy in terms of Brinell hardness and yield strength. The investigated material was produced by a gradient solidification technique and exhibited a microstructure that corresponds to the one of gravity die castings, with a dendrite arm spacing of approximately 25 µm. The study comprises two solution treatment temperatures, five quench rates and artificial ageing times exceeding 100 hours at 170 and 220 °C. The microstructure and concentration profiles of Mg and Si were evaluated using energy and wavelength dispersive spectroscopy. Microstructural examination reveals an increment of solutes in the Al-matrix when higher solution treatment temperatures accompanied with high quench rates are applied and shows how both Si and Mg atoms have diffused towards the eutectic during quenching. Consequently, i.e. by increasing the levels of solutes and vacancies, the highest strength levels were realized. The study confirmed that quench rates above 2 °C /s do not offer substantial strength improvement while quenching at lower rates resulted in a lower peak hardness and longer times to peak